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By Oscar Perales Perez, Atsuo Kasuya, Kazuyuki Tohji, Yoshiaki Umetsu

"The removal of iron and various heavy-metal ions by their incorporation into stable ferrite-type precipitates at 25°C is a promising alternative to clean up large volumes of polluted aqueous effluents. Our research work investigated the conditions to produce magnetite and various M-bearing ferrites (where M: Zn, Cu, Co, Ni, Cd, etc.) directly from aqueous solutions at 25°C by simultaneous control of the oxidizing conditions and pH. The formation of the solids was followed by monit9ring the oxidation-reduction potential (ORP) and rate of proton release during the aerial oxidation of the suspensions at constant pH (contact stage). Only mildly oxidizing conditions, represented by ORP values between -110 mV and -150 mV and a moderate oxidation rate of Fe(II) species were conducive to well-crystallized ferrites at ambient temperature.' It was also found that increasing the Fe/M mole ratio in starting· solutions enhanced the stability ·of the M-bearing ferrites at ambient temperature. When the formation of the ferrite was incomplete, aging of the sludges in their mother liquors at 25°C promoted the crystallinity of the precipitates. The mentioned conditions ·favored the suitable progress of the ferrite-forming reaction involving the oxidation of Fe(II) entities, subsequent hydrolysis of produced Fe(III) species and dehydration of the intermediate:· Furthermore,· the ferrite formation at· low temperature permits the elimination of iron and co-existing heavy metal ions to sufficiently low concentration.In tum, the characterization of the precipitates evidenced their magnetic nature (room-temperature saturation magnetization above 60 emu/g) as well as the effective incorporation of target metal ions into the ferrite structure."

Jan 1, 2000

By T. A. Silva, A. C. Bragança

Lime has been added to the iron ore slurry transported by the Samarco pipeline since its operation start-up in 1977.Initially, internal corrosion was the main concern therefore the reagent was used only for pH correction. Over the last ten years, though, transport of more complex slurries demanded a significantly higher dosage of lime to guarantee adequate rheology control. Several other reagents have been tested for the same purpose yet none has proven to be as effective regarding technical performance, environmental impact and cost. However, an alternative was sought so that the slurry rheology could still be controlled in case lime addition became impracticable. The objective of this paper is to present a technical solution for this matter, which takes into account environmental aspects. It consists of adding soda for pH correction and an organic coagulant as a rheology modifier. The latter is a quaternary ammonium salt which affected the slurry transport properties in the same manner as lime when tested in a laboratory. It showed no plug formation and allowed solid particles to settle, forming a loose sediment after rest. These results indicate a low probability of plug occurrence in the pipeline and the formation of a readily reslurryable sediment upon shutdown of the pumping system. Industrial tests should be performed in order to validate the laboratory results.

Jan 1, 2007

By S. S. Gross

A program was conducted to determine whether sufficient quantities of the flame retardant, ammonium phosphate, could be incorporated in a water-based foam solution to prevent or delay reignition (burnback) without. significant degradation of foam properties. Up to 20% of mono and diammonium phosphate was added .to d high expansion foam solution. This mixture was applied as a high expansion foam to burning wood and coal samples. The effect of this mixture on burnback was laboratory tested by placing the wood or coal sample in front of a radiant panel. It was found that diammonium phosphate levels of 20% by weight prevented reignition without degrading foam properties. A field test was then conducted using a 20%, diammonium phosphate mixture and a control with no phosphate on a wood crib fire. The experimental foam did extinguish the crib fire faster than the control as evidenced by the smoke from the crib. However neither crib reignited.

Jan 1, 1982

By José N. De Piérola C

Qda. Honda es una pequeña quebrada ubicada en la vertiente occidental sur del Perú que aporta agua no regulada a las operaciones de la unidad mineraToquepala de Southern Perú. Sin embargo, durante la temporada de lluvia se arrastra material sólido en suspensión y de fondo, inhabilitando las estructuras de captación y limitando su captación de la cuenca. En ese sentido, el presente texto desarrolla una alternativa para modificar la captación de la cuenca - en tanto permita incrementar el flujo captable en periodo húmedo hasta los 110 L/s, a través de un sistema novedoso de filtración adicional al de ventana superficial; y en periodo seco, se disminuya el flujo captado por medio de un escurrimiento aguas abajo de 20 L/s. De forma que desarrolla una distribución ajustada al comportamiento natural del cauce y ambos usuarios se benefician de una fuente muy errática y limitada.

Sep 14, 2009

By B. M. Nyombolo

The interest shown in our paper by Drs Schaekers and Dew, and their favourable comments, are appreciated. However, some of their remarks require a response. Stability testing procedures Regarding the issue of stability-testing procedures, we concur that no long-term procedure has been accepted by either environmentalists or the mining/processing industry as a valid method to test the long-term stability of solid wastes. We agree that the method we used is no exception, and we certainly did not claim that it should be recognized as such. What we did attempt to portray was that we had designed the test procedure in an attempt to simulate, at a very small scale, a tailings dam environment.

Jan 1, 2001

By M. R. Tek, F. F. Craig, J. O. Wilkes, C. S. Goddin

The waterflood performance of a water-wet, stratified system with crossflow is computed by a finite difference procedure. The effects of five dimensionless parameters on tile oil displacement efficiency, water saturation con-tour.7 and crossflow rates are evaluated in the absence of gravity forces. Crossflow due to viscous and capillary forces is shown to exert a significant effect on oil recovery in a field-scale model of a two-layered. water-wet sandstone reservoir. The crossflow is at a maximum in the vicinity of the front advancing in the more permeable layer. Under favorable mobility ratio conditions, the comparted oil recovery with crossflow always is interrnerliate between that predicted for a uniform reservoir and that for a layered reservoir with no crossflow. INTRODUCTION The important erects of reservoir heterogeneity on waterflood performance are commanding increased attention in the technical literature. Much of this attention is centered on two categories of layered reservoirs: those in which layers are non-communicating and those in which crossflow of fluids occurs between the layers. In the first category, the reservoir is assumed to consist of discrete layers, each uniform within itself and differing from the others only in such properties as thickness, porosity and absolute permeability. The performance within each layer is calculated by one-dimensional flow theory, and the performance of the total reservoir is obtained by summing individual layer performances. Capillary and gravity effects usually are not considered. Representative publications dealing with thi5 type of reservoir are those of Stiles,' Dykstra and Parsons,' Hiatt,3 Warren and Cosgrove' and Higgins and Leighton." Prediction of performance for reservoirs in the second category is considerably more difficult since viscous, capillary and gravitational forces all play important roles in causing crossflow between layers. A number of authors have investigated the simpler problem of two-dimensional displacement flow in a stratified system with a mobility ratio of unity and negligible capillary and gravity effects.'; Others have considered two-dimensional, non-steady-state flow of a single, slightly compressible fluid in a stratified reservoir. A limited number of laboratory oil displacement tests in layered models with crossflow have been reported. Miscible floods (with resultant zero capillary forces) in layered five-spot models were conducted by Dyes and Braun," who studied the effect of mobility ratio with zero gravity forces, and by Craig et al. 12 who studied the effect of gravity forces at constant mobility ratio. Waterfloods in layered five-spot models (with cross-tlow due to capillary, viscous and gravity forces) were conducted by Gaucher and Lindley,"' who showed the effect of gravity forces in causing underrunning of the injected water and by Carpenter, Bail and Bobek, 14 who demonstrated the reliability of Rapoport's" dimension-less parameters for scaling layered systems. Waterfloods in rectangular layered models were conducted by Richardson and Perkins."' who investigated the effect of velocity at constant mobility ratio and with zero gravity forces, and by Hutchinson," who studied the effects of varying mobility, layer permeability and layer thickness ratios. The differential equations which rigorously describe waterflooding in a heterogenous porous medium are non-linear and do not facilitate analytical solution. By using finite difference approximations it is possible to obtain a solution to any desired degree of accuracy. Such a solution, using an alternating direction implicit procedure (ADJP), is described by Douglas, Peaceman and Rachford.18 In the present study, a computer program using ADJP explores systematically the effects of important parameters on waterflood performance of a two-dimensional, two-layered, field-scale model of a water-wet sandstone system. Particular attention is given to evaluation of the water saturation contours and crossflow rates at the interface between layers to gain improved understanding of the crossflow mechanism. PROCEDURE BASIC: FLOW EQUATIONS The basic flow equations for two-dimensional, two-phase, immiscible, incon~pressible flow in a porous medium are:

Jan 1, 1967

By Edward P. Chapman

IN the Leadville district toward the close of the "intermediate mesothermal period" of mineralization, there occurred a stage of ore deposition marked by a rather complex mineral association. As bismuth minerals formed in many places during this period, it is here called the "bismuth stage" for convenience of description. The minerals so far identified with this stage, listed roughly in the order of prominence, are: chalcopyrite; several varieties of galena, differing slightly from one another in their small contents of silver, bismuth and tellurium; altaite; hessite; galenobismutite; alaskaite; aikinite; ,gold; tennantite; argentite; and perhaps sphalerite and arsenopyrite. With the exception of gold, the age relations of these minerals are difficult to determine. As shown in their descriptions, they all appear contemporaneous and hypogene. Gold may be in part contemporaneous, but most of it is distinctly later. Where minerals of this stage occur so that they can be mined alone, as at the Tucson mine, they constitute high-grade ore. Elsewhere their presence in small amounts has served to increase greatly the value of what otherwise would be low- grade pyritic or zinc-lead sulphide ore. The distribution of the bismuth ores corresponds closely to the distribution of gold ores, though not so general. It seems probable that most of the gold in the district was deposited during the "bismuth stage." These ores occur relatively near the supposed centers of mineralization in Breece and Printer Boy Hills or deep down along the Tucson-Maid fault, which is one of the well recognized channels of mineralization in the Iron Hill and Graham Park areas. Consideration of the high-grade nature of this mineralization and the fact that it appears to be found relatively close to the source of mineralization suggests that prospecting along some of the known channels, even deeper than they have yet been prospected, may offer hope of commercial success.

Jan 1, 1939

Jan 1, 1958

By Thomas Fraser

"AIR-SAND" is the term which has been given to a process of separating refuse material from coal by means of a body of dry sand artificially fluidized and maintained in that condition by a continuous stream of air bubbles flowing through the sand body. By proper regulation of the rate of air flow, this fluid air-sand body may be maintained at such a density that coal will float near the surface and the refuse, which is heavier, will sink through the sand to the bottom of the container. This separation is a float-and-sink operation similar to the separation of wood chips and stones in water; the one floats and the other sinks, irrespective of size of pieces. This was the objective sought in the development of this method of cleaning coal-a dry process which requires no preliminary sizing of the coal. METHOD OF PRODUCING THE AIR-SAND MEDIUM Figure 1 shows the cast-iron cell used for testing at the Central District Experiment Station of the Bureau of Mines, Urbana, Ill. This consisted of two castings: a. rectangular box 12 in. square in cross section and 18 in. tall, open at both ends and flanged on the bottom; and a cubical box also 12 in. square inside, with a closed bottom and flanged top. A porous diaphragm is bolted between the flanged ends of the two castings. The upper part of the cell above the diaphragm is filled with river sand screened through 20 mesh without removing the dust. Air under suitable pressure is admitted to the lower part of the cell below the diaphragm. The air passes through the diaphragm and bubbles up through the sand, distending the mass and throwing the sand particles into motion.

Jan 2, 1926

Mining Methods LUCIEN EATON, Chairman GERALD F. SHERMAN, Vice-chairman CHARLES W. WRIGHT, Secretary Alluvial Mining CLINTON BERNARD CHARLES H. MUNRO CHARLES JANE N H. R. NORSWORTHY Open-cut Mining Iron MAX H. BARBER J. A. MacKILLICAN Copper MICHAEL CURLEY H. B. TEMPEST Underground Mining Iron C. H. BAXTER CARL BREWER TENNEY C. DESOLLAR Copper W. B. DALY A. H. WOHLRAB R. W. THOMAS

Jan 1, 1934

By Rowan A' Murry Karstel

One way to ensure dragline productivity is by Increasing the size of the dragline bucket. In August 1994, Optimum Colliery in conjunction with Van Reenen Steel, Northwest Applied Technology, SSAB of Sweden and Barlows Equipment launched the new lightweight dragline buckets. Optimum built the first prototype bucket that was used for the deslgn for future buckets. After knowledge had been gained from measuring the input force of the bucket Northwest Technologies designed the new bucket with finite element analysis. Together with the knowledge of quenched and tempered steel from SSAB of Sweden and Barlow Equipment, the new Wrightech bucket was born.

Jan 1, 1998

By Ivar Eskerud Smith, Ole Jørgen Nydal, Niranjan Reddy Challabotla, Svein Sævik

INTRODUCTION Airlift pumping, utilize compressed air that is injected at the bottom of a vertical pipe submerged in the water, reduces the mixture density inside the pipe and lifts the liquid or mixture of liquid and solids. This type of pumping technology, which is simple and without moving parts submerged in water, which provides several advantages compared to the mechanical pumping. Airlift is used in various difficult pumping applications such as transport of fluids corrosive to metals, explosives, nuclear and toxic materials in chemical industries, diamond mining and coal transport. Application of airlift to deep sea mining conditions was investigated by extensive laboratory experiments [1], theoretical analysis [2], and limited proof of concept field studies [3] starting in 1970’s with the discovery of huge amounts of manganese nodules discovered on the seabed at a depth of ranging from 4000 to 6000 m . Even after extensive investigations over the last five decades, there exists no commercial application of airlift technology for lifting of minerals. The major problems with the application airlift for deep ocean mining was (a) lack of control over the expansion of the injected gas, which increases the velocity in upper part of the riser pipe (b) lower efficiency compared to mechanical pumping [3]. Different flow regimes are encountered in airlift pumping: bubble, slug, churn and annular flow. Annular flow regime is the least efficient in lifting of particles and churn flow has better efficiency [3].

Jan 1, 2018

By M. Rantapaa

Measurable improvements in throughput have been documented at Barrick Goldstrike due to increased ore fragmentation through efficient drilling and blasting techniques. A decrease in throughput at the autoclave, due to increasingly hard ore, was identified in early 2002. A team of individuals from the open pit and process areas worked closely on the Drill-to-Mill (D2M) Continuous Improvement initiative to ensure that it would address the needs of both groups, with the target of actually improving throughput in future years, despite the projected harder ores. A series of tests were conducted to determine if adjustments to drilling and blasting could positively influence throughput. Better fragmentation and a subsequent increase in mill throughput were achieved through the use of electronic caps for more precision and flexibility, as well as for allowing extremely fast shots; explosives with a higher velocity of detonation (VOD) to provide for improved shock energy; and improved distribution of the explosives by decreasing pattern spacing. Early tests indicated a significant increase in throughput when processing identified harder ore. It is anticipated that the total process throughput (hard and soft ore) will increase by 6 tph in 2003 due to the improved fragmentation of the hard ore. Barrick Goldstrike?s D2M initiative includes roaster hard ore (BWI>17), as well as autoclave hard ore (BWI>15). Approximately 6 million tons of D2M material were shot in 2003, a relatively small amount compared to the 150 million tons to be mined. The benefit of additional ounces produced should far outweigh the additional drilling and blasting costs.

Jan 1, 2005

By E. H. Griswold

The surveying of oil wells has in recent months become a common practice in the deep fields of the Mid-Continent area. Borehole surveys have been made by mining companies for many years, but the introduction of such methods into the oil fields has been delayed until the past few years, because the value of survey data was not fully appreciated. The acid and gelatin bottle methods of obtaining the angle of deviation and the floating compass method of obtaining the direction of horizontal drift have been in use for more than 20 years. A photographic recording instrument consisting of a plumb bob, magnetic needle and electrically operated camera was devised and used in the Rand mining fields of South Africa prior to 1912.1 Another and improved photographic instrument, depending upon orientation of the drill pipe instead of polar magnetism for direction, has been invented and used. The acid bottle method has also been used in conjunction with oriented drill pipe. The magnetic compass is not reliable for oil-well work because of the unsymmetrical attraction of the needle to the well casing and possible magnetic formations. Many engineers also concur in the opinion that orientation of the drill pipe from instrument to surface will be inaccurate because of the torque exerted between the drill pipe and walls of the hole, causing the lower sections of pipe to twist. When it is considered that 4000 ft. of 6 in. drill pipe has approximately the same slender-ness ratio as 6 ft. of silk thread, such twisting effects can be readily visualized. The gyroscopic compass has been suggested for use in direction finding, but the high cost of such instruments will prohibit their use, except in special cases. Due to the lack of accurate direction-finding instruments, almost all of the survey work in the Mid-Continent fields has been of the acid bottle method alone.

Jan 1, 1929

By S. Saluja

El presente texto describe las aplicaciones de los pernos de roca como un sistema de sostenimiento en la minería. Asimismo, se comparan los distintos tipos de pernos de roca, se muestran los pernos de roca de madera y la función de los tijerales de sostenimiento en la prevención de la comba del techo.

May 1, 1981

By A. Landsberg

Kaolinitic clays are potentially a vast domestic resource for aluminum. Utilization of this resource could decrease or eliminate the nearly complete dependence of the United States on foreign raw materials for this important metal. Furthermore, processing of clay to aluminum through anhydrous chloride metallurgy could reduce the high electrical energy requirements of the conventional Hall-Heroult aluminum reduction process. Several anhydrous chloride processes have been proposed; however, unresolved technical problems have prevented their commercialization. In particular, an acceptable chemical means has not been found to extract aluminum from clay as a highly pure anhydrous aluminum chloride. This Bureau of Mines report identifies and discusses the important chemical problems involved in achieving an acceptably rapid, self-heating, selective chlorination reaction and the subsequent separation of iron chloride byproduct from the anhydrous aluminum chloride.

Jan 1, 1983

Large mining operations need equipment that consistently performs as expected. The most effective way of ensuring this is to have a defined life cycle with an optimised maintenance strategy. The determination of this life cycle is an economic decision, influenced by the construction and utilisation of the equipment. An effective life cycle costing (LCC) tool must be able to process the many variable factors involved.Many factors influence the costs that are associated with a machine over its life. The most variable of these are the costs of maintaining the equipment. Maintenance costs are dependant not only on the utilisation of the machine, but also on the strategy that has been developed to support the machine through its life. A combination of supplier support, component changes, regular servicing and unscheduled maintenance needs to be modelled, based on a variety of drivers. Traditionally spreadsheets have been used to model these factors, but the increasing complexity of the situation can make spreadsheets unwieldy and difficult to manage. A database solution that breaks each activity into its constituent components, links them to an associated mine plan driver and then aggregates the result is the ideal tool to provide a time based cost profile. The evaluation of a number of scenarios, representing different maintenance strategies/life cycles can be rapidly undertaken. Auditability through inbuilt tools is required to provide easy tracing of data. Use of the host company's account structure allows for reporting against the standard chart of accounts.

Dec 6, 2010

Vale Inco?s Coleman Mine 153 Orebody is a narrow vein deposit with a dip that varies from 30 to 70 degrees. It has a strike length of 1200-feet and the current mining extends from the 4250 level to 5100 level. The primary mining method is mechanized cut-and-fill although drift-and-fill is also used in wider sections of the ore zone. The ore body is divided into six main mining horizons with an average of three mining blocks on each cut. There are some interesting rock mechanics challenges related to mining upward from the 4550 level and these challenges are increasing as the mining front progresses toward the 4400 level. The mining of the 4550 block is currently at cut 13 whereby the crown pillar thickness is approximately 60-feet. Significant factors including increased stress levels in the crown pillar, the change in the orebody dip at this level and a recently indentified geological structure in the footwall, have all combined to introduce seismic activity in the footwall of 4550 level. Closer studies revealed a consistent trend of seismicity that was further examined with core logging and Acoustic TeleViewer technology. The data from these assessment tools disclosed a geological structure that is influencing the mining environment. This paper reviews the seismic analysis for the 4550 level mining zone and the subsequent procedures used to locate the new geological structure. The paper also discusses the key mining practices used to successfully mine cut 13 of 4550 level and briefly reviews the studies that are underway to up-date the mine design for continued extraction of high-grade ore in a safe and productive manner.

May 1, 2009

By Robin O. Williams

Robin 0. Williams (Oak Ridge National Laboratory)— The authors have questioned the degree to which the coherency strains between the iron-rich and chromium-rich phases are isotropic as proposed in Ref. 5 on the basis of the difference between the elastic properties of the two phases. The relative magnitude of the stresses is determined by the moduli as shown by Eqs. [2], [3], and [4] of Ref. 34. However, the moduli of the two phases have no direct bearing on the uniformity of either the stress or strain within either phase. The idea that the strains are isotropic within each phase (but normally of different magnitude and always of different sign) is based entirely upon the experimental observation that X-ray line broadening has not been detected even when the particles become rather large. It has not proven possible to grow the particles sufficiently large that they lose coherency. Based upon this lack of line broadening one can estimate an upper limit for the nonuniformity of the strains within each phase as follows. It is considered possible to detect line broadening if it is as great as 10 pct of the separation of the K, doublet for the (211) line using chromium radiation. The doublet separation would correspond to a total strain of 0.0017 such that the total variation of lattice parameter relative to the average lattice is now k0.05x0.0017 or something less than ± * For the present case the strain in each phase is roughly 0.002 such that the variation of strain within a phase will not exceed 5 pct. It is stated that the expression derived for strengthening for the hydrostatic straining as observed in this system would substantially overestimate the magnitude due to dislocation flexure. This is contrary to the conclusion reached in the original paper34 for the present range of particle sizes. What is the lowest temperature at which a has been observed to form in this alloy? M. J. Marcinkowski, R. M. Fisher, and A. Szirmae (nutlzors' reply)— -Williams' arguments based on X-ray findings for a chromium-rich precipitate and an iron-rich matrix strained to a common lattice parameter are certainly convincing. This being the case, there are no shear components of strain associated with the precipitate-matrix aggregate to interact with the shear components of the dislocation stress fields, contrary to the opinion expressed by the present authors. On the other hand, the present authors, in spite of this error, did not expect the shear interactions to be significant. The chief objection to Williams' model in the present case is that the various segments of the dislocation line are assumed to pass from one potential valley to the next independently of neighboring segments. This is only true for a highly flexible dislocation line, i.e., one whose radius of curvature is something less than the center to center distance between precipitate particles which amounts to about 90A in the present alloy. In order to maintain this curvature, an externally applied shear stress of at least 230,000 lb per sq in. would be required or about four times the observed stress. It is therefore concluded that the dislocation lines move rather rigidly through the lattice. This being the case, the forces on the dislocation resulting from the hydrostatic interaction between the stress fields of the edge-dislocation components and the precipitate particles should average out to zero; that is particles above the below the slip plane produce forces on the dislocation of opposite sign and therefore will cancel when averaged over the entire length of the dislocation. On the other hand, since the dislocation is not perfectly rigid, Williams' model may lead to some strengthening, but far less than that predicted. A second and equally serious objective to using Williams' strengthening model for the present alloys is that profuse wavy slip due to the motion of screw dislocations played a predominant role not only in the unaged alloys but in the fully aged ones as well. Since the screw dislocation has associated with it only shear components of stress the hydrostatic strengthening model no longer applies. In view of these arguments the present authors must reject Williams' model of strengthening as being pertinent to the present alloy system. The present authors have made no detailed study of the lowest temperature at which a forms in the quenched ferritic alloys. None was ever observed n the alloys aged at 500°C so that forma-tion must occur at temperatures higher than this and was therefore not a factor in the present study.

Jan 1, 1965

By F. Wendling, G. M. Peixoto, J. A. M. Cano

A brief introduction is made on the existence of sulfides in the top gas of the Midrex Shaft Furnace, giving consideration to the operation of the furnace and the liberation of sulfur, as well as its consequential effects on the reduction process. The text shows a study of sulfur distribution in the pellet, emphasizing the importance of this distribution in relation to the liberation of sulfur during the reduction. A study was made to determine the sulfur compounds that exist in the pellets, showing ways of controlling the sulfur distribution and reducing its liberation during reduction.

Jan 1, 1991