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By K. N. Han

Copper and nickel are extracted from their elemental state, complex sulfides, ores, and other materials such as scrap by leaching them with a solution containing halogen salts - bromine/bromide, and/or iodide/iodine, oxygen and sodium or potassium nitrate. This US patented process is extremely effective yielding 98% recovery in15 minutes for the treatment of chalcopyrite and pentlandite in an autoclave at a temperature of 100°C - 150°C.

Jan 1, 2003

By Zdzistaw MiGzkowski

At KGHM Polska Miedi S.A. a direct flash smelting process is used for smelting of chalcocite concentrate for the production of blister copper. The paper presents a model of complex oxidation process of single concentrate grains smelted at KGHM. The description covers main chemical reactions, phenomena of heat and mass ex-change inside the grains and between a grain and the surrounding space. In the model, two zones describing the course of process inside the grain were distinguished: ? The first one, which moves faster towards the centre of a grain, both organic and carbonate carbon are freed. The process takes place without the presence of oxygen and results in an increase of the temperature in the core of the particle. ? The second zone moves slower into the grain and the rate of the movement is deter-mined by the presence of oxygen. In that zone the sulphur is eliminated and the oxidation of the organic compounds vapours moving from deeper layers of a grain takes place. Based on the results of laboratory tests, the coefficients that describe the oxygen transportation into the grain and decide the progress in the chemical reaction were determined. The paper contains the results of model calculations for single grains reacting in environment of various content of oxygen as well as the results of model calculations for the laboratory reactor system.

Jan 1, 2003

By V. Avzian Belozersky reg 453524, Vasily V. Lodeischikov, Adolf F. Panchenko, Til E. Vidusov, Olga D. Khmelnitskaya, Vladimir E. Dementyev

"Presently, there is a number of gold deposits which cannot be developed using the conventional technologies with acceptable economic indices due to low gold content, high depth of ore occurence and other conditions. For such ores, an innovation technology of underground gold leaching in the place of their occurrence is of special interest. The technology excludes ore mining and hoisting to the surface. This enables the production cost of 1 g of gold to be considerably reduced in comparison with conventional methods of gold recovery.The Maminskoye deposit oxidized ores were chosen as the subject of underground leaching because they are ideally suited for this purpose due to their composition and hydrological parameters. The ore reserves within the underground leaching block are 90, 000 t with 0.7 g/t average gold grade.An experimental system for underground leaching with a throughput of 15 cubic m solutions per hour was developed. A combined filtration-and-infiltration system of the ore massif development by holedrillingwhere pregnant solutions are air-lifted was worked out.The underground leaching flowsheet includes Au dissolution by chlorine-containing solutions, Au adsorption from solution onto active carbon, carbon concentrate ashing and calcine melting to produce Dore metal."

Jan 1, 2003

By O. A. Punishko, G. G. Mineev, Zabaikalsky Ore-Dressing Plant, M. V. Malova, O. V. Belousova, S. A. Bogidaev

"In order to intensify benefication processes (flotation and magnetic separation) for rebellious tantalitecolumbite ores electrochemical machining of pulp (ECM) is suggested instead of costly mechanic-chemical activation and magnetizing roasting. Any change in the surface mineral-semiconductor potential under the action of electrochemical treatment results in the change in the isoelectrical state of the surface and the adsorption property of the mineral with respect to ionogenic reagents-collectors. In this case conditions are created for regulating the ion composition, reduction-oxidation potential and pH of the liquid phase of the pulp without any extra introduction of expensive and often ecologically harmful chemical substances.Ores containing tantalum and niobium are characterized by complex chemical composition, determining their physical properties (conductivity, dielectric penetration, magnetization value, etc.) and their electric susceptibility.The authors investigations show that the pulp electrochemical treatment leads to the increasing magnetic susceptibility of the paramagnetic minerals. The main chemical elements forming the columbite-tantalite minerals except tantalum and niobium are iron and manganese. They determine the rare-metal minerals paramagnets properties. The electrochemical treatment changes the relation of the oxidized and reduced forms of these elements having. The method of cathode pulp treatment before flotation is successfully tested industrially.In the field of noble metals metallurgy new technological proposals are reduced to the following. As is know, the production of noble metals from unusual raw materials demands the elaboration of principally new technologies new technologies in so far as the methods for gold and silver extraction from ores are as a rule low elective and at the existing level of engineering are economically not expedient.The analysis of the main trends in the field of non-standard raw material treatment shows that the perspective ones are the geo- and biotechnological processes (underground leaching and leaching in heaps - UL and HL and microbiological methods of metal extraction)."

Jan 1, 2003

By Peter J. Coghill, Michael J. Millen, Brian D. Sowerby, Kirby D. Cunningham

"CSIRO Minerals has developed an integrated particle size analysis system for deployment in the grinding circuits of minerals processing plants. The system includes a slurry sampling station, a de-aeration tank and an ultrasonic particle size analyser (UltraPS). The UltraPS analyser is based on ultrasonic attenuation and velocity spectrometry combined with gamma-ray transmission. The technology is applicable to the measurement of 0.1 to 1000 µm diameter particles directly in highly concentrated slurries without dilution. The analyser incorporates a gamma-ray transmission gauge utilising an ultra-low activity radioisotope source that is exempt from International Atomic Energy Agency (IAEA) and Australian licensing regulations.The UltraPS analyser consists of a submersible probe and an electronics package. The probe can be immersed directly in a minerals processing plant stream if the aeration level in the stream is low. For applications where a de-aerated slurry stream is not available, CSIRO has developed an integrated system that includes a sampling station, a de-aeration tank as well as the UltraPS analyser itself. A schematic drawing of the continuous flow gravity fed system is shown in the figure. A commercial sampling system is used to supply slurry at a rate of 2.5m3/hr to the deaeration tank. The aim of the de-aeration tank is to remove air in the slurry to a level where meaningful particle size measurements can be performed. The tank volume is about 0.2m3, thus giving the slurry flowing through the tank a mean residence time in the tank of approximately five minutes. Tests at a number of concentrators have shown that five minutes is sufficient time for slurry to de-aerate to a level where ultrasonic measurements can be made. The tank incorporates an ultrasonic level detection sensor and flow to the deaeration tank is adjusted based on the level of slurry within the tank. The UltraPS probe is mounted through a flanged section of duct, which is bolted to the bottom of the de-aeration tank."

Jan 1, 2003

By Roberto Golchi

This article describes the method used to quantify the Environmental Impact for the mining, by drilling and blasting, of a borrow pit for a gravity-dam. The affected environment was broken down into a number of components, such as public health and safety, social relationship, air and water quality, flora and fauna. The effect of the various impacting factors from the mining activities, both directly and indirectly, was then calculated for each environmental component. To do this, each impacting factor was first given a magnitude, a number based solely on the range of scenarios possible for the impacting factor. A matrix of weighting factors was then derived to systematically quantify, and normalise, the effects of each impacting factor on each environmental component. The overall impact upon each individual environmental component was then calculated by summing the weighted magnitudes for all the impacting factors.

Jan 1, 2003

By Mônica Suede Santos Silva

This work describes characterization of the performance of the tundish of a six strand continuous casting unit of the Companhia Siderúrgica Belgo Mineira, João Monlevade, Brazil using physical modeling. Permanent and transient conditions, due to ladle metal composition changes are considered. Pulse and step tracer addition techniques are employed to assess the control variables. For transient conditions the degree of inter-mixing and the minimum residence time are determined with a view to optimize the process especially during the grade changes of steel.

Jan 1, 2003

By D. E. Walsh, J. T. Hollow, H. K. Lin, J. L. Oleson

At the Fort Knox Mine, Fairbanks, Alaska, carbon fines are generated during stripping, acid washing and kiln regeneration operations. Because of their gold value, carbon fines are collected by a filter press. Samples of the carbon fines show that they consist of 20% to 30% carbon, 70% to 80% grit and 0.17 to 0.68 g/kg (5.0-19.9 oz/st) gold. About 80% of the gold values in the carbon fines used in this study are in the form of recrystallized free gold grains, with the balance being the adsorbed gold on the carbon. High recoveries of gold and carbon were obtained from the fines in laboratory tests using froth flotation, with a high rejection of the grit. More than 95% of gold and 90% of carbon can be recovered by three stages of gold flotation followed by two stages of carbon flotation. Key words: Gold recovery, Activated carbon, Flotation

Jan 1, 2003

By P. H. Oliver

"The current theory of how explosives fracture rock offers no explanation for the improvements in fragmentation and the reduction of fly rock and back break which occurs when an adequate inter-row delay time is used. Nor does it explain why fragmentation improves with rectangular drill patterns where the hole spacing may be as much as four times the hole burden.A new theory of rock fragmentation is proposed which builds on the existing theory. It offers rational explanations for the many blast effects which the current theory does not address and the need for adequate timing delays between rows. It improves on the design of inter-row delay timing by defining the length of free-blasted face needed in front of a hole *Retired from Inco Ltd., Sudbury, Ontario when selecting the delay element which will provide an adequate inter-row delay time."

Jan 1, 2003

By Helmut Antrekowitsch

Nowadays nearly the half of the world zinc production is used for galvanizing. After their life span most of the galvanized products return as scrap to the steel mill During the steel process the zinc is collected in the flue dust It is astonishing to notice that between 40 and 50 % of the zinc produced is brought into the steel processing cycle by the coated scrap while only 3 to 5 % of the zinc production can be covered by the recycling of the zinc-bearing steel mill dusts. Responsible for this worse ratio is the fact that the established recycling technologies suffer from high energy consumption, low zinc yields, halogen problems and hardly any iron recovery. A development of new or an optimization of current recycling procedures for the dusts is unalterable because of increasing zinc amounts in these residues and the rising costs for the disposal. Different pyrometallurgical recycling technologies are tested in rotary kilns and vertical retorts at the Department of Nonferrous Metallurgy, University of Leoben, Austria. Various reducing agents from carbon monoxide to hydrogen and combinations are used. The results should make it possible to draw conclusions that allow an economical and ecological judgement of the different varieties. The goal is to support the affected industry to increase the low recycling rate and prevent a loss of high zinc values in the steel industry filter dusts.

Jan 1, 2003

By S. M. Spottiswoode, J. A. L. Napier, M. Kataka

The move away from the use of strike stabilising pillars at depth and the adoption of the more flexible system of mining towards final dip remnant pillars brings new opportunities for optimising mine design. In the initial planning stage, the size and spacing of the final pillars is designed using classical design criteria, through limiting modelled values of Energy Release Rate (ERR), Average Pillar Stress (APS) and Excess Shear Stress (ESS). In reality, mines often leave pillars that are larger than those originally designed. One of the reasons for leaving more ground is an unexpectedly high rate of seismicity. In this paper, we present developments in integration of modelling and seismicity that are aimed at developing design criteria that are more responsive to local conditions.

Jan 1, 2003

By Freddie Hunter

An underground mining method for extracting an eight metre (26') coal horizon, containing a sandstone layer. A decrease in the thickness of the rock strata between the number two and number three seams of the Sasolburg Coal Field, has resulted in a total mining horizon approximately eight metres (26') thick. This parting varies in thickness and competency and in some areas is impractical to cut with a continuous miner. In addition, the general mining area is highly jointed. The top seam is first mined to a normal bord and pillar plan with a continuous miner. The bottom seam is then mined by selectively undercutting the stone parting constituting the floor of the top seam. In areas where this parting is between 0.75 - 2.50 metres (29.5" - 98") thick, it is suspended from the primary roof support installed when mining the top seam. Secondary, high extraction retreat mining is then undertaken in the coal pillars adjacent to the suspension supported headings in the bottom seam. Left in-situ, the parting provides lateral support to the pillar sidewalls in both the top and bottom seams, enabling high percentage extraction rates in what was previously thought an uneconomically mineable area. The paper proposed, presents the challenges and practical implications of executing the mining method, including the primary roof control of the top seam and the stone parting between scams.

Jan 1, 2003

By J. S. Gardner, R. Woolacott, P. D. Robinson

In 1917, U.S. Coal and Coke Company, a subsidiary of U.S. Steel, opened Mine 31 and built the community of Lynch, Kentucky. For the time this was truly a major engineering accomplishment. It was documented in Howard N. Eavenson’s 1939 AIME paper, “Coal Through the Ages.” In 1996, Arch Coal donated the Portal 31 property to Harlan County for public use. In 2003 the Southeast Education Foundation, Inc. and the Kentucky Coal Museum plan to open the Portal 31 Exhibition Mine to the public to tell the story of Kentucky coalmining through the decades. This presentation will summarize the history of the project, efforts to bring it to reality, the engineering problems, and the challenges of providing a safe environment for visitors.

Jan 1, 2003

By R Loweth

The application of discreet event simulation has matured in modelling manufacturing systems for production analysis. This simulation tool was used in studying a number of mining operations, especially material handling processes. The study of truck-shovel operation including equipment matching, selection, and production estimation utilised the discrete event simulation for providing valuable decision-making information. The sophistication of the available simulation tools grew over times, and simulation driven animation was used to facilitate the validation and visualisation of the simulated system. This form of visualisation enhanced the simulation use greatly. First of all, it provided a communication medium to transfer information to the non-technical managerial personnel as a better decision-making tool. Moreover, the animated visualisation provided a validation tool to check the working of the simulated system and interaction among its components.

Jan 1, 2003

By M. Cambridge

During the latter part of the twentieth century exploitation of mineral resources, and gold mining in particular, experienced a resurgence in Europe, with major mining houses and many junior companies involved in exploration and subsequent mine development. Gold projects in particular were actively encouraged and exploration programmes and permitting studies initiated in more than 15 countries, both within the European Union (EU) and the former eastern bloc. During the initial period, governments in many countries provided active support. Following a series of negative environmental mining incidents in the latter part of the century public opinion, often ill-informed, led to political pressure to withdraw governmental assistance. This in turn resulted in the revocation of exploration licenses, and ultimately to the failure to develop a number of potentially world-class mines within the region. Despite these setbacks, gold production in Europe continues, and is probably higher now than 20 years ago. The mining industry is currently coming to terms with both changing attitudes of governments, and the increase in scope and prescriptive nature of legislation. Recent experiences, particularly in Greece and Turkey, exemplify the problems faced by the industry in the region, which are causing major mining companies to reconsider future activities in Europe. The paper presents an overview of European gold mining and its environmental performance in the context of international practice, new legislation, and public perception of mining generally. The rationale of governments in withdrawing support for the industry is questioned, and the feasibility of achieving sustainability where there is no level playing field globally is reviewed. The question is posed to governments, regulators and mining companies alike as to whether there is a future, not only for gold mining, but for the minerals industry in general, within the EU.

Jan 1, 2003

By Mary Stewart, Jim G. Petrie, Geoff Brent

"Life Cycle Assessment (LCA) is gaining increasing acceptance as a decision-support tool by which to evaluate the environmental performance of a product, process or service. This is evidenced by its inclusion in international policy documents (for example in the European Union’s Integrated Product Policy) and in environmental management standards (the ISO 14 040 series of environmental management codes relate to LCA). In response to this, the minerals industry has conducted a number of commodity-specific LCAs. These include studies for global production of a number of commodities including copper, nickel, aluminium and steel. In addition, a number of minerals companies profess to use LCA as part of their suite of project and technology assessment tools. Often, this collected use represents more a situation of “we do this because we’re told it’s good for business” rather than from any demonstrable evidence of this fact. This has led to a situation of much confusion and disillusionment within the industry, exacerbated by the obvious current limitations of LCA to accurately reflect the environmental performance of minerals and metals.Our point of departure here is that LCA, conforming as it does to the tenets of environmental systems analysis, is a valuable starting point, and that there is merit in exploring to what extent the methodology can be enhanced to better reflect the environmental performance of minerals and metals. Specifically, we explore here the further development of LCA to address the following:• Land Use issues• Consumption of Abiotic Resources including metallic and non-metallic minerals, water and soil)• Human and Eco-toxicity issues relating to mobility and bio-availability of metals• Salinityand address these through selected experimental and simulation case studies relating to energy- and base minerals production. Advances resulting from the United Nations Environment Programme/Society for Environmental Toxicology and Chemistry Life Cycle Initiative are presented in that they directly affect the application of LCA to mining, minerals and metals. Comments are offered on how best the mining and minerals industry might interface with future developments resulting from this Initiative in order that the Initiative can deliver outcomes which render LCA a useful tool for decision making in mining and minerals processing."

Jan 1, 2003

By E. S. Peterson, M. K. Harrup, K. A. Dolbeare, J. E. Wey

Efficient methods for the removal of copper from heap-leach solutions without mobile organic phases are a current mining industry need. To satisfy this need, a selective, high-capacity, durable solid material is required. The Idaho National Engineering and Environmental Laboratory (INEEL) developed a set of materials based on current solvent-extraction chelates that provide selective copper concentration in the presence of high concentrations of iron. In contrast to conventional solvent extractions, the author's strategy anchors the chelators to a nonpolymeric solid substrate through the use of a custom-designed linker molecule. The fundamental synthetic routes to these materials have already been established, and attachment to the solid surfaces have been achieved in an efficient manner. The author's continuing research is focused on the optimization of the synthetic pathways to these solid materials and the evaluation of their copper-capturing capabilities.

Jan 1, 2003

By S. L. Patil, D. E. Walsh

A novel form of calibration of on-line analyzers was implemented. Rather than simple equations, a neural network was used to model the relationship between the scintillation counts (Am and Cs) of an analyzer, and the measured ash for improved on-line analysis of run-of-mine (r.o.m.) coal. Also, a new approach was followed to better evaluate neural network performance. Samples were first divided into various statistically different groups using a Kohonen network. Data was then selected for the training, calibration and prediction subsets, using criteria developed in this paper for sparse data, with representation from each group. A backpropagation based neural network architecture was used in conjunction with quick stop training. Due to noise in the data, the predictions were very good on average, but not individually.

Jan 1, 2003

By G W. Wilson, P Ritchie, N A. Currey

The design and rehabilitation of potentially acid forming (PAF) waste rock dumps is site specific, being a function, among other factors, of the rock types, the dumping and storage method employed, and the climatic setting. The æstore and releaseÆ cover system developed to manage acid rock drainage (ARD) from mineralised waste rock dumps at Kidston Gold MinesÆ open pit operations in the semi-arid climate of North Queensland, Australia, has been monitored for seven years. The paper describes the philosophy behind the design of the PAF dump and æstore and releaseÆ cover system and the adaptation of the cover system over time to suit KidstonÆs conditions. The results of monitoring over the seven years since the first cover was constructed are presented, and the approach being taken at Kidston to ensure that the risk of impacts from any residual ARD is accommodated and to facilitate lease surrender are described. The Kidston story is a valuable case study of a successful approach to remediating an identified source of ARD in a semi-arid climate, which has actively engaged all Stakeholders.

Jan 1, 2003

This paper characterizes the copper cycle, that is, the flows of copper entering and leaving the African economy over a one-year period (1994). The major flows over the entire life-cycle of copper are examined; these include production (mining, milling and refining), fabrication of semi-products and manufacturing of finished products, use, and the waste management system. The results reveal that substantial amounts of copper (of order705 Gg/yr) are mined in Africa; of that amount, about 70 per cent is exported following processing, 18 per cent is utilized by African fabricators, and 12 per cent is discarded. The flows of copper products from African fabricators and product imports from other continents exceed product discards by large amounts. This difference, about 0.25 kg Cu/capita/yr on average, is added to in-use stock, largely as wire, plumbing tube, and in electronics. Some 65 per cent of the copper in discard flows is contained in electrical and electronic products, where it is relatively easy to collect and process for reuse. About a third of the copper discard flows known is recycled. The actual percentage is almost certainly higher because of informal (and unrecorded) recycling. Much of the remaining discarded copper is diluted into the municipal waste stream, where recovery and recycling are probably not economically justified. Keywords: material flow analysis, resource management, material budgets, copper, stocks and flows, systems analysis, Africa, developing country

Jan 1, 2003