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By E. R. Bobicki

"Low-grade ultramafic nickel ores, while representing a large potential nickel resource, are difficult to process due to their serpentine content. Microwave treatment is proposed as a technique to improve the beneficiation of ultramafic nickel ores by converting the constituent serpentine to olivine. The present paper reviews the microwave heating response of ultramafic nickel ores and resultant changes in mineralogy, as well as effects on grinding and slurry rheology. Beyond nickel extraction, microwave treatment improves the mineral carbon storage capacity of ultramafic ore tailings, providing a potential source of additional revenue via the sale of carbon credits. The combined positive effects, considered in the context of the whole operation, suggest an economically viable process is possible.INTRODUCTIONAs high-grade deposits become depleted, the processing of low-grade ores has become increasingly important. One such resource is low-grade ultramafic nickel ores. While representing a large source of nickel, these ores are difficult to process due to their serpentine content. Serpentine is a phyllosilicate mineral consisting of 1:1 stacked sheets of silica tetrahedra and magnesium hydroxide octahedra. There are three primary polymorphs: lizardite (platy), antigorite (corrugated) and chrysotile (coiled, fibrous). The anisotropic nature and non-spherical morphology of serpentine particles leads to complex rheology. Suspensions of serpentine minerals, especially those of chrysotile, exhibit high viscosity and yield stress, which can have a negative effect on comminution, flotation and dewatering operations. In flotation, serpentine is known to slime-coat pentlandite, a valuable nickel mineral, and form bubble-fibre aggregates that report to the froth, reducing nickel concentrate grade and recovery. Methods used to counteract the effects of serpentine in processing include desliming, the addition of chemical dispersants, salts or acid, and dilution (Bobicki et al., 2014a). Microwave pre-treatment has been proposed as an alternative way to eliminate the deleterious effects of serpentine in ultramafic nickel ore processing by converting the serpentine to olivine via dehydroxylation, which occurs at 600-700oC (Reaction 1). Olivine is isotropic, consisting of isolated silica tetrahedra linked by octahedrally coordinated magnesium ions, and has the same surface potential as pentlandite at the pH of flotation (~pH 9). Furthermore, since olivine is more reactive to CO2 than serpentine, microwave pre-treatment creates an opportunity to store more CO2 in tailings, an attractive option for mining operations looking to increase their bottom line where carbon pricing exists."

Jan 1, 2018

By Philip A. Holland

The Bureau of Mines has developed a method for determining helium in water for use in sampling and analyzing surface and subsurface waters for geochemical survey work. The accuracy of the analytical method is within ±10 percent for samples containing above 20 x 10-8 cm3 He (STP)/cm3 H20. The minimum detectable helium-in-water concentration is calculated to be 2 x 10-8 cm3 He (STP)/cm3 water. Water samples are collected in 500-cm3 stainless steel cylinders. The dissolved gases are extracted into a cylinder of equal volume containing a known quantity of neon. The resulting gas mixture is subsequently analyzed for helium and neon-21 by mass spectrometry. The volume of helium in the sample is calculated from the mass spectrometric determination of the helium-to-neon-21 ratio, the known quantity of neon used, and the extraction efficiency of helium.

Jan 1, 1981

By F. E. Pawlek

Copper concentrates can be comminuted in an attritor within a very short time to a particle size of 1 - 0.1 um. Addition of sodium hydroxide enhances commninution. The concentrates, suspended only in water, can be completely dissolved under oxygen over pressure and temperatures ranging from 120 - 180°C (248 - 356°F), because the surface area of the concentrate has been significantly increased by the ultra fine grinding. Addi¬tion of a small amount of silver ions to leach liquor containing sulfuric acid acted as a catalyst for the dissolution of chalcopyrite, because of the formation of local elements on the surface. The addition of C1- ions was also catalytically very effective. With this method it is possible to completely dissolve the copper contained in chalcopyrite concentrates after ultra fine grinding within 30 min at 110°C (230°F) under an oxygen partial pressure of 1 atm (14 psig). Several flowsheets demonstrate the industrial feasibility.

Jan 1, 1976

By George K. Foster, Charles D. Borror

The Jeffrey mine of the Canadian Johns-Manville Co., Limited, is in the town of Asbestos, situated approximately 100 miles northeast of Montreal and about the same distance southwest of Quebec, in Richmond County, Quebec. Mining operations were started in 1881 on outcrops on a hill, as a side-hill cut, followed by a second and third cut. This development was the forerunner of the present large open-pit operations, the mine now ranking as the largest open-pit asbestos mine in the world. Operations were first carried on by hand, then by horsepower and later by stem cableways. By 1924 the derrick spans, 2000 ft. or more long, became unwieldy. To overcome this, and also to eliminate hand labor as much as possible, steam shovels and railroad haulage were introduced. The steam shovels were replaced in 1928 by larger electric shovels of the full-revolving type. The Ore Body The ore body is a serpentinized peri-dotite rock mass. The chrysotile fibers form a network of veins throughout, varying from microscopic width to two or more inches measured across the veins (Fig. I). These veins may be continuous for a few or many feet; they may increase or decrease in width within a few feet. The veins in which the fibers occur per- pendicular to the veins are known as cross fiber. Those in which the fibers lay parallel to the veins are known as slip fiber. The cross fibers are of better quality, and more in demand. The majority of the fiber

Jan 1, 1948

By Joseph Singewald

AMONG the genetically interesting iron ores of the United States are those of the St. Francis Mountains near Ironton and Iron Mountain, Missouri. They are specular hematite in porphyry. The Iron Mountain and Shepherd Mountain deposits are generally spoken of as veins and those of Pilot Knob, Cedar Hill, and Russell Mountain as bedded deposits. Iron Mountain has produced nearly 4,000,000 tons of ore and Pilot Knob about 1,500,000 tons. The output of the other three localities has been insignificant. Pilot Knob is no longer worked as an iron mine, but the rock is now being crushed for use as road metal. Iron Mountain has continued as an active producer. In 1927, the property was acquired by the M. A. Hanna Co. and an extensive prospecting and exploration campaign was undertaken, so that the ultimate production of Iron Mountain will doubtless greatly exceed the figures mentioned.

Jan 1, 1929

By Harold Gibson, Ulrich Schwarz-Schampera, Ralf Freitag, Hendrik Mueller

INTRODUCTION Germany has a long history in marine research in the Indian Ocean. The first German scientific cruise started in 1964, followed by a series of state-sponsored research cruises between 1983 and 1995 leading to the first finding of polymetallic sulfides in the Indian Ocean. The research included regional bathymetric, geological, structural, volcanological, petrological and hydrothermal investigations along the Carlsberg Ridge and the Central Indian Ridge (CIR). Early environmental base line studies covered oceanographic and sedimentology aspects. In 2010, BGR took the initiative for the preparation of a license application for the exploration of polymetallic sulfides with the International Seabed Authority (ISA), and prospecting started in 2011 along the southern Central (CIR) and the northern Southeast Indian Ridge (SEIR) in the southwestern Indian Ocean (cruises INDEX 2011 on board R/V Sonne), INDEX 2012 (R/V Fugro Gauss), INDEX 2013/1-2 (R/V Sonne) and INDEX 2014 (R/V Pelagia). After three years of resource-oriented and environmental base line studies, BGR, in order for the Federal Ministry for Economic Affairs and Energy (BMWi), applied for an exploration license which was approved by and subsequently signed with the ISA in 2015. The license gave permission to start a detailed exclusive resource-oriented exploration program in the license area. The program includes the outline of potential ore deposits and a resource assessment but also extensive and detailed base line studies for the sustainable protection of the marine environment in the license area. The license contract has a fifteen years lifetime and may allow the application for a subsequent mining license. The exploration aims at the identification of inactive polymetallic sulfide deposits, formed below former discharge zones of hot hydrothermal fluids on the ocean floor (“black smoker” systems), by advanced and modern exploration techniques.

Jan 1, 2018

Slope stability is a critical safety and production issue for open cut mines. The æslope stability radarÆ has been developed to remotely scan a rock slope to continuously measure the movement of the face. The system can detect and alert movements of a rough wall with sub-millimetre precision, and with reliability and resolution. The advantage of the slope stability radar over other monitoring techniques is that it provides full area coverage without the need for mounted reflectors or equipment on the wall. In addition, the radar waves adequately penetrate through rain, dust and smoke to give reliable measurements, 24 hours a day. The measurement technique is tolerant of vibrations and overcomes the need for a highly stable footing required by traditional surveying systems, making it easy to move from one location to another. The system is self-powered and designed for minimal maintenance. Radar displacement images, co-registered with digital photography images, are transferred from the radar site in the pit to the mine office via a radio telemetry link. Custom-written software provides mine managers and geotechnical engineers with a complete picture of slope movements over defined time intervals. The time-history of the movement of any selected points or regions on the slope can also be displayed. Also provided is the ability to set movement thresholds that will trigger alarms at the radar site or mine office. The system has been used at numerous coal and metalliferous mines in Australia, and has provided real-time monitoring of slope stability during active mining operations. More than 20 rock wall and spoil failures have been captured by the system, and on every occasion adequate warning was provided to mine operators. The high level of movement precision and broad area coverage of the rock face provides a better understanding of the geodynamics, which leads to extra warning time. This technology enables a radical change in the management of risks in open cut mining operations.

Jan 1, 2003

Arizona E. P. MATHEWSON, Chairman F. W. MACLENNAN, First Vice-chairman CLYDE E. WEED, Second Vice-chairman E.D. GARDNER, : Secretary-Treasurer Box 4097, University Station, Tucson, Ariz. ARTHUR CROWFOOT G.H. DOWELL HENRY F. EASTER R.D. LEISK Boston Meets first Monday each month, October to May, inclusive GEORGE, W. METCALFE, Chairman ROBERT S. WILLIAMS, Vice-chairman F. LEROY FOSTER, Secretary-Treasurer Rooms G-202, Mass. Inst. of Tech. Cambridge, Mass. FREDERICK K. MORRIS GEORGE A. PACKARD

Jan 1, 1934

By Aziz N

The objective of the paper is to develop an understanding of the influence of caving on powered support rating by examining the geology and support performance at two sites which represent the current extremes in support rating, ie 6/240 Ton supports operating in the Hirst Seam at Solsgirth Colliery, Scotland, and 4/900 Tonne supports operating in the Bulli Seam, West Cliff Colliery, Australia. A conceptual model is introduced which considers the coal ahead of the face, the powered support, and the caved waste to be three yielding foundations which interact to control the subsidence of the roof strata. Different caving mechanisms are identified for the strata of the Hirst and Bulli Seams, ihese mechanisms being related to rock properties, ie to the palaeogeography and depositional conditions at each site, producing caved wastes with different yield characteristics. The results obtained for convergence and support reaction during production cycles at both sites are analysed to show the manner in which support reaction is developed, indicating the importance of high setting load densities in the Bulli Seam. Evaluation of the work done on the subsiding roof strata during typical production cycles by two of the yielding foundations, ie the powered support and the caved waste immediately behind the powered support, is used to further demonstrate the influence of caving mechanisms on support rating.

Jan 1, 1986

The on-going technical developments to enhance the productivity and cost effectiveness of large blasthole drills incorporate many of the blasthole drilling operating experiences garnered over the past half century.Those experiences have shown in part that on a drill unit with good quality structural elements the higher the percentage of the electrical and electronic components designed into the product, the higher its productivity and the lower its operating cost.

Jan 1, 1992

By T. P. Mucho

Mine roof failure due to excessive horizontal stress has been recognized as a major cause of hazardous roof conditions in some mines. Stress measurements gathered by the U.S. Bureau of Mines (USBM) at 24 different eastern mines show horizontal stress to be typically 2 to 3 times as great as vertical stress. The focus of current Bureau work is to develop detailed design parameters to assess and control the effects of horizontal stress. To facilitate the recognition of horizontal stress effects and to easily determine principal stress direction without resorting to cumbersome, expensive, and time consuming field measurements, the Bureau has developed a stress mapping methodology. Stress recognition and direction determination are required to successfully employ a number of control strategies such as mine layout, mining sequences, and support optimization to control the effects of horizontal stress, thereby increasing the safety of U.S. coal mines. This approach has been used in other major coal producing countries, most notably Australia and the UK, and has greatly enhanced the safety of their mines (1). This paper discusses horizontal stress, directional based control techniques, and provides guidelines for the use of the stress mapping technique. A case study of a mine where the technique has been used is also presented.

Jan 1, 1994

To provide cooler air to miners working in hot areas of mines, particularly new deep hardrock mines. Approach Air supplied to hot working areas of mines is cooled by passing it through a series of water sprays. How It Works Water nozzles mounted inside a section of ventilation tubing release cooling sprays of water into the air being blown through the tube. The prototype of the water spray cooler consists of six evenly spaced water sprays located inside a 10-ft. long section of 16-inch-diameter fiberglass ventilation tubing. See diagram. This section of rigid tubing is installed into one of the positive pressure ventilation tubing lines that conduct fresh air into working stopes. The intake manifold to the six water sprays is connected to the mine?s cool water line, and the water valve on the manifold is opened. Warm ventilation air being supplied to the stope passes through the water sprays, and is cooled by the lower temperature water.

Jan 1, 1979

By G. A. Calboreanu

One way of cost reduction is attained when using materials with improved erosion ? corrosion resistance. For many years hard irons successfully answered the Mining Operation needs however application ranges were limited due to the low chemical resistance of such alloys. Corrosion resistance of any hard iron increases when microscopically homogenizing chromium and generating passivation conditions throughout and between all metallographic phases. Chromium distribution of the new material called Max10 was analyzed with EDS ? energy dispersive spectroscopy. At critical depleted chromium carbide ? matrix interfaces chromium increased to 31.72% which is well within passivation levels. Generally the corrosion resistance of high chromium hard irons provided by Metal Casting Industry is limited to 0.5% sulfuric acid and 28 PPM ionic chlorides. Such restrains increased when using Max10 to 2.0% sulfuric acid and 100 PPM ionic chlorides. Max10 contains 35% carbide volume fraction, has excellent corrosion resistance within pH = 1.15 ? 13.6 while fracture toughness under plain - strain conditions and Mode I opening is KIC = 20 KSI.(inch)1/2. Wear rate was calculated with the pin-on-disk apparatus using a diamond indenter per ASTM G99 recommendation. After years of research, experimentation and implementation the Max10 castings were service installed in slurry pumps and mixing equipment. In some applications the life time of slurry pumps manufactured in Max10 tripled versus previously used materials.

Jan 1, 2012

By John W. Burd

A system is described for the simultaneous deposition of epitaxial layers on as many as eight substrates. A high degree of uniformity of both physical and electrical characteristics is achieved in the films. Variation of film thicknesses is consistently less than ±10pct within a wafer and from wafer to wafer within a run with the variation typically on the order of 55 pct. Composition variation of GaAs1-x PX layers within a wafer and from wafer to wafer within a run is consistently less than 51 pct. Electrical evaluation of the films by several techniques indicates excellent doping uniformity within a wafer and from wafer to wafer within a run. Mobilities for lightly doped GaAs films at 300°K are consistently >6000 cm2 v-1 sec-1 and mobilities > 7000 cm2 v- 1 sec-1 are regularly attainable. Techniques for the preparation of material with carrier concentrations from 1 x 1015cm-3 to 1 x 1019 cm-3 n-type and 5 x 1016 to 5 x 1018 cm-3 p-type are discussed. METHODS for the preparation of 111-V compounds by vapor phase reactions have been extensively reported in the literature.1-6 Almost all of the apparatus described for these various methods are suitable for processing one or at the most a very limited number of wafers simultaneously. With the recent rapid advances in the use of vapor grown GaAs for microwave oscillators and GaAs1-xPx as visible light emitters the requirements for these materials are steadily increasing. In order to satisfy these requirements it is necessary to move from a laboratory scale apparatus to one which is capable of processing a large number of wafers simultaneously. Desirable features would be a high degree of uniformity among the wafers and good reproducibility from run to run. The apparatus to be described fulfills these requirements very well. DISCUSSION The various methods reported in the literature can be classified under three headings: 1) closed tube, 2) open tube, and 3) the close-spaced method. Of these three the open-tube method is the most amenable for scale-up to a manufacturing process. It is the most versatile and the various operating conditions can be more precisely controlled than with the other two methods. A number of chemical reactions may be used to achieve vapor-phase growth of 111-V compounds. Sev-era1 of the more generally used reactions are shown in Fig. 1. All of these reactions have the following points in common: 1) generation of a volatile group III(Ga) species by the reaction of the transport agent (halide or HC1) with either Ga or GaAs, 2) introduction of the Group V(As and/or PI component, 3) a method of adding dopant, if desired, and 4) a region in which deposition from the vapor will occur and form as a single crystal epitaxial film on the substrates. The laboratory scale reactors permit the hot re-actant gases to flow into the relatively cooler deposition zone and pass successively over the several substrates which are arrayed along the long axis of the tube parallel to the gas flow. With this arrangement the composition of the reactant stream is continually changing as solid material is deposited on each successive substrate. As a result of this changing gas composition the reaction driving force also changes from substrate to substrate and the degree of uniformity of layer thickness, doping level, and so forth, is poor. This effect can be partially overcome by imposing a controlled temperature gradient along the deposition region to compensate for change in gas composition. However, even when this is done variations in layer thickness on the order of 30 to 40 pct are common and as high as 50 pct are frequently experienced between adjacent wafers in the tube. To expand this arrangement to a large number of wafers would only increase the nonuniformity from the first to last wafer in the line. From the above discussion the two undesirable features of changing gas composition and temperature gradient become evident. A reactor system which eliminates or minimizes these undesirable features is one in which the apparatus is mounted vertically as shown schematically in Fig. 2. The vertical mounting permits the disposition of a number of substrates on a suitable support so that all wafers are at the same vertical height in the furnace and hence at essentially the same temperature. By using only a single row of wafers the reactant gas mixture passes over only one substrate in its path through the reactor. Thus the two undesirable features of changing gas composition and temperature gradient are minimized. An additional design feature which further minimizes temperature variations is rotation of the substrate holder. Rotation serves to integrate any radial temperature gradient existing around the resistance heated furnace. A photograph of a reactor assembly at the completion of a run is shown in Fig. 3. MATERIAL PREPARATION Apparatus. Although any of the several chemical systems shown in Fig. 1 are adaptable for use in this apparatus the one generally used is System 2, the hydride synthesis system. This system has been de-

Jan 1, 1970

By G. G. Barbante

An understanding of the thermodynamics of smelting copper anode slimes is a prerequisite for improvements to the process. During slimes smelting, a silver-copper selenide matte is formed and subsequently oxidised to silver metal. As part of a series of investigations, molten silver selenide matte was oxidised at 1 100 degrees C with pure oxygen. The chemical potential diagram for the system was developed and used for qualitative prediction of the results of the experiments. A simple, computational thermodynamic model of converting is presented, the adjustable parameters of which were determined by matching the model with the experimental results. The practical usefulness of the model was demonstrated by predicting the effect on silver recovery of smelting temperature and of using either oxygen or air as the smelting gas

Jun 21, 1905

By G. J. Knighton

Introduction The Sullivan concentrator treats the complex lead-zinc-iron ore from the Sullivan mine of the Consolidated Mining and Smelting Company of Canada, Limited, to make a lead and a zinc concentrate for its metallurgical plants at Trail. Three miles separate the mine and mill, which are situated near the town of Kimberley, in the East Kootenay district of British Columbia. The orebody consists typically of banded sulphides, mainly galena, sphalerite, pyrrhotite, and pyrite. Important factors in the concentration of the ore are its exceedingly complex and its high specific gravity. It should be remembered throughout the paper that results and figures are based on Consolidated's experience with the Sullivan ore. The present mill feed rate is 8,500 dry tons of ore per 24 hours, for an operating week of five and a half days. Grinding and classification of the ore are carried out in three stages and, in addition, there is a re-grind section which re-treats the zinc middling. It is the purpose of this paper to discuss the classification in the various stages and to give the results o comparative tests which have been carried out for the purpose of improving operations in the mill. The Primary stage consists of six units, each made up of a ball-mill and classifier (see accompanying flow-sheet). Four units operate in open circuit and two in closed circuit. The secondary stage consists of eight ball-mills operating in closed circuit with twenty-one classifiers. In the Tertiary stage are two ball-mills in closed circuit with eight classifiers. The re-treatment section for re-grinding the zinc middling comprises one ball-mill in closed circuit with two classifiers.

Jan 1, 1947

By Andrew Howard

As the mining industry moves further into developing countries in search of new resources, its role in international development is coming under increasing scrutiny. This is a trend that is likely to accelerate, along with the potential for headaches among managers in the industry. Public interest in development and environmental issues is rising as faith in “big business” falls. This has strengthened nongovernmental organizations (NGOs) campaigning for sustainable development. And it has put more pressure on banks, governments and development agencies to curb corporate misdemeanors. Developing world governments are also becoming emboldened to reject previously agreed terms they do not consider equitable. The mining industry has begun to formulate a response to these pressures but must go much further. Societal and environmental issues must move from public relations to core strategic thinking. Abiding by rules or codes is not a relevant response. Instead, genuine support for sustainable development is required. This will involve delegating the responsibility for engaging with local communities to on-the-ground staff and developing a dialogue with local stakeholders rather than conducting an initial assessment and disengaging.

Jan 1, 2006

Jan 1, 1935

By Bruce Conard

For many years, Bruce Conard has been engaged in reading about and discussing the desired sustainability of the mining and metals resource industry. He has, however, become concerned that there is a greater issue that requires our urgent attention: what challenges do we face as a global society? His Distinguished Lecturer presentation traces the idea of environmentally sustainable economic development but concludes that a business’ interest in its sustainability is predicated on the sustainability of our global society. Conard reviews some of the most serious challenges, including population growth, clean energy supplies, freshwater availability and climate change, and calls on scientists and engineers not only to apply their skills in helping solve these challenges, but most urgently, to speak with intelligence and passion about the need to act now.

Jan 1, 2014

By Gang C, Changyi S, Liangde G

Geophysical and geochemical methods and techniques for gold exploration and their applications in China are summarised in the paper. Some case histories are also presented. The effect of prospecting for gold deposits using these methods is well illustrated through these examples.

Jan 1, 1997