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By D. Y. Wang, G. Y. Sha, X. L. Shen, D. R. Gu

The study of the volatilization kinetics of zinc and lead in pellets made of zinc-leadbearing dust mixed with coal powder, in a nitrogen atmosphere and at a temperature range between 1100 °C and 1300 °C, shows that the reduction temperature has a significant effect on the volatilization rates of zinc and lead, and that both the particle size of the coal powder and the extra carbon content has no effect on the volatilization rates. The obtained activation energies for the volatilization of zinc and lead are 79.42kJ/mol and 88.74kJ/mol respectively. The volatilization rate of zinc is controlled by the reaction between the zinc oxide and carbon monoxide while that of lead is controlled by the lead evaporation reaction, and the diffusion of gaseous lead through the gas boundary layer covering the surface of the reduced liquid lead.

Jan 1, 2000

By J. D. Robertson

An in situ water sampling device has been developed to measure biologically-available or “labile” metals in natural waters and effluents. The active mechanism involves the use of a polyacrylamide gel layer to quantitatively control metal transfer to a trace-metal-adsorbing, gel-imbedded resin. Because the resin only adsorbs free metal ions (the gel sampler methodology is a kinetic speciation technique), and because metal bioavailability is related to the free-ion activity, the device provides a direct measure of the biological-availability of metals in the environment sampled. The prototype consists of a layer of ion-permeable polyacrylamide gel which separates the solution to be sampled from an ion exchange resin. Because approximately 90% of the polyacrylamide gel is water, mass transport through the gel is diffusion-controlled, and is therefore well defined. Metal ions are rapidly bound by the resin, creating a steep concentration gradient in the gel. The amount of labile trace metal that accumulates on the resin can be related directly to the concentration of the metal in solution, the exposure time and the molecular diffusion coefficient of the labile species. In addition, the passive nature of this device affords it the potential to address many of the limitations presented by conventional sampling methods, such as sample contamination introduced during collection or filtration and changes in trace metal speciation prior to analysis. Laboratory studies and limited field trials indicate that the sampler behaves as anticipated and illustrate that biologically- available metal concentrations in many environments are a small fraction of the total concentrations and often significantly less than the dissolved concentration. The implications of this on regulatory criteria are discussed. Additional field trials and correlation with bioassays are currently underway.

Jan 1, 2000

By A. Karami

It is well established that an ordered sequencing of charge initiations in a blast pattern is an important design consideration that affects blasting performance. Delay times must be chosen such that damage to the rock mass is controlled. The accuracy of delay detonators is also of major concern. A large scatter could lead to an incorrect blast sequencing that would lead to damage to the rock mass causing increased over-break, degraded fragmentation, increased fly-rock and poor vibration control. In this study, the effect of using accurate delay detonators on the explosive energy generated is investigated. For this purpose, power spectral density of the blast vibration for delayed shots are calculated and compared with the case where holes are shot at the same time (no delay). At the end the results are presented and discussed.

Jan 1, 2000

By Tim Wolf

The author has seen an increased use of shaft-mounted, right angle drive assemblies. These designs use the pulley shaft as its 'foundation" and can create significant overhung loads. To reliably perform, the pulley and shaft must be designed for these special requirements. This paper will focus on the development of overhung loads and their design effects. Special considerations to maximize performance will be presented and comparisons with other drive options will be made. Experience in heavy mining applications will be used throughout.

Jan 1, 2000

By Peter Radziszewski

"Typical mining operating costs can be divided between extraction (30 % to 70 %), comminution (30 % to 50 %) and separation (5% to 20% ). Cornminition process costs, representing an important contribution to mining operating costs, can themselves be divided roughly between energy (50 %) and linerkharge wear (50 %). Developing the ability of predicting mill wear will allow a more accurate estimation of wear costs. However, total media wear in a given ball mill grinding process is a product of three recognized wear mechanisms those being abrasion, corrosion and impact. Further, the contribution to total media wear of each of these wear mechanisms has not been well established. In this paper, a overview of abrasive, corrosive and impact wear mechanisms is made from which an empirical wear prediction procedure is proposed. Further, future directions in wear prediction research is outlined. INTRODUCTIONTypical mining operating costs can be divided between extraction (30 % to 70 %), comminution (30 % to 50 %) and separation (5 % to 20 %). Comminition process costs, representing an important contribution to mining operating costs, can themselves be divided roughly between energy (50 %) and lined-charge wear (50 %). With respect to wear, world wide steel consumption as grinding media is estimated at over 600 000 tomes per annum (Malghan, 1982). As such, developing the ability of predicting mill wear will allow a more accurate estimation of wear costs.Charge media wear prediction is actually estimated using the Bond abrasion test. From Bond abrasion index tests, it is possible to determine a wear rate using the following function:"

Jan 1, 2000

By J. C. Willett, J. R. Sanfilipo, S. M. Podwysocki, P. D. Warwick

The U.S. Geological Survey is concluding an assessment of the major coal regions of the country. In this program, the quantity and quality of coals that are expected to be mined during the next 30 years are characterized. For the Gulf Coast region, the evaluation includes reviews of the stratigraphic setting, coal resources, and the quality of the Cretaceous to Eocene coals in four coal-producing areas. The coal-bed methane potential for these areas will also be evaluated. The results of these efforts will be a series of digital maps, text, and tables that will be published in a CD-ROM format.

Jan 1, 2000

By Kenneth J. Leib, Laurie Wirt, M. Alisa Mast

Chemical-constituent loads were determined for an alpine stream in southwestern Colorado that is affected by natural acid drainage from weathering of hydrothermally-altered rock and from acidic metal-rich discharge from abandoned mines. Base-flow loads were compared to storm-related loads using a tracer-dilution approach. A rainstom occurred during the tracer injection, providing the opportunity to measure metal loads before, during, and after storm runoff. Chemical-constituent loads during the storm increased by 1 to 2 orders of magnitude relative to base-flow conditions. The increase in loads was related to two distinct periods; (1) a flush of higher concentrations that occurred soon after rainfall began, and (2) the peak of storm runoff. The initial flush-having no measurable change in discharge--contained the highest loads of trace metals and dissolved iron. The chemical character of peak runoff was distinctly different, as evidenced by the highest loads of total and dissolved major elements and total iron.

Jan 1, 2000

By F. Woodcock, A. R. Laplante

A test to characterize the amount of gravity-recoverable gold (GRG) in an ore is described. Typical GRG results are given and possible uses are discussed. The overall database, which includes 68complete tests, is presented. The ore samples treated had an average GRG content of 63% of the total gold in the sample, with a standard deviation of 20% and a range of 3% to 97%. Both the F8(, of gold and the GRG content at a grind of 100% finer than 850 pm correlate well with the overall GRG content (at 80%finer than 75 pm). The primary use of the test is to determine whether gravity recovery should be used and how. Results can also be used to predict gravity recovery, as many of the ores tested are from plants employing gravity recovery. Gravity-circuit simulation can be used to refine recovery estimates or for optimization studies.

Jan 1, 2000

By K. Viking

The vibratory characteristics of full-scale sheet piles, vibratory driven into the ground, have so far not been described systematically in detail. This paper concerns the preliminary results of a series of full-scale field tests where both the driveability and induced ground vibrations have been continuously monitored. Furthermore, the results of measured ground vibration levels have been measured at two different sites characterised as having hard and easy driving conditions. In the light of the presented results, the paper briefly discusses how the complexity of a driveability and vibration prediction can be subdivided into three parts, namely, vibrator-, sheet pile-, and soil-related parameters, all of which significantly affect both the driveability and induced ground vibrations.

Jan 1, 2000

By P Bourke, S Ronkainen

Since the early days of flotation, process technicians have known that the speed at which the froth is recovered over the lip of the cell has a very direct and consistent influence on the grade and recovery of the circuit. No plant would deny that, even to this day, one of the most important aspects of a process technicianÆs job is ensuring that the froth is moving at a desired and controlled speed over the lip. Unfortunately, process technicians cannot watch the froth throughout the entire shift, as there are always other problems to attend to. A considerable amount of work has thus been done to develop a æsystemÆ that automatically measures the speed of the froth. This measurement would then be used in simple controllers to emulate the steps taken by the process technician in correcting deviations of the froth speed from its desired level. Many of the earlier attempts to measure speed were ineffective, as they were unable to cope with turbulence on the froth surface. The FrothMasterÖ instrument makes use of machine vision technologies to measure the speed of the froth over the lip of a cell at a very high sampling rate. This instrument produces an extremely reliable and accurate measurement of the froth speed (as well as other parameters such as bubble size and froth stability). As we will show, the effectiveness of the speed measurement in controlling the performance of the plant is a testimony to its reliability. Three FrothMasterÖ units have recently been installed on the Cadia Hills Gold Mine in New South Wales (Australia). The objectives of this installation were:to control the mass-recovery of two Tank Cells in series on the same level where differences in the hydrostatic head between the two cells result in the cells pulling inconsistently with respect to each other; control of the concentrate grade (per cent copper) from the first rougher; reduction in the frother consumption in the rougher circuit by monitoring the froth speed. A simple controller was designed to react to disturbances in the same way that human operators react. This was done after consultation with the metallurgists and the process technicians at Cadia. The controller had two functions: Stabilisation: The stabilising controller made use of three manipulated variables (level, frother addition rate and aeration rate) to control the froth speed to a setpoint. Optimisation: The optimising controller adjusted the froth speed setpoint based on deviations of the grade (measured in real-time by the OSA) from a setpoint. The plant metallurgist adjusted the grade setpoint based on information about the ore. The results from a 21-day trial have shown the following:The ratio of concentrate mass-recovery between two cells in series on the same level has been successfully balanced, thereby overcoming problems due to differences in hydrostatic heads. It is possible to control the speed of the froth, in mm/s, to within five per cent of its setpoint using the aforementioned manipulated variables. It has also been shown that, for reliable control, it is necessary to control more than just one variable (eg level or air). The grade of the first rougher concentrate has been controlled to within 0.3 per cent of the grade setpoint for long periods of time, which has important implications for the circuit recovery. The frother consumption has been reduced significantly. This paper will thus show that substantial progress has been made to demonstrate the value of using on-line froth speed measurements in flotation plant control to obtain real financial benefits.

Jan 1, 2000

By David Kress

Mill crushing drive systems are essential to cement producers. With the increased emphasis on operating efficiency, it is vital that these systems be dependable and reliable. No one needs the costs or headaches associated with unscheduled downtime or inefficient machinery operation. A reliable drive system starts with the proper selection of the ring, or girth, gear and continues through proper maintenance. Ideally, selecting the right girth gear brings together the gear manufacturer, the system designer and the end user. The gear manufacturer must know the details of the application, the demands that will be placed on the gear and the nature of the equipment to be driven. Similarly, the user and the system designer must be familiar with the variables that affect gear drive performance and service. For example, an application that places a torque load on the drive in excess of its rated capacity will result in gear tooth distress and, in severe cases, breakage.

Jan 1, 2000

By G. A. Munoz, J. D. Miller

Gold leaching of an auriferous pyrite ore from the Portovelo deposit in Ecuador indicates that noncyanide leaching systems, such as thiocyanate and thiourea, are not as effective as the traditional cyanide system. For example, whereas approximately 95% of the gold can be leached from the ore with cyanide, only about 50% gold dissolution can be achieved with a thiocyanate leaching system. Electrochemical measurements indicate that gold is not cathodically protected by pyrite in these systems. Based on the results of preliminary diagnostic experiments, it appears that gold dissolution in thiocyanate and thiourea systems is limited by passivation due to the formation of either elemental sulfur or sulfur compounds on the gold surface.

Jan 1, 2000

By P Williams

The Sunrise deposit is one of AustraliaÆs largest and most profitable gold deposits. It has consistently and spectacularly outperformed every resource model created. Currently over the life of the Sunrise pit there has been a 50 per cent under estimation of ounces mined. Without a solid basis for predicting the tonnes and grade or the spatial location of mineralisation, mine planning becomes problematic. Recently, through a better understanding of the mineralising processes the reconciliation of the resource model has improved to be in the order of ten per cent under on ounces mined. This paper will describe how the mine geologists at Placer Granny Smith have implemented the changes required to improve the resource model. Work began with the development of a three-dimensional lithological and structural model based on historical drilling and pit mapping. Continual updating of the geological model with grade control logging, assays and in pit face mapping, now allows for the on-going improvement of the resource model and the planning of mine development drilling.

Jan 1, 2000

By L. Shevenell

Nevada now has, or will have, 35 pit lakes resulting from open-pit mining below the water table. State regulators are requiring that the ultimate pit lake water quality be predicted as part of the permit application process. Water balances/pit lake filling rates must be esti¬mated in support of the geochemical modeling. In Nevada, analytical and numerical methods have been employed for the study of pit lakes. In the current work, analytical solutions are investigated for one pit lake, the Getchell south pit lake, which previously filled be¬tween 1968 and 1982 during a hiatus in mining. Water levels vs. time are available for this lake and these data have been fitted with a hyperbolic curve. This water-level-vs.-time curve was used in simple water-balance computations to find the net inflow rates by forcing computed water levels and volumes to match those of the known water levels and volumes through time. The model described here provides realistic volume fluxes into and out of the lake on a monthly basis as the pit lake filled.

Jan 1, 2000

By Christina Viklund-White

Life Cycle Assessment has been used to compare the environmental performance of landfilling versus recycling of the zinc used for galvanizing steel. Hypothetical process routes were com-posed involving four different EAF dust treatment processes; Waelz kiln, DC-furnace, EZINEX and slag fuming, as well as scrap dezincing. The study shows that recycling of zinc used for galvanizing steel has environmental benefits in that it saves zinc resources. However, zinc recovery does not necessarily decrease the potential impact on global warming and acidification. The magnitude of these two impact categories is tightly correlated with the amount and type of primary energy consumed in a process. Due to the high electricity consumption in the dezincing process, this route has the highest impact on Global Warming Potential as well as Acidification Potential. The major part of the energy requirement for the production of zinc from primary and secondary sources is consumed in the reduction of ZnO to Zn. The consequence is that the theoretically possible savings in primary energy by recycling zinc-containing materials are relatively minor. The impact categories "land use" and "waste generation" are not considered in this study, but most likely the evaluation of such impacts would further increase the potential environmental impact of the landfill alternative. The results also show that the location of an electricity-intensive process highly affects the potential environmental impact. Comparing process and material alternatives in LCA studies where branch average data is used, is considerably more complex than when LCA is used within a company.

Jan 1, 2000

By Kallioinen Jouko

"Advanced Flotation Technology is the application driven design of Don-Oliver flotation cells to achieve the optimum performance for each type and grind of flotation. Optimum performance is the combination of both recovery and selectivity.Optimized performance is the combined product of optimized mixing and effective froth removal. Optimized mixing is applied to roughers, scavengers, cleaners and specialty cells such as those to float hydrocyclone underflows in both primary and regrind circuits in order to reduce overgrinding. Effective mixing for fine material is easy, but overmixing reduces selectivity in frothbed.Selectivity in flotation is an important target, especially when treating complex ores, and parameters in frothbed have been examined to improve the separation of minerals and eliminate circumstances that reduce separation rate.Advances in process control have been achieved with expert controls and instructive operator information data. This has gained a higher degree of understanding of cell operation and ore type being processed to be used in future process development work. Excellent results of this Advanced Flotation Technology have been achieved and designs through 7000 cu ft (200 m3) are currently available for high capacity concentrators. This paper will detail how flotation cells are more responsive to the exact requirements of the duty specified."

Jan 1, 2000

By K Ellis, K Quast, R Newell

The use of ammonia as a leaching agent in the recovery of copper from ores and concentrates has a number of potential benefits. These include the ability to treat ores with an acid consuming gangue, non-corrosivity, the insolubility of iron in the solution and increased selectivity. This paper reviews the previous and current use of ammonia based leaching systems for copper recovery and presents the results of a laboratory investigation that involved leaching of a copper concentrate and a low-grade ore. The effects of the operating variables (particle size, oxygen addition, agitation and temperature) are discussed. Of these, the particle size had the greatest effect, with decreasing size giving improved leaching rates and recoveries. The possibility of using ammonium salts in heap leaching is also discussed, and the results of some small-scale column leach tests presented. Possible methods for recovering the copper from the leach solution are outlined, and the types of ores and concentrates for which ammonia leaching may prove to be a viable alternative processing route are discussed.

Jan 1, 2000

By Regina N. Tempel, Laurie S. Balistrieri, Lisa L. Stillings, Maggy F. Lengke

The Dexter pit lake, within the Tuscarora volcanic field in Elko County, Nevada, formed after closure of the Dexter mine. Mineralogy at the Dexter mine is related to widespread feldspar, silica, and chlorite alteration. Major mineralogy includes quartz, alkali feldspar, albite, phlogopite-biotite, hornblende, iron-titanium oxide, chlorite, kaolinite, smectite, illite, and sericite, with lesser amounts of calcite, zircon, apatite, and rutile. Trace element geochemistry is characterized by high levels of As, Ba. Cr, Cu, V, Zn, B, Zr, Li, and U. Detailed mineralogy and geochemistry are required for geochemical models to accurately predict trace element concentrations in pit lake waters.

Jan 1, 2000

While there is reasonable agreement on the basic chemistry of the slag fuming process, there has been an on-going debate for nearly 50 years as to the nature of the rate controlling factors in its industrial application. There have been advocates in the technical literature for thermodynamic limitations on the one hand or kinetic limitations on the other. The different viewpoints result in very different predictions as to the technical and commercial potential of the process. A resolution of the debate becomes of importance as pyrometallurgical processes are advocated as a means of extracting environmentally deleterious elements from metallurgical wastes. The present paper reviews the arguments in favour of both equilibrium and kinetic control and puts forward the view that much of the evidence for limitation of the process by kinetic factors under all conditions is unconvincing. It is maintained that the process can approach thermodynamic equilibrium under industrial conditions and that this determines the ultimate limitation on its technical performance. It is acknowledged, however, that kinetic considerations may cause the batch process to fall well short of performance predicted on thermodynamic grounds. The strong process limitation arising from the influence of chemical thermodynamics on the likely outcome of a hypothetical continuous fuming process is contrasted with optimistic forecasts resulting from the extrapolation of process models based only on kinetic considerations.

Jan 1, 2000

By V. A. Shumsky, I. P. Polyakov, N. M. Ospanov, M. A. Lyamina, N. N. Ushakov

Studies on the kinetics of the competitive processes of PbS volatilization and PbS oxidation, as applied to the heat and mass transfer conditions in the flame of the Kivcet furnace, revealed that the rate-determining factor is the supply of heat. Therefore, low yields of fume in the autogenous flash smelting of lead sulphide feeds are noted despite the high volatility of PbS at 1,300-1,400°C. Dust formation in the autogenous flash smelting of Kivcet-smelters does not exceed 5-7%, of which fumes amount to ~ 80%. Using extra fuel during autogenous smelting involves the mismatch of the sulphide oxidation rate and the release of heat in the flame, and increases the fume yield. This is a major cause of the high dust formation in pilot plant trials. The analysis of dust formation in the Kivcet smelting of oxidized lead feeds in an industrialscale smelter shows an overall increase of dust formation (up to 10% of the feed), with fumes constituting ~ 80% of the dust. A pronounced increase of the zinc component of the fumes is also noted. Lead

Jan 1, 2000