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By Kostas Fytas, Pierre Bousquet, Bill Evanelou

Acid mine drainage (AMD) is a serious environmental problem that preoccupies the Canadian Mining Industry. Considerable amounts of money are spent every year in an effort to prevent or reduce the acid mine drainage phenomenon. AMD occurs when sulphide minerals (ex. pyrite) contained in rock are exposed to air and water and subsequently oxidise to produce low pH water. This acid effluent has the potential to mobilise any heavy metals contained in the rock. Coating the sulphide minerals with silicates is a new promising technology to reduce AMD. Pynte is treated with a solution containing H2O2, sodium silicate and a buffering agent. H2O2 oxidises a small part of pyrite producing ferric iron (Fe3+) ions. These ions subsequently react with the silicate ions to produce ferric hydroxide-silica that precipitates on the pyrite surface producing a passive coating. This silicate coating can protect the grains of pyrite from oxidation. This paper presents a series of experiments that confirm that silicate coating can considerably reduce AMD.

Jan 1, 2000

By JoAnn Silverstein, Eric A. Marchand

Competition between Thiobacillus ferrooxidans and non-iron-oxidizing heterotrophic bacteria was induced by the addition of glucose to a co-culture of T. ferrooxidans and A. acidophilum in an oxygen-limited environment. Iron oxidation was inhibited as dissolved oxygen was used preferentially for glucose metabolism. Furthermore, as the water became anoxic, glucose was consumed along with the oxidized iron species (Fe3+) during iron respiration resulting in a pH increase from 2.0 to 4.0. Results suggest that biologically mediated acidification of drainage water can be reversed by dispersion of an easy to degrade, soluble, and inexpensive carbon source such as glucose into the subsurface.

Jan 1, 2000

By R. J. Wesely

Non-ferrous smelters traditionally have a hot gas handling system. In these systems, the dust is captured as a dry material which is often recycled to the process. Some smelters use wet gas cleaning methods with the recovery of the dust as a wet sludge. Although this sludge can be recycled to the process, in some cases it is preferable to dispose of the sludge. This paper will discuss the disposal methods available and specifically will deal with one type of sludge which has a high arsenic and high lead content. Problems with this sludge were investigated and methods were tested with the aim of stabilizing the sludge so that it passes the EPA TCLP test. Results of the laboratory tests are given.

Jan 1, 2000

The concept of Extreme Gravity is the latest in a series of innovations that has seen a re-introduction of gravity recovery systems into the milling operations of most gold mines. Traditionally, most gold milling circuits are designed around flotation and cyanidation requirements, with the gravity circuit being fit in where possible. Extreme Gravity takes the novel approach of optimising the circuit, in order to maximise recovery by gravity. In some cases gravity systems can achieve high enough recoveries to eliminate the need for chemical systems such as cyanidation or flotation. There are many advantages of such a system including low capital cost, reduced permitting, improved cash flows and much reduced environmental issues. There are a number of plants currently in operation which utilise this new methodology. The Muzhievo project has been an example of a recent turn key success achieving recoveries from 85 - 90 per cent. The details of this project are examined as a case study.

Jan 1, 2000

By A. C. Cascalheira, L. M. Abrantes, M. Savic

This paper reports our results on the application of a novel process for the spontaneous and sustained reduction and recovery of elemental silver and gold on an electroactive polymer surface. This work incorporates the metal recovery from photographic films (silver) and goldsmith residues (gold), by direct contact of metal containing solutions with polymer. The performance on such process of electrochemically and chemically prepared polyaniline (P ANI) is evaluated. SEM coupled with EDX and XRD analyses confirmed the presence of metallic silver and gold deposited onto polymeric material.

Jan 1, 2000

By R. L. Grayson

Conventional mine safety wisdom states that "the most efficient mines are also the safest." Since the 1980s, small mines (and contractors) have been targeted as the most dangerous because of their fatality records. However, statistical analysis of West Virginia safety and production data from 1993 indicated that, when considering the correlation between accident severity and tons mined per employee-hour worked, the most efficient mines were, with the exception of very small mines, not the safest operations. This paper presents the results of an extended analysis of West Virginia mine safety using 1993 and 1996 data and concludes with the method used to suggest current priorities for focusing interventions.

Jan 1, 2000

A general review of grinding mill steel liner evolutions/developments in recent times. The driving force behind these developments has been the mill operators desire to minimise the nett cost of their operation. These developments have resulted from a team approach between supplier, operators and reline crews. The move towards larger diameter high aspect mills, faster mill speeds, pebble ports and the use of large diameter grinding media has affected the traditional liner designs, which is placing higher demands on the supplier to meet these new working parameters and expectations. Operators are also taking closer ownership in the liners being supplied, as demonstrated by the development of their own mill liner specifications. This paper outlines some of liner developments and changes undergone at various milling operations around Australia and overseas (such as Cadia Hill, Kidston, Ok Tedi Mining, PT Freeport, etc) and where to in the future?

Jan 1, 2000

The extraction of world-class mineral deposits using massive underground mining techniques is not an entirely new theme to world mining companies and experts. Previous MassMin conferences have helped to gather and disseminate the valuable experience and knowledge so important for the proliferation of safe and efficient mining of large underground deposits. With the passing years since the first MassMin conference in Denver in 1981, a number of factors have contributed to an increase in massive underground mining around the world, including environmental pressures, gradual exhaustion of shallower deposits and the enabling effects of improving technology in disciplines related to underground mining. Massive underground mining is heading deeper, embracing challenges which include working with elevated temperatures, increasing in situ and mining induced stress levels and longer ore transport routes. Improvements in mineral processing technology will tend to lead operators to contemplate the extraction of lower grade orebodies in the event that the ore can be efficiently transported to the surface and hence the plant. No doubt this tendency, and its associated challenges is encouraging a rich growth in innovative engineering in such fields as mine planning and materials handling as well as geomechanical issues such as support design and the simulation of extraction sequence effects on stress re-distribution. MassMin 2000, we are sure, will showcase a wide variety of new contributions in thought and actions in these fields. There is a definite place for academic institutions and mining related suppliers in the process of developing new technologies and practices in support of present and future endeavour in this field. Dyno Nobel has its own part to play, certainly as an enthusiastic and proud major sponsor of MassMin 2000, but also by means of identifying common cause between our Vision and Values and the needs, present and future, of the underground massive mining industry. The critical success factors, which Dyno Nobel pursues are:health, safety and environment, customer relationships and market development, cost optimisation (while maintaining quality), technology and innovation, organisational development, and leveraging capabilities globally. Through the present paper we would like to share some of these values and offer some practical insights as to how their realisation will contribute to the achievement of MassMin goals and needs.

Jan 1, 2000

By Chris Harnan

This paper describes the geology of three European cities and outlines how the geology has lead to the development of specific foundation construction techniques. Comparative tables of techniques commonly employed are given in Section 5. It can be seen that despite the presence of the 'single market', techniques still have wide diversity despite some similarities in geotechnical conditions.

Jan 1, 2000

By Thomas L. Vandergrift

Multiple-scam mining is becoming more common in the United States, especially in the East, where primary reserves arc being depleted, forcing mining companies to develop secondary seams, Although mine engineers and planners are aware of the basic effects of seam interaction and generally follow guidelines for columnizing entries and avoiding load abutments, mine design earn greatly benefit bum more quantitative estimates of scam interaction effects. This paper presents case studies from two eastern mines subject to seam interaction effects where pre-mining stresses were quantified: the Mingo Logan Coal Company's Mountaineer Alma A Mine, and Peabody Group's Lightfoot No. 2 Mine. In each of these mines. mining is being carried out within 60 to 90 ft of overlying longwall and pillar panels under maximum cover of about 1,100 ft As part of overall mine planning and design efforts al these mines. NSA Engineering performed numerical modeling analyses using the non-linear boundary-element code MULSIM/NL Input parameters were calibrated by modeling areas where ground conditions resulting from seam interaction were well documented. By incorporating actual cover loading based on topography and seam dip, and the integrity of remnant, gate road, arid harrier pillars in the overlying mines, the pre-mining vertical stress in the underlying scants was estimated based on the pre-mining stress, plans for mains, gate road, bleeder, and pillar panels were developed. Although mining experience in these areas has beers somewhat limited to date, she designs developed as a result of these analyses have so far proven successful.

Jan 1, 2000

By L. Alan Weakly

Coal mines and power plants utilize different methods to control dust for the safety of their workers and to protect their installations. The methods that they use are limited by the Environmental Protection Agency or the states in which they operate. Now there is a new technology for controlling dust at conveyor transfers! The Passive Enclosure Dust Control System utilizes several proven technologies to mitigate fugitive dust. This new system has been proven to be four times more effective than standard enclosures utilizing bag house collection and is considerably less expensive to install and operate.

Jan 1, 2000

Over 45 of the Best Qualified Technical Specialists, Consultants, Engineers, Scientists, Explosive Supplies, Educators and Mine Operators in the World!

Jan 1, 2000

By M. -V. Wang

Hydrotreating and hydrorefining (HT and HDS) spent catalysts contain molybdenum, vanadium, nickel or cobalt at concentration levels that can make metals recovery economically viable. Quanzhou Jing-Tai of China has developed, through many years of operating experience in metal recovery from spent catalysts, a simple process for recovery of these metals and the production of environmentally benign residues. The process first subjects the catalysts to a low-temperature calcination step, followed by grinding of the calcine. The ground material is then leached with 10-20% v/v hydrogen peroxide to recover metals such as Mo, V and Ni or Co. This step has a selectivity that is greater than 95% for the metals. The undissovled residue, which contains mainly Ah03 and Si02, can be dewaterd and used in the production of masonry bricks. The pH of the rich liquor is then adjusted to between 0.5 and 2.5 by adding dilute sulfuric acid to co-precipitate Mo and V, with a recovery rate of greater than 99%. The lean liquor contains mostly dissolved Ni or Co, which can be recovered through precipitation at a pH of between 8.5 and 9.5 by caustic additions. The final liquor is then sent to an ion exchange step for final recovery and cleanup of residual metals. The effluent is then discharged after a simple wastewater treatment process, which has been found to meet all environmental requirements. The entire process has been found to be simple, cost-effective with minimal environmental impacts while achieving the goal of complete resource recovery from spent catalysts commercially.

Jan 1, 2000

By John W. Pickens

The recycling of industrial wastes and by-products is an important component of ecologically responsible industrial management. Converting waste streams into value-added products or material and energy resources with a profit margin assures the continued viability and practice of recycling. The recycling of aluminum stands out as one of the best examples with major economic and environmental benefit. However, the benefits are compromised by landfilling of black dross and salt cake, waste streams produced from within the recycling process itself. This paper reviews Alumitech's strategy and progress in establishing a tertiary aluminum industry based on closed-loop recycling of black dross/saltcake; one which does not compete with the primary and secondary aluminum industries, but rather serves their needs to ensure the continued economic benefits of aluminum recycling and elimination of environmental liablJity associated with landfilling of black dross/saltcake. Alumitech has made significant progress toward that goal in operation of its new recycling facilities in Cleveland where recovered aluminum and nonmetallic residue from salt based drosses is being converted into commercial products, eliminating the landfilling of the greatest portion of dross/saltcake. The economic strategy for recycling saltcake and its progressive achievement is reviewed.

Jan 1, 2000

By N. Mizutani, S. Harada, Z. Asaki, T. Tanabe

"The development of lead-free solders is urgent in view of environmental standpoints. In this -work the wettability of tin-bismuth- silver solders on copper was studied. Three kinds of fluxes were used. The wettability of conventional eutectic tin-lead .solder exhibited an excellent level over the other solders of tin-bismuth systems. Poor wettability of the tin-bismuth solders may be caused by the growth or dendritic copper-tin compounds at copper/solder interface, in contrast to the case of tin-lead'· solder. The wettability was improved by the addition· of silver in the solder. In this tin bismuth- silver system, silver was abnormally concentrated at the copper I solder interface even in the initial stage of contact. The wettability of the solder and the thickness of compound formed on the copper have a good correlation; the solder containing 2% silver exhibited the best wettability and the formation rate of copper-tin· compound on the copper was slowest.IntroductionSocial demand to avoid lead use in the industrial fields has been recently promoted· (1) because of the environmental protection of water resources. Especially the lead-bearing solders have been widely used in electronics and automobile products, and it is urgent to replace them with nontoxic materials (2)-(4). Thus the development of lead-free solders becomes an indispensable subject to the new generations and many works (5)(6) have already been carried out on the research and development of new solders. New lead-free solders are expected to have some requirements, for example, moderate melting temperature, proper strength and integrity, and lower prices, as compared with conventional solders. There have been already several alloy systems developed. Among ·these alloy systems, tin-bismuth binary or tin-bismuth-silver ternary alloys have great advantages such as having a wide range of soldering .temperature by controlling con:ipositions, though they have such disadvantages as ""lift-off"" (7)-(9): It is said, on the other hand, that a frequently overlooked property of solders, or one that is typically ignored by the research scientist as an ""issue"" for the manufacturing or product engineer, is wettability (10), although a ·work on the wettability has recently been published (11). In this Work, therefore, the authors selected Sn-Bi-Ag solders and focused mi the effect of Ag-addition to wettability of the solder."

Jan 1, 2000

By Jason Ryan, Stephen Harria

Q.E.D. (QED) is a blast design and evaluation model that allows full three-dimensional design specification including the development of unique “live” terrains and an unlimited variety of complex charge configurations. QED’s analysis package allows the examination of likely outcomes resulting from changing various design variables in terms of vibration, fragmentation, rock-mass damage and muck-pile profile. Especially applicable to use cautious blasting applications, QED’s damage model uses vibration to estimate rock damage beyond excavation boundaries. This relates directly to operations such as Yucca Mountain Nuclear Waste Repository in Nevada, where damage beyond the excavation perimeter must be tightly controlled. The U.S. Department of Energy (DOE) h as b een studying a site at Yucca Mountain, NV to determine its suitability for long term storage of nuclear waste. The main mechanism of waste isolation will be the natural barrier of the host rock Total Systems Performance Assessment (ISPA) is used to model the excavation design and its behavior over time. Of importance to TSPA is quantifying the condition of the rock-mass before and after excavation. Ideally, there should be no excavation-induced changes to the rock-mass’ structure (removing the requirement to model the effects). At the least it may be possible to keep excavation-induced damage far enough away from waste packages so that modeling of these effects will not be required. QED can calculate a prediction of the extents of blast induced damage to the rock-mass. By using this metric as a design parameter, it may be possible to complete excavation of the repository more rapidly and inexpensively than previously thought, without jeopardizing the structural integrity of the waste containment areas or requiring blast damage to be modeled by the TSPA. This paper will explain the structure of the QED blast modeling system and show the analysis of historical data from Yucca Mountain. Processing of the historical data and the subsequent results will demonstrate how blast modeling can be used on an ongoing basis to assist the excavation process at Yucca Mountain.

Jan 1, 2000

By R. Peterson, D. C. Popko, J. Y. Hwang, R. McChesney, A. M. Hein, R. C. Greenlund, M. Jeong

MTU is conducting a study to recycle and reuse the aluminum waste generated from various segments of the aluminum smelting industry. This research is supported by the U.S. Department of Energy and industry. A portion of this effort is to determine the operating efficiencies of Eddy Current Separation, comparing separating characteristics of white and black dross. The results of this effort will be presented here.

Jan 1, 2000

Hindustan Zinc Limited (HZL) is one of the leading base metal producers in India. It operates a two-smelter Complex at Visakhapatnam, Andhra Pradesh. At this zinc-lead smelter zinc is manufactured by the conventional hydrometallurgical route and lead is produced by Blast furnace technology generating residues or wastes which contain substantial quantities of metal values. Disposal of such wastes is a problem in any non-ferrous industry. Both the stringent environmental regulations and the changing industrial scenario emphasise the need for industrial research to find economically viable and environmentally friendly technologies to recover the metal values from these waste materials. The in-house R&D Centre at Vizag Zinc Smelter (VZS) thinking globally re-engineered its activities and major thrust was given for converting waste to valuable metals and metal compounds. Basic analytical chemistry with the hydrometallurgical concepts has been adopted in developing these innovative technologies. In this paper attempts are made to provide a clear history of the different waste raw material, the process developed for each raw material and their superiority of over other parallel work. Most of the processes described here are pilot plant tested and under patenting. The process flowsheet, results obtained and advantages of each process are presented. This paper provides a consolidated approach through which the varied smelter waste materials can be processed with cost effective and eco-friendly innovative technologies. In-house R&D efforts at VZS with its contribution and achievement in converting æwastes into wealthÆ technologies are presented in this paper on the following the major thrust areas:recovery of zinc from liquid effluent; recovery of zinc from effluent treatment plant (ETP) gypsum sludge; production of highly pure electrolytic zinc metal powder from zinc bearing gypsum residue/sludge generated at the effluent treatment plant; hydrometallurgical recovery of copper as copper sulphate solution which can be used for CuSO4.5H2O, copper cathode/copper metal powder from copper-cadmium cement; recovery of manganese, lead and silver from anode mud generated at Zinc Cell House and 4-metal extraction/recovery of manganese, cobalt, copper and nickel from Indian ocean bed manganese nodules; recovery of zinc, lead, silver and sulphur values from silver concentrate residue generated at the froth flotation process; recovery of silver and lead as lead-silver sponge/lead-silver sulphide concentrate from lead bearing residues; recovery of lead, silver and copper from copper matte; recovery of antimony as antimony metal or lead-antimony master alloy from antimony bearing dross; and recovery of nickel and dimethylglyoxime from Ni-DMG complex.

Jan 1, 2000

By M. Tamura, K. Fujita, K Shinozuka, H. Daimon, H. Esaka

"In-situ observation of unidirectional solidification using transparent substance has been performed to investigate the growth direction of solid phase. Cell or dendrite of which preferred growth direction is not parallel to the heat flow direction was observed with various solidification conditions. Dimensionless growth direction (p) changes from 0 to 1 with increasing growth velocity at a constant temperature gradient. Introducing the dimensionless growth velocity, the relation between p and growth condition could be correlated.IntroductionTransition in macroscopic solidified structure from chill to columnar zone which is found in normal castings takes place via grain selection1). Cast products such as turbine blades are unidirectionally solidified, grain selection plays an important role to choose suitable crystals which have reasonable orientation in the region called ""starter"", which is a very initial part of casting2). Therefore, grain selection is a very important process in the formation of casting structure. The present authors have been studying on the process of grain selection using succinonitrile, which is a transparent organic substance and have found that the growth distance necessary for grain selection depends upon the solidification condition3-5). When the solid/liquid interface is dendritic, the grain selection occurs quickly. On the other hand, when the solid/liquid interface is cellular, it occurs slowly. We supposed that the growth direction of dendrite is different from that of cell when the substance is unidirectionally solidified. Indeed, Kurz and Fisher wrote in their text book that dendrite grows along its preferred growth direction, <100>, regardless of heat flow direction and that cell grows along heat flow direction regardless of its preferred growth direction1). However, there is no quantitative description about the growth direction when the solid/liquid interfacial morphology is cellular. Furthermore, there have been little works6) to study the growth direction of cell and dendrite."

Jan 1, 2000

By Paul Worsey, Richard P. Ayres, Mark F. C. Schmidt

A new alternative technique designed to reduce rock scatter and flyrock during boulder blasting is being developed at UMR. The method uses small explosive charges and is designed for shooting in close proximity, while utilizing common blasting products found on the operators’ site. This ongoing work is being conducted internally as graduate and undergraduate level research. A paper describing the general technique was published in last year’s proceedings. This particular portion of the work was performed as an undergraduate research project as part of the requirements for the explosives emphasis degree option at UMR. Previous model work was performed using cubes of concrete. However, in real life boulders are often flat and irregular rather than perfect cubes. The purpose of this work was to determine how to deal with flatter boulders. The work comprised using different geometry blocks (simulated boulders) of the same volume (1 cubic ft.). Square concrete boulders using an 8.5bag concrete mix were cast using different width to height ratios (varying from 1: 1 to 3.7:1). Single 5/8 inch holes were drilled to 2/3 the depth of the blocks, charges placed approximately l/2 way in to the holes and the holes filled with water. The explosive charges comprised ICI Masterdets containing a OSg High Explosive base charge and incremental added weights of C4 explosive. In the experiments, the block height was progressively reduced and to compensate the charge weight was increased until acceptable fragmentation was achieved. It was found that a significant increase in charge wt is required to achieve the same fragmentation as the width to height ratio increases (the boulder becomes flatter). Furthermore, the increase in charge weight required is proportional to the width to height ratio. Basically, you have to use a higher powder factor for flatter boulders.

Jan 1, 2000