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By Michel R. Julien, Michel Lemieux, Jean Cayouette, Daniel Talbot

"The Louvicourt Mine located near Val d’Or, Quebec has been in operation since 1994. It produces copper and zinc concentrates. The tailings generated from the ore processing operations have a strong net acid generating potential. Louvicourt Mine, a grass root project, was designed for closure with the best available technology at the time of design. In order to inhibit short and long time acid potential generation, sub-aqueous disposal was selected at the design stage. Given the fact that disposal in a natural lake was ruled out up front for obvious reasons related to loss of natural habitat and risks of permitting delays, a man made facility built with dams was planned. This mine includes therefore the first fully man-made sub-aqueous tailings disposal facility built in Canada. The requirement of using sub-aqueous disposal had serious implications on the placement of tailings. This tailings facility located about 9 km from the mine site has been selected based on the available natural confinement, the favorable foundation and hydrogeological conditions. This paper describes the site and the design criteria that were used. A presentation is also made on the placement technique to maximize storage and its impact on the operation of the basin. The performance of the basin, the dams and the decant structures is reviewed.Résumé : La mine Louvicourt, située près de Val d’Or, Québec est opérationnelle depuis 1994. Elle produit des concentrés de cuivre et de zinc. Les résidus générés par les opérations de traitement du minerai possèdent un fort potentiel net de génération d’acide. Le parc à résidus de la mine Louvicourt, implanté dans un milieu naturel intact, fut doté dès sa conception initiale de la meilleure technologie de fermeture disponible à l’époque, soit la déposition sous couverture aqueuse et ce, dans le but de bloquer le potentiel de génération d’acide à court et à long terme des résidus. Etant donné que la déposition dans un lac naturel fut mise de côté dès le départ pour des raisons évidentes reliées à la perte d’habitats naturels et au risque d’introduire des délais dans l’émission des permis, un étang artificiel délimité par des digues a été conçu. Cette mine fut donc la première au Canada à être dotée d’une installation anthropique de disposition des résidus sous une pleine couverture aqueuse. L’exigence d’une déposition sous couverture aqueuse a eu des implications sur le mode de mise en place des résidus. L’emplacement de l’installation de gestion des résidus a été choisi en un lieu situé à environ 9 km du concentrateur sur la base du confinement naturel disponible et des conditions hydrogéologiques et géotechniques favorables. Cet article décrit le site et les critères de conception utilisés. Une présentation est faite sur la technique de mise en place utilisée pour maximiser l’entreposage et son impact sur l’opération du bassin. La performance du bassin, des digues et des structures de décantation est également revue."

Jan 1, 2004

By S. H. Ash

[On December 2, 1932, the Governor of California called upon the representatives of the mining industry of the State to attend a meeting at Sacramento to discuss ways and means of assisting is relieving some of its perplexing and extremely distressing problems, particularly the mounting cost of accidents which faces the industry with an industrial insurance rate for classification of $11.85 per $100 of pay roll, effective January 1, 1033. The significance of this fact is at once apparent when it is realized that the classification rates per $100 of pay roll for mining have steadily increased for some time, as follows: $3.91 in 1924, $5.54 in 1925 and 1926, $8.04 in 1927, $8.53 in 1928, $9.05 in 1929, $9.42 in 1930, $10.54 in 1931, $10.99 in 1952, and $11.85 in 1133. In other words, the cost rates have acre than doubled, wile statistics indicate that the accident rates nave shown an entirely different trend. At the meeting mentioned, one of the management officials sounded an effective keynote when he declared that a spade should be called: a spade. The perplexing problems of any industry can be approached best and remedies applied if that policy is kept to the front. It is appropriate to mention that high accident rates and a decrease in wages in recent years have unquestionably accounted in part for a unit cost rate, on a pay-roll basis; it also is well to explain that the policy years3 1926 to 1930, inclusive, are the years on which the accident-cost experience for 193: is based. That accident rates :lave not undergone the expected beneficial chance in California's experience is apparent in the words of a Bureau of Mines report:4]

Jan 1, 1933

By F Hungerford, T Ren

"Gas management has always been a major concern for the ventilation officer of any gassy mine. With an increase of mining depth and gas content, there is a great demand for the development of in-seam drilling sites where boreholes can be drilled for the pre-drainage of gas prior to longwall operation. The ventilation and gas management in the drilling site therefore becomes a critical component of mine safety. In this study, advanced computational fluid dynamics technology was adopted to investigate the aerodynamics of gas emitting from the drilling site and boreholes during normal drilling and, in the case of a sudden gas inrush, from the borehole. In addition, the impact of different ventilation controls on gas removal in the drilling site was investigated. Modelling results indicate that gas accumulation zones could be formed if the ventilation system fails to deliver sufficient airflow to the drill site, especially when a sudden gas inrush from a borehole occurs. The configurations of brattice, layout of ventilation tubes and the gas emission rate all have a significant effect on the gas distribution. Due to variations in site-specific conditions, it would be desirable to conduct modelling studies to assess the effects and efficiencies of a ventilation design for the varying environment on-site before carrying out drilling practice. CITATION: Ren, T, Hungerford, F and Wang, Z, 2015. Computational modelling studies of ventilation management for underground in-seam drilling sites, in Proceedings The Australian Mine Ventilation Conference, pp 239–250 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 31, 2015

By Bowden MW

Sintering of lead-zinc concentrates is practised by Sulphide Corporation to provide both desulfurised lump sinter feed, for simultaneous reduction to zinc and lead in the Imperial Smelting Process blast furnace, and sulfur dioxide gas for sulfuric acid manufacture.Moisture control of feed mixes is of paramount importance in the sintering operation and improvements in this area have realised increases in overall plant performance.

Jan 1, 1985

By M Darby, B Burdett, F Lovell

The results of the process control improvement project aimed at improving the quality of Australian Bulk MineralsÆ (ABM) iron ore pellets produced by four vertical shaft furnaces are very positive. These results are achieved through process stabilisation and optimisation, improvement in process monitoring and taking early corrective actions when operating variables were outside the target ranges. A number of benefits are obtained from this project. These benefits include: More consistent and improved pellet quality. The average cold compression strength (CCS) value of pellets produced during the eight-month trial is 260 kg/pellet, which is 16 kg/pellet higher than that produced during the 12 months prior to the trial (244 kg/pellet). Reduction in the heat input by eight per cent, from 727 MJ/tonne to 668 MJ/tonne. Reduction in bentonite rate by six per cent, from 7.1 kg/tonne to 6.7 kg/tonne. Increase in the furnace throughput rate by four per cent and additional production of 10 000 tonnes per annum through process stabilisation. Better understanding of the process behaviour. This knowledge is valuable not only for setting the target operating conditions but also for developing the ABM expert system to control the process.

Jan 1, 2005

By I. Demers

Doyon mine, Quebec, Canada evaluates the possibility of desulphurizing their tailings to produce material to be used in as cover over the acid generating tailings disposal site. Laboratory tests were conducted and showed that a single-layer cover made of desulphurized tailings placed over reactive tailings can prevent the generation of acid mine drainage. Modelling with the software Vadose/W was undertaken to optimize the design parameters, namely cover thickness, water table position, and residual sulphide content of desulphurized tailings following laboratory work. It was found that the optimal configuration includes a 1 m desulphurized tailings cover containing 0.8%S, with the water table kept at the interface between the reactive tailings and the cover. To maintain the cover performance to reduce oxygen flux towards acid-generating tailings even in the event of a long dry period, a sand layer is suggested to protect the cover from excessive evaporation. It is possible to reach the environmental objective chosen for Doyon mine (10 mol/m2/year) with the protective sand layer, even in extremely dry conditions.

Jan 1, 2008

By Vnenk L, Hargraves AJ

Metropolitan Colliery has some areas of roof where immedi- ate support is required in development. The disadvantages of percussive roof bolting at the face have led to recent produc- tion trials with rotary boring and rapid=setting resin anchored roof bolts developed at the Colliery. The three innovations involved are: (1) the wet drilling of small holes with an all- hydraulic, portable rotary boring machine; (2) the rapidity of loading a "point anchored" resin bolt; and (3) the consistently high anchorage strength available. All three innovations provide striking advantages over the previously available alternatives. The greatest disad- vantage - that of cost of resin - is not prohibitive, and there is promise of improvement in the future. There are possibilities of variations of the techniques for special support problems in particularly difficult roofs.

Jan 1, 1971

By H. E. Cline, T. H. Alden

A study zvas made of rate-sensitive plastic deformation and superplasticity in alloys of lead and tin. These alloys (lead, PO-19 pct Sn, Sn-38 pct Pb, Sn-2 pct Pb, tin) were extruded, aged at room temperature, or melted and resolidified to produce a variety of ~nicrostrnctures. Flow stress us strain rate data were obtained frorn tension tests for strain rates between 10-6 and 1 min-1. The curve log o .us log £ was S-shaped jor fine-grained materials and approxinzately linear for coarse-grained nzaterials. At constant grain size, the behavior was relatively insensitive to conposition. High rate sensitivity (d log o/d log k) and superplasticity occurred at intermediate strain rates in fine-grained materials and are believed to be associated with a transition with strain rate in the mode of plastic flow. This transition was shifted to higher strain rates with increasing temperataire or decrensing grain size. The high rate rneclzanisrn is presunzed to be slip, while rnetallographic evidence sug-gests that the low rate lnechanism is pain boundary sliding. PEARSON' discovered that extruded eutectic alloys of Pb-Sn and Bi-Sn could be elongated as much as 2000 pct in tension. The ability for stretching decreased with aging time or annealing to increase the grain size. At high strain rates, or if the material was in the cast condition, normal ductility was observed. Following deformation of the extruded Pb-Sn eutectic at low rates, Pearson observed an equiaxed granular structure on an initially flat surface, while rapid straining produced elongated grains. He attributed the large deformation in the extruded alloys to the persistence of extremely small grains to a temperature sufficiently high for inter granular flow. Avery and backofen2 measured the strain rate sensitivity of the flow stress, m = d In old In 6, in the Pb-Sn eutectic and established a correlation between m and the tensile elongation. In the extruded eutectic alloy the strain rate sensitivity was 0.1 to 0.2 at rapid rates and the elongation was small, while at low rates m increased to 0.4 to 0.6 and superplastic elongation was observed. They also noted a grain size effect. In the case of the cast Pb-Sn eutectic the strain rate sensitivity remained at 0.1 over the range of strain rates of their experiment (3 x 10"3 to 2 min-I). These authors suggested that diffusional (Nabarro-Herring) creep was the mechanism by which deformation occurred at low strain rates, while climb-controlled creep occurred at high rates. Two predictions of this model are that, at low strain rates, the strain rate sensitivity approaches 1, i.e., Newtonian viscosity, and that the strain rate at constant stress varies as D/L2, where D is the coefficient of self-diffusion and L the grain size. More recently, a mechanical and microstructural investigation of the dilute superplastic alloy, Sn-5 pct Bi, has been done.3 The results show that the high strain rate sensitivity is associated with a transition with strain rate of the mechanism of plastic flow. At low strain rates, grain boundary sliding and its associated accommodation processes were evident, while at high strain rates quasi-uniform slip was concluded to be the dominant deformation process. The following experiments were performed to extend our knowledge of the phenomena of superplasticity to a larger range of strain rates, compositions, temperatures, and microstructures in the Pb-Sn alloy system. The question of why a cast structure does not exhibit viscous behavior although it appears to have a fine microstructure2 was investigated.

Jan 1, 1968

By M. Alnot, J. A. Mielczarski, J. J. Ehrhardt, J. M. Cases

The flotation behavior of minerals depends on the balance between hydrophobic and hydrophilic species present at the surface of the minerals. The direct characterization of the interfacial products formed by the interaction of water and an aqueous solution of amyl xanthate with chalcopyrite, tetrahedrite and tennantite (the two former contain antimony and arsenic) were carried out by X-ray Photoelectron Spectroscopy (XPS) and infrared (IR) reflection spectroscopy. The experimental data collected from in-situ (IR ATR) and ex-situ (XPS, IR External Reflection) measurements have let us determine the types of the adsorption products and to propose mechanisms of interaction between the aqueous solution of surfactant and surface of the investigated minerals. It is shown that two major processes take place at the mineral interfaces: (i) the interaction with water and oxygen resulting in the formation of the oxidation products which are mainly hydrophilic (but also a hydrophobic product was found), and (ii) the adsorption of xanthate producing different types of hydrophobic surface products. The results obtained show differences in the composition of the outermost atomic layers of the investigated minerals which obviously will produce differences in the flotation behavior of these minerals. This work forms a good fundamental basis for a better separation between copper minerals containing arsenic and antimony, and chalcopyrite.

Jan 1, 1995

We are moving into an era where we experience the consequences of the skills crisis û namely many resource models have been generated by inexperienced people under pressure to deliver high quality resource estimates in unsupported environments, often without technical mentors. These resource models form the basis of our decision to pursue actual mining. This begs the question: how valid are the resource models that form the basis of our mining decisions? This paper presents various model validation tools such as comparison of input and output statistics, swath plots, sectional or bench comparisons between drill holes and models as well as a variety of other approaches. Each model validation tool currently used in industry is examined:how the tool generates results,what assumptions exist,what constitutes a pass/fail in the test, and what interpretations to consider when using the validation tool. Each validation toolÆs suitability and the inherent flaws in the underlying assumptions are also discussed. These are supported with examples of good versus bad validations. Our principles based reporting codes provide flexibility in how models are generated and what approaches and/or parameters are used to generate resource estimates. This flexibility works well when used by experienced practitioners. However, our reporting codes assume a level of experience not always available in the current skills crisis. This paper seeks to provide minimum model validation prerequisites for model acceptance and suitability, regardless of the resource analystÆs experience. As we move forward, our immediate challenge is to ensure our baseline resource models are material, transparent and competent.

Jan 1, 2009

By Di Yang

The influence of high density (104 -105 A/cm2) electric current pulses (70 us duration) and continuous DC (~103 A/cm2) on the flow stress and ductility in tension of a high carbon steel wire were determined at 204°, 427° and 649°C. Electropulsing (100 pulses per second) with an effective current density of 100-200 A/cm2 gave a 10% enhancement in the uniform elongation of the wire at 204°C, but had no effect at 427°C and 649°C. In contrast, continuous DC either had no significant effect on the ductility or gave a decrease. The electropulsing per se decreased the flow stress only slightly at 204° and 427°C, but gave a significant decrease at 649°C. Continuous DC increased the flow stress at all three temperatures. The present results along with those by others suggest that the enhanced ductility by electropulsing and the reduction in flow stress may be further increased by raising the effective current density through increases in either the pulsing frequency, maximum current density of each pulse or pulse duration. This could conceivably increase the reduction per pass during wire drawing or the number of passes between anneals.

Jan 1, 2001

By Claude Cunningham

AEL’s Electronic Delay Detonators are in routine use and growing in both volume and breadth of application in Africa. This trend will continue and grow internationally owing to increasing pressure on rockbreaking operations to conform to sustainable development principles. A fundamental breakthrough has been achieved, bringing production blasting into line with technologies, which leverage performance through tight monitoring and control. When moving from pyrotechnic systems, benefits are normally realized without having to adopt different timing patterns, but significant additional benefits are realisable by using the flexibility and precision of the electronic units to enter windows of timing previously closed. The higher price and increased care needed are a worthwhile investment, enabling operations to cross the chasm to stronger revenues, but the system must be robust and suited to the application and personnel. Economic models are vital for keeping track of the potential and achieved benefits of these systems. Some resistance can be expected from those who stand to lose income as a result of the improved efficiencies.

Jan 1, 2004

By R. Oler

The need for yieldable ground support, particularly in high stress or deep mining conditions, has grown in recent years. This paper highlights some of the current industry limitations and provides selection criteria for a new yielding ground support system, DSI?s Dynatork Bolt. This bolt distinguishes itself by withstanding 16 ? 30 kJ of energy deflecting loads anywhere from 7 ? 20 tons (depending on the energy). A summary of the laboratory test results and case studies will also be presented as a measure of the performance of this dynamic product.

Jan 1, 2012

By Georgene Renner, Chee Theng, William Gleason

"With more than 900 booth spaces sold and 630 exhibiting companies displaying their wares, there was something for all 7,804 attendees on the exhibit floor of the 2015 SME Annual Conference & Expo in Denver, CO Feb. 15-18. The following is a sample of what was offered at the 2015 meeting.3D Laser MappingData collection and data analysis are changing how mining is done. One field in which technological advancements have made safer and more efficient operations possible is through site and slope monitoring.3D Laser Mapping, a United Kingdom-based company, was on hand at the 2015 SME Annual Conference and Expo to display its solutions for the mining industry, including its SiteMonitor4D system.The state-of-the-art laser measurementbased system was developed in partnership with geotechnical engineers and mining surveyors, and is a simple-to-use, reliable solution that has the flexibility and performance to function in a range of monitoring applications.The system measures and monitors the stability of rock faces, landslips and man-made structures, including ongoing, periodic measurement of volumes - stockpiles, cutbacks and waste dumps and has high-speed laser scanning for regular mapping of large areas by mounting the scanner on a vehicle.With specifications that other monitoring techniques cannot achieve, laser scanning opens up a new dimension in mine measurement and monitoring.www.sitemonitorsystems.comA.R. Wilfley and Sons Inc.Founded in 1919, A.R. Wilfley and Sons Inc. has been manufacturing dynamic-seal and static-seal pumps in Colorado for nearly 100 years, delivering its high-reliability, low-maintenance, heavy-duty process pumps and slurry pumps to the global mining industry. The family-owned company is now in the hands of the fifth generation."We are the dynamic-seal experts," regional sales manager Cesar Murillo said. "Most other companies are unable to do 100 percent dynamic seals and have to use mechanical seals or packing," he said, but Wilfley’s sealing technology does away with the need for mechanical seals and packing and their associated problems. As a result, solids and slurry handling capabilities are high, the pump can be run dry, and product dilution is eliminated. The pump can tolerate more misalignment, more cavitation, and more vibration in the pump during operation."

Jan 1, 2014

By E. P. Dahlberg, R. E. Reed-Hill

On the assumption that stress or strain relaxation occurs as the result of a thermally activated process, equations are derived relating to tensile experiments that give the strain as a function of the time under the condition of constant stress, and the stress as a function of the time for constant strain. It is demonstrated that if the strain-rate equation i = previously proPosed by Kuhlmann., is used as a starting point, then the relaxation of strain at constant stress may be expressed by the equation c = (-RT/(Y) 1tz tanh (t + is the strain capable of being relaxed at any given instant. Similarly, it is shown that the relaxation of stress at constant strain may be given by a = (-RT/B) In tanh (t + t0)/27, where a is the instantaneois value of the relaxable stress. The fact that these relationships reduce to well-known empirical equations at both large and small values of the stress Or strain is also shozcn. The present theory is shown to agree well with experimental data obtained from tensile elastic aftereffect experiments on a zirconium specimen prestrained at 77 k as to make it strongly anelastic. It is also demonstrated that elastic aftereffect data obtained using torsional specimens ?,Lay agree reasonably well with the equation derived for the case of tension. RELAXATION experiments are often employed as a means of studying metallic deformation mechanisms.' The simplest and most commonly employed techniques involve stress relaxation at constant strain and strain relaxation at constant stress. In general, however, investigations of this nature have been seriously handicapped in the past by a lack of suitable equations giving the time dependence of the relaxing variable over an interval that extends from small strains up into the region where internal-friction experiments become strain-amplitude dependent. This paper presents a derivation of such a set of equations for the case where the time-dependent part of the strain is anelastic or recoverable and the specimens are loaded in simple tension. The relaxation of strain under the condition of constant stress will be considered first. Let us assume that strain relaxation occurs as the result of a reversible thermally activated process that occurs at a number of relaxation centers lying in an elastic matrix. Then, following Kuhlmann,2 we may express the rate of strain relaxation as follows: where C is the strain rate, AFx the free energy of activation of the process controlling strain relaxation, a, the effective or average resolved stress at the relaxation centers, u an activation volume, R the universal gas constant, T the absolute temperature, > a factor with dimensions of a volume that accounts for the strain contribution of a successful operation of a unit process, N the number of relaxation centers per unit volume, and v the Debye frequency. The first term on the right of Eq. [I] represents a strain rate in the direction favored by the stress, while the second term represents the rate in the opposite direction. It is implied in Eq. [I.] that both F and v are symmetrical with respect to the two basic directions of operation of a relaxation process. Eq. [I] may also be written where and S and Q are the activation entropy and activation energy, respectively, of the relaxation process. In the following, A will be considered a constant. This is compatible with a set of experimental conditions where the relaxation rate is controlled by a single basic reversible process in which it may be assumed that the temperature dependence of the product ?Nv is negligible in comparison with the temperature variation of the exponential term. It is also implied that v, 7, and N do not depend strongly on a, . In deriving a relationship for the strain as a function of the time from her equation, equivalent to Eq. [2], Kuhlmann2 chose to consider only the limiting cases where the time was either very small or very large. It will now be shown that it is possible to integrate Eq. [2] to obtain a single equation valid over a wide range of strains if the concept of relaxable strain is introduced. The use of this quantity, which is the difference between the instantaneous value of the strain and the value of the strain at complete relaxation, represents the primary point of departure of the present theory from that of earlier workers. Let us express the effective stress at the relaxation centers in terms of strain. For this purpose we may use the following equation derived by zener3 for the case of strain relaxation at slip bands: where M? and M are the relaxed and unrelaxed moduli respectively, go the applied constant tensile stress, and m an average orientation factor that takes account of the fact that a,, the effective stress at the relaxation center, may not be a tensile stress (i.e., a

Jan 1, 1967

By R. L. Perrine

A stability theory is developed for miscible liquid-liquid displacement within a porous medium. In the usual case considered, a high-density high-viscosity "oil" is displaced downdip by a low-density low-viscosity "solvent'! Perturbation methods are used to find the conditions under which the spreading mechanism changes from the stable dispersion process to unstable viscous fingering. We find that instability is conditional, that there is a dependence on the shape of a disturbance leading to a"diameter" effect and that very difficult experimental scaling problems may result. A useful consequence is the definition of a minimum "slug size" for stable miscible displacement. This should make possible optimum use of the solvent process for oil recovery. The results may apply to many situations in which one fluid displaces another of somewhat different fluid properties within a porous medium. INTRODUCTION The process of miscible liquid-liquid displacement looked very favorable when it first received serious consideration as a means to increase petroleum recovery. Some early laboratory results were interpreted to mean that only a small "slug" of solvent was needed, perhaps 2 to 3 per cent of a hydrocarbon pore volume. This "slug" could recover the oil in an entire reservoir provided the fluids remained miscible.1,2 Only a slow growth of the "mixing zone", or gradual transition from oil to solvent, should occur. This would follow naturally from mixing by a dispersion mechanism such as that described by Scheidegger.3 And, indeed, laboratory cores have shown this kind of behavior provided solvent viscosity was at least as great as that of the oi1.2,4-6 The same kind of behavior has also been observed with solvent viscosity lower than that of the oil after the distance traversed became large. Not all laboratory results have been this favorable, however.7-9 Mixing zone growth may become proportional to the distance traveled rather than the square root of this quantity. Such behavior accompanies high rates in short systems of large diameter, provided the viscosity ratio is adverse. If this more rapid spreading were to persist in a reservoir, the solvent requirement for miscible "slug" displacement could exceed 30 per cent of a pore volume. There is considerable economic importance in the difference between 3 and 30 per cent solvent. A 1ogical conclusion is that two different kinds of flow behavior are possible, with each kind leading to a different result. One kind gives efficient displacement, the other does not. In the efficient case, the solvent bank spreads out only by the mechanism we have termed dispersion. Under these conditions, displacement is as near piston-like as possible. In the second kind of flow, found only with adverse viscosity ratios, viscous fingering occurs. That is, permeability variations cause a small finger of low-viscosity solvent-rich fluid to move ahead of its average position within the mixing zone. This creates a path of low resistance to flow, and an even greater amount of solvent-rich fluid follows. Thus, the process is autocatalytic. Once started, the fingering mechanism rapidly becomes dominant. The question to be answered is this. Under what conditions will each of these two different kinds of flow occur? In particular, what conditions denote the transition from dispersion to viscous fingering as the solvent spreading mechanism? The answer may tell us whether or not the desirable, near piston-like miscible displacement process is practical. An answer to this problem can be obtained from theory by the use of perturbation methods. The procedure is as follows. We first formulate a mathematical representation of the system. Then a small disturbance (or perturbation) in solvent concentration profile is introduced and observed to see what happens. Unstable flow is indicated when a small disturbance will grow larger. This will lead to eventual viscous fingering. If on the other hand the disturbance dies out, the displacement is stable. In this latter case, with dispersion as the spreading mechanism, near piston-like displacement is possible. Thus, this paper presents the development of a stability theory for miscible liquid-liquid displace-

By H. L. B. Gould, Jr. Wenny D. H.

TO date there has been but limited interest in alloys of 80 to 95 pct Co and Fe with or without other additions. In 1932, S. R. Williams' reported practically zero magnetostriction for the 90 pct Co-10 pct Fe alloy. This same composition was used for pole pieces to control the magnetic field in magnetrons operating at high temperatures.' In 1947, a 90 pct Co, 9.5 pct Fe, and 0.5 pct Mn composition was investigated3 for use in ballast lamps because of its high temperature coefficient of resistance. Recently, as part of a survey of ductile and malleable magnetic alloys capable of being processed to thin gages for possible applications in memory devices, the high Co-Fe alloys have been re-examined to determine their fabricating and magnetic characteristics. Alloys from 80 up to 95 pct Co and Fe with and without additions such as vanadium were prepared. In general these all had excellent ductility and malleability. Wire was drawn to thin gages without difficulty and fine hard-drawn wires flattened to 2) The phenomenon may have potential in estimating the carbon content of molybdenum. A given solution-treating temperature and cooling rate could perhaps be calibrated so that the area fraction of surface covered by carbide could be interpreted in terms of carbon concentration. By segregating to the surface, a big "magnification" of the carbon content is obtained, which should make the method cheap, direct, and sensitive and, therefore, perhaps of interest to the molybdenum industry. This work was conducted at Battelle Memorial Institute. Financial support by the Aeronautical Systems Division, United States Air Force, under Contract No. AF 33(657)-7376, is gratefully acknowledged, and the writer is thankful for the experimental assistance of Miss Marjorie Cantin. ribbon without splitting. Similarly, strip was cold-rolled as much as 99.75 pct reduction to a 0.25 mil thickness without intermediate anneals. Samples of round and flat wire and foil, in the severely cold-worked and annealed states, were checked for magnetic characteristics. The alloys exhibited widely divergent magnetic characteristics depending on the processing and heat-treating procedures used in preparing the samples. Direct-current hysteresis loops showing the different magnetic characteristics of 90 pct Co, 9.5 pct Fe, and 0.5 pct Mn alloys are shown in Figs. 1 to 8 inclusive, while Figs. 9 and 10 show the loops for an alloy of 82 pct Co, 11.75 pct Fe, 5.6 pct V, and 0.65 pct Mn. Figs. 1 and 2 show the high remanence and exceedingly square-loop characteristics of the hard-drawn wire and ribbon roll flattened therefrom. With the change in processing from roll flattening to flattening by drawing through flat diamond dies the resultant change in texture is accompanied by the drastic change in the shape of the loop as shown in Fig. 3. This skewed loop on annealing reverts to a more normal loop as shown in Fig. 8. The most unique loops are obtained with flat rolled strip. These are shown in Figs. 4 and 5. In the case of the hard-rolled material, Fig. 4, there is little change in induction until the magnetizing force reaches 50 oe. From 50 to 60 oe there is a sharp increase in induction to over 15,000 gauss, which for all practical purposes is saturation. The induction remains at a constant value while the magnetizing force decreases to 40 oe. At this point the

Jan 1, 1965

By D. Marcus

A methodology was developed wherein. the increase in compressive strength, mineralogical changes and pore water composition were all studied simultaneously as a function, of moisturized spent shale curing time. From these results the relationship between the nature of cementation process and the composition of pore water was established. Heavy metals were entrapped in the cementing constituents and the pore water became mainly a solution of alkaline sulfates. While the specific data are applicable only to the material studied, the methodology and general conclusions are useful for evaluating the environmental factors in spent shale disposal and expected leachates composition.

Jan 1, 1984

By A. W. Ashbrook

There are many methods of analysis available for compounds similar to those used in solvent extraction processes. However, the majority of these methods are not directly applicable to the determination of solvent extraction reagents, especially in raffinates. The number which are applicable is further reduced if limited to the more simple methods suitable for process control purposes. Commercial extractants are complex mixtures. The complexity is increased by the addition of diluents and modifiers in two-phase systems containing metals. Raffinates from solvent extraction processes contain the more polar components of the extractants and the products of decomposition. Only a limited amount of information is provided by total organic carbon or spectrophotometric analysis. The complexities of the systems require a combination of methods.

Jan 1, 1978

By Emilie Williams

The Mouska Mine uses primarily shrinkage mining to extract the narrow veins that contain its mineralization. Mining is currently occurring on levels 12 to 14, reaching depths of 800 m below surface. Although the mine is not considered ?deep?, no backfill is available to fill empty stopes and certain areas remain open for over 500 m in height. As only narrow sill pillars remain to separate the levels, a highstress environment is created. Seismic activity was first observed when mining reached Level 11 (600 m deep) and has steadily increased since then. Seismic activity is associated with the highly-stressed sill and rib pillars; no geological structures have demonstrated significant seismic potential to date. In response to this increase in activity, pillar dimensions have been increased with depth and dynamic ground support has been installed. Seismic and pressure monitoring have been implemented, among other types of instrumentation. The following paper further describes the challenges associated with using conventional methods in the high-stress environment typical of the Canadian Shield, as well as several solutions implemented to mitigate these risks.

Feb 1, 2008