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By T Tran, F Lucien

Supercritical fluids (SCFs) have gained recognition as solvents for the extraction of a wide range of organic materials. Their principle advantages over conventional organic solvents are that they possess much more favourable transport properties and that such properties can be easily altered by adjusting the system temperature and/or pressure. More recently, SCF solvents have been employed in the extraction of metal ions. The direct extraction of metal ions using SCFs such as CO2 is normally not possible due to the charge neutralisation requirement for solubilisation. However, extraction can be achieved with a SCF solvent containing an organic complexing agent as a cosolvent (Laintz et al, 1992; Laintz and Tachikawa, 1994; Dehghani, 1996). The role of the SCF is therefore similar to the role of a diluent in conventional liquid-liquid or solvent extraction processes. In this regard, SC-CO2 is a particularly good diluent since it exhibits good solubility for many organic complexing agents. The extraction of metals with SCF solvents has been examined mainly in the analysis of environmental samples and the treatment of metal contaminated wastes. Nonetheless, some interesting results have been reported recently on the extraction of rare earth metals, which highlight the potential of SCF solvents in mineral processing applications (Laintz and Tachikawa, 1994; Dehghani, 1996).

Jan 1, 2000

By Akita Ito, Sumio Kato, Mikio Sugai, Shinichi Nakata

"Spark Plasma Sintering (SPS) is a newly developed method for the sintering of metal and ceramic powders, and completes their densification at low temperature and in short period. The SiC powder was synthesized from diatomite and graphite or carbon black by heating at 1 450°C for 1 hr in an argon atmosphere. The synthesized SiC powder was heated at 1500-1800°C, 50 MPa for 15-18 min by SPS. The relative density of sintered SiC body increased with the rise in the temperature. The oxidation of the surface of the SiC particle and impurities in SiC from diatomite greatly influenced the sintering promotion of SPS.IntroductionThe SiC has high hardness because of the covalent bonding, and is also excellent in thermal and chemical stability. However, it is difficult to obtain a dense SiC sintered body by the combustion heating-method. Therefore, the dense SiC bodies have been made by the use of additives and I or the hot pressing (HP) method.In this study, the SiC powder was synthesized by using diatomite of natural products and graphite, and carbon black of reagent as raw materials, and the relationship between the properties of SiC powders prepared at various synthetic conditions and the density of sintered body by SPS was examined."

Jan 1, 2000

By Houston Kempton, David Atkins

Mining in semi-arid climates can produce environmental impacts that will not begin for hundreds of years, but once started, may continue for thousands of years. Pit lakes may eventually exceed toxicity thresholds as metals are evaporatively concentrated, and slow unsaturated flow through acid-generating waste can eventually load several kg-SO4/m2-yr to underlying water tables. U.S. regulations are poorly equipped to respond to delayed and long-term environmental impacts, delaying permits as operators and regulators grapple with uncertainty. Improved uncertainty analysis, additional long-term mitigation options, and explicit regulatory guidance offer solutions to this dilemma.

Jan 1, 2000

By A. J. Hudson, M. R. Yenchek

Faulty insulators on mine trolley/track haulageways may allow leakage of currents into the mine roof, which may ultimately result in the combustion of the roof material. The National Institute for Occupa¬tional Safety and Health (NIOSH), Pittsburgh Research Laboratory (PRL), devised a passive means to detect overheating insulators on di¬rect current systems. The detector consists of a spring- loaded car¬tridge that ejects a reflective streamer of white Teflon tape when subjected to elevated temperatures. The cartridge assembly can easily be installed over the outer metallic shell of an existing trolley line insu¬lator. If an insulator overheats due to ground leakage currents, the vis¬ible streamer alerts mine personnel traveling on the haulageway.

Jan 1, 2000

By Carl-John Grävare

This paper deals with some of the systems and equipment that are being developed and/or are in use in Scandinavia. The main subject is the development of loading tests on the piles using monitoring equipment. This paper also describes ground improvement using lime-cement columns, expander body piles and steel core piles.

Jan 1, 2000

By S. S. Peng

Horizontal stress is an important factor that contributes to roof failure during longwall entry development, especially when the immediate roof is weak. In this paper, the effects of stress angle between the maximum horizontal stress and entry development and stress ratio of the maximum to minimum horizontal stresses on the stress distributions in the weak immediate roof of a three-entry system are analyzed using the finite element method. The results have confirmed that stress angle has a significant influence on the stress distributions. Generally, the three-entry system is in the worst stress condition when the stress angle is about 60° to 75° . The stress ratio has also some effects on the roof stresses.

Jan 1, 2000

By R H. Eric

Surface wave formation induced by a high-strength submerged jet in a bottom blown metallurgical vessels has been studied experimentally by using one-seventh water model of CLU (Creusot-Loire Uddeholm) reactor with two different tuyere configurations. Experimental results have been discussed in terms of the wave period, wave frequency and wave amplitude with respect to air injection rate and tuyere configuration at a 0.23 m bath height. The results from high speed photography observations displayed the formation of rotating surface waves which circulates within the water model. It was found that the frequency and the amplitude increased with gas injection rate. The wave period for off-centre nozzle orientation was found to be lower than those of the centre configuration. The experimental results also showed that the frequency of a rotating wave increases when the tuyere orientation becomes off-centred . The predicted amplitudes were in very good agreement with the experimental values over a range of gas flowrates between 0.00599m 3/s to 0.01081 m 3/s.

Jan 1, 2000

By Robert F. Randolph

Research on improving haulage truck safety, started by the U.S. Bureau of Mines, is being continued by its successors. This paper reports the orientation of the renewed research efforts, beginning with an update on accident data analysis, the role of multiple causes in these accidents, and the search for practical methods for addressing the most important causes. Fatal haulage accidents most often involve loss of control or collisions caused by a variety of factors. Lost-time injuries most often involve sprains or strains to the back or multiple body areas, which can often be attributed to rough roads and the shocks of loading and unloading. Research to reduce these accidents includes improved warning systems, shock isolation for drivers, encouraging seatbelt usage, and general improvements to system and task design.

Jan 1, 2000

By L. L. Newman, K. D. Ferguson

Traditional methods for mine waste management produces two waste streams and the construction of separate disposal facilities. Tailings impoundment design is usually controlled by physical stability problems. Alternatively. the waste rock offers high stability characteristics but hydraulic properties that create ideal conditions for oxidation. The problem of oxidation is significantly reduced for tailings due to a fine texture that augments water saturation. This paper introduces concepts for the co-disposal of tailings with waste rock and evaluates the physical behaviour of an integrated waste system. 'he potential benefits of co-disposal are shown for a typical mine such as Equity Silver.

Jan 1, 2000

By P J. Terbrugge

The concept of vertical pit mining has been developed as an alternative mining method for the exploitation from surface of small, vertical or near-vertical, massive orebodies down to depths of some 200 m, where ore extraction from conventional open pit excavations is rendered uneconomic due to high associated waste:ore mining ratio. Systematic lateral support maintains vertical pit sides, thereby minimising waste mining volumes. Stability analysis techniques have been developed for design of this lateral support, with the support quantum, primarily comprising long cable anchors, dependent upon country rock strength characteristics and pit configuration. Where the cost of support is less than the cost of the comparable conventional pit waste excavation, vertical pit mining becomes an economically viable alternative, additionally providing the benefit of reduced environmental impact and rehabilitation requirements for the mining area. The technique has been successfully applied for the mining of a chrome deposit in Zimbabwe to an 80 m depth, believed to be unique in the world, and a full feasibilty study for a 3000 m2 diamond pipe has been carried out for mining to 200 m depth.

Jan 1, 2000

By Masayasu Kawahara

"The extraction and separation of nickel, cobalt and copper were investigated with a solvent impregnated resin which was produced from UX84-I and XAD-4. The extraction behavior of metals with the solvent impregnated resin is similar to that with solvent extraction. The extraction ability of solvent impregnated resin improves when using finer particle resin and with a higher concentration of extraction solvent.IntroductionSolvent extraction is well known-as a method for separation of metallic elements in solution. However there are problems with intermediate phase and solvent loss. Ion exchange resin is also used in hydrometallurgy, but it is not fit for separating a large quantity of metals. Amberlite XAD-4 resin is known as a absorption agent of organic matter in water. It is expected that the resin which has the ability of extracting metals can be made by absorbing organic extractant on XAD-4 resin In this study, solvent impregnated resin (SIR) was produced from LIX84-I and XAD-4, and extraction and separation of nickel, cobalt and copper were conducted using SIR. The extraction properties of SIR were investigated, and a comparison between ordinary solvent extraction and SIR was made.Experimental ProcedureAmberlite XAD-4 was used as absorption resin for the organic extractant in this study. The physical properties of XAD-4 are shown in Table I. Amber lite XAD-4 has a large surface area and shows good ability to absorb organic matter in water, but the: resin does not have the ability of exchanging metallic ion."

Jan 1, 2000

By Chikabumi Yamauchi, Mitsuru Tanahashi, Jutaro Miura, Takaharu Iwadachi, Toshiharu Fujisawa

"Tue oxidation behavior of molten Cu-Be alloys was investigated by exposing· the molten Cu-Be alloys to various Ar-O2 atmospheres to control the oxygen partial pressure, PO2 = 10 ~105 Pa at 1423 K. The following results were obtained:• The oxygen · partial pressure in gas phase affects the morphology of the oxide formed on the surface of the alloy and · the oxidation rate of beryllium.• At lower oxygen partial pressure, a molten Cu-Be alloy is covered with a homogeneous and compact internal layer of BeO. Thus, the beryllium oxidation rate can be minimized.• By adding a small amount of calcium or zirconium into the molten Cu-0.5 mass% Be alloy, a protective BeO layer is formed even at higher oxygen partial pressure. Thus, the beryllium oxidation rate can be reduced.IntroductionCopper-beryllium (Cu-Be) alloys are well recognized for their unique properties, such as high electrical conductivity, high strength, high fatigue strength, excellent properties at elevated temperatures, good formability and good corrosion resistance. .This extraordinary collection of properties are the reasons why Cu-Be alloys are expected to be ""Key-materials"", which are necessary to further advance science and technology and to be applied in.various fields such as electronic devices, machine parts, repeater housings of undersea optical fiber communication cables, etc.However, a large amount of beryllium is oxidized to BeO in melting stage of the current Cu-Be alloy production process, because beryllium is a highly reactive element. This is one of the ·main factors that negatively affect the production yield and th_e product quality."

Jan 1, 2000

By Y. Sako, E. Nomura, K. Muraguchi, K. Shibata

In 1998, Mitsui Mining & Smelting Co., Ltd. (MMS) produced 70,000 tonnes of lead, 231,000 tonnes of zinc and 214,000 tonnes of copper. MESCO, Inc. has been in charge of the automation and mechanization of smelting facilities promoted by MMS as well as the construction of facilities for chemical production and electronics materials plants, by which MESCO has contributed to the development of MMS. Initially, MESCO developed a casting machine for refined lead in the early 1960's, and thereafter, it developed a casting machine for refined zinc, a stripping machine for zinc tankhouses and energy saving facilities. In the field of copper smelting, it has also developed automation and mechanization facilities.

Jan 1, 2000

By B. K. Rath

The Industrialization of a country depends on its mining activities to a great extent. In mineral production, India has a top rank not only in South Asia, at the global level too. Quantum of mineral production is almost directly proportional to the quantum of explosive production. Mining sector consume more than 80% of country’s explosive production. Due to rapid growth of mining activities in the country, the explosives industry has been developing very fast in terms of quantity, quality and types. , In this paper, India’s post independent chronological date regarding use of explosives, their types, their constraints and a profile of well-known manufacturers has been meticulously presented. A production figure for three years with system analysis has been presented. The paper also deals with present consumption pattern while making a futuristic forecast. In view of the anticipated changes that are to take place in mining industries in near future, the manufacturers of explosives have to pay a vital role. The paper highlights some concrete and valuable suggestions and recommendations. Small scale Companies have to limit their production to Slurry and Emulsion types of Cartridged explosives whereas the large manufacturing units have to concentrate on Bulk explosives, specialized explosives and better initiating systems. The large manufacturing units have also to make all concerted efforts to compete with global market for significant export. The Country for its rapid growth needs basic raw materials like Coal, Iron Ore and Limestone. So, the extraction of these minerals is of prime importance. The more we produce and consume, the more will be Industrialization. The Industrial growth rate has been around 6% during the last few years. As the Industrial growth rate is moderate, there is moderate increase in mineral extraction in the Country. Additional mineral extraction demands additional explosive production (Annexure-1).

Jan 1, 2000

By W. J. Pennstrom, J. R. Arnold

This paper focuses on solution-balance management around heap-leach operations. Experience has shown that increased leach recoveries can be achieved by utilizing various leach-solution recirculation techniques. The most prominent solution-recirculation technique is intermediate leaching. The net effect of intermediate leaching is to increase recovery plant performance by increasing solution concentration tenors, to increase metal recovery by increasing the total leach time and to decrease the overall capital expenditures required for metal-recovery facilities. The adverse effect on the flow of cash from increased metal inventories in the recirculating solutions is offset by increased metal recovery and lower operating costs per unit produced.

Jan 1, 2000

By Yoshinobu Fukumori, Testuya Watanabe, Futoshi Shikata, Hiroyuki Tokumitsu, Hideki Ichikawa, Masahito Miyamoto

Nano-particulate systems have attracted much attention recently in pharmaceutical field as drug carriers and functional components of pharmaceutical dosage forms. This paper describes our approaches in design and preparation of nano-particulate systems, including lipid nano-emulsions, chitosan nanoparticles and thermosensitive acrylic nanoparticles, for certain pharmaceutical applications mentioned below. The lipid nano-emulsions with their particle size smaller than 100 nm were prepared for gadolinium neutron-capture therapy (Gd-NCT) of cancer by a thin-film hydration method with sonication, and intraperitoneally injected into Greene's melanoma (melanotic No. 179)-bearing Syrian hamsters. This provided such a high gadolinium concentraton in tumor as 107 µg/g tumor (wet basis) at 48 h after administration. As an alternative gadolinium nano-carrier for Gd-NCT, biodegradable and highly gadopentetate-loaded chitosan nanoparticles (Gd-nanoCPs, 426 mTI in particle diameter and 9.3% in Gd content) were prepared by a novel emulsion-droplet coalescence technique. A significant tumor-killing effect could be obtained when Gd-nanoCP suspension was injected intratumorally twice 24 and 8 hours before neutron irradiation into B 16Fl O melanoma-bearing mice and subsequently thermalneutron was irradiated toward tumor site with a flux of 2 x 109 n/cm2/sec for 60 min. As one another application of nanoparticles, a novel acrylic composite latex with a hydrophobic core and a thermosenstively swellable shell was designed for fabricating microcapsules showing thermosensitive mode of drug release. The microcapsules with the composite latex-dispersing membranes exhibited an exceptionally rapid on-off response of drug-release in a thermosensitive manner.

Jan 1, 2000

By M Hino, D R. Swinbourne

The thermodynamic properties of arsenic in metal, speiss, matte, slag and gas phases are first summarised in this paper. Arsenic associates with sulphide minerals and generally has compounds of high volatility, but it has a weak affinity for sulphur and a strong affinity for metals, especially copper and iron. In the initial stage of the oxidation of sulphide concentrates arsenic is volatilised easily prior to the oxidation of FeS, although it tends to be fixed in the condensed phase as FeAsO4 if the concentrate is over-oxidised. Thermodynamic simulation of oxidative copper smelting reveals the distribution of arsenic between matte, slag and gas, and the possibility of condensation of arsenic from the resulting waste gas is discussed. In reductive smelting more arsenic remains in the metal or matte, and is sometimes concentrated as a separate speiss phase. The phase relations and thermodynamic properties of speiss are also summarised briefly. Arsenic refining from smelted copper metal is shown, from an examination of the basic principles of arsenic removal into slags, to be difficult. Owing to its weak affinity for lead however, arsenic refining from lead bullion is seen to be much easier.

Jan 1, 2000

Tracey Khanna, Assistant Editor of UK?s Mining Magazine discusses some of the new and important environmental challenges, physical and social, that are facing mining companies. The tide of public opinion has turned strongly against those companies which are unable to show that they are practising responsible environmental stewardship. This is, no doubt, in part due to the recent focus of the international media on environmental issues and constantly improving means of communications, which has brought the whole subject of mining and the environment to those who, in the past, had only a limited awareness of the industry. Mining companies today face new and important challenges with regard to the environment, both physical and social. New technology and a greater understanding of waste management techniques has helped to bring about improved handling and disposal of mines wastes, so reducing some of the impacts. However, improved technology has also brought about the economic viability of exploiting increasingly lower-grade ore from open pits, resulting in a greater visual impact.

Jan 1, 2000

By Uchil Jayagopal, P. V. Krupakara, S. Manjunath

"This paper deals with the corrosion characterization of quartz particlate ZA-27 alloy metal matrix composites (MMCs). Quartz particles of size 50-80 microns are used as reinforcement. MMC's are prepared according to ASTM standards. Composites containing. 2, 4, and -6% by weight of quartz and unreinforced matrix were tested using 1 -N hydrochloric acid: The composite was found to be more corrosive resistant than matrix alloy. In each test the corrosion resistance of both alloy and composites were found to decrease with the exposure time.1. IntroductionMetal matrix composites- (MMCs) offer designers many added benefits, as they are particularly suited for applications requiring good strength at high temperature, good structural rigidity, dimensional stability, and light weight 1-5. The trend is towards safe usage of the MMC parts in the automobile engine, which work particularly at high temperature and pressure environments Particles reinforced MMCs has been the most popular over the last two decades.ZA alloy MMCs have most popular families being represented by. ZA-27 alloy reinforced with ceramic particulate. Although the incorporation of the second phase into a matrix material can enhance the physical and mechanical properties of the base metal, it could also significantly change the corrosion behavior.ZA alloys have been used extensively in industry. This is attributed to their excellent fludity, castability and good mechanical properties. Among the zinc-based foundry alloys, the ZA family of alloy have been widely used during the past few years. ZA alloys have many advantage over aluminium based ones, especially high strength with a low casting temperature 8."

Jan 1, 2000

By J L. Kanau

In this study some drawbacks of using Bond grindability as a measure of grindability characteristics for mill control have been discussed. After reviewing the merits of alternative methods of determining the Bond grindability published in the literature, a new alternative method has been proposed.

Jan 1, 2000