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By N. Ohmura, H. Saiki, T. Nagaoka

A microbiological flotation system that facilitates the removal of pyritic sulfurfrom coal is reported. The chemoautotrophic bacterium Thiobacillus ferrooxidans is utilized as a pyrite-selective biological surfactant that augments the flotation-mediated rejection of pyritic sulfur. The bacteria were produced by continuous cultivation in 50-L tanks, where it was possible to produce 3.8 x 1012 cells/day when the dilution rate was optimal and the pH was 1.6, a condition that prevented ferric precipitation. Prior to flotation, the bacteria were mixed with coal, which allowed cells to selectively adhere to the pyrite. The adherence of bacteria made the pyrite surfaces more hydrophilic, which facilitated separation by increasing the tendency of pyrite to sink, while the hydrophobic coal floated. When a synthetic coal/pyrite mixture (10.1 % sulfur) was subjected to microbial flotation, the level of sulfur rejection was stable during the entire period of operation (i.e., one hour). In the absence of bacteria, flotation reduced the sulfur content of a coal/pyrite mixture to within the range of 6.7% to 7.4%, with the combustible recoveries ranging from 93.9% to 99.0%. In the presence of bacteria, the sulfur content of cleaned coal was in the range of 1.3% to 1.4%, with the combustible recoveries ranging from 80.8% to 86.3%. Bacterial activity accounted for 57% of the total sulfur rejected through flotation. The desulfurization capacity of the system was further confirmed by testing it with run-of-mine coal. The pyritic sulfur content was reduced from 2.9% in the feed coal to around 1.2% in the froth product, while 80% of the combustible recovery was retained. Microbial flotation removed 60% of the pyritic sulfur from the feed. These findings demonstrated that micro¬bial flotation could be utilized for the removal of pyritic sulfur from coal in a semicontinuous system.

Jan 1, 2000

By M. Olper, M. Maccagni

"The crude zinc oxides (CZO) produced in any thennal process dealing with EAF dust also contain lead, cadmium, and a considerable amount of halides (chlorides and fluorides). The high halide contents make these crude zinc oxides less and less attractive, both technically and economically, and a further refining procedure is nece'ssary to meet the zinc and zinc oxide market requirements.Hydrometallurgical techniques commercially used to dehalogenate the crude zinc oxides are not effective enough to upgrade the crude zinc oxides to the required specification for their direct use in the traditional sulphuric electrolysis by primary zinc producers.The EZINEX® PROCESS has solved the problem of the halides contained in the crude zinc oxides. This process is the only proven technology electrowinning zinc from a chloridebased electrolyte in a conventional cell house. This paper discusses the process economics taking the data from feasibility studies of different size commercial plants."

Jan 1, 2000

By A. Cichowicz

In this study, techniques used to design earthquake-resistant structures are applied to the deep-level mining environment. Earthquake engineers seek to identify the cause of potentially damaging resonance, and design or reinforce structures to reduce these effects. Similar techniques have been used to analyse the dynamic behaviour of the rock mass surrounding a stope in a deep South African gold mine. A three-dimensional seismic array installed in a stope at TauTona Mine (previously Western Deep Levels, East Mine) provided an opportunity to examine the evolution of the wave field close to an underground opening. A set of three-component geophones installed in a borehole above the panel revealed the development of surface waves as wave fronts reached the excavation, and an array of vertical component geophones fixed to the hangingwall provided a two-dimensional map of site effects. While the collected data do not include damaging seismic events, quantitative analysis enabled phenomena which could lead to damage, to be recognized. In the vicinity of the excavation, the energy of the seismic signal is generally transformed from high frequency to low frequency. It was found that seismic events with relatively high corner frequency (150 Hz?200 Hz) usually excite several modes of vibration (30 Hz to 110 Hz), while events with low corner frequency (30 Hz?50 Hz) do not always excite higher modes of vibration in the structure. This implies that the rock mass around the excavation is a complex medium, and should be studied using the multi-degree-of-freedom model. A strong structural effect (due to the excavation shape) was revealed as a low frequency coda wave (at 40 Hz and 60?70 Hz), well developed on the skin of the hangingwall. A strong site effect was revealed by changes in signal properties between hangingwall geophones, exhibiting strong resonances around 160 Hz and in the range 200 Hz to 300 Hz.

Jan 1, 2000

By Richard M. RusselI, Jerry Sweeney

"The disposal of Aluminum slag wastes continues to challenge an otherwise environmentally beneficial and highly desirable industry - Aluminum Recycling. Slag wastes contain soluble salts that can be reused in aluminum smelting. Reclaiming salt is a logical first step in eliminating slag waste.Reclaiming salt flux has been conducted on a limited basis in the United States for reasons of economy. Practical methods and rising landfill tipping fees will increase the number of plants which opt to recover salts from slag wastes.The authors share their experiences in the design, operation and startup of a commercial scale flux reclamation plant operated by Tennessee Aluminum Processors at Mt. Pleasant Tennessee. This paper identifies three elements that allow practical operations:• Minimizing Evaporator Heat Duty• Simplifying Evaporator Operations• Potassium Chloride Fortification of the Recycled Salt"

Jan 1, 2000

By Michael J. Rinker, P. A. Tibble, M. Wiseman, R. V. Nicholson

Tailings, from an active copper-zinc operation, containing about 10% sulphur were investigated to assess the onset of acid production and potential lime requirements for treatment of drainage. Oxygen consumption rates were measured over two years to verify spatial and seasonal variations in sulphide oxidation rates. Shallow cores were collected to assess the quality of tailings porewater and to characterize solids that had been subjected to oxidation and depletion of neutralization potential (NP) for several years. Oxygen consumption data were used to quantify rates of NP depletion and onset of acid drainage from the near- surface tailings. Based on measured oxygen consumption rates and identification of NP remaining in the tailings, future lime use in the treatment plant was expected to rise significantly without mitigation. Geochemical modeling calculations were calibrated with observed oxygen consumption rates and the model results agreed well with actual lime use in the waste water treatment plant during operations. The modeling also demonstrated the benefits of lower lime demands and treatment costs after closure as a result of construction a soil cover on the acid generating tailings.

Jan 1, 2000

By C. Jewell, G. H. Rupay

"67 - 2:15-3:00Regeneration of Hydrochloric Acid from Waste Pickle Liquor Using a Fluidized Bed Reactor System. G. H. RUPAY and C. JEWELL, Dominion Foundries and Steel Ltd., Hamilton, Ont.The disposal of acidic waste liquors from pickling processes has always been a problem for the steel industry. With increased awareness toward environmental control and the problems acidic wastes create, processes utilizing recovery and regeneration of the waste acids are becoming more popular. This paper describes the Keramchemie/Lurgi process for regenerating hydrochloric acid from waste pickle liquor using a fluidized bed reactor system. The process parameters are outlined, together with a brief description of the equipment. This is followed by a discussion of the operating problems and concludes with economic data."

Jan 1, 2000

By G. E. Jones, G. K. Hoffman

Through the USGS National Coal Availability pro-gram, two San Juan Basin studies have been completed. The study areas are in the northwest Bisti field, Fruitland Formation and in the eastern Standing Rock field, Menefee Formation. Original resources are 4.66 Gt and 3.46 Gt (5.14 billion stand 3.82 billion st), respectively, in the Bisti and Standing Rock areas. Bisti coal resources are greatly reduced by the Bisti-De-Na-Zin wilderness area (1.13 Gt (1.25 billion st)). Technological restrictions remove 31% from Standing Rock original resource. Available resources are 60% (2.79 Gt(3.07 billion st)) of the Bisti original resource and66% (2.26 Gt (2.49 billion st)) of the original Standing Rock resource.

Jan 1, 2000

The Ministry of Economic Development has as its slogan æTogether making the differenceÆ. The Ministry is required to work in partnership with the private sector, local authorities, Maori economic entities, trade unions and community groups to transform New Zealand's industrial and economic base. The Government is seeking to achieve sustainable and balanced economic development by: being more actively involved in economic management; working in partnership with the public and private sector and with worker and business interests; focusing on adding value in industries (including primary industries) with long term potential; and bringing the tools of economic policy together in a coordinated way. The Ministry, particularly through its operating group Crown Minerals, is committed to working with industry to achieve mutual goals and to obtain continuing investment in minerals and coal exploration and mining and an active New Zealand minerals industry.

Jan 1, 2000

By Ali S. Al-Watban

"In this paper, the room temperature friction and deformation properties of various polycrystalline diamonds; i.e. aggregates of diamond crystals with a ""binder"" phase of cobalt and a polycrystalline coating produced by a chemical vapour deposition processes (CVD) were studied when softer metallic and ceramic sliders were used. The experiments were conducted· at relatively low sliding speeds (10 mm/min), in a vacuum of 10-5 mbr after having cleaned the specimen surfaces by out-gassing them for about 30 min at 800 °C. As a result of increasing the number of traversals significant wear of the coated diamond by softer metallic sliders (aluminium and mild steel) was observed. With ceramic sliders, it is shown that the multiple traversals result in the formation of wear groove. With diamond silicon carbide, high friction and adhesion lead to significant metal transfer which then pre-empts cumulative deformation of the harder materials. With the diamond-cobalt composite, the friction is surprisingly low, there accumulation of wear debris on the tip of the slider but no permanent transfer of metal and the harder specimen is not damaged even after 5000 traversal.IntroductionPolycrystalline diamond is mainly produced as tool materials for the machining of hard metals and composites. Thus, the sliding friction and wear resistance are amongst the most important properties relevant to those applications.During cutting by PCD the wear mechanism is mostly influenced by the chemical affinity between the tool material and the workpiece. For example, diamond based materials are not recommended for machining ferrous materials because carbon is highly solubie in iron: This leads to the graphitisation of diamond particles and hence a high rate of diffusion wear is observed (Brookes and Lambert, 1982)."

Jan 1, 2000

By A. Siegmund, Gerhard Martin

The recycling of metal containing scrap is a common practice in the industry and has a long tradition. . In rec~nt years, this philosophy has been transferred to organic materials, in particular to thermoplastic polymers. BSB . Recycling GmbH, a company with a long experience in the treatment and recovery of lead from battery scrap,· had recognized this exploitation at an early stage and challenged it by a consequent continuation of the idea to recycle materials other than metals without degradation and maintaining the quality. These efforts resulted in an economic and environmentally acceptable solution producing high quality polypropylene compounds at BSB beside lead and lead alloys from battery scrap. The raw material fair the production of polypropylene compounds is shredded plastics from the separated casings of spent lead-acid batteries. The production of polypropylene with specific physical and mechanical properties is carried out by the accurate dosing of organic as well as inorganic additives. The result of the procedure is a novel product group "Seculene PP", a registered trademark of BSB Recycling GrnbH.

Jan 1, 2000

By Serdar Aksu, Fiona M. Doyle

"CMP will be an essential process in the production of integrated circuits containing copper interconnects. This study aims to improve our mechanistic understanding of the role that organic chelating agents might play in the reactive slurries used in copper CMP. Copper dissolution behavior in EDTA arid glycine was first examined by producing potential-pH diagrams for the copper-water-EDTA and copper-water-glycine 'systems. The results of potentiodynamic polarization experiments were then considered in light of these diagrams. . In-situ polarization experiments were conducted to gain insight into the electrochemistry of copper during dynamic polishing in slurries prepared from EDT A and glycine.IntroductionCopper has recently started to replace aluminum as the interconnect metal in integrated circuits. Copper interconnection offers faster and more reliable integrated circuits due to its higher electrical conductivity and superior electromigration resistance (1). The damascene method is used to form multilevel interconnects in the manufacture of integrated circuit devices with copper metallization (2, 3). Copper is deposited by CVD or electroplating into vias and trenches etched in the interlayer dielectric (IDL), over a diffusion barrier usually made from titanium, tantalum or their nitrides. Chemical mechanical planarization (CMP) then prepares the wafer for the next deposition step, by removing excess copper and planarizing the surface. During CMP, the wafer is rotated and pressed against a rotating platen covered with a polishing pad. Chemically active slurries containing submicron size abrasive particles (Si02, Al20 3, ceria, diamond, etc.) are applied. Both the mechanical action of the abrasive particles and the chemical action of slurry constituents remove material from the wafer surface. Planarization results because material is removed faster from protruding regions on the surface than from recessed regions. Since CMP can globally planarize .the entire wafer, it has become one of the key technologies for producing integrated circuits with copper metallization."

Jan 1, 2000

By A. N. Aposhian

The electronics industry generates tin/lead bearing by-products that can be recycled for their metal value. This paper will cover the processes used to recycle these tin/lead bearing byproducts from the plating, circuit-board fabrication and assembly industries. Though these processes are well known to the companies who do the recycling, few outside the industry including the generators of the by-products, understand the processes or needs of the industry. This paper will give a broad overview of these processes, and describe the services provided by this industry. The paper will also touch upon the future of the recycling industry, including the legislative and environmental push for the elimination of lead from electronics.

Jan 1, 2000

By Kadir Sariiz

Abstract - The Akçayir-Yürükakçayir Miocene-Pliocene basin in the Central Anatolia hosts ancient lacustrine sepiolite deposits. The succession in this basin consists of conglomerate (Yürükakçayir conglomerate), clayey and silty limestone, dolomitic marl, sepiolite beds and lenses, and dolomitic limestone (Kepeztepe formation). The main impurities within the sepiolite rock are dolomite, opal-CT, calcite, smectite and feldspar as sepiolite + dolomite and sepiolite + opal-CT are the main mineral assemblages. Smectite and feldspar are thought to be of detrital origin. Calcite is found as a secondary filling in root tubes and casts. Sepiolite samples studied display root-marks and root tubes, soapy and massive structure indicating direct precipitation. Sepiolite deposits probably formed at a pH of 8 to 9, and Mg+2 and SiO2 concentrations in moderately saline environments of internal facies of an alkaline lake.

Jan 1, 2000

By Rüdiger Wunsch

The new high speed Vienna - St.Pölten line and the Lainzer tunnel are to be connected to the existing Western railway line in Vienna. This involves building an underground cut and cover branching tunnel which will be connected to the Western railway line by ramps. A key structure is the Herzmansky Street tunnel, which has a length of some 820m. It is to be constructed as a cut and cover tunnel using the top down method. The walls of the tunnel are designed as a water resistant structure consisting of double walls, an outer wall of bored piles and an inner reinforced concrete wall. The bored pile wall will be used as a temporary retaining wall during the construction phase and will also be a structural part of the per­manent tunnel wall. The retaining walls of the open pit, which will have a depth of up to 14m and a width of 12m, were investigated as a non-contiguous bored pile wall and overlapped bored pile wall. Preventing ground water from penetrating into the pit is of paramount importance. The high ground wa­ter level is the determining factor for the dimensioning of the bored pile wall and results in the require­ment for a water resistant concrete structure. It has been necessary to adopt adequate measures, therefore, in order to reduce the hydrostatic water pressure during the construction phase, assuming economical pile dimensions.

Jan 1, 2000

By A Grice

AMC has completed a number of backfill options studies, including several in recent years for large, three-dimensional orebodies involving total extraction by longhole open stoping with backfill. This has led to the development of a thorough review methodology that assists in the selection of the most appropriate backfill system and the most economic mixes to achieve the required performance. A recently developed design tool has simplified the calculation of backfill strengths for various exposure dimensions and automatically determines strengths incrementally over the height of a stope. Using a generic orebody with a plan dimension of 120 m wide by 360 m long, several different stoping layouts have been analysed to determine the effect of stope dimensions and sequencing on backfill strength requirements. This has been done for stope heights from 50 m to 300 m, in 50 m increments. The required strengths have been calculated in slices and summarised for each stope in four equal layers. The average strength requirement for each layout at each stope height has been compared graphically. For all stope heights, a panel stope layout that minimises the proportion of primary stopes results in a lower average strength requirement than grid layouts on a checkerboard pattern. However, for very high stopes, smaller plan dimensions become more economic. The increase in required strength with stope height is non-linear, making taller stopes potentially more attractive. The main cost factor in most backfills is the rate of binder addition, which is closely related to the strength required. By choosing a layout that minimises the backfill strength requirement, significant savings in binder addition rates and overall costs can be achieved. These must, of course, be weighed against other factors to determine the optimum stoping layout and backfill system.

Jan 1, 2000

By Wantae Kim, Furnia Saito, Qiwu Zhang

"A novel mechanochemical processing technique for the preparation of zeolites from kaolinite in NaOH solution was investigated. Dry and wet mechanochemical treatments combined by subsequent moderate heat treatment could accelerate the synthetic reaction for zeolites from kaolinite. This stimulating process produced zeolite-A and zeolite-X from activated kaolinite at extremely lower reaction temperature than conventionally applied for zeolites production. Conversion to zeolite-A and zeolite-X was strongly dependent on the activated state of kaolinite. Wet mechanochemical treatment modified the chemical composition of activated solids. Rapid dissolution of AIO species rather than SiO ones in the reactant solution was accelerated by wet milling together with NaOH that promoted the formation of zeolite-X of high specific surface area.IntroductionZeolites are a family of hydrated alumina-silicate minerals contains alkali and alkaline earth metals. They have a framework structure that encloses inter-connected cavities occupied by large metal cations and water molecules. Zeolites are characterized for their ability toward ion exchange and reversible dehydration. Properties of them are exploited through commercial productions of particular structural and chemical features. Zeolites are used as commercial uses for catalysis for FCC (fluidized catalytic cracking) of petroleum refining, drying reagents of gases and liquids, and selective adsorbent for pollution control [1-3]. In such purposes, artificially synthesized zeolites are employed, although natural ones are associated with hydrothermal and hot spring alteration of volcanic materials. Commercially, a hydrothermal process has been used for the preparation of zeolite synthesis. This preparation method gives zeolites of high chemical homogeneity and purity, however, this wet-chemistry-based processing is significantly influenced by reaction temperature, pH, concentration, and composition of starting substances [4]."

Jan 1, 2000

By Sehoon Lee, Duhwoe Jung, Eunsu Cha, Kyeonghwan Jeong

This case study presents the effectiveness of underground rock blasting to facilitate the trench cut in the hard rock layer using a conventional trench cutter for the construction of a diaphragm wall. Rock blastings are pre-performed up to the scheduled depth and then the fragmented rocks can be easily cut using a conventional trench cutter. Two trial underground rock blastings have been performed and the effectiveness of pre-blasting is presented in terms of a cutting rate, a loss of cutter heads and an amount of overbreak. Based on the results obtained from the trial underground rock blastings, the following conclusions can be appropriate: 1) A pre-blasting of hard rock layer located in depth can help to overcome the limitation of the trench cut using a conventional trench cutter. If the hard rock layer is fragmented after blasting, the fragmented rocks can be easily cut using a conventional trench cutter, 2) The speed of cutting works was accelerated and the loss of cutter heads was significantly reduced in the sections where the blastings were applied prior to cutting. 3) The amount of overbreak, expressed in terms of the amount of poured concrete, can be reduced to some extent. However, the location of blast holes in the trench can also contribute to the amount of overbreak. The closer the location of blast holes to the edge of the trench, the more extensive fractured and cracked zone can be formed on the face of the trench. This can increase the amount of overbreak if the trench is left empty for a while.

Jan 1, 2000

By C. J. Boreiko

Traditional patterns of lead and zinc utilization are being evaluated in accordance with new paradigms that seek to ensure the long-term compatibility of global industrial activity with precepts of sustainable development and sustainable consumption. As a consequence, both industry sectors are experiencing intense scrutiny from the international community, and numerous regulatory options are being considered that may impact upon international industry practice. This paper reviews the growing expectations being placed upon industry, and highlights some of the common regulatory concerns being expressed regarding both metals despite their differing toxicological profiles.

Jan 1, 2000

By Kim A. Lapakko, William W. III White

The ASTM standard method D 5744-96 was developed to provide a well-defined kinetic test protocol, conducted under controlled reaction conditions, with the intent of generating reproducible results. A preliminary indication of the repeatability of a simplified alternative method (MN DNR method) was assessed and results from the MN DNR method were compared to those from the ASTM method. To provide an indication of repeatability, six samples from three different rock types were subjected to dissolution testing for periods of 20 to 68 weeks. Drainage pH values at the end of the tests were within 0.5 units in all cases and within 0.05 units in four cases. The percent difference from the mean for overall sulfate rates from paired cells ranged from 0.04 to 1756, with a median of 6.3%. Nine samples from four rock types were subjected to both MN DNR and ASTM tests for periods of 20 to 132 weeks. The difference in final drainage pH values forsix of the samples was less than 0.1 unit, and these values were less than pH 3.65 or greater than pH 8.0. The final drainage pH difference for the last three samples ranged from 0.15 to 0.4, and these values were ill the pH range of 6.2 to 7.2. The sulfate release rates for the periods of record for the MN DNR method were 70 to 150% of those for the ASTM method, with a median value of 110%. Sulfate and calcium release from the two methods was not substantially different. The MN DNR method typically produced higher magnesium release.

Jan 1, 2000

By R. Codell, D. L. Hughson

While benchmarking the integrated finite-volume code MULTIFLO against the analytical solution of Philip et al. (1989) for cylindrical underground openings, we found numerical simulation of dripping threshold flux consistently higher than the analytical solution for both rectangular and unstructured grids. The magnitude of error is proportional to the alpha parameter characterizing capillarity. This may bias estimates of repository performance towards non-conservatism.

Jan 1, 2000