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The paper point out the testwork has been carried out with real process solutions from the Chambishi cobalt plant in Zambia, showing that the ISEP® continuous ion exchange system can effectively remove nickel from cobalt sulphate electrolyte. Laboratory testing confirmed published data, and was subsequently verified on site at Chambishi in a pilot test program. Based on the testwork data, a commercial unit is being installed at Chambishi.

Sep 13, 2001

By M. E. Wadsworth

"For his creative efforts in explaining the electrochemistry of sulfide mineral leaching systems." Leaching reactions that occur during the dissolution of selected base metal sulfides and metals are considered in terms of surface reactions and the influence of intermediate or final products formed. These products may be solid layers, requiring solid phase diffusion for the reaction to proceed, or ions in solution that can influence the kinetics by controlling the mixed potential of the solid. Three general types of reactions are proposed to explain observed rates of reaction. Examples are presented for non-oxidative and oxidative leaching of galena (PbS), anodic dissolution and oxidative leaching of molybdenite (MoS2) and cyanidation of silver and gold.

Jan 1, 1986

By Cornell J. B

Scaling in Bayer Refineries is a natural consequence of the super-saturated liquors used in the process. The caustic liquor is supersaturated not only with alumina but also silica and calcia at various stages of the process. The basic scaling mechanisms are reviewed and examples of the two basic types, growth and settled scales, are given. Examples include gibbsite scales formed in the precipitators and silica scales formed in heat exchangers. The main factors affecting the rate of growth of growth scales are temperature and supersaturation and are highlighted using a silica scale example. For growth scales chemical cleaning rates can readily be predicted from kinetics and an example for a gibbsite scale is given. For settled scales the growth rate cannot be predicted and the hydrodynamics within the system have most effect. There is no simple method to predict the potential for chemical cleaning of settled scales; some of the relevant issues are discussed, in particular methods to identify the cementing phase in the scale. An example of design considerations for a scaling system, transport of slaked lime, is Given.

Jan 1, 1996

By J. S. Hattrup

INTRODUCTION Tunnel boring machines in non-abrasive competent rock with little or no water have set new performance standards in the driving of tunnels. However, when the machines have hit blocky or running ground, they have encountered difficulties. The success of a tunnelling machine is usually due to a thorough geological investigation which accurately describes the rock conditions, a well designed tunnel support system, and a tunnel boring machine designed to cope with these conditions. In some cases machines have had to be modified in the tunnel after the machine had commenced boring, because geological conditions were not correctly anticipated before tunnelling began. The features described herein are not a panacea for all conditons, and some of them, like an auxiliary thrust system that thrusts off a precast invert segment requires pre-planning of work on the part of the contractor. CUTTERHEAD DESIGN Figure 1 shows typical cutterheads of ten to fifteen years ago. Note the large buckets and large openings between the buckets. These large openings were considered necessary to gain easier access through the cutterhead for cutter changes. The standard cutter in those days was an 11 inch or 12 inch cutter with small bearings, and was generally a delicate tool for the duty it was to perform. These large buckets would clog up if a formation with clay seams was

Jan 1, 1981

By D. F. Stein

In spite of the apparent usefulness of autoradiography in demonstrating segregation, it has had very limited success in demonstrating grain boundary segregation. Because of this limited success, a model system amenable to mathematical analysis was devised to determine which variables in the experiment are most important. As a result of these calculations, it was concluded that autoradiograPhy is a rather insensitive technique to measure grain boundary segregation. The range (energies) of the emitted particles (ß and a) must be low, and the concentration of the radioactive speczes at the grain boundary must be (in general) two or three orders of magnitude greater than the concentration within the grain. Because of these very restricted conditions , the limited success of the technzque is not surprising. In spite of the apparent usefulness of autoradiography in demonstrating segregation, it has had very limited success in demonstrating grain boundary segregation. Sulfur segregation in iron1 and possibly polonium segregation in Pb-5 pct B1 2 alloys are the only autoradi-ography experiments that have demonstrated segregation to grain boundaries in metals without the formation of a second phase. Segregation to a boundary without the formation of a second phase is often called Gibbs' absorption and is discussed by McLean in Chapter 5 of Ref. 10. There are several394 experiments showing grain boundary diffusion of a radioisotope, but this type experiment is not representative of equilibrium between the concentration of an element at a grain boundary and that in bulk, so it will not be discussed in this paper. In an attempt to determine if temper embrittle ment of low-alloy steels was associated with segregation of antimony to grain boundaries, a program to use auto-radiography (using Sb-125) was initiated. Even though other measurements strongly suggest that segregation is occurring during embrittlement, no evidence of grain boundary segregation was observed in the auto-radiography experiments. An attempt was also made to detect segregation of carbon (using C-14) to grain boundaries in iron during slow cooling. There is again strong indirect evidence7 that segregation occurs during such a treatment, but the autoradiography experiment gave no evidence of such segregation. Because of the failure of these experiments and the general lack of success by our metallographic unit in measuring grain boundary segregation using autoradi-ography, a model system amenable to mathematical analysis was devised to determine which variables in the experiment are most important. MODEL SYSTEM The model system is illustrated in Figs. 1 and 2. It is a semi-infinite bicrystal with a single grain boundary perpendicular to the top face. The width of the grain boundary, W, is defined as the region to which segregation has occurred and it is assumed that this region is of constant composition. The assumption of an infinite dimension is for mathematical reasons but the results of such an analysis (as will be demonstrated later) are valid for even very small specimens. It also is assumed that the measurement is not limited by means of detecting the radiation (photographic emulsions, counters, and so forth) but that the means of detecting radiation is linearly sensitive to the radiation and has infinite resolving power. The distance y is the perpendicular distance from the center of the grain boundary to the point at which the background radiation is measured and x is the integration variable. CALCULATION FOR BETA PARTICLES Two values of the intensity of radiation will be calculated, the intensity at the center of the grain boundary and the intensity far from the grain boundary. The radiation at the center of the grain boundary can be calculated in the following way. Assume a grain boundary of width W having a uniform concentration equal to Cgb + Cb where CGb is the excess concentration of the element under consideration at the grain boundary and Cb is the bulk concentration. The intensity of radiation, IgB, at the center of the grain boundary, is a consequence of the amount of radioactive material, decay rate, absorption, and geometrical factors which can be represented mathematically by the following expression:

Jan 1, 1968

By C. T. Sheeran, J. C. Franklin

A commercially available microprocessor-based system capable of monitoring 512 channels has been interfaced with monitors for radon, working level, air velocity, and fan power. The basic system utilizes both 280 and 8080 microprocessors in a desktop central processing unit (CPU). CPU hardware includes keyboard, video display (CRT), and disk drive; a printer is used to keep permanent data records. Signals from all channels are transmitted to the computer in digital form where they are processed for alarm status. Software developed for the system allows for audiovisual alarms in the event of low and high readings, rate change, change of state, or communica- tion failure. Up to six channels can be continuously displayed on the CRT for current readings. Shift reports and trend logs may be generated to help the ventilation engineer determine average working levels and ventilation effectiveness. Additional software permits the operator to program command sequences which may be used to automatically restart fans after a power outage.

Jan 1, 1982

By Dmitriy Makarov

The paper presents the modeling and analysis of oxidation of pyrite copper-zinc ore samples from the Letnee, Yaman-Kasy and Valentorskoye deposits. It is found, that the oxidized samples contain copper and zinc sulfates that are leached under the sample and water contact. It is shown, that sulfide floatability is decreased by the longer-term oxidation.We advise to improve nonferrous metals recovery by joint leaching and ultrasonic treatment of oxidized compounds. Study of the geotechnological processes of non-ferrous metal extraction, on the basis of two copper-zinc ore deposits shows, that heap leaching is of little use for the ores of the Letnee deposit. Leaching results for the Yaman-Kasy ore showed more promise.

Sep 1, 2012

By V. Velicka, J. Ptacek, R. Snuparek, P. Konecny, G. Takla

Coal mining in Ostrava-Karvina coalfield is being accompanied by rockbursts. 82 rockbursts occurred within the period between 1990 and 2002. Natural and technological factors from these rockbursts were collected and analysed. They confirmed that rockbursts are complex geomechanical events and that the relations between co-acting technological and natural factors are very complicated. Der Abbau in dem Ostrava-Karvina Steinkohlenrevier wurde von Anfang an durch Gebirgsschläge begleitet. 82 Gebirgsschläge in dem Zeitabshnitt von 1990 bis 2002 erfolgten. Die Angaben über natürliche und technische Faktoren der Gebirgsschläge wurden gesammelt und analysiert. Es wurde bestätigt, dass die Gebirgsschläge komplexe geomechanische Phänomene sind und dass die Beziehungen zwischen den zusammenwirkenden Faktoren sehr kompliziert sind. L´abattage d´houille dans le Bassin houiller d´Ostrava-Karvina est accompagnée par les coups de terrains. 82 coups de terrains s´étaient produit dans la période entre 1990-2002. Les données sur les facteurs naturels et techniques ont été ramassées et analysées. Les résultats ont corroboré que les coups de terrains sont des phénomènes géoméchaniques complexes. Les relations entre les facteurs techniques et naturels coopérants sont très compliqués.

Jan 1, 2003

By M. Furuta, M. Hasimoto, Y. Komoda, K. Haiki

"Tamano Smelter & Refinery started its operation in 1972 with high current density electrolysis (350Nm2 of maximum) applying PRC technology. After the start up, four times of expansion have been done, the cathode production capacity has increased from- 84,000 t/y to 191,000 t/y. However, recent refining technology with permanent stainless steel cathode enabled to increase current density up to 300 Nm2 or more without PRC method. In order to increase current density more than 350 A/m2 , experimental work using commercial size cell has been carried out at several conditions, such as current density, PRC conditions, electrolyte composition and electrode condition. As a result, it was found that high quality (LME A grade) cathode can be produced at such a high current density as 405 A/m2•IntroductionWhen considering the production increase of electrolytic copper, what becomes important is the improvement of productivity per unit of production facility. Conventionally, production had been expanded by increasing the number of cells but a huge investment required for this had a influence to the business profitability. Because of this, increase of current density, which is one of the methods to improve unit productivity, 'was expected and this method at the same time has another advantage of shortening the retention time of copper and other precious metals in the cells. At present, the average current density at Tamano during full capacity production is around 350 A/m2 and this used to be the limit throughout the world (1)."

Jan 1, 2000

By B. J. Arnold

Coal blending inherently means homogenizing a mixture of coals so that the properties of the blend meet some specifications for maintaining power plant performance and emission requirements. In practice, however, coal blending is, at best, coal mixing. The degree of blending sophistication required depends on the reason for coal blending in the first place. If it is to maintain fuel characteristics that will diminish the chance of slagging and fouling, then some swings in variability may be tolerated at some power stations. However, if emissions limits are the issue, then more sophistication may be needed. Emissions limits are becoming stricter with requirements to meet averages for shorter time frames (hours and days instead of weeks and months). These restrictions require closer control over the quality of the blend being fed into the bunkers at the station. Even scrubbed units should have a consistent quality of fuel as feed so that sorbent additions can be minimized. To meet these challenges, engineers must consider available equipment and control techniques and the properties of the parent coals when evaluating new blending systems.

Jan 1, 1994

By George H. Holmes

The water situation in Nevada mineral and related industries is described in this report. It contains information on the sources and adequacy of supply to current operators, requirements and uses, quality and costs, geography, hydrography, precipitation and evaporation characteristics, and Nevada water laws. Also, information is given on the water requirements of one public utility powerplant, and the source and consumption of water in four major cities. Water distribution at 24 operations is shown on schematic waterflow diagrams. The mineral industries of Nevada in 1962 used 8.6 billion gallons of new' water and reused 3.8 billion gallons for a total usage of 12.4 billion gallons. The copper industry was the major water user. The 1962 value of all mineral production in Nevada was $85.5 million. The large amount of water required to maintain thin high production is obtained principally from ground-water sources in alluvial valleys and the permeable rock formations of some mountain ranges. Some water is also obtained from perennial streams and springs. Sources of water utilized by existing industry ire near most mineral industry operations; however, seven companies are forced to pipe water distances ranging from 2 to 8 miles. Although water supplies of presently operating companies are adequate at most operations, several companies resort to large-scale reuse of water as a matter of conservation and economics. Acquisition of water by new operators is possible but takes considerable negotiation. Water rights, surface and underground, are controlled by the State. The quality of the water is satisfactory for most purposes. Analyses of 19 samples, listed in the appendix, show the range in water quality at various plants throughout the State. Costs of delivering new water to current operations range from 2 to 26 cents per 1,000 gallons with an average of 10 cents per 1,000 gallons for power and maintenance. No firm costs for recirculating water were available; estimated costs range from 1.5 to 2.5 cents per 1,000 gallons. The mineral-product value of the entire Nevada mineral industry in 1962 was equivalent to $10 per 1,000 gallons of new water and $26 per 1,000 gallons consumed. Projection of the 1962 water requirements of the Nevada mineral industry indicates that the demand For new water will increase from 8.6 billion gallons in 1962 to 11.9 billion gallons in 1980, a 43-percent increase. Water requirements in the year 2000 are estimated as 14.8 billion gallons, an increase over 1962 water demand of 78-percent.

Jan 1, 1966

By William Loblowitz

A simplified system of flotation testing has been developed recently at the Bureau of Mineral Research of Rutgers University. The technique involves the known principle of skin flotation and can be used with minute quantities of sample and reagents in a beaker. A vessel containing the conditioned sample with added water and flotation reagents is held inclined and rotated slowly. Water-repellent particles come in contact with air and float on the surface of the liquid, while wettable particles are submerged. The float is poured off and filtered whereas the nonfloat remains in the beaker. The filtrate may be returned to repeat the process.

Jan 6, 1951

By V S. T Ciminelli

This work aimed at evaluating the acid rock drainage (ARD) potential of five samples of a Brazilian gold sulfide mine in a decommissioning process. Three of the most traditional ARD prediction techniques, Standard Acid Base Accounting (Std ABA), Modified Acid Base Accounting (Modified ABA), as static methods, and humidity cells as a kinetic method were tested. Both the Std ABA and the Modified ABA results indicated an acid generation potential for some of the studied samples. In the other cases the results were inconclusive. The five samples were then submitted to humidity cell tests during 27 to 30 weeks. At the end of the period, the leachate pH was stabilised in a range from 3.4 - 4.1 (four samples) to 5 (one sample). The presence of relatively high levels of sulfate and dissolved metals was detected throughout the operation, specifically, Ni and Zn, and less frequently, As. These findings are discussed with the help of the samples mineralogy and Eh-pH diagrams. The results obtained in this investigation indicated potential environmental risks of this mining area. In this particular case, the kinetic tests were shown to be essential to the identification of the samples ARD potential.

Jan 1, 2003

By T. F. Deems

The nature, usage and comparatively rare occurrence of ball clay is described. The importance of these white firing plastic clays in ceramics, particularly in the production of industrial sanitary ware and tiles, is emphasized. The US deposits are briefly discussed. What is known about relevant deposits in Brazil, Argentina, Colombia and Venezuela (the four largest ceramic producers in South America) is also described. The ceramic plants have been sited near the centers of population rather than the plastic clay deposits. At present, extraction is probably concentrated on surface residual deposits and lenses which require minimum investment. Native plastic clays are used exclusively in the tile plants, but in sanitary ware, they are often used as extenders of imported ball clays.

Jan 1, 1997

By James S. Browning

The principal uses of fine ground mica are as filler in wallboard joint cement, as a filler and surface coating for roofing, as an ingredient in paints, and in oil well drilling mud. The mineral has other uses in the manufacture of rubber, wallpaper, plastics, welding rods, electric insulation, house insulation, and textiles, and as an annealing agent in metal treatment. In recent years, more than 999 percent of the domestic mica produced has been scrap and flake mica (mica which does not meet specifications for sheet mica and is used for producing fine ground mica). There has been a continued increase in mica production for, several years, the 1963 production of scrap and flake mica totaling 117,251 tons.

Jan 1, 1966

Eldorado Resources Ltd.(ERL) uses a solvent extraction process for the processing of uranium ores. The solvent extraction plant consists of 4 extraction and 5 stripping stages with regeneration carried out as required (Wyper, 1982). Extraction is carried out with a solvent consisting of 4.5 vol % Alamine 336, 4.5 vol % Isodecanol and 91 vol % kerosene. The extraction step can be represented as In equation (1).

Jan 1, 1988

By Michael L. Sorokin

The various methods of converter slag cleaning operation are analysed from the thermodynamk point of view: cleaning using coal, cleaning using combustion products of natural gas and cleaning in presence of matte. All calculations were done, applying the developing computer procedure based on the free energy minimisation algorithm. Three-suffix Margules equations were used to calculate thermodynamic properties of melts; The calculations resulted in recommendations for the practical appliance.

Jan 1, 1995

By María Cristina Ruiz

In the processing of copper concentrates by the conventional smelting-converting technology, complying with the increasingly severity of environmental legislation in some countries has become difficult, mainly due to severe fugitive emissions of gases produced during the batch PS (Peirce-Smith) converting step. In this work, the results of an investigation on the pressure leaching with sulfuric acid and oxygen of white metal (produced in a Teniente Converter reactor) are discussed. The study was carried out at laboratory scale and the main variables studied were temperature, concentration of sulfuric acid and partial pressure of oxygen. The experimental results indicated that most of the sulfur in the white metal was oxidized to sulfate in the whole range of temperature studied (105ºC to 150 ºC). The concentration of sulfuric acid over 0.05 M, and oxygen partial pressure over 6 atm had little effect on the dissolution of copper from the white metal. On the other hand, temperature had the most significant effect on copper dissolution; below 130 ºC copper dissolution was incomplete after 5 hours of leaching while at 150 ºC the dissolution was complete in 90 minutes and 10 atm of partial pressure of oxygen

Jan 1, 2006

By W. Birch

The traditional concept of scaled-distance modelling for predicting blast induced ground vibration holds many drawbacks, not least of which is the major effect data scatter imparts on confidence determination. An investigation by the Department of Mining and Mineral Engineering, The University of Leeds, England has resulted in the development of simple but effective method of improving prediction capacity through the reduction of effective error by incorporating individual location response into a scaled-distance model. The work is the product of an l&month blast-monitoring campaign at a limestone quarry situated in North Yorkshire, England. The data, when presented in the form of a scaled-distance model, indicates a typical scenario where a good overall correlation becomes marred by the extent of data scatter. Examination of the individual monitoring locations however indicates that the response of the individual location is an important factor in the explanation of the large residuals. The novel approach thathas been developed incorporates a series of locational site factors which when incorporated into a scaled distance model reduces the effective error and therefore improves prediction capacity. The approach is based on using a standard computer package “spread sheet” on the understanding that these are commonly available on all quarry or home computers. This approach has been validated by comparison with a more rigorous statistics method.

Jan 1, 2001

By G. Willard Quick

FAILURES in railroad rails have been of vital concern to engineers; railroad executives, rail manufacturers and the general public for years. Failures from transverse fissures originating from internal nuclei have received particular attention in the past 20 years. Dr. J. E. Howard first reported this type of failure in 1911, as being responsible for a wreck-on the Lehigh Valley R. R. in which several lives were lost. Since then many transverse fissures have been found. In 1919, Waring and Hofammann1 etched longitudinal sections of rails in hot acid and found cracks extending both longitudinally and transversely in certain used rails as well as in some new rails.. Since then it has been thought by many that these "shatter" cracks are the nuclei from which transverse fissures subsequently develop in service. Methods for reducing the rate of cooling rails on the hot. bed have been devised to decrease the temperature gradient and consequently the stress gradient in the rails. A study of the tensile properties of rails at elevated temperatures was made by Freeman and Quick,2 who investigated the properties at temperatures through which rails pass on the cooling bed after leaving the hot saw. In their investigation a special study was made of the ductility of the steels in the temperature range 400° to 700° C. In this temperature range it was found that certain rail and other steels showed a marked decrease in elongation and reduction of area. The phenomenon was called "secondary brittleness" and the temperature range the "secondary brittle range." A tentative explanation was presented that internal failure such as "shatter cracks" and "hair cracks" in rails are the result of thermal stresses developed in the steel structure while cooling through the secondary brittle range. The investigation showed that the magnitude of the phenomenon varies for different heats, but that it did not differ for specimens from different ingots or for different rails in a particular ingot. It was also shown that annealing rail steel at a temperature either above or below the critical

Jan 1, 1932