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By Keizo Uematsu, Kumiko Sanda, Nozomu Uchida

"Full understanding of mechanical properties is the most important assignment in ceramics. Establishment of defects-property relationship is crucial for fulfilling the assignment. This study reports detailed characteristics of defects and their relevance to the mechanical properties for alumina ceramics made through a typical industrial processing. Novel characterization methods were applied to evaluate their defects. A very simple direct correlation was successfully found between defects and properties in ceramics. This result is a great epoch in the field of ceramics. IntroductionThe ceramic materials are used in refractoriness, corrosion resistant materials and structural materials. The low fracture toughness and scatter of strength are very important problems in ceramics. The toughness of ceramics is lower than metal and polymer materials, and the allowed defect size is small. Very small internal defects (pore, crack, huge particle) can be a fracture origin in the brittle fracture. The characteristics of defects such as size, distribution and shape change markedly by process condition, which cause the scatter of strength. This study conducts quantitative evaluation and direct observation of the sizes, shape and a number of internal defects with a light microscope, and discusses the relationship for mechanical properties and defect sizes"

Jan 1, 2000

By S. G. Malghan, D. Santhiya, S. Subramanian, K. A. Natarajan

The adsorption of poly(vinyl alcohol) (PVA) of molecular weight 25,000 onto alumina was studied as a function of pH. The adsorption isotherms were also determined. The adsorption density increases with increasing pH, while the isotherms are rounded and of the low affinity type. Electrokinetic studies indicate that the electrophoretic mobilities are reduced in magnitude in proportion to the PVA concentration, without any shift in isoelectric-point (iep). This resembles the influence of an indifferent electrolyte. The calculated values of the free energy of adsorption between alumina and PVA are suggestive of hydrogen bonding. FTIR spectro-scopic data provide additional evidence in support of hydrogen bonding.

Jan 1, 2000

As has been the case since the early Phoenician traders, the minerals used by modern man come from deposits scattered around the globe. The price received is more and more being set by worldwide supply and demand. Thus the price component in the profit equation:Profits = Material sold (units)x(Price/unit û Cost/unit) is largely determined by others. The recent price history for two of the major metals, copper and iron, are given in Figures 1 and 2, respectively. As can be seen there has been a steady decline in the prices (when expressed in constant dollars) over the 20 years which have lapsed since the first of the International Conferences on Mass Mining, æDesign and Operation of Caving and Sublevel Stoping MinesÆ was held. If one would look back over the entire 20th century this would also be the trend. Cost containment/reduction through efficient, safe and environmentally responsive mining practices is serious business today and will be even more important in the future with increasing mining depths and more stringent regulations. A failure to keep up is expressed very simply as: Profit This, needless to say, is unfavourable for all concerned (the employees, the company, and the country or nation). The mining companies have had to look at ways of reducing the expense part of the profit equation while maintaining safe, environmentally conscious operations. Table 1 summarises the rules for working in todayÆs economy.

Jan 1, 2000

By Axel Preusse

This paper shows basic considerations about the prognosis and prediction of surface subsidence and other ground movements in the German hardcoal industry. The following case studies describe experiences collected in projects between university and industry.

Jan 1, 2000

By Charles A. Ramsey, Kathleen S. Smith, Philip L. Hageman

We developed a statistically based strategy for sampling the surficial material of mine-waste dumps for use in screening and prioritizing historic dumps on abandoned mine lands. This sampling strategy entails the collection of a representative composite sample from individual dumps and allows for regional or watershed-based assessments. One 30-inment dump-composite sample collected using this sampling strategy contains as much information, relative to average value, as 30 individual grab samples at 1/30 of the analytical cost.

Jan 1, 2000

Develop a means of determining both the fill level of material in an ore pass or bin and the location of bridging material causing a blockage.

Jan 1, 2000

By Hanjie Chen

Mining experiences have shown that in a pitching seam, roof behavior is significantly different from a flat seam. Uphill mining usually experiences more roof problems than downhill mining. Based on a case study at RAG American Coal Company, Willow Creek Mine, this paper presents the roof control problems experienced in a high pitching seam. Then, finite element modeling is conducted to analyze the roof stress distribution for an entry developed in different directions relative to the seam strike. The results shows that seam inclination has a significant effect on roof stability in terms of tensile stress. Uphill mining experiences higher tensile stress than downhill mining. The modeling technique utilized in this analysis presents a first of kind methodology.

Jan 1, 2000

Introduction The objective of the design and operation of a mine is to make as much money as possible within certain reasonable and responsible constraints. The imposition of constraints on the objective of maximizing profits can result in an optimum mine design. This paper deals with the maximization of profits. Optimization will be discussed in a future paper. In the mining industry, it is generally accepted that the maximum economic recovery is defined by identifying the reserves and the sequence of mining that results in maximum net present value (NPV) or discounted cash flow-rate of return (DCF-ROR), as indicated in Fig. 1 (see Lemieux, 2000). Current parametric analyses techniques, such as varying the mining costs; profit reservation; sales price or metal content, to define pit limits and mining sequence technically referred to single, double or triple parameterization, do not assure that the curve in Fig. 1 will be maximized. In defining the sequence, the first material to be mined should be the first grouping of recoverable mineral that has the highest after-tax unit value and that forms a feasible mining unit. The assumed mining of the first pit should be followed by the assumed mining of the second most profitable and practical pit or pit expansion. If this process of grouping and sequencing is followed until the profitability approaches zero, the general sequence required to extract the maximum economically recoverable reserve is identified. The curve in Fig. I is constructed by calculating the NPV for a series of sequences, each assuming operations are terminated on successively lower profit pits. If the operation ceases on a pit with too high of a profit, opportunity is lost, and the NPV is lower than the maximum. The NPV curve peaks and then starts to decline before the zero-profit pit is assumed mined. This occurs because the money invested in advanced stripping would have produced a greater return if it was invested at the dis¬count rate. The maximum economically recoverable reserve is defined by the pit limit corresponding to the maximum NPV or DCF-ROR. Pit and phase definition The real challenge of reserve definition is identifying the phasing and after-tax profit per ton, so that the curve in Fig. 1 can be plotted. The after-tax profit cannot be properly addressed until after the pits are designed, the production is scheduled and the cash flow is estimated. Throughout the years, many investigators have ad¬dressed this problem. A major thrust of the famous paper in which Lerchs and Grossman (1965) presented their algorithm was to identify a sequence that would produce a result similar to that identified in Fig. 1. Whittle's (1988) four-dimensional analysis is designed to address this issue. The author addressed this same issue in a paper presented to the 1968 Canadian Institute of Mining national convention (Lemieux, 1968). Without a relatively simple methodology to con¬struct the curve in Fig. 1, the number of iterations in a trial-and-error method becomes prohibitively burden-some. The pit designer seeks a simple pit-planning parameter that will serve as a proxy for the after-tax profit per ton used in defining the curve in Fig. 1. The designer's goal is to apply this pit-planning parameter using standard pit-wall location techniques to design a series of pits that will provide a guide to the sequencing. Common techniques used to position pit walls are strip-ratio limits, highwall incremental analysis, floating-cone methods or "maximizer" applications1. Costs, revenues, noncash charges, taxes and profits are usually structured on a unit basis for use in the pit-wall location analysis. Application of the proxy parameter using the pit-design tools should, ideally, result in the definition of pits and sequences that will maximize the curve in Fig. 1. 1 The pit-design tool frequently referred to in the literature as an "optimizer" defines a pit boundary that maximizes the value contained within based on the input parameters and the safe pit-wall angle. The optimization of the pit design involves selection of rate of production, cutoff grade, product quality and other considerations. These considerations constrain the maximization of value. Therefore, pit-design tools that maximize value should be called "maximizers."

Jan 1, 2000

By Regina N. Tempel, Mae S. Gustin, Mark A. Engle

This study characterizes the hydrogeochemistry of groundwaters near opalite-hosted epithermal hot-spring type mercury deposits in the Ivanhoe mining district, Elko County, Nevada. Local groundwaters generally range from Ca-HCO3 to Ca-Mg-Na-SO4 type waters with background mercury concentrations ranging from 0.014 to 0.32 ug/l. Leaching experiments conducted on mineralized rocks, using typical water chemistries to represent local groundwaters, yield total mercury concentrations ranging from 6.3 ug/l to 27.4 ug/l after one year of reaction. Geochemical modeling indicates dissolved mercury is dominated by HgO(,) and that precipitation of quicksilver controls mercury concentrations to an upper limit of 63 ug/l.

Jan 1, 2000

By A. L. Anderson, J. T. Rybock

Lime, soda ash and similar precipitants have been the industry standard for treatment of acid rock drainage (ARD) because of their proven ability and low per-gallon operational cost. However, these methods carry serious environmental drawbacks and high life-cycle costs. KEECO’s Silica Micro Encapsulation (SME) technology has all the positive characteristics of conventional ARD-treatment systems but none of the drawbacks. SME achieves highly effective treatment in a single step, provides options for ARD prevention and recovery of metals, requires lower capital expenditures, generates smaller volumes of higher-density sludge, consistently passes leach tests, and eliminates long-term liabilities associated with potential metal remobilization and hazardous waste landfilling.

Jan 1, 2000

By V Kainulainen

Sandvik Tamrock Corp has developed an underground rock flow simulation tool OPTIMINEÖ which is a direct simulation tool for matching suitable technology in rock material flow for underground mine layouts and production requirements. The tool gives the possibility of determining intersections, limitations and critical points in the layout and working procedures at an early stage of a new mine/mining area planning process. The tool combines the supplier machine knowledge with operational know-how and mine environment. It can be used for identifying the effect of an individual incident such as the effect of one additional turn in a continuous loading cycle to the daily capacity. This paper discusses the way the OPTIMINEÖ simulation tool operates, the benefits and restrictions, and reviews how it simulates some example cases and how the mines benefit from the tool in maximising the performance and optimising the mobile fleet, scheduling work and fine-tuning the layout.

Jan 1, 2000

This paper is in two parts. The first part provides background to coal in New Zealand, information on Solid Energy the Company and details of the resources, mines and products of the company. This part of the paper is intended for people who have limited knowledge of the New Zealand coal scene. The second part of the paper focuses on developments underway in New Zealand and discusses planned or possible changes and opportunities. This paper was first presented at the Coaltrans Asia Conference in June 2000.

Jan 1, 2000

By R. T. Dec

A review is undertaken of existing mathematical models of compaction process in roll press. The example of plane-strain, plane-stress model is presented together with comparisons between computed and experimentally recorded pressure distribution in roll nip region. Next, the discrepancies between predicted and measured values are discussed and practical method based on experimental optimization of compaction process using laboratory roll press is proposed. Examples of the selection of optimum roll press operating parameters for calcium oxide fines, sodium chloride and iron oxide dust are presented to illustrate advantages of the method. Finally scale up procedure is discussed for estimating the performance of commercial size roll press based on the data collected on laboratory size equipment.

Jan 1, 2000

By S. M. Pickering, L. T. Gregg

Appraisal of industrial minerals beneath privately owned land requires a different approach and mindset from valuation of base and precious metals or energy minerals, and from valuation of government-owned mineral lands. First, is it the value of inground minerals or of mining rights that is being sought? Second, value to whom, the mining company, a potential investor, the mineral landowner, a lending institution, the property tax assessor, or a condemnor? Third, how should mineral value be apportioned between the land and mineral owner, and a mining company with limited years of lease-hold interest? These and many other questions must be addressed before a valuation method and Discount Rate are selected. For various reasons the Income Method is most often used, with Net Present Value calculations made for long term predicted mining income. Choice of an appropriate Discount Rate is critical.

Jan 1, 2000

By Robert Hopler

The literature of explosives and blasting consists of a great variety of printed materials. These materials include technical papers, books, and articles by individuals and organizations; manufacturer’s product catalogs and brochures; handbooks offering guidance for the field blaster; complete encyclopedias on the subjects, and short entries in general-interest encyclopedias; government publications; proceedings of organizations devoted to the subjects; magazines specific to the subjects; articles in general circulation magazines; and other miscellaneous sources. In short, there is a multitude of literature on the subject, some well indexed for retrieval, but most not. This presentation will be a broad-brush look at some of the most important or interesting literature on the subject, since in no way can all the various references be mentioned, much less covered in depth. To illustrate the presentation, interesting materials from the author’s collection will be shown.

Jan 1, 2000

By L. A. Obasi, C. Obasi

Investigations were carried out to determine the effects of changing metamorphic conditions on the formation of magnetite from the Itakpe iron ore deposit. Various magnetite grain sizes from ferruginous quartzites from different zones were determined and analyzed statistically. The results reflect the reaction of mineral individuals. In particular, the granulometry of magnetite changed with changes in the mineral formation conditions in the deposit and correlate with the mineralo-geochemical zones. This is interpreted as part of a readjustment of the mineral to the prevailing conditions. Because granulometry is a prebeneficiation parameter, this work will be, no doubt, of importance to the exploitation and beneficiation of the quartzites and rich ores.

Jan 1, 2000

By James C. Foley, David K. Rehbein

"In-situ characterizations of green state part density and sintering state have long been desired in the powder metal community. Recent ·advances in non-contact electromagnetic acoustic transducer (EMAT) technology have enabled in-situ evaluations of the acoustic attenuation and velocity as sintering proceeds. Pure aluminum (99.999%) and aluminum alloy powders were prepared with high-pressure gas atomization (HPGA). The powders were pressed in a uniaxial die and examined with acoustic waves for changes in velocity and attenuation during sintering. The changes in acoustic properties were correlated with sample microstructures and mechanical properties. Evolution of the acoustic echo train during sintering is shown to provide information on the state of sintering as well as having the potential for detection of interior flaws.IntroductionThe versatility of powder metalallurgy (PIM) technology in the manufacture of complex shapes has enabled an increasing amount of wrought and casting production capacity to be converted to PIM technology. However, ultrasonic inspection of green components produced using PIM techniques remains a challenge and is not generally practiced [1]. Inspection of PIM components in the green state is highly desirable, because the green part can be reclaimed with only accepted components being subjected to further costly processing. Another potential benefit is characterization and greater understanding of the sintering process itself. An increased scientific understanding of the sintering process enables intelligent process control, greater reliability of the production process and a lower rate of rejection of the finished product. In order to realize these potential benefits, it is necessary therefore that accept/reject criterion be based on real time nondestructive evaluation of the green-state components and the sintering process.Most current nondestructive inspection techniques suffer from their inability to perform inspections below the near-surface region with the exception of X-ray and to some extent pulsed eddy current [2]. X-ray inspection requires extensive shielding of production personnel and expensive film and film processing. While development of pulsed eddy current techniques have lessened the impact of the well-known skin effect, the depth of penetration of the induced eddy currents remains somewhat of an issue [2]."

Jan 1, 2000

By Janice M. Zinck, W. F. Griffith

Four different high density sludge-type processes, Cominco HDS, Geco HDS, Tetra HDS Process and the Staged- neutralization process were studied for their effectiveness in treating a low strength Zn-Fe rich acidic drainage solution. Each proms was run continuously for at least two weeks after obtaining steady state conditions. The final effluent quality, lime consumption, sludge density, settleability, filterability, viscosity, neutralization potential, metal leachability, operating and capital costs were measured and evaluated for each process.

Jan 1, 2000

By K Lee, K Fernando, S Rayner

Copper-gold ores have been technically difficult and uneconomical to process due to high consumptions of cyanide. Many copper oxide and sulphide minerals react with cyanide to form copper cyanide complexes, partly contributing to the high level of weak-acid dissociable cyanide in the tailings which is normally experienced during the processing of copper-gold ores. The cost for detoxification, if required for treating these tailings, would further inhibit the development of these copper-gold resources unless the cyanide used for leaching was recovered. Several technologies have been proposed to process copper-gold ores, aiming to recover copper as a co-product and cyanide for recycling in conjunction with the leaching process. A critical review of these processes reveals that a pre-concentration stage (solvent extraction or resin ion exchange) is required. Cyanide is recovered by the conventional Acidification-Volatilisation-Regeneration technique in most cases. A critical evaluation is also provided on technical aspects related to the use of Vitrokele Technology and a newly developed Elutech process in processing copper-gold ores, in particular with its application at May Day Mine.

Jan 1, 2000

By Taiping Lou

The coarsening process of precipitates in non-equilibrium systems was studied, and then a physical model of coarsening was proposed. The coarsening process of CaO'TiO2 in MgO-TiO2-Al2O3-SiO2-CaO-CaF system was investigated. It is shown that the coarsening process by the model predicting is agreed with the experimental results.

Jan 1, 2000