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By F. A. Steward

Copper is one of the trace minerals essential to life. It is added, usually in the form of copper sulfate, to virtually all formulated feedstuffs and to dietary supplements fed to animals on forage. Over the past five years, an improved inorganic copper source trademarked Micronutrients TBCC™, has been developed, tested and commercially introduced. TBCC is a crystalline form of basic copper chloride. Synthesis is accomplished in a continuous neutralization I crystallization process. In current commercial production, the primary sources of copper currently used as feedstocks are the etching solutions used to manufacture electronic printed wiring boards. These solutions have traditionally been managed as hazardous wastes, but their use to manufacture TBCC™ exempts them from regulation as wastes under the "Use/Reuse" provisions of RCRA. Research conducted over five years at multiple universities has shown that animals are healthier when fed this source of copper and that vitamin losses in feed are reduced by its use.

Jan 1, 2000

By F. Pagliacci

Retaining walls for the construction of underground urban infrastructures have to be executed considering the impact of a deep foundation job-site within an urban network. Traditional excavation systems, based on the use of grabs and bentonite mud, involve serious problems such as: the opening of trenches adjacent to existing buildings; the cleaning of the working area; the site installation for the production and storage of the bentonite mud; the transport and disposal of soil contaminated with bentonite mud. Alternative solutions have therefore been developed in order to overcome these problems. For temporary works soil consolidation methods, combined with the use of sheet piles, have been implemented, by a combination of traditional mixing methods and jet grouting systems to speed up the operations, consequently reducing the construction time. For permanent works two new techniques named respectively CSP (Cased Secant Piles) and CDW (Continuous Diaphragm Walls) have been studied, applied and tested.

Jan 1, 2000

By R. Stenne

This paper presents the trends in deep foundations in Europe, both in terms of design and construction. Eurocode 7 which is a design code for geotechnical engineering will be introduced in the European Union member countries, and will oblige geotechnical engineers to abandon traditional methods based on a global factor and adopt a new approach based on partial factors of safety. Execution codes (for construction of foundations and other geotechnical processes) are currently being introduced without problems. Ever more demanding environmental constraints push foundation contractors to adapt old techniques and develop new ones to comply with new regulations.

Jan 1, 2000

By Masao Miyake, Eiichiro Matsubara, Tetsuji Hirato, Yasuhiro Awakura

"Zn-Cr alloy coating with around 15 wt% Cr has been found to have much higher chemical corrosion-resistance to steel than conventional zinc plating, while· its structure has not been clarified. The Zn-Cr alloy plating is performed at high current densities around 1 A cm-2 and for 10 to 20 sec using acidic aqueous sulfate solutions with some additives in the iron-steel industry. Due to the high current densities, it seems reasonable to consider that the Zn-Cr alloy plating proceeds under an unsteady-state condition and that the resulting coatings have a non-equilibrium phase and have a structure change in the .direction of thickness. In this research, the crystal structure of the Zn-Cr alloy coating electrodeposited at high current densities and change of the structure in the direction of thickness were examined by X-ray diffraction. The coatings containing under 20 and 35-40 wt% Cr had hcp and bee structure, respectively, while the coatings containing 20-35 wt% Cr comprised two phases with the hcp and the bee structure. The structure of the coating varied in the direction of thickness; both the hcp and bcc phases coexisted in the vicinity of the substrate, while the hcp phase became predominant with increasing distance from the substrate.IntroductionRecently it has been reported that Zn-Cr alloy coating containing around 15 wt% Cr has much higher corrosion-resistance to steel than conventional zinc plating.1-3) The corrosion-resistanc·e of Zn-Cr alloy plated steel sheet with a plating amount of 20 g m·2 is, for example, superior to that of Zn plated steel with a plating amount in the range 60 to 90 g m·2 , which is widely used for automotive bodies today.4l The Zn-Cr alloy plating is obtained by electrodeposition at current densities over 0.5 A cm·2 from a sulfate solution containing zinc and trivalent chromium ions and some additives.5•6) The deposition current densities mentioned above are much higher than those for usual electroplating processes, e.g., Zn, Cu and Ni plating, carried out about 0.05 A cm·2 • Therefore, the time required for plating is very short; around 10-20 sec. Due to the high current densities, it seems reasonable to consider that the· Zn-Cr alloy plating proceeds under an unsteady-state condition and that the resulting coatings do not have a phase expected from equilibrium diagrams; no phase diagram of the Zn-Cr system with a full composition range has been available. 7). In other words, the alloy phase plated would be a non-equilibrium phase with unknown structures."

Jan 1, 2000

By Pieter Steeneklm, Mazi’ Rejaee

"EXECUTIVE SUMMARYThe automotive industry's search for increased fuel efficiency through component weight reduction has driven the growth in consumption of magnesium metal in the form of die cast alloys. This trend, which began in North America and should soon accelerate in Europe, will require enhanced recycling services since each tonne of metal used for die cast parts production produces about 500 kg of scrap.Currently, the European die cast market is plagued by very high tolling prices for scrap recycling due to lack of competition and high transport costs due to the distances between the scrap generator and the recycling facility. This situation clearly increases the cost of magnesium die cast components and reduces magnesium's competitiveness with other materials. The challenge for the magnesium industry in the short term is to provide cost ·effective recycling solutions for the die cast industry. In addition effective recycling, in the medium to long term, is needed for the anticipated large volumes of secondary or used scrap that will become available as the die cast components reach the end of their life cycle. This paper will present The Antheus Integrated Magnesium Project as a Novel approach addressing some of the key recycling related issues facing the magnesium industry, in particular the die casters. The paper outlines the many advantages of an integrated magnesium metal park, in an overall goal of increasing magnesium metal's competitiveness."

Jan 1, 2000

By Roger J. Hornberger, Paul F. Ziemkiewicz, Dirk J. A. vanZyl, Gene E. Krueger, Harry H. Posey, Kim A. Lapakko, Charles H. Buckmam

The Acid Drainage Technology Initiative (ADTI) was initiated in 1995 by federal agencies, the National Mining Association and the Interstate Mining Compact Commission to identify, evaluate and develop cost- effective and practical acid drainage technologies. In 1999 ADTI was expanded through the addition of the metal mining sector group, which began organization efforts in 1998. ADTI addresses drainage quality issues involving metal mining and related metallurgical operations and acid drainage from coal mines, for abandoned, active, and future mines. ADTI is a technology development program. It is not a regulatory or policy development program. The guiding principle of ADTI is to build a consensus among industry, federal and state regulatory agencies. ADTI is focusing these efforts on technology development and technology transfer in the areas of mine drainage sampling/monitoring, prediction, avoidance/remediation and modeling.

Jan 1, 2000

"Mining with blast holes drilled upwards may be done to recover sill pillars, or for economic reasons when the distance between the levels is relatively large. If the rock is sufficiently competent to accommodate large stope size, the distance between sublevels could be increased to as much as drilling accuracy allows. The same drill drift can be used for the drilling of both down holes and up holes. In the case of down holes, the initial opening of the stope (drop raise) is not as much a problem as for the inverse drop raise for mining with up holes. This is because, with a drop raise, a lot of space is available at the toe for the blasted rock to expand. In addition, the raise can be blasted in many shots, thus allowing smaller blasts each time. Inverse drop raises are generally much more difficult to blast because of the limited space for muck flow, and must, therefore, be taken down in a single blast, requiring special considerations in order to ensure a success. A case study of a 29 m (95 ft) inverse drop raise successfully blasted in a single shot at Heath Steele Mines is described. The paper covers technical considerations such as drilling accuracy, hole deviation survey, delay extension and protection, initiation methods and initiation sequence. Finally, a novel method for creating the initial opening called ’slot drilling’ is presented. This method, inspired from LKAB in Sweden, consists of drilling a row of interconnected holes using a special guide mounted on a regular production drill hammer.With a case study of blasting an inverse drop raise of 29 m (95 ft) in one blast, this paper further discusses some technical issues that are critical for the development of inverse drop raises. A novel method for creating the initial opening with a slot of interconnected holes is also presented with the experience acquired at different mine sites across the Noranda group."

Jan 1, 2000

By Frank Yu, Bob Fukuhara

"The Stillwater mine is a 3,000 tons/day platinum/palladium underground mine and flotation concentrator located in the Beartooth mountain range in south-central Montana. The site elevation is 5,000 feet above sea level providing a climate with pleasant summers and cold winters. The winters are particularly characterized by very strong winds.The mining methods at Stillwater had been variations of overhand cut-and-fill and some blast-hole stoping. Until construction of the paste back-fill plant, mine back-filling was being practiced using classified hydraulic sand-fill methods. Where higher strengths were necessary, cement was added to the hydraulic fill, however, excessive quantities were necessary due to significant losses with the water drainage from the comparatively low-density fill. There was a need for higher strength back-fill with reduced cement content to augment the hydraulic-fill process.In early 1998, Stillwater Mining Co. commissioned AGRA Simons (then H.A. Simons) in a joint venture with The Industrial Company, TIC, to design and construct a treatment facility to re-process the mill flotation tailing, incorporating the following process alternatives:Produce 100 tph of low strength paste with unconfined compressive strength of 25 to 50 psi,Produce 100 tph of high strength paste with unconfined compressive strength of 100 to 125 psi,Direct all of the excess mill tailing to the sand-fill plant,While no paste is being produced, pump all of the mill tailing to the sand-fill plant,While no paste is being produced and the sand-fill silos are full, direct the mill tailing to the tailing pond.The paste backfill plant was therefore to be designed to produce the two different types of backfill paste as well as have the function of being the distribution center for the mill process tailing .Moderate to high slump pastes would be required because of the comparatively long horizontal transport distances, up to 8,000 feet, and the requirement for a low angle of repose to fill the stope evenly without numerous discharge points."

Jan 1, 2000

By Leticia Rosales Hoz

A chemical and geological study of beach samples from the Mexican North Pacific was undertaken in order to evaluate the chemical composition of the beach sediments and it s association to lithology, climate, topography and weathering. The North Pacific Mexican littoral is characterized by arid weather with wide coastal plains and three geological provinces. The sands from the area are mainly finer, well sorted and show high maturity because of the high wave regime and the high energy conditions produced by the California Current in the coastline. The provenance index reflects that the region has a source of deep seated rocks, now exposed and dissected. Factor analysis made using the chemical composition showed the samples can be differentiated by five factors: 1) SiO2, 2) Al2O3; 3) Cu; 4) Sr and P2O2 and 5) Na content. Samples located in the northof the study area showed the highest values of Fe2O3 (17.72%), TiO2 (2.43%), V (576 ppm) and Zn (141 ppm) associated to methamorphic rocks present in the area.

Jan 1, 2000

By Francis S. Kendorski

Rock reinforcement has been in widespread use and generally has been accepted in underground mining and tunneling since the 1950s. The first rock reinforcement technologies employed were mechanical anchors such as split wedges or expansion shells with 5/8-inch-diameter steel bolts. Failures occurred in weak strata which provided poor anchorage or in ground with corrosive waters. Friction rock fixtures consisting of relatively thin-walled tubes have been in use for about 15 to 20 years. While generally performing adequately, longevity problems have developed from corrosion in water bearing ground Longevity of rock reinforcement is much enhanced with grouted bolts. Portland-cement-grouted rock reinforcement has been in use since the mid-1950s, primarily in funneling and other civil engineering underground construction. Tests of decades-old installations have revealed few problems except in ground with aggressive waters. Polyester-resin-grouted rock reinforcement was introduced in the United states to musing in the late 1960s and to tunneling in the early 1970s. Experience from 30 years of resin-grouted bolt installations and field tests have identified longevity problems associated with degradation of steel reinforcing bars, but in generally unusual situations. Improvements continue in resin chemistries, packaging, corrosion protection, grout quantities, and mixing and distribution in the drilled hole to achieve long-term performance. Specific case histories cited with resin- or Portland-cement-grouted rock reinforcement longevity or performance problems, upon close examination, reveal that the causes of the problems were qualify control procedures being inadequate and not in accordance with good practice. Manufacturers' recommendations and engineering specifications, if followed in the field, and with competent inspection and supervision, would have prevented must, if not all, reported longevity or performance difficulties.

Jan 1, 2000

By Harry Siewert, Tom Milner, Jack Stickney

"LocationThe Gibraltar mine is located in central British Columbia (NTS 93B/9W), 362 km north of Vancouver. Access is provided by 20 km of paved road from McLeese Lake, which lies 45 km north of Williams Lake on Highway 97. Latitude and longitude of the mine are 52° 30' and 122° 16', respectively.The total area of the McLeese Lake site is approximately 1700 ha (4200 acres). This includes the orebodies, dumps, surface drainage collection system, plant site, roads and tailings ponds.Brief Description of OperationOre is mined by open pit methods and is concentrated using conventional crushing, grinding and flotation processes. Copper and molybdenum flotation occurs at an average rate of 40 000 tons per day. Tailing is discharged to an impoundment area and the water recycled as process water. Additional copper is extracted from the waste dumps using sulphuric acid as a leach solution followed by solvent extraction and electrowinning.HistoryExploration by Gibraltar began in 1964, continuing until late 1970, at which time it was announced that the property would go into production. Construction started in early 1971, with initial production in March 1972. Target capacity of 30 000 tons per day was achieved by the end of March and is currently at 40 000 tons per day.Ore reserves as of January 1, 1998 were 184 384 000 tons grading 0.31% Cu and 0.010% MoS2."

Jan 1, 2000

By Mamoru Kuwahara, Tomohito Taki, Masamichi Sano

"Theoretical basis and experimental results on ultrasonic separation of dispersed inclusions from molten metal are outlined. Transitional formation of an ultrasonic standing ·wave field in a liquid bath is numerically predicted based .on the wave equations. Numerical solution of the equation of motion of a fine particle in a standing wave field indicates that the inertia term can be neglected during conventional ultrasonic separation of fine particles: Analytical solutions for the position at which particles are coagulated the minimum power for separation, and the ultrasonic separation time are derived to incorporate such key process parameters as the density difference and the acoustic energy density exerted. Cold model experiments have been carried out to observe ·transitional coagulation of polystyrene particles in an aqueous sugar solution with the incidence of standing ultrasonic plane wave. Experimental results agree well with the theoretical predictions.IntroductionDespite of recent progress of fundamental and applied researches in metallurgical systems, advanced materials· with less inclusions and better properties may demand more innovative processing in a: molten state. It may be realized by applying electromagnetic and/or ultrasonic external fields to the systems. The present authors1)·2) have been proposing : new methods of ultrasonic processing of materials based on such phenomena as acoustic streaming, acoustic radiation pressure on dispersed phase in a standing wave field, and the cavitation in liquid associated with use of high-intensity ultrasound and so on. Taking account of common physical natures between ultrasound and sound wave, we call such · a processing assisted by acoustic wave as ""sonoprocessing"". This report ·deals with some theoretical and technological aspects on the ultrasonic separation of fine particles from liquid, which could become an important operation to produce clean materials. Fundamental theory and ·supporting experimental results will be given below to give an insight into the liquid metal sonoprocessing."

Jan 1, 2000

The Kunwarara magnesite deposit is the largest known magnesite (MgCO3) deposit in Australia. It is located under black soil plains to the north of Rockhampton in Queensland. The deposit consists of magnesite nodules set in a fine-grained sandstone, siltstone and mudstone matrix. The magnesite is derived from weathering of serpentinite in adjacent hills and transport of magnesium in solution to a Tertiary/Quaternary river system. The magnesium has come out of solution in the active river system, and combined with atmospheric and biogenic CO2 to form magnesite nodules. The magnesite can be very pure with certain varieties up to 98 per cent MgO (LOI free). The deposit has been mined since 1991 and processed into magnesia (MgO) which is sold into refractory, agricultural and other markets. The geologist is an integral part of the small mine technical team. The role of the geologist includes characterisation of the ore through drilling and bulk sampling, supervision of geological aspects of mining and assistance in the optimisation of ore processing.

Jan 1, 2000

By G P. J Dijkema, M A. Reuter

From a material cycles perspective all processes are interconnected and consequently a process can never be evaluated as an isolated and independent unit. This also holds true for the evaluated co-incineration options. Environmental and sustainability issues for example, such as raw material and energy utilisation or air pollution, are a resultant of the whole system of industrial activities. It is therefore important, not to optimise a single process or industrial activity, but rather the whole system. Although engineering procedures for the design of individual industrial units are well developed, the problem of determining the best arrangement of these interconnected units is often far more difficult. Regulation that manages the arrangement of the units for waste processing is still under construction. In the evaluation of co-incineration, analogous principle from process control can be used: feedforward control. This principle includes the determination of which outlets can be used for all process outputs, hence avoidance of any æunusableÆ products or wastes possibly arising from co-incineration. To establish the extent, to which produced wastes are usable, a system overview is necessary, in addition to in-depth information on the subsystems, which produce and can consume wastes. Material cycles modelling can be used as the basis for a tool that supports the development of a suitable playing field. It should provide overview of the system and in-depth information on its subsystems. This tool then represents an attempt to bridge the gap between æholisticÆ industrial ecology and process engineering.

Jan 1, 2000

By D R. Swinbourne

In the recent past a number of smelting plants were commissioned in India to supply the rising demand by domestic steelworks for manganese-based ferroalloys, and they enjoyed cheap electric power and readily available high-grade manganese ore. Presently, the cost of electric power is much higher than in some neighbouring countries, there continues to be poor transport infrastructure and the prices of high-grade manganese ore have increased. Additionally, the Indian Government has opened its economy to the outside world, resulting in the import duties on ferroalloys being drastically reduced. In this paper the current situation in India will be detailed, the electric arc furnace and blast furnace smelting methods for ferroalloys compared and proposals for the construction of a new ferromanganese blast furnace in India outlined. The future of ferroalloy smelters in India will be assessed and actions which could be taken to improve their position discussed.

Jan 1, 2000

By K. Saikiran, A. R. Nalla

Longwall management, regular shield maintenance, and evaluation of ground control problems can be performed using real-time shield monitoring program. Based on real-time shield pressure data, evaluation of intensity and interval of periodic weighting, estimation of time-dependent pressure increase and the effects of geologic anomalies can be obtained. In this study, full-face shield pressure data of over 457 m (1,500 feet) of face advancement is analyzed to evaluate shield response in the presence of surface lineaments, floor undulations, and multiple main roofs. Shield pressure increase due to web cutting is also correlated with setting pressure during periodic weighting and normal time. In addition, time-dependent pressure increase rate on Sundays and holidays is also correlated with time average pressure and the location of previous periodic weighting.

Jan 1, 2000

By Kirstin Girdner, Tom BoBo, Brian Norton, John Kemeny

Split Engineering is a truly customer oriented company dedicated to providing quantified fragmentation information of the highest integrity to enable process management and control. Technical decisions, blasting costs, operational efficiency and productivity and equipment performance can all be related to optimum fragmentation. In the past, the lack of an easy, non-disruptive, economical measuring technique has meant that, in most cases, rock fragmentation has not been defined in quantitative terms. Now, the Split-Desktop@ software provides an economical alternative to manual sampling and screening and an objective measure rather than subjective qualitative estimates. This workshop will present the latest features of the Split-Desktop@ software and show users how to quickly get quantifiable results from their blast fragmentation. A step-by-step demonstration will display the software’s flexibility, user-friendly options, and ease of use. Outlining where other mines have benefited from using the Split-Desktop@ software will provide insight to a wide range of software uses and potential applications like creating a database of geologic zone specific post-blast fragmentation information, underground draw point monitoring, stockpile, leach pile, and waste dump size measurement and monitoring, as well as many other applications.

Jan 1, 2000

This is a sampling of the papers presented at the conference, the proceedings can be bought from the SAIMM The technique reported here involves measuring the air pressures generated within sealed boreholes located behind blasts. Results from twelve free face blasts in competent rock environments a represented. There were no instances of high pressure gas penetration, even at distances corresponding to less than one blast burden. Rapidly generated underpressures were measured in most holes, with the magnitudes of the peak pressures decreasing with distance behind the blasts. It has been proposed that the under pressures are the result of new volume created due to crack formation and overall rock mass dilation. The experimental evidence is consistent with this, including a correspondence of the onset times of the peak underpressures with the nominal firing times of the nearest blastholes. New post-blast cracks were observed when using borehole video cameras in the monitoring holes. A calculation of new volume produced within the monitoring holes is proposed as an indicator of damage. While the data exhibit considerable scatter, there is a power function dependence on scaled distance, which resembles that of typical vibration data. The data also lie within the normally quoted vibration regimes for rock damage and are consistent with measured extents of damage. It is concluded that this technique may provide an inexpensive and practical comparative measure of near-field rock damage due to blasting. It is further concluded that gas penetration is not a common phenomenon. Damage appears to be mainly attributable to the nearest blastholes and the control of charge mass in perimeter blastholes is emphasized for damage minimization.

Jan 1, 2000

By C. Allen

A series of zinc chloride electrowinning tests was carried out in a laboratory scale cell to evaluate the effect of temperature, current density, electrolyte composition, gas sparging and additives on the performance of the cell with respect to current efficiency, voltage, specific energy consumption and deposit morphology. The anode material was DSA for chlorine evolution and the cathode was made of aluminum. At 400 A/m2 current density, a current efficiency of 90.9%, a voltage of 3.4 V and an energy consumption of 2.78 kWh/kg were observed. Air sparging was found beneficial but was not pursued for health and safety reasons. Various additives in the same chemical family as tetrabutyl ammonium chloride (TBAC1) were tested. Both TBAC1 and tetrabutyl ammonium bromide were found to be equally effective. Attempts to carry out the electrolysis at 1200 A/m2 were not as successful.

Jan 1, 2000

By M. Krishna, Jayagopal Uchi1, Shanta Sastry, B. M. Satish

"A well-considered composite of ZA-27 reinforced with weight percentage 0, 2, 4, and 6% of alwninite particulate has been made by compocasting technique. The elastic properties of ZA- 27 /alwniniute particulate composite were determined by using U1M. The results showed that the modulus of elasticity and UTS of the composite gradually increases with increase in the wt.% of reinforcement. However, the overall ductility decreased monotonically with an increase in reinforcement. The results of these tests· as well as the predictions of several model~ for composite strengthening available in the literature were compared with experimental results. The data observed from Young's modulus by measurements studies were compared with theoretical results predicted by Eshelby model.IntroductionMetal matrix composites (MMCs) have received increasing attention in _the recent decades as engineering materials. The introduction of a ceramic reinforcement into a metal matrix produces a composite material resulting in an attractive combination of physical and mechanical properties that cannot be obtained with monolithic alloys. Particulate reinf9rced MMCs among the discontinuously reinforced MMCs have attracted quite a lot of attention both in the industrial sectors and the academic communities. There is an increasing need for knowledge about the processing techniques and mechanical behavior of particulate MMCs in view of their production getting enhanced and their commercial applications becoming wider [I]. Interest in particulate reinforced MMCs is mainly due to easy availability of particles and economical processing techniqu"

Jan 1, 2000