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By D. R. Taylor, R. G. Goss

The use of clay-based granules as carriers for pesticides dates back to the early 1940s. It now represents a business conservatively estimated at between 180 and 270 kt/a (200,000 and 300,000 stpy) in the United States alone. Prices for these materials typically range from $110 to $165/t ($100 to $150/st). Aside from economic and specific target pest efficacy advantages, the use of clay granules as pesticide carriers also delivers a number of environmental benefits, which are reviewed. Topics discussed include drift control (vs. liquid sprays), mobility (in the environment), worker safety and transportation (spill) safety.

Jan 1, 2000

By Toshitaka Ota, Hisao Suzuki, Minoru Takahashi

"Perovskite-type lead zinc niobate (PZN) exhibits excellent electrical properties such as high dielectric constant, high electrostrictive coefficient and superior piezoelectricity. Therefore, PZN ceramics are very promising for high performance electronic devices. However, perovskite phase PZN is not stable under the ambient atmosphere. Accordingly, it is very difficult to prepare single-phase perovskite PZN ceramics. In this study, A-site cation of lead was partially substituted for barium to stabilize the perovskite phase of the PZN (Ba-doped PZN) powder. In addition, molecular design of an alkoxide precursor was controlled for a low-temperature processing. As a result, molecular design to suppress the lead-volatilization during calcination was preferred for a low-temperature processing. Processing temperature for a single-phase perovskite was depended on the amount of barium dopant. Doping of20 mole% of barium resulted in the single phase perovskite at 900 °C. The temperature for the single phase perovskite of Ba-doped PZN powder, which depended upon the amount of Ba-doping, was lower than that of the powder prepared by the atmosphere controlled conventional powder processing at least by 150 °C.IntroductionFerroelectric thin films and powders with perovskite structure are of renewed interest for micro-electronic applications, including ferroelectric random access memory (FRAM), dynamic random access memory (DRAM), and thin-layer capacitors integrated onto a silicon wafer [1-3]. In addition, recent advancement in micro-machine requires a high performance micro-actuator [4]. A perovskite type relaxor of Pb(Zn113 Nb213)03 is one of the promising materials for a high performance capacitor and microactuator because of their high permittivity and electrostrictive coefficient [5]. Therefore, this paper focuses on the low temperature processing of Ba-doped PZN powders.Chemical solution deposition (CSD) from molecular-designed alkoxide precursor solution is one of the most promising techniques for processing high-performance powders and thin films because it offers precise control of compositions on a molecular scale as well as a low processing temperature [6]. However, chemical solution deposition of perovskite type PZN powders and ceramics are very difficult because of the formation of stable pyrochlore phases. Therefore in the past, PZN powders and single crystal have been prepared by the hydrothermal method or flux method as well as the partial substitution method of a A-site cation [7-10]. In this study, a suitable molecular design for a preparation of perovskite type Ba-doped PZN powders with a chemical solution deposition process is investigated as well as the effect of A-site cation substitution. Chemical solution deposition from molecular-designed alkoxide precursor solution is expected to decrease the amount of a A-site substitution and/or a crystallization temperature for a single phase perovskite. This paper describes ""the relation between molecular-design and processing temperatures for a single-phase perovskite of Ba-doped PZN powders in comparison with the conventional oxides mixing method."

Jan 1, 2000

By A D. Farmer

Power ultrasound may be used in a number of ways to enhance the processing of minerals. It is both technically and commercially feasible to apply ultrasound to leaching processes in order to enhance the removal of contaminating minerals, or the rate and ultimate recovery of valuable mineral. When applied to the production of synthetic rutile from reduced ilmenite produced by the Becher process, its use proved beneficial to both the aeration and the final acid leach process. The enhanced performance is achieved through the very localised high energy release at the mineral surface from the collapse of cavitation bubbles produced by power ultrasound. This gives rise to two effects: initially, the rapid cleaning of mineral surfaces û of oxidation products and coatings of fine adhering gangue minerals û and the attenuation of the boundary layer at the mineral surface during leaching, which allows fresh leachant to contact the surface more readily.

Jan 1, 2000

By M. M. Rajkovich, L. Adams, J. J. Zaluski, S. Gardner

In 1998, Kentuckians for the Commonwealth filed an Administrative Petition with the Kentucky Natural Resources and Environmental Protection Cabinet to designate 8,903 +/- hectares (22,000 +/- acres) on Black Mountain, which contains the state’s highest point, as unsuitable for mining. A fast track legislative process was triggered which could have "taken"100 million tons of coal reserves or, in the alternative, imposed severe restrictions on mining. Even with all parties represented by reasonable individuals, this process can be extremely cumbersome and expensive. The legal and technical preparation for this unusual hearing process as well as issues and strategies of the negotiated resolution are reviewed.

Jan 1, 2000

During conventional eddy current separation, a repulsive force is applied to metallic particles by placing them in a rapidly changing magnetic field generated by a spinning magnetic rotor carrying an arrangement of alternate magnetic poles. This method works effectively for larger non-ferrous metallic objects, such as aluminium cans, but as the metallic particles become smaller, the bulk repulsive force on the particles is increasingly replaced by a rotational torque. Therefore, for small metallic particles it makes sense to use particle rotation, rather than particle repulsion, to effect a separation. Eddy current separators using particle rotation are similar in construction to present separators, but are designed to produce a rotating field of essentially constant angular velocity and field strength. Practical and economic particle rotation eddy current separations are possible down to particle sizes of about 200 ¦m, but separations, at probably uneconomic rates, can be carried out on particles as small as 50 ¦m.

Jan 1, 2000

By H. Möhle

Premier Mine is a large underground diamond mine, situated at Cullinan in the Gauteng Province of South Africa. The mine hoists over 3 millions tons of diamond bearing kimberlite per year, from a modern, mechanized panel retreat block cave mining operation. Troughs sited at the base of the cave are developed into the overlying caved ore, allowing loading access to the ore through draw points. Trough opening is therefore a vital aspect of the mining operation. Most of the production is dependent on fast, reliable and safe trough opening. Successful trough openings are achieved under difficult mining conditions due to restricted void, long up-holes and the inherent properties of kimberlite?soft, elastic rock with a high swell factor. Early in 1998, Premier Mine undertook a joint development project (with an electronic initiation system supplier) to determine whether the use of a fully programmable electronic detonator system would enhance the mining cycle in the trough opening process. Blasting commenced in February 1998, initially with blasts of a similar size and duration to those that had been previously blasted with shock-tube systems, to confirm the operational capabilities of the blasting system. The accuracy, reliability and flexibility of the electronic delay detonators (EDDs) minimized associated risks for re-engineering of the trough opening process. Further, as blast timing was optimized, larger blasts were successfully initiated. To date over 20 troughs have been opened successfully with the use of EDDs. Not only did it take less time to open troughs, but also drilling and blasting operations have been optimized, as well as an overall improvement in safety. This paper details the benefits that EDDs have delivered to Premier Mine in this area. The logic followed is: ?Review of the original trough opening practices ?Re-engineering of the trough opening process ?Implementation of EDDs ?Evaluation of improvements and conclusions.

Jan 1, 2000

By Thomas Lautsch

After a short description of geology and gateroad roof support technology in the German coalfields the development of roof bolting as primary roof support is presented. Based on geotechnical parameters, different strategies used for roof support at depths of 3,300-4,600 ft. are explained. Strict quality management and a strict monitoring program are part of the entry development. A number of recently finished developments are described such as the introduction of standardized bolts and accelerated resin systems. An outlook of future goals is presented. The paper concludes with a comparison of roof control systems at RAG's mines in the US and Germany.

Jan 1, 2000

By Yasuhiro Konishi, Kazunari Mizoe

"This paper describes a new processing of ultrafine, magnetic ferrites from sulfuric acid pickling solution in steel industry. In the ferrite processing, the iron (II) in the pickling solution was first oxidized to iron (III) by using the acidophilic thennophile Acidianus brierleyi. The bio-oxidized pickling solution was treated with solvent extraction to separate the iron (III) into the organic solution of tertiary aliphatic monocarboxylic acid. After that, the carboxylate solutions of iron (III) and other metal (cobalt) were hydrolyzed and precipitated ultrafine particles of crystalline ferrites at l90°C and l. 3 MPa for 20 min.IntroductionHot-rolled steel sheet has always a layer of oxides on its surface. The oxide layer arises as scale in hot rolling processes in steel industry, and the scale consists of the three iron oxides such as hematite Fez03, magnetite Fep4, and wustite FeO. Pickling removes chemically the scale layer that adheres to the steel surface. For normal steels, pickling is carried out in 15-20% hydrochloric acid at 60-70°C or in 20-25% sulfuric acid at 95-100°C. When steel is pickled with sulfuric acid, the scale oxides dissolve to give iron (II) sulfate.Spent pickling solutions are hazardous wastes containing a large amount of dissolved iron (II) and sulfuric acid, e.g., about 40 kg/m3 of dissolved iron (II) at pH 0. In typical commercial processes, spent pickling solution is usually cooled evaporatively to 5°C, and then to 0°C to crystallize iron (II) sulfate as its heptahydrate. After the crystallization operation, the sulfuric acid can be reused in the pickling operation.In this paper we describes a new processing of ultrafine, magnetic ferrite from sulfuric acid pickling solution, in order to recover dissolved iron (II) in the form of a valuable product. In the ferrite processing, the iron (III) was first supplied by the microbial oxidation of iron (II) in the pickling solution, and then the biooxidized pickling solution was treated with solvent extraction to separate the iron (III) into the organic carboxylate solution. After that, the carboxylate solutions of iron (III) and other metal (cobalt) were precipitated crystalline ferrites under hydrothermal conditions."

Jan 1, 2000

By Steve Colbum

LTl’s MapStar LPS (laser positioning system) utilize both tripod mounted and hand held reflectorless distance meters. These are eye safe, easy-to-use, and specifically designed to endure the harsh environment characteristic to the mining, quarry and explosives industries. Survey data collected by the systems is digitally stored in a ruggedized data collector and then processed with a specialized, interactive software program, which can be run on any standard PC. Win Prof, the Windows-based analytical software package is used to reduce the data for generating bench face profiles, surfaces, volumes, estimating true burdens and mining ratio calculations. In addition, the software has many other built-in routines to calculate powder factors, toe shear, to map structural contacts and to predict the flyrock potential based on the Burden to Energy ratios. An extensive, built-in library of explosive’s data facilitates these calculations. It will also conform automatically to user-specified minimum and/or maximum burden in relation to the explosive energy, hole diameter and bench geometry - for both vertical and inclined holes. Numerical data can be represented in 2D or 3D to emphasize the hole-burden-face relationships.In this workshop, the MapStar LPS instruments and Win Prof analytical software will be thoroughly demonstrated. Demonstrations include equipment configuration, typical field setups and several effective survey procedures, including processing of some sample data.

Jan 1, 2000

By Katsukiyo Marukawa, Mashamichi Sano, Shigeta Hara

"Various subject of studies are discussed to develop ·innovative refining processes in the 21st century for cost reduction, production of high quality steel and environmental conservation. The future refining reactor should have abilities of highly efficient mixing and separation of different phases. It is stressed ·that applications of electromagnetic and ultrasound energies, and control of flow fields rate required to create the highly efficient mixing I separation reactor.IntroductionIn recent years, it seems that the research and development in the field of steelmaking has shifted its emphasis to the solidification I ingot-making process in which continuous casting plays the leading role. From a long-range point of view, however, the need for continual development of the refining process will probably increase but is very unlikely to decrease. In order to meet such demands, it is required that problems and issues of the present process should be clearly grasped and that there must be rapid progress in process elements, such as highly efficient mixing and separation of different phases.Applications of electromagnetic and ultrasound energies and flow field control will become important options for resolving the above-mentioned problems. By efficiently and skillfully incorporating these new technologies into high-efficiency mixing/separation reactors, the innovative refining process will be established in the early 21st century."

Jan 1, 2000

By I. J. Wu

China’s land area, comparable in size to United States or Canada, contains diverse geological environments and mineral resource potential. The diversity in geological environments is such that the potential for developing many world-class mineral deposits in China is good. However, China’s mining sector was not open to foreign investment until the1990s. The long-term prospect for Chinese resource development is attractive because of China’s enormous population and cumulative demand for minerals. Approximately 33 foreign mineral companies, including 11 major internationals, are to various degrees active in China. Chinese mining laws and regulations pertaining to joint ventures with foreign companies are, from the international investment prospective, evolving slowly, but positively. This positive trend is continuing under the current government reform process, which is moving China towards a freer market economy. Although improving the enforcement of relevant laws and regulations is an ongoing process, the environment for mineral investment and joint ventures is increasingly more accommodating to foreign companies.

Jan 1, 2000

By R. R. Klimpel

This paper is a summary of the author's industrial experiences on the selection and optimization of flotation reagent schemes for the recovery of gold species. The trends given are a composite of data and experiences gained on 24 different gold ores from around the globe. The primary emphasis is on the benefits of matching the associated gold mineralogy to a reagent scheme most appropriate for that mineralogy. Two general categories are discussed: the flotation of free or native gold species and the flotation of gold associated with a variety of sulfide minerals. Important plant operating factors influencing each of these two categories are presented with supporting examples. Carefully matching reagent chemistry and appropriate operating conditions to any given gold-bearing ore will not only lower the total reagent cost but, more importantly, can lead to measurable increases in gold recovery.

Jan 1, 2000

Distinguished guests ladies and Gentlemen. As many of you know, before I became a Labour Member of Parliament, I had an unusual career path for a politician, in that I spent quite a few years working in the business community. In other words, I was mainstreamed before I was institutionalised. Given that some of this time was spent working for the then Macraes Mining Company Limited, now Gold and Resource Developments NL, I feel that I may have a perspective on how things are seen, on both sides of the fence. In terms of public perception and esteem I am not sure which career option was the step up and which was the step down. So far what I have found very familiar, is that in both roles there is a gulf between the reality and the perception of that reality - a gulf that is both huge and hard to bridge. I think it is a point worth making here amongst another busy industry cluster, that we can all too easily get so embroiled in the day to day activities, that we lose sight of how this might look to those running on a different treadmill. I can still remember scratching my head at the beginning of some days, as I worked to get new mining projects started that I knew were going to bring real jobs and economic benefit to New Zealand, but ending the day feeling like I may instead have been proposing bringing back both strip mining and slavery. If I learnt one valuable lesson out of that time it was this: .... mining has become so publicly demonised on the road to ecological nirvana, that even attempting a lucid dialogue on mining issues, with some, is incredibly difficult.

Jan 1, 2000

By Du Sichen, S. Seetharaman, Wei Liu

"The viscosities of two-phase mixtures are of great importance in the modelling of the fluid flow in metallurgical processes. For example, in steel making and refining, the intimate mixing of metal droplets in the slag phase requires a consideration of the effective viscosities for the mixture. The present work was aimed at an understanding the phenomena underlying the viscous flow in a two-phase mixture with widely differing viscosities.Emulsions of silicone oils of known viscosities (345mPa.S and 1010mPa.S at 293K) with small amounts of water evenly distributed in the same were prepared by subjecting the mixture to uniform stirring using a magnetic stirrer. The viscosities of these emulsions were measured at constant temperature by rotating cylinder method using Brookfield Digital Rheometer. The uniformity of the preparation of the emulsions was confirmed by the reproducibility of the results. Th7 measured viscosities were generally found to be independent of the torque under the experimental conditions so that the two-phase mixture could be considered as a Newtonian liquid. The variation of viscosities with temperature and the effect of addition of a surface-active substance were also studied in this work.The measured viscosities were found to be· higher than those of both pure water and silicone oil. The experimental viscosities were found to increase with increasing concentration of water. The influence of surface tension on the viscosities was examined by adding surfaceactive agent to the mixtures. The result is discussed and compared with theoretical models developed by Einstein, Taylor and Oldroyd."

Jan 1, 2000

By Tsembel Darjaa, Toru H. Okabe, Yoshiaki Umetsu

"With the purpose of extracting molybdenum and rhenium from molybdenum sulfide concentrate; .electrolysis of slurry, solvent extraction and ·precipitation operations were carried out. The slurry of the concentrate in 10 mass% NaCl aqueous solution was continuously circulated into a vertical type 10 stack bipolar electrolytic cell consisted of carbon electrode disks, and, the concentrate was dissolved by electrochemically generated oxidizers at 313 K. The current efficiency for molybdenum dissolution was 73 % after 10 hours electrolysis, and the leach solution was found to contain 0.2 mol/l of molybdenum and 4x10-5 mol/l rhenium. This result shows the dissolution is more than 8 times faster than that obtained using a single cell. The leach solution from electro-oxidation was then subjected to a solvent extraction for rhenium which is then recovered as sulfides. After rhenium separation, molybdenum was precipitated by pH adjustment, and solid MoO3 (H2O)x crystals, free of sulfate, were obtained from the leach solution containing large amount of so42-.IntroductionIn the past, electro-oxidation using a bipolar cell was applied for leaching molybdenite concentrate and ores at U. S. Bureau of Mines [1-3] and also at Bhabha Atomic Research Center [4]. In· these previous studies, Moebious type bipolar cells, in which electrode plates were vertically inserted into the free surface of the electrolyte, were employed and its effectiveness was demonstrated.Recently, the present authors studied on leaching of Mongolian molybdenite concentrate, and the effectiveness of leaching of the concentrate by electro-oxidation in alkaline and acidic NaCl solutions was demonstrated [5]. The leaching reaction during the process can be explained by the 18 electron transfer reaction of molybdenite (MoS2) with the oxidizers produced in-situ by electrolysis of NaCl aqueous solution. Further investigation was made with respect to various process parameters for electrooxidation such as pH, pulp density and temperature of the slurry, and the dissolution behavior of minor elements such as iron, copper, and rhenium [6]. Solubilities of molybdenum in the leach solution at, various temperatures and pH .was · studied, and feasibility of molybdenum recovery by hydrolysis of molybdenum species was demonstrated. By adjusting the pH of the leach solution, molybdenum oxides or hydroxides free from sulfate were successfully obtained from the solution containing large amount of sulfate ion. Rhenium present in the concentrate at a level of several tens of mass ppm was found to dissolve into the leach solution, and co-precipitate with the molybdenum compounds. Rhenium in the leach solutions, therefore, has to be recovered before precipitation of molybdenum, otherwise it is lost in the precipitate."

Jan 1, 2000

By Alfred W. Hefferan

A longwall face conveyor system serves the primary function as all material handling systems; i.e., to transport material between the source and its destination. However, the conveyor system must provide many other functions as opposed to the traditional belt conveyor system. In this paper, we will attempt to contrast the longwall face conveyor system with a belt conveyor system. In addition, the unique problems encountered along with the solutions to these problems will be covered. Table 1 lists the characteristics required of each conveyor system. The table demonstrates the contrast in the two systems. Both must be designed specifically to encounter its unique problems. The balance of this paper will explain how the longwall face conveyor is designed to address its requirements.

Jan 1, 2000

By G. Taylor

A 21st Century worker is one who works less with his physical power and more with mental ability. Such a worker is more skilled than a labourer and is consequently rewarded accordingly. A21st Century supervisor is one who ensures that workers are constantly supported so that they can maximize safety and productivity. A 21st Century manager is one who constantly searches for ways to maximize returns for the various stakeholders. Given the well-known constraints in narrow reef mining, all of the above is meaningless unless a mining method is found which provides conditions which support the 21st Century initiatives. [ ] The identified mining method is a continuous non-explosive stope breaking system using rocksplitter technology. Rocksplitting is defined as: The fragmentation of rock through high energy pulse wave transmission in a fluid-filled hole or hydro fracturing. Shotholes are effectively filled with a water-based geland 30 grams of explosive after which the hole is closed off with a ?rocksplitting gun?.

Jan 1, 2000

By Denis Murphy, James Gusek, Carl Mann, Thomas Wilderman

An active underground lead mine produces water having a pH of 8.0 with 0.4 to 0.6 mg/L of Pb and 0.36 mg/L. of Zn. This water is pumped at the rate of 1.200 gpm into a five-cell, bioreactor system covering about 5 acres. The gravity flow system is composed of a settling basin followed by two anaerobic bioreactors arranged in parallel which discharge into a rock filter polishing cell that is followed by a final aeration polishing pond. The primary lead removal mechanism is sulfate reduction/sulfide precipitation. The discharge has met stringent in-stream water quality requirements since its commissioning in 19%. However, there have been startup and operational difficulties. The system was designed to last about 12 years, but estimates suggest a much longer life based on anticipated carbon consumption in the anaerobic cells.

Jan 1, 2000

By J. W. Slatter

Cast in situ screw piling techniques (both displacement and non displacement) have seen considerable growth in recent years due to competitive production rates, low noise and vibration free installation. However the discussion on the mechanics of auger installation, which has implications on the installation effects and installation forces of screw piling augers, has been almost exclusively targeted towards non displacement techniques and in particular continuous flight augers (CFA). This paper discusses the historical development of the understanding of screw piling auger mechanics in sands and presents a new theoretical model to predict the soil transport and displacement characteristics of both displacement and non displacement augers with variable geometry.

Jan 1, 2000

By M. E. Rossi, V. Camacho

Reconciliation of production information is critical to evaluating the effectiveness of predictive models that would allow for the optimization of mining operations. Whether mining open pit or underground, mine-to-mill reconciliations can be one of management's better tools for the performance of proper accounting. Such reconciliations can also be a very useful tool in evaluation and optimization. This paper proposes a set of criteria and objectives for a typical reconciliation program. This paper also presents a stepwise, logical approach to performing reconciliations and discusses the benefits associated maintaining good information. It also highlights some of the potential pitfalls involved and the methods used to avoid collecting misleading information. These issues are illustrated with an example of a model-to-mine-to-mill reconciliation program that is being implemented at an operating mine. The program involves multiple predictive models (long-term and short-term block models), feed from three open pits and one underground mine, in addition to intermediate stockpiling, for a total of 23 mill streams. This paper presents a summarized version of this reconciliation program and its initial results as implemented at Minera Michilla S.A.

Jan 1, 2000