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By N Stockton

Some preliminary results on the secondary leaching of previously heap leached gold ore are presented. Alternative lixiviants for gold comprising chlorine, thiourea and thiosulphate were compared with cyanide using bottle roll tests. Chlorine was subsequently selected for column leaching tests. Column tests at 1.0, 0.1 and 0.01 gL-1 Cl2 at pH 2 were conducted. The results indicated that about 23 per cent of the gold was leached over 45 days using 1 gL-1 Cl2 at pH 2. The experiments conducted proved that the chlorine/chloride system has good potential for further extraction of gold and silver from the existing cyanide heap leach residues and a process for secondary leaching of gold has been proposed. Further testwork is recommended to extend conditions, sample types, and the duration of leaching period.

Jan 1, 2000

By N. Ono, H. Fujiwara, S. Otsuka-Yao-Matsuo, T. Omata

"The electrical conductivity and the oxygen release and uptake of sintered indium tin oxide (ITO) upon heating and cooling under the condition that P(O2)/P*=4.9X10-4 (P* = atmospheric pressure), :when P(O2) was approximately 50Pa, were simultaneously measured by using a closed-system oxygen-gas analyzer. A large increasing in -the electrical conductivity - upon the· oxygen release detected in 1130<T<1273K was observed. Quantitative relationship between the number of oxygen atom released from ITO and the conduction electron density in ITO was studied. The release of one oxygen atom agreed with the generation of two conduction electrons, i.e., the efficiency-carrier-generation for the oxygen release from the ITO was almost one. The oxygen atom released must be originally at the quasi-anion site in the C-type rare-earth lattice, i.e., the 16c site in the space group of Ia3, as an interstitial excess oxygen, Oi"". It was concluded that the mechanism of conduction carrier generation and compensation upon SnO2 doping into In2O3 can be expressed by the defect equation, 2SnO2-2Sn1n +2(1-z)e'+zOi""+3O0 x+(l-z)/2O2, and that the oxygen release bringing the increase in the electrical · conductivity can be expressed by the equation, Oi""-1/2O2+2e'.IntroductionThin films of SnO2-doped In2O 3 (generally designated as ITO, for indium tin oxide), which have high optical transparency for visible light and high electrical conductivity, have been used as transparent electrodes for liquid crystal and electrochromic displays. It is well known that the electrical conductivity of ITO depends on the content of SnOi-dopant and oxygen. However, a reliable relationship between electrical conductivity and the absolute oxygen content in ITO has yet to be reported. The elucidation of such a relationship is one of the important clues for realizing extremely highly conductive ITO electrodes."

Jan 1, 2000

By A. D. Davis, C. J. Webb, T. V. Durkin

This project took a watershed approach in the evaluation of water-quality impacts from past mining activities and current restoration projects in the Bear Butte Creek basin, a small and well-defined drainage in a heavily mined area of the northern Black Hills. The basin contains numerous inactive and abandoned mines, as well as a heap-leach surface gold mine. Bear Butte Creek normally loses all of its discharge to sinkholes in the Madison Limestone aquifer. Thus, it can affect the water quality of this regionally important water resource. Water-quality data were analyzed, stream surveys were conducted and two abandoned-mine restoration projects were monitored to evaluate the effectiveness of the watershed approach and to identify practical remediation techniques that could be applied to other watersheds. A geographic information system (GIS) was developed to organize information on stream quality, abandoned mine locations, and other geologic and hydrologic data. The watershed approach toward assessing and reclaiming abandoned mines appears to be effective when compared to a point-source approach that might improve water quality at specific sites but not result in significant overall improvement to the watershed because of adjacent sources.

Jan 1, 2000

By P D. Munro

The Mine to Mill concept, as it has become known, is a philosophy which is being increasingly embraced by mining companies committed to increasing their profitability through better integration and global optimisation of their mining and processing operations. Autogenous (AG) and semi-autogenous (SAG) mills are the principal primary grinding devices currently in use, their performance is particularly sensitive to feed size distribution. Most efforts to-date have centred on modifying and controlling the run-of-mine (ROM) size distribution to maximise grinding mill throughput. The complexity of the interaction between ROM size distribution, primary crusher product and AG/SAG mill performance precludes the trial-and-error approach as an effective means of determining the optimum blast-induced fragmentation size distribution. To overcome this limitation, the Julius Kruttschnitt Mineral Research Centre (JKMRC) has developed modelling and simulation techniques that are able to accurately reproduce both the fragmentation processes during blasting and the subsequent performance of the comminution circuit. These models are tailored to suit local ore types, rock structure and comminution circuit design and calibrated using high quality field data. MIM Holdings Limited (MIM) have been particularly active in the Mine to Mill area and have instituted optimisation programs at three of their associated base metal operations viz Alumbrera, Ernest Henry and the Mount Isa Mines. This paper describes these programs with particular reference to the data acquisition and modelling phases, the predictions of potential productivity gains and the extent of the realisation of these gains to-date.

Jan 1, 2000

By J. Costigan, C. Corless

In 1997, damage as a result of Castrol R40 entering the INCO pressure carbonyl plant carrier gas stream was becoming increasingly severe. The oil in the gas stream was adversely affecting both equipment availability and process control resulting in rising unit costs. The main source of the Castrol R40 was determined to be the carrier gas and low pressure gas blowers. Plant personnel initiated a plan to prevent the Castrol R40 from entering the carrier gas stream by replacing the mechanical shaft seals with Ferrofluidics seals on these blowers. The following paper details a brief case history of the Castrol R40 in the carrier gas including impact on the plant. This will be followed by a technical discussion of the new sealing arrangement that was developed by plant personnel, Roots Blower and Ferrofluidics. Lastly, this paper will update the status of the blower upgrade project and document the results to date.

Jan 1, 2000

By M. Cavallini, G. Cannavale, P. P. Milella, A. Pescetelli, C. Lupi

Ni-Cd sealed and vented cells have been widely used in the last few years. The environmental hazard related to the heavy metals contained in Ni-Cd batteries is well known. Therefore, a number of scientific studies and commercial processes have been implemented in order to recycle them. Since spent batteries are a heterogeneous and complex material, any kind of recovery process needs some preliminary treatments. The proposed process described in this paper has been tested in laboratory and further developed in a pilot plant. It consists of a combination of mechanical and hydrometallurgical treatment steps, and is able to treat all type of Ni-Cd batteries. In particular, the mechanical treatments have to be done separately on vented and sealed cells, while the hydrometallurgical step is performed on a mixture of the two products obtained from mechanical steps. A fully automated dismantling line would allow the separate recovery of the plastic or metallic casing, terminals, KOH electrolyte, and electrodes to be further processed· for Ni and Cd recovery. The electrodes coming from dismantling line and sealed batteries are submitted separately to an original crushing and elutriation treatment to separate metallic and active paste in the first case and metallic, plastic and active paste in the second case. The hydrometallurgical treatment is carried out on active paste bearing product to produce Ni, Cd, and Fe comn1ercial salts through acidic leaching followed by a multi-step solvent extraction operation to obtain pure solutions.

Jan 1, 2000

By Pasi Korkeakoski

There are about 400 multi-storey buildings founded on wooden piles in the city centre of Turku in Finland. Soil conditions are variable from hard rock to very soft clay. Due to the soil conditions and ground water lowering there are basically four different types of underpinning projects. Under dimensioned cohesion piles in a deep clay layer, decaying cohesion piles, a combination of these two reasons and decaying end bearing piles in a thin clay layer area. Many different execution methods have been used such as impact driving, jacking and drilling and combinations of these.

Jan 1, 2000

By Robert E. Brown

Magnesium recycling has been used to recover both new scrap and old scrap. It was used extensively in Germany during WWII to expand the magnesium supply. There were a large number of magnesium recyclers in the US who got their start smelting old scrap, old airplanes and old waste dumps from the WWII build up. As the world magnesium industry dwindled, only a few companies were left that did magnesium recycling as a primary business. The sand foundries tended to recycle of their production scrap in their melting furnaces. Even the original die casters tended to put scrap directly back into melting furnaces at the die casting machines. As high purity alloys were developed and the use of die castings in automotive work increased, the tendency was to let the magnesium recyclers convert the scrap back to high quality ingot. Automotive use has grown because of the low density of magnesium. This property is the one of the biggest problems to overcome in shipping scrap. Gates and runners from die casting are very irregular shapes and it is very hard to load a truck with enough material to get a low shipping cost per pound. Recent new equipment companies have developed magnesium equipment that is specifically designed to recycle, refine and cast secondary magnesium metal. These melt cells are supplied as integrated units to magnesium casting sites. The cost and effectiveness of this approach will be discussed.

Jan 1, 2000

By Markus A. Reuter

In this paper, the kinetics of phosphorous production in submerged-arc furnaces will be discussed as a function of temperature, as well as various ore and reductant types. Interesting positive synergetic effects on the rate of reaction could be observed when mixing different types of ores. The results will be discussed with reference to a kinetic model, microprobe analyses, etc. The effects these results have on the control of the furnace will also be discussed in detail, indicating how these could be incorporated into the electrode and metallurgical control systems for submerged arc-furnaces.

Jan 1, 2000

By K S. Fisher, J D. Pease

The installation of the George Fisher flowsheet in the lead/zinc concentrator at Mount Isa Mines Limited has recently been completed. The George Fisher flowsheet involved moving flotation capacity from the lead circuit to the zinc circuit and changes in zinc circuitry, changes in the reagent regime and increased regrinding capacity, using IsaMills, to regrind some streams to 80 per cent passing seven microns. The project was highly successful, delivering a five per cent increase in zinc recovery within a fortnight of commissioning. The George Fisher flowsheet was developed over six years. Laboratory work built upon the knowledge gained from investigating and processing the Mount Isa and Hilton orebodies. The engineering design and construction for the brownfield expansion of the existing lead/zinc concentrator had significant involvement from the operational, maintenance and technical personnel. Experienced personnel were seconded from the concentrator to the design and construction groups to ensure smooth integration of the new flowsheet into the existing concentrator with minimum downtime, and maximising the reuse of existing equipment. The combination of thorough design, good project integration with operations, and a good commissioning plan allowed almost immediate delivery of project gains. The project was highly successful, the full design improvements were achieved within two weeks, allowing the focus to move to developing future improvements.

Jan 1, 2000

By Brian Carr

This workshop will display all of the existing products that are available as stemplug devices and discuss the general concept of the use of them. Actual results will be discussed along with several case histories. There will be adequate time for questions and answers.

Jan 1, 2000

By M Gao, V Lawson, W Valery

Changes in metal prices and mine output over recent years have required the Copper Concentrator of Mount Isa Mines to operate at annual tonnage rates varying from 4.0 million to 6.5 million tonnes. Several circuit combinations were operated during this period utilising up to two semi-autogenous grinding (SAG) mills and up to two ball mills. The aim was to maximise grinding efficiency and keep unit costs constant regardless of throughput rate. Measures to improve the SAG-ball mill unit operation were implemented with each circuit change. These included installation of a splitter to divert SAG Mill cyclone underflow back to the mill, increase SAG ball charge from four per cent v/v to eight per cent v/v, reduce in SAG top feed size and increase of ball mill grinding medium size. Modelling work and surveys led to a new design of the SAG liner profile from 60 rows of rail bar liners in a high-low arrangement to 40 rows of top hat liners in a high-high arrangement. An on-line SAG Mill feed sizing monitor was recently installed to improve grinding control.

Jan 1, 2000

Coal that meets customer specifications is often stored in silos before being loaded into cars. It is often found that coal in a particular car does not meet customer specifications due to the mixing of coal inside the silo. Some new contracts require meeting specifications on a per car basis. Silo flow models are used to predict quality in such cases. However, coming up with an accurate silo flow model for each case is very difficult and time consuming. This paper examines the viability of using an online analyzer at the loading end of the silo in conjunction with a feedback circuit, to optimize the quality of the coal being loaded into trains, so that each car meets quality specifications.

Jan 1, 2000

By Seppo Lähteenmäki, Pertti Koivistoinen, Jaakko Levanaho

"This paper describes the benefits and disadvantages of fully autogenous grinding when compared to grinding with steel grinding media. The study is a real case study based on a low tonnage, high grade mining project in a remote location in a developing country. The study compares the capital and operating costs of using either SAG mill, Ball mill, Crusher (SABC) or fully autogenous (AG) grinding circuits and produces an economical analysis of the project for both options. The economics have been developed for the overall project, including mining, processing, environmental and the infrastructure as well as for the additional cost of constructing a fully autogenous grinding circuit instead of the original plan of a SAG Mill, Ball Mill circuit.The paper also describes the development of the autogenous grinding circuit at Outokumpu Oy, Pyhäsalmi mine. This experience was used to design the autogenous grinding circuit for the case study. Pyhäsalmi Concentrator has over 30 years of experience in operating autogenous grinding circuits and therefore provides a sound base for the new circuit design.INTRODUCTIONGrinding of ore using steel grinding media is currently the most commonly used method in the mining industry. Autogenous grinding, ore replaces iron media, is also common especially in Europe and Africa. Iron ore industry in North America uses autogenous grinding in primary and/or secondary stages extensively. In gold, copper and other base metal industries, autogenous grinding is not as common, although there are operations where pebble grinding is or has been used in the secondary grinding stage. There are many variations of autogenous grinding in use in the mining industry. These variations include different mill sizes, mill length to diameter ratios, ore lump sizes, screening and pebble crushing configurations."

Jan 1, 2000

By J. Glazewski

The mining industry in South Africa has developed its own environmental guidelines in the form of an Aide-Mémoire1,which is an extension of the previous rehabilitation provisions to include all aspects of the environment and all phases of a mining operation. This development, at the time, recognized an international trend towards the formalization of environmental management in mining practice, which resulted from the realization of the large environmental liabilities that mines could face, particularly on closure. Over the past decade the international environmental focus in the mining industry has moved from operational management, to the reduction of liability on mine closure. Mine closure guidelines are being developed internationally by nations (for example, SRK, 19982) and by large mining groups (for example, Rio Tinto, 19983). In South Africa the Department of Minerals and Energy (DME) is presently reviewing the Aide-Mémoire to bring it in line with international and local developments and a separate mine closure plan is being considered.

Jan 1, 2000

By M. Boussuge, M. -D. Dupuits, A. Piant

This paper summarises a part of the work that has been essentially carried out at the Ecole des Mines de Paris in the framework of an Eureka European programme funded by the French Ministry of Industry, in partnership with Metaleurop and Carborundum (subsidiary of Saint Gobain). It deals with the measurement of different properties (density, thermal linear expansion, elastic modulus, strength) of a SiC-based refractory constituting the trays that are used in the refining columns in the New Jersey zinc distillation process, especially in the boiling section. These parameters have been investigated to check the homogeneity of the asreceived trays as well as to estimate the influence of ageing of the material under operating conditions. With this aim, specimens have been sampled in used trays having more than two years of operation. The as-received trays exhibited a good homogeneity, the strength being slightly lower in the direction in which they are compacted. Despite microstructural changes, most of the properties measured at room temperature are not significantly affected by ageing. High temperature tests involved thermal treated under vacuum to remove metallic zinc before testing at high temperature. An increase in temperature, as well as ageing, induces a decrease in the elastic modulus and strength.

Jan 1, 2000

By W. L. Dalmijn, J. M. Krowinkel

A recycling concept of end-of-life televisions starting with shredding will produce a complex material mixture, very heterogeneous in size, shape and degree of liberation. Basically all materials in television scrap are valuable, which means that recovery is important for either economic, environmental or sustainability reasons. However glass, plastics and metals are the materials with the highest potential for recovery. Non-magnetic materials from shredded television sets can be separated into three characteristic size fractions that need further separation for a high value-added recycling of the materials. This study investigated the potential of physical separation of these size fractions into valuable material streams using polyseparator, tlrldy current separator, dry and wet shaking tables and electrostatic separator. An overall mass balance of the mechanically processed televisions was calculated. Evaluation of the produced material fractions showed that heterogeneity in particle shape and size together with the presence of unliberated materials caused sever difficulties in separation when exclusively based on mechanical techniques. The results indicate that a certain degree of dismantling is necessary to achieve products of appropriate quality in physical separation. In order to improve recycling of electronic scrap through design for recycling cooperation between the electronics industry, the manufacturers and the recyclers of electronic goods is necessary.

Jan 1, 2000

By M. A. Rabah

This paper focuses on the separation and extraction of lead and zinc from Egyptian ore at the Eastern Desert close to Red Sea. The ore sample contains cerussite, galena, hemimorphite and other impurities. Experimental program includes flotationof galena using xanthate collector and cerussite using oleic acid as collector and sodium silicate to depress hemimorphite tailing. Galena, and hemi-morphite are converted to carbonate with sodium carbonate prior to metal extraction. Lead and zinc are extracted pyrometallurgically at 1050°C and750°C or electrochemically respectively. The overall performance of the applied method amounts to 99.2%. Extraction efficiency of lead and zinc amounts to 98% and 94.5 % respectively. A model assumed that galena and cerussite in the ore are partially oxidized and can be liberated by grinding. Oleic acid selectively reacts with cerussite in a multistep sequence. Preliminary cost estimate shows that the price of the products is competitive to their local market prices.

Jan 1, 2000

By T. Shoji

"The human history is characterized by social development based on mineral and energy resources, and many conflicts to take the resources by power. This is shown by not only world wars but also many local conflicts as well as international supremacy.IntroductionThe world population after B. C. 10000, which is summarized in several papers, is approximated by four straight lines on a semilogarithmic diagram as shown in Figure 1 [l]. The annual rates of increasing are 0.0041, 0.071, 0.53, and 1.85 % from the old and young periods. The boundaries among four periods are approximately B. C. 4600, AD. 1670, and 1930. The start of the second period seems to correspond to the beginning of agriculture and cattle breeding. Precisely speaking, the usage of natural energy resources such as woods and domestic animals already began, but is inferred to have become common after the age. The third and fourth periods are characterized by the common usage of coal and oil, respectivety. Not only energy resources but also mineral resources including gold, copper, iron and others are also important for the human history.Mineral and energy resources have supported the development of the .human civilization, and have caused many conflicts because of this reason. Every day newspapers report conflicts, such as Chechnya, East Timor and Ache. We can easily point out the facts that the conflicts closely relate to mineral and energy resources. Groznyj, Capital of Chechnya, is located on the western margin of Caspian oil field. Many mineral deposits occur in Kavkaz Mountains running south of Chechnya. Subsea oil fields occur in Timor Gap located between East Timor and Australia. Ache is also one of oil fields in Indonesia. It is very difficult to state present conflicts independently of a political view of point. For this reason let us try to historically review the relation between mineral and energy resources and international domination and conflicts [2] based on many papers [3]."

Jan 1, 2000

University education in Australia is changing, driven by greater market orientation, reduced funding available per student, especially in the higher-cost minerals industry disciplines, and the call for more flexible delivery of subjects and courses to meet changing lifestyles and expectations. The opportunity exists for a true partnership to develop between industry, government and academia that will reshape minerals education in Australia and secure the future supply of the specialists industry needs to maintain international competitiveness. If this partnership does not emerge, it is anticipated that AustraliaÆs somewhat fragmented and unstable higher education system, especially in the disciplines of particular relevance to the minerals industry, will be put under further pressure so decreasing its effectiveness to produce quality graduates. The Minerals Council of Australia in 1998 published æBack from the BrinkÆ, a discussion paper which proposed strategies to build a world class minerals tertiary education system in Australia. Those strategies are now being implemented collaboratively with principal emphasis on the disciplines of mining engineering, metallurgy and earth science and as far as process is concerned, on the necessity to æcooperate to competeÆ. For metallurgy, the challenge is to integrate more closely undergraduate teaching with the existing world-class research centres and to link the tertiary institutions in such a manner that the strengths of all components are harnessed and then made available nationally in major population centres and at remote sites where appropriate. For industry the challenge is to build effective partnerships with the academic community that will enable and assist the agreed course of action to take place.

Jan 1, 2000