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By Zhijing Zhang

Long-term thermal stability of ionic liquids is essential for reliable performance of ionic liquids in any engineering applications. TGA studies were carried out on a series of ionic liquids with different cations and anions such as 1-butyl-3-methylimidazolium chloride ([C4mim]Cl), 1-hexyl-3-methylimidazolium chloride ([C6mim]Cl), 1-hexyl-3¬methylimidazolium tetrafluoborate ([C6mim]BF4), 1-hexyl-3-methylimidazolium hexafluorophosphate ([C6mim]PF6), 1-octyl-3-methylimidazolium hexafluorophosphate ([Csmim]PF6), and 1-butyl-3-methylimidazolium bis(trifluromethanesulflonyl)imide ([C4mim][Tf2N]). The short-term thermal stability of ionic liquids was evaluated by measuring the onset temperature of decomposition of ionic liquids, and the long-term thermal stability of ionic liquids was also evaluated by weight loss of ionic liquids over a long period of time at various temperatures. The experimental results showed that the long-term thermal stability of ionic liquids decreased with increasing temperature and was significantly lower than the onset temperature of decomposition of ionic liquids.

Jan 1, 2002

By J. Eldridge, A. J. Carter, D. N. Leavell

Minpro International has developed an innovative, flexible¬shaft impact crusher that produces glass aggregate from mixed¬color, post-consumer glass. The crusher operates with low power and generates a subangular aggregate, with minimal fines. Output is screened to yield sized aggregate, which can be used directly as surfacing material in Owens Corning's shingle process. Metal, plastic and paper waste is preferentially removed by the Minpro system. Duval County and the City of Jacksonville collect more than 12,000 tons of glass bottle waste per year. It is anticipated that a successful end-use application by Owens Corning, will allow increased collection and cost-effective glass recycling in north Florida.

Jan 1, 2002

Current models for the origin of banded iron-formation (BIF) derived in situ iron ore deposits assume that the typical chert and iron oxide banded BIF is the primary rock from which enriched iron ore deposits arise by the selective leaching of quartz and the residual accumulation of the iron oxides. Weathering extends to the base of all the hematite deposits of the Hamersley Province, which lie within the saprolitic weathering zone, as shown by the preservation of the primary textures, and are overlain by a hydrated goethite zone representing the solum. Since groundwater typically contains dissolved silica, derived from the hydrolysis of silicate minerals, greatly in excess of the saturation solubility of quartz, it is incapable of removing quartz from below the watertable, and quartz is preserved in all saprolites derived from quartz bearing rocks. Quartz may be dissolved in the solum due to the influx of meteoric water having little or no dissolved silica, but soil-forming processes that dissolve quartz likewise alter the oxides by hydration and transposition with consequent destruction of primary textures, and there is no suggestion of soil-forming processes having produced the deposits, which typically extend to considerable depths below the water-table. A characteristic feature of the typical hematite orebodies is the unaltered nature of the iron oxides in the ore compared to those in the adjacent cherty BIF. Although the solubility of ferric iron at >10 ppb is much less than quartz, any process capable of dissolving the huge volume of quartz must also affect the iron oxides, but evidence of this is completely lacking in most ore deposits. Hydrothermal alteration at Koolyanobbing in the Southern Cross Province affects both cherty BIF and ore, and clearly shows equal mobilisation and recrystallisation of hematite within quartz/hematite veins and in the surrounding cherty BIF, which shows no evidence for the selective leaching of quartz. Similarly, any metamorphic process capable of removing all quartz from BIF would leave characteristic evidence in the remaining oxides. However, a hydrothermal process may account for at least portions of certain ore deposits, in which the chert bands have been replaced by carbonates at comparatively low temperatures, to produce a quartz-free magnetite/ carbonate rock that is readily upgraded to high-grade ore by supergene dissolution of the carbonates. This process is interpreted to have formed high grade ore at Mt Gibson, Koolyanobbing æAÆ Deposit and Mt Tom Price North Deposit. In addition to carbonate replaced cherty BIF at Mt Gibson in the Murchison Province, there are extensive sequences of magnetite BIF without chert bands, and this chert-free facies of BIF is interpreted as the precursor to the majority of in situ hematite ore deposits, through oxidation and weathering of magnetite and iron silicate and carbonate minerals. The world-class martite/microplaty-hematite deposits of the Hamersley Province are a special case of BIF-derived iron ore deposits that were initiated during the Proterozoic era. Evidence from overlying Wyloo Group conglomeratic horizons containing clasts of Hamersley Group BIF indicates that microplaty-hematite formed within the clasts before deposition, and that Proterozoic subaerial oxidation and weathering of uplifted Hamersley Group formations produced the microplaty-hematite in both chert-free and cherty BIF.

Jan 1, 2002

By Karl A. Gschneidner

The magnetocaloric effect has been known for 120 years and has been utilized for cooling about 70 years. But in the last four years significant advances have been made to show that magnetic refrigeration is a viable and competitive cooling technology. Most of the work has focused on reciprocating devices, but rotary apparati are being developed. To date the magnetocaloric properties have been characterized for more than 200 materials. The magnetocaloric effect behaviors have been classified into three types of behaviors. The most common one is found in magnetic materials which exhibit a second order magnetic phase transition. Magnetic materials which exhibit a first order magnetic phase transition account for the second group of materials. Materials which exhibit multi-magnetic phase transitions make up the third group. The best candidate materials for magnetic cooling over the range from -4 to -1 350 K are also presented.

Jan 1, 2002

By B, J Bianchini, N Voermann, C Crowe

Operational and economic imperatives in the metallurgical industry have led to numerous advancements in furnace design. Modern furnaces provide high production rates, high percentage online time, long campaign life between rebuilds and safe operating conditions. Current trends for maximising plant efficiency include increasing the throughput of existing process vessels (often by a factor of two or more) and the use of newer, highly intense processes. In both instances, the process intensity results in the generation of higher heat fluxes to the crucible walls. High-intensity furnace operation with the objectives mentioned above has become possible with the following furnace design features: Strong sidewall cooling systems, using copper coolers, to accommodate the high heat fluxes encountered while protecting the crucible refractories; Robust, spring-loaded furnace horizontal and vertical binding systems which maintain tight brick joints through-out all stages of operation; and Well-designed, intensely cooled tapholes for metal, matte and slag. The integration of these features along with properly selected refractories, appropriate instrumentation systems and efficient water-cooling systems is also highly critical. These design features have been successfully implemented in electric smelting furnaces, flash smelting and converting furnaces (Outokumpu and INCO types) and lance injection furnaces (Mitsubishi, Ausmelt and Isasmelt types). This paper will discuss design aspects and operating results for several installations.

Jan 1, 2002

By M. M. Rajkovich, L. Adams, J. J. Zaluski, S. Gardner

In 1998, a group called Kentuckians for the Commonwealth filed an Administrative Petition with the Kentucky Natural Resources and Environmental Protection Cabinet to designate 8,903± hm2 (22,000± acres) on Black Mountain, which contains the state's highest point, as unsuitable for mining. A fast track legislative process was triggered that could have "taken" 91 Mt (100 million st) of coal reserves or, in the alternative, imposed severe restrictions on mining. Even with all parties represented by reasonable individuals, this process can be extremely cumbersome and expensive. The legal and technical preparation for this unusual hearing process as well as issues and strategies of the negotiated resolution are reviewed

Jan 1, 2002

By Michel Bustamante

The occasional substandard performances of continuous flight auger in particular soil conditions have prompted the drilling rig manufacturer to improve the standard CFA in order to reduce its negative effects. A real improvement of interest was the launching of the double rotary CFA system. The promising features of the latter have incited the authors to implement an extensive experimental research on pile constructed using this type of technique but in the specific context of cohesive soils. Short-term static load tests were carried out on a total of 9 test piles of various installation techniques in order to compare the respective performances. The promising features of the double rotary CFA have incited the LCPC & Durmeyer Company to implement an extensive experimental research on this type of pile technique but in the specific context of cohesive soils and more particularly in clayey marls. After load tests completion the research has been completed by an excavation of the double rotary CFA piles. All the collected data concerning the implemented program are reported.

Jan 1, 2002

By K. A. Lapakko, D. A. Antonson

Fourteen samples of pyrite-bearing Archean greenstone rock (d < 6.35 mm, 0.04% < St < 1.22%) were characterized (particle size, chemistry, mineralogy) and subjected to laboratory dissolution testing. The only sulfide and carbonate minerals identified were pyrite and siderite, respectively. Quartz, chlorite and sericite typically comprised 90 to 98 percent of the mineral content. For the first 60 weeks, seven samples with sulfur contents less than or equal to 0.16% produced drainage pH values exceeding 6.0. Over this period, six of the seven samples with sulfur contents greater than or equal to 0.20% produced drainage pH below 6.0, with minimum values ranging from 3.2 to 4.7. The seventh sample (0.72% S) had a siderite content of 18%. Small amounts of magnesium and, to a lesser degree, calcium carbonates present in the siderite apparently dissolved to neutralize acid and maintain drainage pH above 6.0. Sulfate release rates generally increased as sulfur content increased, and the rates of pyrite oxidation estimated for individual samples were roughly half to five times that reported in the literature for the abiotic oxidation of pyrite by oxygen. Observed neutralization potentials ranged from 0.2 to 2.0 g CaCO3/g rock.

Jan 1, 2002

By Julián Ortiz C., Clayton V. Deutsch

Indicator simulation allows specification of different continuity of high and low values through the use of grade thresholds. The sequential implementation of indicator simulation has been widely used, but the problem of order relation deviations remains a significant drawback. A new procedure for "Hierarchical Indicator Simulation" is introduced that avoids order relations and offers greater flexibility than the conventional sequential approach. The new implementation simulates all locations at the largest threshold and then considers decreasing thresholds in turn. All nodes with grades that are above the previous threshold are excluded from the domain of the current threshold and therefore, they are not used as conditioning data. The probability of being above or below the threshold is calculated using simple indicator kriging using all conditioning data in the domain, thus the covariance structure is preserved. The theoretical framework of this new approach is fully developed. Practical implementation details are discussed. Application to a copper deposit shows the advantages and drawbacks of the method. Finally, the possibility of incorporating multiple-point statistics is discussed.

Jan 1, 2002

By S. M. Pickering

Banks frequently manage large privately owned mineral land trust accounts for estate heirs. The bank has a fiduciary obligation to follow the “Prudent Man Rule”, which requires that trust properties be managed at least as well as a prudent and knowledgeable owner could. However, banks may not have internal staff proficient at mineral property values, lease contracts, royalties, mining practices, etc. This is an opportunity for experienced geologic consultants and certified minerals appraisers to provide needed help. Items valuable to Trust managers may include: 1. Marketing privately owned mineral trust lands to mining or oil & gas firms, assuring competitive offering prices and terms; 2. Negotiating favorable new mineral lease and purchase-option contracts; 3. Monitoring progress of mining, royalty payments, land reclamation, and environmental clean-up work; 4. Balancing future mining income with later industrial, commercial or housing development, timber harvest, etc.; 5. Assuring that Depletion Allowance tax advantage is taken for actual mine royalty payments, but not for annual non-mining lease (rental) income; 6. Appraising in-ground mineral value for bank audits, estate tax valuations, and equitable property division between heirs; and 7. Serving as expert witness, representing the legal interests of the bank, trusts, and the mineral heirs in litigation. Banks do welcome reliable advice which assists them in achieving the “Prudent Man Rule” and improving mineral income to their land Trust accounts.

Jan 1, 2002

About 90 per cent of the pre-mining BIF-hosted iron ore resource of the Hamersley Province of Western Australia is of the Phanerozoic supergene martite-goethite type. The remaining ten per cent formed as supergene deposits at ~2000 ¦ 200 Ma, and were later modified by burial to form the Proterozoic martite-microplaty hematite ores. The supergene-metamorphic segment of this general unified model has been challenged by three recently published hypogene-based genetic models for the hematite ores, all requiring meteoric oxidation to produce the ore. The most recent and detailed, by Taylor et al (2001), is based on data from the small Southern Batter and North deposits of the Mount Tom Price mine. The authors proposed that during Stage 1 æoverpressured bicarbonate-saturated basin brines from the dolomite aquifer of the Wittenoom FormationÆ at 150 - 250¦C, dissolved free silica from BIF to produce a stratigraphically thinned, magnetite-carbonate-silicate-apatite rock. In Stage 2, meteoric oxidation of siderite to secondary microplaty hematite + ankerite, and magnetite to martite, at unspecified elevated temperatures and pressures, was followed by carbonate leaching (Stage 3). Finally, during Stage 4, weathering with removal of apatite, produced the typical low-phosphorus, porous martite-microplaty hematite ores of the Tom Price-Whaleback type. However, evidence of both microplaty hematite and martite reduced to magnetite, and of infill silica, apatite, and ferroan chlorite, with late-stage pyrite, in the pore space of martite-microplaty hematite ore, shows that the hydrothermal activity at Mount Tom Price is a post-ore event. Neither pyrite nor ferroan chlorite could resist the oxidation required to form hematite ore. Recrystallisation of microplaty hematite in these infilled zones to a typically coarser form than present in most of the normal ores, is a further supporting factor. A more credible, post-ore alternative to the hypogene genetic model is suggested here. Re-exposure to leaching by ground water of the metamorphosed ore deposits in the Phanerozoic resulted in the partial removal of remnant goethite. Localised modifications in the porous BIF/ore contact zones were driven by exothermic oxygen/pyrite/carbon reactions in the footwall Mt McRae Shale. Cool descending oxygenated meteoric water in the permeable ore horizons, acted as one limb of a thermal convective cell. In the other limb, heated reducing solutions rose through the permeable contact zones, to produce the observed localised modifications of BIF and ore. Expelled silica from the carbonatised BIF invaded adjacent porous ore to form erratic silicified ore zones, and to produce the local quartz vein systems found in the associated overlying BIF.

Jan 1, 2002

By Denis Huber

The technical assessment of the final works on the "Stéphany Palace" project at Menton in France&apos;s Alpes-Maritimes region shows the importance of daily project monitoring based on the observation method recommended by the European standard Eurocode 7 which applies to Foundations and Geotechnical Engineering. Excavation operations to a depth of 10 m near the France-Italy railway track and adjacent buildings required precise observation of land deformations, regular piezometric monitoring as well as special design arrangements. Temporary active tie-rods were thus placed in phases in order to control deformations in the retaining structures resulting from excavation operations. The Menton region, terminating the Alpine arc of mountains, naturally required the consideration of seismic forces in phase in the lower floors of the building, directly linked to the buried walls. These calculations were carried out in accordance with the PS69/92 rules, calling for an increase in dynamic thrust under the effect of gravity field rotation.

Jan 1, 2002

By Khaled Morsy

Longwall mining is one of the most widely practiced underground coal mining method. The behavior of the longwall gob is very critical in the understanding of the complex ground response to longwall mining. In the limited data available, the values of gob moduli used in numerical modeling ranged from 1,000 psi to over 300,000 psi. Such a wide variation in moduli would greatly affect the results of the numerical analysis. A better understanding of the behavior of the gob will allow numerical models to be more accurate for simulating longwall mining conditions. In this study, a gob model based on the Terzaghi&apos;s model was incorporated into the comprehensive finite element package, ABAQUS, to simulate the loading behavior of longwali gob material. A case study was used to verify the proposed gob model.

Jan 1, 2002

By Hector M. Henao

To provide thermodynamic data for converting nickel matte to liquid nickel at high temperature, an experimental study was conducted on the phase equilibrium between the Ni-S alloy and the FeOX-SiO2, FeOx-CaO, and CaO-A12O3 base slag in a magnesia crucible and the CaO-Al2O3-MgO slag in an alumina crucible. All experiments were carried out at 1773 K under controlled pso2 of 0.1 atm and po2 in a range between 5x10- and 10-5 atm by using CO-CO2-SO2 gas mixtures. The dissolution of nickel in the slag was found to be minimum for the CaO-Al203¬-MgO slag with a molar ratio of NCaO/NA1203=1.7. The solubility of nickel in this slag at p02 of 6x10 atm (just before the precipitation of solid NiO) was 4 mass%. This result suggests that a CaO-A12O3 base slag could be used in converting Ni-S melt to nickel while minimizing nickel losses to the slag.

Jan 1, 2002

The Pongkor Gold Mine employs 678 staff. The mine is owned by the Indonesian state company PT Antam Tbk and is located 100 kilometres south west of Jakarta, in Java, Indonesia. Mine and infrastructure development started in 1992 following intensive geological exploration over 15 years. First gold production was in June 1994. The mine comprises three main orebodies: Ciguha, which is nearly mined out, dips at 75¦ from surface to 150 m. Kubang Cicau, dipping at 80¦ from surface to 230 m, and averages 3.5 metres thick at a grade of 10 g/t Au and 128 g/t Ag; and Ciurug, dipping at 60¦ from surface to 300 m and averages eight metres thick at a grade of 14 g/t Au and 172 g/t Ag. Present global ore reserves are 4.6 million tons at a grade of 12.3 g/t Au and 133.6 g/t Ag. Exploration is continuing for new veins. Initial mining was by manual cut and hydraulic fill at Ciguha, followed by Kubang Cicau. In 1996, it was proposed to convert Ciurug to a mechanised cut and fill operation. Two single boom jumbos and three load-haul-dumps (LHDs) were purchased with the assistance of a gold loan from NM Rothschild and Sons. Implementation of this upgrade was delayed by both a national economic crisis and an invasion of the concession by illegal miners. It was not until May 1999 that raise bore vent rises and access drift infrastructure commenced. Major underground development started in 2000 and is continuing. Production cut and waste fill stoping started in July 2001. The change from manual to mechanised methods has required a total change in work practices and attitudes. However, the process has resulted in a production increase from 600 tpd to 1200 tpd. A three-month compliance test (a condition of the financing loan) was successfully completed, from July to September 2001, with an average production of 700 tpd at Ciurug and 500 tpd from Kubang Cicau.

Jan 1, 2002

By B. Simser

At Brunswick Mine, an increase in the number of seismically-related falls of ground and in particular rockbursts occurred during 1999. This was due to the ever-increasing stress levels in the remaining ore reserves, mining in difficult highly stressed areas and in particular troublesome geological features. In conjunction with the Noranda Technology Centre, development of rockburst support systems started at the Brunswick Mine in 1996 and efforts were accelerated in 1999. A support package consisting of #6 gauge chain link mesh, #0 gauge heavy mesh straps, and a 1 m by 1 m pattern of modified conebolts was developed. The conebolts were modified to enable mixing of the resin anchoring. Two major rockbursts occurred during an intense seismic episode at the Brunswick Mine from October 13th to 17th , 2000.The area was evacuated approximately four hours before the first burst hit, and remained closed during the seismic ?flurry??. The first damaging activity occurred around midnight on Friday the 13th, and a second damaging episode occurred on the 17th that included a local Richter Magnitude 2.7 event. The second rockburst had dimensions of approximately 5 m by 5 m by 20 m or 2150 tonnes of massive sulphide material (density 4300 kg/m3). The first failure area was more extensive, caving approximately six metres of an intersection back with the lateral extent not safely measurable. This paper briefly describes the mining conditions that led to the bursting, the seismic response of the region, the mechanisms thought to have caused the bursts, and a yielding support system which had been partially installed before the burst.

Jan 1, 2002

By K. N. Han, N. S. Kim, H. Yoon, J. S. Sohn

The leaching behavior of silver and silver oxides in ammonical solutions has been studied. The current study is concerned with an effective recovery of silver from secondary sources such as spent silver batteries. Silver associated with these batteries appears in various forms including metallic silver, argentous oxide, Ag2O and argentic oxide, AgO. The leaching behavior of metallic silver in ammoniacal solution has been studied using an electrochemical mehtod. Oxidants used in this study include hyperchlorite, hydrogen peroxide, bromine and iodine. Results on cyclic polarization and Tafel plots on the silver anode in ammoniacal solutions are presented and the results are discussed. The dissolution rate of metallic silver in ammoniacal solutions is also compared with those of silver oxides.

Jan 1, 2002

By Selamet G. Ercelebi, Mahmut Yavuz

An inherent aspect of longwall mining is moving the equipment from a mined-out panel to a newly developed panel. Moving times may be reduced by detailed preplanning. A very useful tool for planning is MS Project. Using MS Project, one can efficiently plan, manage and coordinate a project from conception to conclusion. The critical path analysis identifies potential critical activities which may cause excessive time delays. Changes to the tasks on the critical path can have significant impact 0.n the completion of a project. Assigning additional resources to these tasks (either moving labor from other tasks to critical tasks or providing labor overtime work) may reduce the move time. Simultaneous activities are the candidates for moving the labor from an activity to another. Each time a change is made, the critical path should be recalculated. MS Project quickly recalculates schedules and lets you see how changes in one part of the project will affect the overall plan. In this fashion it is possible to minimize the longwall move time.

Jan 1, 2002

By D. J. Leidel

The offshore production of oil and gas resources has been active in the Gulf of Mexico since Kerr- McGee drilled the first commercial well out of the sight of land in 1947. Since then, approximately 60% of the offshore oil/gas production structures used globally have been erected in the GOM to support the production of energy resources’. The shallow, shelf and shelf edge waters of the Gulf of Mexico have reached or are rapidly approaching production maturity, requiring that the fixed structures used to support energy production be removed or otherwise disposed of by suitable means. The use of energetic materials has been determined to be a safe, efficient and cost effective technology to remove fixed offshore structures whose service life has been exceeded.

Jan 1, 2002

By Maral Papazian Bedian

Construction contracts in the USA contain the clause "Value Engineering" ? an interesting and curious clause allowing contractor initiated design changes. Misleading is the interpretation of value engineering implying cost saving and sharing with the owner, and curious is the timing, just before beginning of actual construction. It is not surprising that such a clause would simply be ignored, because it involves change, often major design changes in very short time; and change is feared, moreover, it is vehemently resisted by all parties, owner, designer, contractor. The problem in the USA may lie in the divergence and separation of the two entities: Designer/Engineer and Builder/Contractor, assigned to the "one" engineering project. The priorities and incentives of these two groups are very different. The Engineer spends years, even decades, in design and prepares contract drawings often without a deep understanding of construction methods. Worse, with all the time available to him and in our era of tremendous advances in computational methods and speed, the designer turns in plans that are inexcusably exaggerated code-based design with excessive safety factors. As to the Contractor, he builds, often without appreciation of design principles or regard for design engineers. Redesign to apply a new technology or optimization of an inferior design just before construction becomes unthinkable. It is not surprising that adverse and hostile relationship between the designer and the contractor is a norm with extended disputes and claims, not to mention the cost these entail. Surprisingly, "Value Engineering" was successfully implemented in record speed on several very large projects in the metropolitan New York area. The process of change was unconventional, painful, and even comical. Four case studies are presented: two Design/Build: the 1.2 billion dollars Hudson-Bergen Light Rail Transit System in New Jersey and the 90 million dollars MTA Bus Depot in Manhattan, and two Conventional Design/Bid/Build: the 90 million dollars Queens Boulevard Bridge and the 150 million dollars Long Island Expressway.

Jan 1, 2002