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The purpose of this work is to determine the equilibrium-state of the aqueous-solution which is produced by the leaching processes, including natural weathering of pyrite minerals. The latter can lead to acid-mine-drainage (AMD). The ferric iron species (Fe3+) resulting from bacteria-catalysed oxidation of ferrous iron (Fe2+), in the presence of water and air, is known to bring about steady-dissolution of minerals chalcopyrite (CuFeS2), sphalerite (ZnS), pyrite (FeS2), and so forth. Good-aeration, relatively high-porosity and sufficient bacterial activity tend to promote leaching in waste-rock-dumps. The composition of the aqueous-phase that accumulates in the pore-space (or in open-pits) is of practical interest as it would strongly influence the leaching of both sulfide and non-sulfide minerals. Since the reactions among the various ionic species occur relatively fast, the solution-phase may be regarded as approaching a state of virtual-equilibrium and it is possible to determine by computation the respective concentrations of the many dissolved species. For the Cu-Fe-H-O-S system, these species may include: H+, Fe2+, Fe3+, Cu2+, HSO4-, SO42-, OH-, CuSO4o, H2O, Fe(OH)+, Fe(OH)2+, Fe(OH)2+, Fe2(OH)24+, Fe(SO4)+, Fe(HSO4)+, Fe(HSO4)2+, and Fe(SO4)2-. The aqueous-system which may be constituted from appropriate mole-quantities of H2SO4, FeSO4, Fe2(SO4)3, and CuSO4 is in fact the result of various natural processes (reactions) and due respect must be accorded to the extents of these reactions. The present model computes the equilibrium molalities of the foregoing ionic and neutral aqueous species, using the iterative equilibrium constant method that ensures strict-adherence to charge-balance and elemental molar-balance constraints. The dissolving sulfide-minerals (FeS2, CuFeS2) consume Fe2(SO4)3, H2O, and O2 and yield FeSO4, H2SO4, and CuSO4 while the aqueous-phase tends to become progressively acidic (declining pH) reflecting the gradual increase in the extents of sulfide-dissolution reactions. The equilibrium-state of the solution-phase is computed for specific set of values for the extents of respective reactions. The temperature and pressure of the system are 25¦ C (298.15 K) and 101.325 kPa (1.0 atm), respectively. The mica-like minerals such as the biotite [H2K(Mg,Fe)3Al(SiO4)3] tend to consume much of the H2SO4(aq), with the extracted K+, Mg2+, Fe2+ and Al3+ ionic species accumulating in the solution. The precipitation of the jarosites (potassium, hydronium, or ammonium) contributes to the removal of ferric and ferrous species from the solution-phase. In the present work, the emphasis is on predicting the compositions of the aqueous- and condensed-phases with advancing time or increasing æextent of reactionÆ. The results of such calculations are compared to published data on raw AMD (acid-mine-drainage).

Jan 1, 2008

By Jun Lu, Min Chen, Wei-jian Su, Jian-zhong Luo, Yu-tao Lei

"In the case of treating phosphatizing wastewater containing zinc, zinc had an impact on the solution chemistry, especially on pH. Fe2(SO4)3 and CaCl2 were used as precipitators to remove phosphate from zincic phosphatizing wastewater and the optimum pH was investigated. Zinc ion had a significant effect on the optimum pH. The optimum pH ranges were 12.10(inlet concentration of 15.67mg/L, outlet concentration of 9.53mg/L), 3.04-5.50(inlet concentration of 11.97mg/L, outlet concentration of 0.44-0.26mg/L), and more than 10.72(inlet concentration of 12.24mg/L, outlet concentration of less than 0.47mg/L) under the conditions without precipitator, with Fe2(SO4)3 and with CaCl2 respectively.Introduction Phosphate coating is commonly used for protective coating of machine elements. Including oil removal by caustic washing, rust removal by acid washing, phosphatization and inactivation, the phosphatization process produces wastewater containing inorganic salt of high concentration, especially the phosphate, beyond the environmental standards and polluting environment seriously. What’s more, the wastewater from zincic phosphatizing technology also contains another pollutant, zinc. At present, Chemical Precipitation (CP) and Biological Nutrient Removal (BNR) are two of most common technologies of phosphate removal. BNR, such as A/O, A2/O and UCT technology, is suited for wastewater containing organ phosphorus of low concentration and CP for wastewater with phosphate of high concentration [1]. Researches on CP treating wastewater containing phosphate of high concentration, mainly focus on adding quantity of precipitators[2-5] and coagulants[2-4] and the choice of technologies[3-9]."

Jan 1, 2008

By J Stojanovic, V Kasic

Gold-bearing polymetallic sulfide deposits are common in Serbia, and mostly occur in the Karpato-Balkan and, to a lesser extent, the Serbo-Macedonian metallogenic province. These deposits û Coka Marin (Majdanpek), Grabova Reka (Blagojev Kamen), Lece (Medvedja) and Veliki Cip (Boranja) û are dominated by Cu and/or Pb-Zn mineralisation that contains a variety of Pb, Zn, Cu and Fe (¦ Sb, As, Bi) sulfides and sulfosalts, as well as native elements. Gangue minerals are composed of quartz, carbonates and rare silicates and barite. Based on their gold content these deposits can be divided in three groups:1. Polymetallic deposits with a high gold content (>1 g/t).2. Polymetallic deposits with an intermediate gold content (0.1 to 1 g/t), and3. Polymetallic deposits with a low gold content (<0.1 g/t). Gold occurs as native gold or as an alloy with silver. Native gold ranges in size from 5 to 20 ¦m, with a few rare grains over 100 ¦m, as isolated grains or as microveins (in the first group of deposits). Its distribution within the deposit in uneven. Native gold in the second group is smaller in size (1 - 5 ¦m, rarely 20 ¦m), where it is uniformly distributed in a quartz-silicate matrix. The third group is of no economical importance. The subject of research has been the first group of polymetallic deposits.

Jan 1, 2008

By G. Triantafillou

The aim of this paper is to present the progress of the plan of the Greek Public Power Corporation S.A. (PPC S.A.) at the Lignite Centre of Megalopolis in Peloponnesus (southern Greece) to manage impacts on local communities in areas affected by its activities during the lignite mining operation and post-closure. The reclamation works in the waste dump areas of the mines that constitute the Megalopolis Lignite Centre, concerning the utilization of waste dumps for infrastructure community projects constructions are discussed. Moreover, selected environmental indicators concerning land use and closure and rehabilitation are presented.

Jan 1, 2008

By Hong N. Vu, Jitka Jandova

"Gypsum and limestone methods were examined in this study to process zinnwaldite wastes originating from dressing Sn-W ores mined in the Czech Republic. These wastes containing 0.20-0.30% Li and 0.10-0.20% Rb were subjected to magnetic separation to obtain a zinnwaldite concentrate with 1.36% Li and 0.94% Rb. It was observed that processing of the zinnwaldite concentrate with gypsum resulted in almost 96% recovery of Li into aqueous liquors, whilst rubidium extraction was only 25%. At the same time, it is possible to extract almost 92% Li and Rb from the identical zinnwaldite concentrate if the concentrate is processed by limestone method. Lithium carbonate, a final product of both methods was recovered from the refined sulphate solution using K2CO3 as a precipitation agent and/or from unrefined hydroxide solution using gaseous CO2. In the continuation of this study, rubidium will be separated from carbonate solutions after Li2CO3 precipitation as RbAl(SO4)2, an intermediate for Rb2CO3 production. IntroductionLithium is used as an alloying constituent in lightweight alloys, as a heat transfer medium in nuclear reactors and as a component in primary and secondary batteries. With the development of a new generation of electric vehicles, the lithium demand will dramatically grow. Lithium chemicals find extensive application in many industrial branches such as metallurgical, glass, ceramic and pharmaceutical industries. Rubidium compounds are predominantly used in psychiatry and medicine, in magneto-optic modulators, solid-state lasers, phosphors and components of electrolytes for fuel cells. The four most important lithium minerals are amblygonite, spodumene, petalite, and lepidolite. Spodumene LiAlSi2O6 (6.0-7.5% Li2O) and petalite LiAlSi4O10 (3.5-4.5% Li2O) belong to aluminosilcate minerals. Lepidolite (Li.Al)3(Al.Si)4O10(F.OH)2 (3.30-7.74% Li2O), lithium mica, is the most important representative of the mica minerals, a subgroup of the aluminosilicates. It frequently contains 3–5% Rb2O and eventually caesium. Zinnwaldite, which has the general formula K(Li.Al.Fe)3(Al.Si)4O10(F.OH)2 (2-5% Li2O), is regarded as a variety of lepidolite with a high iron content. Commercial amblygonite is a complex phosphate (Li.Na)Al(F.OH)PO4 (up to 9.88% Li2O), however, its deposits have not been commercially exploited because of their small size. Natural brines with a high lithium chloride content are important in the industrial production of lithium [l]"

Jan 1, 2008

By Rudiger Baltz

The sudden failure of bodies of rock is a serious problem commonly experienced in the international mining industry. These explosive releases of energy are referred-to as ?bumps?, ?outbursts? and ?rockbursts?. Rockbursts can occur at such a rapid speed that they present a direct threat to safety in large parts of the mine workings. The build-up of excess stress within the body of rock can be attributed to different causes. In shallow workings, for example, sudden and violent failure of the roof strata can be caused by leaving insufficient pillar width when practising room-and-pillar mining. At much greater working depths, as it is the case in the German coal industry, rockbursts are generally attributable to high levels of rock pressure. This can even result in coal outbursts when driving individual roadways. More than thirty years ago the German coal industry suffered from numerous rockburst incidents which caused many deaths and serious injuries. This led directly to the establishment of the Rockburst Prevention Centre, which was created at the instigation of the mining companies and the chief mines inspectorate. The consistent logging and analysis of all rockburst incidents has led to the development of a system that is still used as a basis for preventing underground rockbursts and minimising the risk of such phenomena occurring. Working closely with the mining authorities and mining companies the accredited experts of the Rockburst Prevention Centre have played a key role in helping to develop and implement a range of methods for the early detection and prevention of rockbursts.

Jan 1, 2008

By X Zhang, Z Guang, R Lin

To improve the existing process of a large-scale scheelite concentrator in Jiangxi Province, this paper presents an advanced process æselective flotation of copper and flotation desulfurisation û rougher flotation of scheelite û heating-stirring and cleaning of rougher concentrate at normal temperature without reagent removalÆ. The test work was conducted on an ore sample containing 0.75 per cent tungsten (WO3), and the following technical indices were obtained: 1.03 per cent of the scheelite concentrate yield, 65.37 per cent of the concentrate grade and 86.31 per cent of WO3 recovery, indicating that the study achieved the objective of improving the tungsten recovery. The technical key of this process is to employ combined regulators and direct flotation of the slurry after being heated, which not only assured the technical indicators of beneficiation but also simplified the process.

Jan 1, 2008

By F. Nava-Alonso, O. Alonso-González, A. Uribe-Salas, R. Pérez-Garibay

"Cyanidation is the most used method to recover gold and silver from their ores. In this process, other metals besides gold and silver may sometimes dissolve and interfere with the efficiency of extraction. Copper is one of those metals, reaching concentrations as high as 1000 mg/L in some cyanidation plants, making difficult the extraction and purification processes, and increasing the operating costs.This preliminary work was intended to study the feasibility of using amines to form a precipitate and to eliminate copper from a synthetic solution containing high copper and cyanide concentrations, as is the case of some cyanidation effluents. The solid formed is removed from the solution using conventional filtration techniques. Seven amines were evaluated at different pH values and amine additions. Up to 90% of copper present may be removed at the natural pH of the effluent (alkaline). The remaining copper would permit to recycle the solution back to the cyanidation process. IntroductionCopper is generally considered the most problematic metal in gold leaching due to the rapid formation of copper cyanide complexes when some readily-soluble minerals are processed (e.g., azurite, malaquite, cuprite, chalcocite and bornite). The copper solubilization as cuprous cyanide complexes leads to a significant economic penalty in terms of excessive cyanide consumption and high cost for cyanide elimination. When activated carbon is used to recover gold and silver, the copper-cyanide complexes decrease the efficiency of the process because of the competition of the cuprocyanides with the aurocyanide for the adsorptive sites on the activated carbon (Rees and Deventer, 1999).Several techniques have been developed to attempt to overcome the problems caused by the copper presence in cyanidation solutions, notably: acidification-volatilization-regeneration (AVR), ion exchange-electrolysis or solvent extraction-electrowinning (Lu et al., 2002). In this work the use of some amines is proposed to remove the copper-cyanide complexes by precipitation of a copper-cyanide-amine solid. The process was evaluated for different amine additions and pH values, using copper-cyanide synthetic solutions of composition similar to that presented by some cyanidation plants with high copper."

Jan 1, 2008

By P F. Knights

Mining companies are striving to achieve new levels of operational maturity and drive process improvement across the organisation in the face of unprecedented demand and limited supply of experienced human resources. Advanced analytics techniques can help overcome these fundamental challenges by applying data techniques not previously applied in mining. Today, decisions are usually locally optimised but do not achieve optimum capability for the value chain. Although more information is collected then ever before, it is difficult to link many sources of data together in the same place in real-time, for example plant history, maintenance, mine planning, logistics and engineering data. Consequently complex analysis of data is time consuming and requires specialist skills and knowledge, and is often neglected in the decision-making process. In the future, analytics will close the loop between analysing data and taking action. Analytics will become embedded in the business and routinely applied to improve decision making across the organisation, from senior management to operations and maintenance workers, but will not require specialist skills or be time consuming to analyse data. As analytics becomes embedded in the business process, decisions are supported by data (not on gut feel), and critically, data from many sources are integrated in real-time to improve the quality of decisions. Ultimately, predictive tools will help suggest, or even in some cases automate, courses of action. The main opportunities for analytics exist where the enterprise requires supporting technology to enable it to continue to evolve to higher level of maturity. This will be in the areas of asset management, rapid reconciliation and adaptive planning, and the inbound and outbound supply chains. Advanced analytics are also a key enabler for increasing the effectiveness and realising the true value of Remote Operations Centres to safely and efficiently support operations in remote locations with smaller workforces.

Jan 1, 2008

By Takahiko Okura

"It is said that the energy and resources crisis will come before long because the lifetime of known deposits of crude oil and common metals such as Pb, Zn, Cu is estimated to be less than 50 years. Establishing the sustainable society by means of resources-recycling has become an absolute necessity.The non-ferrous metals industry in Japan has been involved in the resource- recycling business for many years, along with the introduction and enforcement of various legislations to preserve the environment and natural resources. Including process-linkage during various manufacturing activities, the non-ferrous metals industry, the iron-making and cement industries are treating considerable amounts of recycled materials and wastes, in an environmentally-sound and economic manner.The Mining and Materials Processing Institute of Japan has submitted “The present and issues in Japanese non-ferrous metals and recycling industries.”The topic of the paper is to highlight the actual conditions within the resources-recycling structures and the present issues.IntroductionGlobalization has been changing the world, introducing the spike of energy and metals price. In addition, the preservation of the environment has also been strongly facing the crisis and many people have been aggrieved by both shortage and the increment in the price of the meals.In the world of metals, even though their reserves are coming depleted, the production rates are increasing, and then the industry has to enhance their productivity under stricter environmental regulations. The Japanese industry experimented the same scenario some 40 years ago, facing big pollution problems, but concurred them and enhanced the technology to overcome the more severe regulations. It will be fruitful to present the current situation in the Japanese industry for the world. The present issues are also presented."

Jan 1, 2008

By Bradford F. Townsend

A study was made on six collapses that occurred during large-diameter tunnelling through weak sedimentary rocks and soil using SES methods in three stages?top heading, bench and invert. The collapsed lengths are between 20 m and 277 m. The collapses were re-mined using essentially the same tunnel-ling method with larger excavation profiles to accommodate the designed remedial measures consisting of ground treatment, pre-support and stronger initial support/outer lining required to carry higher ground loads acting in the collapsed lengths. The paper presents information on the collapses and the design and execution of the remedial measures.

Jan 1, 2008

By Eric Monrad

Discrete event simulation modeling provides a tool to quantify the throughput capacity of stockyards. Interactions between the main equipment types (trains, dumpers, conveyors, stackers, reclaimers, shiploaders) can be captured, including route blockages, breakdowns, and planned maintenance. Simulation has been successfully used at world-class stockyard facilities to determine current capacity and to identify gains resulting from improvement projects. Recent projects have focused on iron-ore, coal, and soya facilities, but the technology is suitable to be used on any bulk material type.

Jan 1, 2008

By D. He

In China, the total reserves of vanadium, reported as V2O5, in stone coal is 118 Mt (130 million st). Recovering vanadium from such a large resource is very important to China?s vanadium industry. The technology now being used to recover vanadium from stone coal has the following two problems in the leaching process: a low recovery of vanadium and high acid consumption. To resolve these problems, a new leaching technology is proposed. The effects of factors such as H2SO4 concentration, liquid-solid ratio, temperature and time, and the types and additions of additives were studied. By adding 1.5% (by weight) CaF2 and leaching the roasted residue of stone coal with 5.4% (by weight) sulfuric acid at 90°C for 12 hours at a liquid-solid ratio of 2 mL/g, the leaching degree of vanadium reached 83.10%. This proposed leaching technology gives a feasible alternative for the processing of roasting residue of stone coal and can be applied in the comprehensive utilization of stone coal ores in China.

Jan 1, 2008

By Ulrich Leiste, Andrew Wardlaw, William Fourney

This paper describes the loading on a plate suspended directly over an explosive charge submerged in water. This problem is of interest because it yields results similar to those obtained in the detonation of an explosive buried in saturated soil and thus it is associated with landmines. Recent experiments [1] indicate that plate loading from a submerged charge is similar to that for a buried one, with respect to impulse and pressure. Compared to the buried explosive problem, the submerged explosive case is attractive from a computational point of view; it replaces sand, which is diffi cult to simulate, with water, whose properties are well known. Studying this problem allows modeling uncertainties to be separated from sand simulation issues.

Jan 1, 2008

By Jozef F. Zurawski

Increasingly new interceptors or new Combined Sewer Overflow (CSO) projects require connections to existing tunnels. More often than not, the existing facilities are old, in poor or questionable conditions, without proper construction records or as-built drawings. Many cannot be easily inspected unless major construction effort provides flow by-pass for safe access. This paper provides general guidelines on how to approach the problem of assessing the condition of old tunnels, how to plan and design the connection with limited physical assessment, how to develop the scope of work for the bid documents and how to provide geotechnical guidelines and designs for the bid documents.

Jan 1, 2008

By John Carson

Belt feeders are commonly used to meter the flow of bulk solids from bins and hoppers. If the interface between the hopper outlet and belt feeder is not designed correctly, flow from the bin may be severely compromised, resulting in problems of no-flow, segregation, flooding, etc. By knowing the flow characteristics of the bulk solid being handled and applying proven design techniques, such problems can be avoided. Relevant bulk solids flow characteristics are identified, along with measurement techniques. Design procedures for correcting problems with existing feeders as well as proper design of new feeders are presented, along with case histories of successful application of these procedures.

Jan 1, 2008

By M N. Ingham

X-ray fluorescence (XRF) spectrometry has always been considered to be a comparative method of analysis. Reference materials are required to calibrate the analytical system. This paper describes the use of a set of æsyntheticÆ oxide standards, made from commercially available high purity compounds, to calibrate a spectrometer for 21 major and minor oxides. The spectrometer software uses simple methods of background correction, and a fundamental parameter method of matrix correction. Sample preparation is by fusion in 66 per cent lithium tetraborate, 34 per cent lithium metaborate. The use of synthetic standards, made from traceable compounds, brings XRF significantly closer to being a primary rather than a comparative method. Reference materials were used to validate the method described and examples of accuracy for major constituents are given using ores and other minerals. This method has successfully been used to analyse a wide variety of minerals and ores, as validation data shows. A titanium process example clearly shows the benefits of highest accuracy analysis.

Jan 1, 2008

By B. Grinbaum, A. Mazuelos, F. Carranza, N. Iglesias, M. Avila, J. L. Lozano, G. Perez, R. Romero, M. \/aliente

Following a failure of a tailings pond darn at a mine in Andalusia, Spain, a huge effluent stream, that contained about 1 g/1 Zn and significant amounts of ferrous, ferric, calcium, copper, aluminium and manganese cations has to be treated, to prevent pollution of a nature reserve. EGMASA, as the regional government environmental agency, suggested to improve the current depuration process by recovery of the Zn from the effluent. A solvent extraction (SX) followed by electrowinning (EW) was proposed and developed to remove zinc.. A pre-treatment stage consisting in bio-oxidation of ferrous iron by using a bacterial process followed by an alkaline precipitation was employed because iron in the effluent is incompatible with both the SX and the EW processes. The SX process was developed successfully at the laboratory scale and verified in a pilot plant on-site, using two Bateman Pulsed Columns for extraction and stripping of zinc. The results were satisfactory obtaining a recovery of 90% of Zn. The process was suitable for industrial application.

Jan 1, 2008

By N. V. Sujathkumar, I. Vasudhevan, R. Santhakumar

"Freshwater ornamental fish culture is gaining importance in India and cheaper and nutrient rich live foods such as infusorians, daphnids, copepods and tubifecids are needed urgently. In this regard, adequate research has been conducted to produce such live feeds through recycling of agriculture and animal wastes. By this venture, besides generation of additional income, environment is also kept clean. In order to popularise the technologies relating to production of live foods from wastes and generate employment opportunities, training programmes were conducted for 100 Self Help Group women belonging to Thoothukudi district. The topics of the training included, breeding of ornamental fishes by utilizing the building material wastes, production of live foods through recycling of agricultural and animal wastes. A study on feed back was conducted with 100 respondents represented from different villages. The variables such as socio economic status, economic motivation, usefulness of training and constraints were included in this study. The impact assessment of this training of rural women indicated that 79 percent respondents were in favour of using the training for self employment by utilizing different kinds of wastes. Similar training programmes have also been planned in other parts of Tamilnadu. Introduction Ornamental fish culture is one of the most appropriate sectors to provide opportunities of employment to uplift the status of rural women. To ensure women utilize their full potential in useful and profital activities like freshwater ornamental fish culture, it is necessary to provide training and support for rural women which will ultimately lead to empowerment. Self Help Group Women are being trained routinely in India on the production of live foods for ornamental fish culture through recycling of agricultural and animal wastes. In this regard, training programmes were organized for the Self Help Group Women on freshwater ornamental fish culture. Which is gaining much importance in India. Cheaper and nutrient rich live foods such as infusorians, daphnids, copepods and tubifecids are needed urgently. The techniques of live feed production through recycling of agricultural and animal wastes would not only generate additional income by would also keep the environment clean."

Jan 1, 2008

By Roberto Parra, Roberto Parada

"A novel process for minor elements control in copper pyrometallurgical production is proposed based on a theoretical analysis and the results of an experimental program. Its application can solves operational problems related to volatile elements that determine pollutants gas emissions and the final quality of anodes. The process considers a calcination of mixtures of the dust with sulfidizing agents such as dirty copper concentrate or elemental sulfur at temperature under 800 °C. The product are a clean calcine that recovers all the Cu content on the dust and a gas stream that collect the minor elements as sulfides species. The calcine can be returned to the smelter avoiding the As increasing in the circuit and so on, the capacity for the treatment of dirty concentrates for the smelter can be higher. The possibility to apply vacuum in the calcinations step can decrease the operation temperature. The solid condensed from the gas has different options for its stabilization, with the advantage that this stream represents few mass with high As content.IntroductionThe control of undesired minor elements (IVIES) in conventional pyrometallurgical copper production is especially relevant for ore deposits associated to Andes region. The concentrates that are being produced present every time higher levels of volatiles and harmful elements: group Va (As, Sb and Bi), Pb, Zn, and Sn."

Jan 1, 2008