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By L. Lacerda, C. Rose, E. Zellers

Approximately six hundred air sample measurements were taken at several U.S. underground metal/nonmetal mines in 1998 and 1999. This air sampling effort was organized by the Nevada Mining Association to evaluate mining conditions and to evaluate the Mine Safety and Health Administration’s (MSHA) Proposed Rule on Diesel Particulate Matter Exposure of Underground Metal and Non-metal Miners. MSHA’s proposed air sampling method, NIOSH Method 5040, was tested under controlled conditions and under normal mining conditions. Unfortunately, NvMA sampling results have indicated that carbonaceous rock dust, oil mists and even cigarette smoking create severe sampling interference problems for NIOSH 5040.The main conclusion was that NIOSH 5040 did not distinguish between DPM and other airborne carbon particulate. Thus, it is not a reliable method of accurately and unequivocally measuring DPM in underground metal/nonmetal mines.

Jan 1, 2000

By Lon D. Santis

This paper summarizes explosives transportation incident and accident data collected by the U.S. Department of Transportation (DOT) from 1993 to 1998. The paper briefly describes the legislation and regulations that cover hazardous materials transportation. The multimodal incident data collected by the Research and Special Programs Administration (RSPA) contained 86 incidents involving Class 1 materials during transit. Thirty-two occurred on public highways. The Federal Highway Administration (FHWA) data showed there were 8 1 motor-vehicle accidents involving explosives. The FHWA Crash datafile extract contained 649 records categorized as involving Class 1 materials although closer analysis revealed that nearly 90% of these did not involve explosives. In both databases, there were no fatalities caused by the explosive materials although 7 fatalities were the result of injuries suffered during the motorvehicle accident. There were also no serious explosions during any of these incidents or accidents. The paper concludes with an analysis of the risk involved with transportation of commercial Class 1 materials on the highway.

Jan 1, 2000

By P. Henry

A novel electrochemical cell has been developed for the recovery of MnO2 from residue of pyrolusite ore leading loaded with Fe, Al Ni, Co and Si impurities, This new process can be considered as an alternative to the traditional methods : S02, H2O2 or bioleaching. It has been observed to proceed fairly rapidly and could prove to be a more economically viable process, as well as being more environmentally acceptable. Electrochemical characterization and kinetic studies have shown that MnO2 is effectively leached by electrogenerated ferrous ions at high current density from a pulp containing less than 5 g8 Fe. The chemical reactions are : Cathode (inox) : 2F23+ + 2e ? 2 Fe2+ Bulk: MnO2 + 2 fe2+ 4H+ ? Mn2+ + 2 Fe3+ + 2 H2O Anode (Pb-Ag) : H2O ? ½ O2 + 2H+ + 2e Global: MnO2 +2H+ Fe2+ = Mn2+ + H2O + 1/2 O2 The catholyte (MnO2 pulp) circulates upward in the expanded mesh cathode separated from the sulfuric acid solution anolyte by a separator which shows high mechanical resistance, low porosity, low potential drop, and reasonable cost. Laboratory and mini-pilot tests have led to the construction of an OT crating pilot plant (100 kg/hr) able to leach more than 95% of Mn, Ni, Co at 1000-1200 A/m2, 50°C with high faradic yield (> 95 %) and low power consumption (3.2 kWh/kg kWh/kg &4D). New applications like the treatment of spent Zn-Mn batteries, polluted soils, spent catalysts and oxide ore (cobalt, nickel) with electrogenerated redox species are now investigated at a laboratory and mini-pilot scale.

Jan 1, 2000

By H. -P. Behrendt

Muldenhiütten Recycling und Umwelttechnik GmbH is a lead smelter with a very long tradition. The first reference to the existence of smelters on this site is given by a document of inheritance dated 1318. Originally run as a primary lead smelter, which was supplied with ores from the Freiberg mining district and from overseas, it was required to change it over to secondary raw materials due the abandonment of mining in the Freiberg area in 1968. Today, Muldenhüitten Recycling und Umwelttechnik GmbH has two production lines; lead production from secondary lead and waste incineration, which are closely connected and gain advantage from each other. Installations, improved technologies, and the highly skilled personnel have contributed to satisfy all demands for a production concerning quality and environment.

Jan 1, 2000

By Hwa-Soo Park, J. K. Yoon, Hoseok Nam

In a thin slab casting process, control of fluid flow in mold is particularly difficult due to the high casting speed and large aspect ratio of the mold and the understanding of the fluid flow motion as well as heat transfer in mold is regarded as the most important information because the melt delivery is directly related to the problems of shell growth nonuniformity, surface turbulence and mold powder entrapment. A mathematical model has been developed for the coupled analysis of fluid flow, heat transfer and solidification in funnel type mold using finite volume method based on a body fitted coordinate and the characteristics of the transport phenomena in the mold of thin slab caster were analyzed by numerical simulation. As a result of simulation, the basic flow pattern is characterized as four large recirculations and two small eddies near the narrow faces of mold, which is somewhat different from that of parallel type mold or other conventional slab caster. The heat transfer model accurately predicted the mold positions susceptible to cracking as a result of thermal stress and the predicted shell thickness shows good agreements with the measured shell thickness on breakout products. We also investigated the influences of some operation parameters such as casting speed, nozzle type, submerging depth and mold material on fluid flow, heat transfer and distribution of solidifying shell and various information for the determination of optimal operating conditions were obtained.

Jan 1, 2000

By K. L. Money, R. R. Bleakney, R. H. Hanewald

The processing of EAF baghouse dusts, rolling mill scales, and belt grinding swarfs from the specialty steel industry will be reviewed. In addition, the INMETCO process has been modified so as to recover nickel, chromium and iron from many other waste materials such as pickling solutions, filter cakes, spent nickel and chromium plating baths, super alloy wastes, and nickel-cadmium batteries. INMETCO is the only North American company presently capable of recycling nickel-cadmium batteries by high temperature metals recovery.

Jan 1, 2000

By E. A. Metz

Work related pulmonary diseases are in the top TEN causes of occupational disability and death in the United States. Likewise, it also ranks high inmost of the other industrial countries. It is difficult to know the true occurrence of occupational lung disease because of poor documentation. This is especially true when one examines workers’ compensation claims. Most frequently, silica and asbestos are paramount in our discussion of work related pulmonary disease. Little consideration is given to other “dust-related” diseases, irritant reactions, reactive airway responses, and hypersensitivity reactions. The major classification of occupational lung diseases will be discussed. This includes both acute and chronic disease that arises in the work place, especially, the mining industry. It’s more important to make an accurate evaluation and diagnosis for the prevention of disease among other workers.

Jan 1, 2000

By L. L. Ludwig, S. E. James, B. L. Motycka

Significant modifications to the electrolytic zinc plant operated by Big River Zinc Corporation were made at the end of the 1990's resulting in increased capacity and improved efficiencies. A new cell room, with the innovative use of acid-resistant concrete cells and a modern ventilation system, was installed to raise the capacity from 80,000 tonne/y to 106,000 tonne/y of finished zinc. Improvements to the leaching section include the conversion from a single to a two-step process, with associated equipment changes, to improve the quality of the residues produced. Another key change is the construction of a facility to allow the use of zinc oxides from secondary sources as a feed to the plant. This paper describes these improvements and the current operations.

Jan 1, 2000

By D. G. Hattingh, A Els-Botes

"Considerable information is available on the factors influencing the iron-zinc reaction rate at 450° C of low carbon steels, in comparison there is a scarcity _of similar fundamental information of spheroidal graphite irons. This can be attributed to the more complex microstructure and ferrous alloy chemical analysis of spheroidal graphite irons. Hot-dip galvanizers have identified the complexity in controlling and predicting the thickness of the galvanized coating formed on commercial cast irons, which has serious financial implications for both the galvanizer and customer.Commercial hot-dip galvanizing has been in use for over 160 years and yet an elementary understanding of the dynamics associated with the hot-dip galvanizing of spheroidal graphite cast iron is still insufficient. To allow the. process to become a modem surface engineering technology, the fundamental aspects of the process must be thoroughly understood.When a clean iron or steel article is dipped into the molten zinc, zinc initially solidifies around the steel or iron. As heat is transferred to the article form the bath, this initial solidified zinc layer remelts and a series of iron-zinc alloy is formed by the reaction of the zinc with the surface of the article; on removal from the bath, some of the molten zinc is taken out on top of the alloy layers. At normal galvanizing temperature (450 °C), the reaction between iron and zinc is usually parabolic with time. The rate of reaction is rapid at first but then slows down and the coating thickness does not increase greatly if the article is immersed in the bath for longer times(1)."

Jan 1, 2000

By Peter Hayes

Moonee Colliery operates a longwall extraction system in the Great Northern seam of the Newcastle Coal Measures, approximately 100km north of Sydney, NSW. In the initial mine area of longwall blocks1-4a, the Great Northern seam is overlain by a massive conglomerate approximately 35m in thickness. Unanticipated sudden, blocky caving of this material has produced windblasts with associated velocities of 100m/sec and over-pressures of 35kPa. Although these events have not resulted in fatality, the potential safety risk to face personnel was such that the mine was threatened with closure. The development of a Windblast Management Plan to minimise the exposure to windblasts, a Micro-seismic Management flan to predict caving events, and the use of hydraulic fracturing to generate caving on demand, have all contributed to the salvation of the mine. Prior to the introduction of hydraulic fracturing, falls were highly variable and ranged in goaf area from 2000m2 to 30,000m2 with an average of around 7.000m2. Hydraulic fracturing has introduced consistent and far less variable falls, planned as averaging around 5000m2 and all accompanied by microseismic warning, Moonee Colliery is believed to he the only operation in the world using real-time microseismic warning and using hydrofracturing as a day-to-day operational process. These processes have enabled it to return to financial viability in an environment of strict procedural control, whilst ongoing efforts are made to optimise and enhance these systems. Moonee's story is a case study of the successful application of research and development work to the economics of a mine.

Jan 1, 2000

By J. S. Heath

Many disputes related to environmental issues in mining are resolved through often-antagonistic negotiations in a regulatory context or through litigation. These approaches are certainly the best choices for resolving certain disputes. However, just as no single remediation technology is the right fit for every site, so no single dispute resolution process is the best choice for every situation. This paper introduces a range of dispute resolution alternatives (from collaborative decision making through mediation, arbitration, and litigation). Especially when money is tightest, cost-effective dispute resolution(and the outcomes that can accompany it) can have an impact on the bottom line.

Jan 1, 2000

By Carla Lupi

Zinc electrowinning from sulfate solutions is the traditional industrial method to produce SHG zinc. Over the past few years several efforts have been done to improve process efficiency in order to reach high productivity with low energy requirement. The latter aim can be pursued both by means of a hard purification of the electrolyte and reducing the anodic voltage. This work is a comparative study of the results obtained in several previous researches on zinc electrowinning from both sulfate and chloride solutions. Zinc electrowinning tests on industrial sulfate solution have been carried out by using Pb alloy anodes and by adding organic depolarizers such as ethanol, acetic acid or ethylene glycol. Experiments on chloride solutions, obtained by purification of zinc exhausted electrolyte, have been performed by using DSA anodes and by testing the effect of additives such as TEACI and TBAC\. Comparing the best results obtained with the two methods it can be highlighted that a high quality zinc is electrowon in both cases with comparable energy requirements.

Jan 1, 2000

By Hamid Maleki

During the last decade, a significant amount of research has been conducted by Energy West Mining Company, government agencies, academia, and consulting companies to develop predictive tools for assessing the stability of the Castlegate Sandstone, which is found approximately 250 m above multiple-scam coal reserves, Energy West Mining uses longwall mining techniques in its operations near Huntington, Utah, and these studies were initiated to satisfy requirements for maintaining the stability of the Castlegate Sandstone and resource recovery. In this study, the authors have used multiple-regression analysis techniques and a wealth of data collected over many years on geology, mining, and escarpment stability. The volume of failed rocks is used as the response variable after several other factors were considered, including measurement of surface deformation and frequency of mining-induced surface fractures. Geologic and geometric variables were obtained along 3.7 km of escarpment exposure at 130 study locations. Regression analysis of data for the first 29 study location, which had been fully' undermined, showed that surface topography played a critical rule in influencing escarpment stability. Preliminary regression analysis results from 70 study loca¬tions identified several other important geologic arid mining factors that influence be stability of the sandstone escarpment These are canyon slope, sandstone thickness, and mining influence ante.

Jan 1, 2000

By H R. C Pratt, G W. Stevens

Hydrodynamic and mass transfer performance are presented for a 72.5 mm diameter pulsed disc and doughnut column of the type used by Western Mining Corporation, Olympic Dam Operation, for the extraction of uranium from sulphate media using Alamine 336 as extractant. For the present purpose, 4.0 g/L sulphuric acid was used as solute. The mass transfer data were interpreted in terms of the diffusion model, thus accounting for continuous phase axial dispersion. The results indicated that an efficiency corresponding to approximately one transfer unit over the 1.0 m height of the column was obtained. This efficiency is comparable to that observed by Gottliebsen (1997) for a pulsed perforated plate column using 173 gm/L sulphuric acid.

Jan 1, 2000

By M Freeman

Significant improvements in the metallurgical performance at Pasminco Rosebery Mine have occurred over the last two years. Lead and silver recoveries have increased by more than ten per cent, lead concentrate grades are four per cent higher, zinc recoveries are up 1.5 per cent, and zinc concentrate grades have increased by two per cent. These impressive results have not occurred through the application of some new wonder reagent, but through the application of some fundamental metallurgical principals. The basic premise applied during this study was that to make an effective separation you must first achieve liberation. Therefore, the laboratory and plant studies examined the liberation characteristics within the lead circuit, and the impact of regrinding. The work demonstrated clearly that galena/sphalerite liberation was poor, and significantly impaired plant performance. Further, it was suggested that the application of lead regrinding of the lead scavenger concentrate and the lead first cleaner tailing would not only benefit lead metallurgy, but also improve sphalerite flotation. A similar approach was then applied to the zinc circuit. From these studies, solutions applying simple circuit changes utilising existing equipment were proposed and implemented. Further to the improvements in galena/sphalerite liberation, significant improvements in concentrate quality were achieved by reducing variation within the process. The implementation of changes in work practices negotiated in the Enterprise Agreement, employee contributions and specialist training also made a significant contribution to the unprecedented improvement in the lead and zinc flotation circuit performance. The results of these plant changes are discussed, along with the suggested scope for further improvement.

Jan 1, 2000

By Yang Xianwan, Zhu Xiaoyun, Guo Zhongcheng, Zheng Yanping, Zhai Dacheng

"Corrosion resistance of RE-Ni-W-P-SiC composite coating and 3 l6L stainless steel in corrosion media of H2SO4, HCl, H3PO4 and FeC13 solutions at different concentrations by means of immersion methods and anodic polarization curves obtained by DHZ-1 electrochemical synthetic tester and HDV-7 transistor constant potentiometer. Immersion experiment results show that corrosion rate of RE-Ni-W-P-SiC composite coating as-deposited in HCl solutions increases with the rise of HCl concentrations, on the contrary, the corrosion rate of the composite coating after heat treatment decreases with increasing the HCl concentrations the corrosion rates of the coatings as-deposited and after heat treatment in H2SO4 and H3PO4 solutions respectively decrease with the rise.of H2SO4 and H3PO4 concentrations the corrosion rate of the deposit as-deposited in FeC13 solutions decreases with increasing FeC13 concentrations, while the rate of the composite coating after heat treatment increases .with the rise of FeC13 concentrations.In addition, the corrosion rate of 3 l 6L stainless steel in the corrosion media of H2SO4, HCl, H3PO4 and FeC13 solutions at different concentrations increases with rising of concentrations. Furthermore, the corrosion rate of 316L stainless steel in the corrosion media of H2SO4, HCl, H3PO4 and FeC13 solutions respectively is much greater than that of the RE-Ni-W-P-SiC composite coating as-deposited and after heat treatment in the same corrosion media.1. IntroductionAll the materials and their products, when processed, stored and used, it is inevitable that the corrosion, wear, fatigue and crack occur owing to the actions of surroundings. Those early failure and abrasion, through all kinds of departments and profession that corrosion consumes one percent of tens of the steel products of the whole world; and two or four percent of the GDP is lost because of the corrosion."

Jan 1, 2000

By Julian Malnic

The emerging marine minerals exploration and mining industry is currently focused mainly on the technical elements for its success such as developing exploration and mining technologies. However, in one sense, the technical challenges are quite soluble whereas those arising in the fields of the environment and public opinion could present this new generation of miners with problems that are far more difficult to overcome. One need only look at the issues currently faced by mining projects on land to see how powerful the new forces of so-called ?civil society? are in stopping mineral developments in many countries. From the geographic viewpoint, there are many countries but there is just one ocean, so the impacts experienced by any one operation are likely to have pervasive repercussions throughout the industry. A well-oiled NGO development protest lobby will see leverage in resisting this new industry and will seize on the single-ocean angle. The Australian Minerals Industry has established a voluntary Code for Environmental Management that provides an active and valuable model for satisfying the ?court of public opinion? and in delivering economic results to industry that are in current jargon, sustainable. An explanation of the Code for Environmental Management, and the reasons behind 44 companies representing more than 300 operations and 85% of Australia?s sizeable mineral production being signatory to it will be given. Participants see it as a means to future shareholder wealth.

Jan 1, 2000

By D W. Nisbet

Today Hudson Bay Mining and SmeltingÆs 777 Project is the largest mining construction project under way in Canada. The project comprises six components: construction of the new 777 zinc-copper mine; construction of the new Chisel North zinc mine that will truck ore out from 600 metres below surface; expansion of the Flin Flon ore concentrator; expansion of the zinc plant to increase throughput by 15 per cent; a spill gas project that will reduce fugitive gas emissions by some 90 per cent; and infrastructure improvements including construction of a new electrical substation. Total investment in The 777 Project is over $US 260 million. Seven years ago, the Flin Flon, Manitoba-based company was fighting for its very existence. How does a company go from down-for-the-count to robust contender in just seven years? Contributing reasons are many, but all have their root in a process HBMS calls æTransformationÆ. It is transformation that has taken HBMS, a very traditional company, through a very non-traditional turnaround (Figure 1).

Jan 1, 2000

By M. A. Gimenes

The utilization of chlorination in extractive metallurgy and advanced ceramics areas has been widely investigated as a preparative route in order to obtain intermetallic compounds, which are used as precursors in the development of new materials and process. The major processes of decomposition of rare-earth ores use sulfuric acid and sodium hydroxide at high temperatures, however there is not much work concerning chlorination. In this work, a systematic study of the reaction between xenotime (REPO4), chlorine and carbon has been performed. Particular emphasis was on kinetic studies to establish optimized conditions for the reaction. The kinetics of chlorination of xenotime raw material by rare-earth elements/compounds has been studied over a temperature range from 600°C to 950°C. The influence on the rate of conversion of xenotime to RECl3 on temperature, partial pressure of chlorine, carbon content, and particle size were investigated. A global rate equation that includes these parameters has been developed. The results show that the process follows the unreacted core-shrinking model with a formation of a porous product layer. The powder X ray-diffraction technique corroborated this model showing clearly the patterns related to the formation of yttrium oxychloride (YOCl), indicating that the reaction mechanism involves the presence ofan intermediate step before the formation of lanthanide chloride.

Jan 1, 2000

By Z. Q. Chen, M. H. Loretto, Y. G. Li

"As-cast, As-forged, as-solution-treated, and solution treated and aged microstructures of Ti-15Mo (IMI205) with and without carbon were examined using optical microscopy, scanning electron microscopy .and transmission electron microscopy. Tensile testing was carried out at room temperature. It was found that carbon acts primarily as a titanium carbide former: Titanium carbides increase slightly the tensile strength, but decrease the ductility of IMI205. These observations are interpreted in terms of the titanium carbide morphology observed using SEM and TEM and the phase diagrams of Ti-Mo, Ti-C, and Mo-C.IntroductionIn a recent study on the development of a burn-resistant 13-Ti alloy, carbon was introduced· into the Ti-V-Cr system in order to optimise the mechanical properties. Research results[1, 2] demonstrate that carbon addition can refine the 13 grain size and improve the stability of the 13 phase in Ti-V-Cr alloys. The most attractive result is that carbon addition produced a marked improvement in the ductility of alloys when the carbon content is over 0.1 wt.% in this alloy system. Even after long exposure, the alloy with carbon addition maintains good ductility. One of the main reasons for the ductilising of the alloy is that titanium carbides can getter the oxygen from the 13 matrix.In view of the success of carbon addition in improving the properties and the stability of the Ti-V-Cr alloy, it is of interest to investigate the behaviour of carbon addition in other beta Ti-base alloys. The objective of the present work was, therefore, to assess the microstructures and mechanical properties of IMI 205, a metastable beta titanium alloy, with and without carbon addition using optical microscopy (OM), scanning electron microscopy (SEM), transmission electron microscopy (TEM), wavelength dispersive X-ray (WDX) analysis, room temperature tensile testing."

Jan 1, 2000