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By Hideki Yamamoto, Junji Shibata

"The chemical reactions of fluoride and chloride gases with metal chloride or metal oxide are utilized as an effective treatment for harmless disposal. These chemical reactions can be adopted in the temperature range of 80°C~400°C, which is lower than that in the combustion treatment (800°C). Reaction products are metal fluoride or metal chloride which are a harmless and a valuable chemical material as one of new resources. This paper, concerns with a new harmless disposal treatment of toxic global warming gases.IntroductionNew technology to make fluoride and chloride gases such as NF3, CF4, SF6 BF3, Cl2 and BCl3 harmless has been developed and a new concept on the removing toxic gas to be used in the advanced process of materials has been established. The fluoride gases ~re toxic and special type of gases to be used in the process of manufacturing semiconductors and their specific applications include the dry etching of semiconductors, cleaning of CVD systems, an oxidation agent for rocket fuel etc. Especially, NF3 is also attracting an attention as a high-energy source for chemical laser systems. As a fluoride gas like NF3 is, however; toxic and highly stable chemically, if discharged into the atmosphere, it is liable to cause far-reaching adverse influences on global warming in the same manner as carbon dioxide gas and feron gas.Up till now, the combustion treatment method has been adopted for the disposal of the gas, and when treating the gas by high-temperature combustion (800""C), the generation of nitrogen oxides (NOx), sulfur oxides (SOx) and hydrogen fluoride (HF) have been confirmed: These chemical substances are not only linked with an intense c0rrosion of the combustion systems but also create the generation of atmospheric pollution and acid rains, and therefore, constitute a serious social issue."

Jan 1, 2000

By J. Vander Linden, R. De Ketelaere, M. Verhaege

In this paper, results are presented concerning the search to implement Supported Liquid Membrane (SLM) technology for the recovery of copper from electroplating effluents. Acid copper electroplating rinse solutions or effluents resulting from the post-treatment of, for example, cyanide-containing copper electroplating baths all contain copper (2+) in the lower concentration levels. A thorough study of the influence of the individual parameters and of their combined impact on mass transfer in small scale laboratory SLM modules has been performed, enabling to set forward the appropriate operating conditions for a pilot plant installation. The pilot plant, containing two SLM modules. of 18 m2 of surface area, has been tested extensively, including short and long term runs, with real process solutions. It was demonstrated that this installation is able to treat 40 l/h of acid copper sulphate rinse solutions· containing 500 ppm of copper. The final copper concentration in the effluent can be reduced to a few ppm while copper metal is recovered by electrolysis of the concentrate. This technology is also applicable to the treatment of solutions with low copper content of origins other than plating shops, such as tailings from copper plants or mine waters.

Jan 1, 2000

By J. Hansen

"ABSTRACTThe paper addresses the application of automated monitoring, control, and navigation to improve dragline performance. SummaryImproving dragline performance in the Canadian coal mines is critical to the continued success of the industry. Draglines represent a large capital investment and coal prices are low by historic standards. This paper argues that the introduction of monitoring, control, and navigation on draglines offers an opportunity to significantly reduce a dragline’s operating cost per cubic metre moved. To place the importance of this in perspective, a North Dakota mine calculates that every 1% increase in dragline productivity means a savings to the mine of US$340,000 per year. MonitorsAutomated dragline monitoring is a well established technology with commercial products available since the early 1980s. The three main reasons for placing monitors on draglines are (Walker, 1993):1. productivity increases: reduce variations between different operators’ performance across different shifts;2. quality increases: increase the percentage of ore and waste loads that go to the correct destination; and3. special projects (engineering projects): justify installing static field exciters and regulator upgrades; implement power management; aid operator training; study high performance buckets, rigging changes, and various excavation sequences.Mines as diverse as Kennecott’s Cordero- Rojo Complex in the United States and Natal Coal Corp.’s Optimum Mine in South Africa report dragline productivity increases of 10% to 20% in the region attributed to the implementation of dragline monitoring."

Jan 1, 2000

James Barnes is Managing Director of James Barnes & Associated Ltd which is a company that has invested ten years of development to provide developers with a transparent, user friendly consultation framework that identifies who needs to be consulted, how they are to be consulted and procedures required to manage the risks associated with getting all the wrong! Despite the assertion above, this paper is not about to provide delegates with the answer to whom they ought to consult or identify the expectations that Maori might have in regard to the consultation process. It would be a very brave person indeed who would venture an opinion on such a sensitive subject. There are no short cuts to finding out what expectations Maori might have on any given situation. Nothing can be taken for granted. What this paper will attempt to do however is provide practical insights into what might be on the minds of Maori interests as they deal with the issues associated with mineral resources, particularly those under Treaty of Waitangi Claim. The Treaty of Waitangi has a significant bearing on the current debate between Maori and the Crown regarding ownership of mineral resources in New Zealand. The Waitangi Tribunal is currently hearing a case presented by a number of Iwi over the ownership of oil and gas resources in Taranaki and Hawkes Bay. Others will follow. The Crown and Maori have never been able to settle differences over ownership rights without resorting to legal action and it looks like this scenario is about to be repeated in regards to minerals. The Crown has a duty to actively protect the Maori interest. This is a fundamental expectation in the relationship between Maori and the Crown. In the case of minerals, Maori have yet to see the Crown do its duty. The impact on developers has become evident through Maori objections to consent applications as the issues of mineral right remain unresolved.

Jan 1, 2000

By Masaru Tomoguchi, Tom Nishiyama, Naoto Sasamoto

"In Hanaoka Mine, which was one of the major ""black ore"" (Kuroko) mines in the north part of Japan, mining has finished in 1994, and only mineral processing plant is available now. Recently this mineral processing plant has been applied to the soil washing. Soils contaminated with heavy metals are excavated and transported to the plant. The soils are separated to cleaned soil and metal enrichment through the process which consists of scrubbing, classification, extraction, insolubilization, flotation, and so on. The process is flexibly designed for each contaminated soil, in order to the products can be recycled as cleaned soils or metal sources. . Soils contaminated with arsenic and lead were treated in 1999, which were entrusted from Environmental Agency of Japan.IntroductionDowa Mining has had the mine site named ""Hanaoka Mine"" and ""Kosaka Mine"" in the north part of Japan. Those mines consisted of some ore deposits and produced ""black ore"" (Kuroko) and ""yellow ore"" (Oko), which are complex sulfide ore. The ""black ore"" mainly consists of sphalerite, galena and barite with accessory chalcopyrite, tetrahedrite and Au, Ag minerals. The ""yellow ore"" mainly consists of powdery and clayey ore containing chalcopyrite and. pyrite, with a little sphalerite and galena. Each mine site had mineral processing plant respectively, ""Hanaoka Mine"" had two and ""Kosaka Mine"" had one plant. Those plants were operated by flotation process to separate each mineral, and produced concentrates of copper, lead, zinc, pyrite, barite and so on.Unfortunately, the mine had closed one by one because of change in economical circumstances and the lack of ore reserves. Mill plants were also closed and dismantled, but the last ""Matsumine mill plant"" of Hanaoka Mine was remained to be utilized usefully. In the circumstance like that, we came across with soil remediation business. Recent reports say that subsurface contamination in Japan is being grown substantially and that it can be a serious matter beyond the imagination of our society. So nowadays we have a tendency to pay attention to the environmental issues including subsurface one."

Jan 1, 2000

To provide a practical method to reduce hand and arm injuries during roof bolting operations.

Jan 1, 2000

By P Hanna

Following the Busang fiasco, more detailed guidelines were appended to the latest revision of the JORC Code released in September 1999 (JORC, 1999). Although the definitions and terminology essentially remained unchanged, the additional information in the guidelines has highlighted a number of issues for consideration by geologists undertaking computer-based resource estimations. The three main issues are:Data Integrity û details such as drilling and logging techniques, sampling procedures, assay tests, site visits, data recording and aggregation methods need to be considered. Geological Interpretation û is the Competent Person applying the appropriate software interpretation to the deposit in accordance with the regional setting. Are the correct computer-based tools being applied and are they producing the desired result (without compromise) to the satisfaction of the Competent Person? Modelling Technique û the importance of the relevant experience of the Competent Person not only in regard to the geology, but also with respect to the modelling algorithms and resource calculation methods of the computer software system involved. At the end of the day, it is essential that the Competent Person undertake a reality check on the resource estimation itself. They should also check that the borehole spacing is in accordance with the level of continuity for each critical parameter (such as structure, grade, impurities, etc) for which the resources are categorised.

Jan 1, 2000

By Masayuki Kudoh, Tohru Maruyama, Yohichi. Ito

When hypo-peritectic carbon steel is quenched during unidirectional solidification, the region of fine columnar grain is observed. It is classified into two coexisting phases. One is coexisting phases of liquid, delta and gamma in the upper part of the region, and the other is coexisting phases of delta and gamma in the lower part of the region. To form the coexisting part of the three phases means that solidification in this experiment proceeds in non-equilibrium state. The size of the narrow side of one fine columnar grain coincides with the arm spacing of a primary dendrite and this result is the same as the hyper-peritectic carbon steel. However, the boundary of the fine grain in the hypo-peritectic carbon steel is formed in different location from that of the hyper-peritectic carbon steel. The former is formed in the skeleton of the dendrite, while the latter is formed in the interspacing of the dendrite. The region of the fine grain changes suddenly to that of the coarse grain when the delta phase in the coexisting part of two phases disappears completely. Therefore, the delta phase in the hypo-peritectic carbon steel might prevent the growth of gamma grain. In order to recognize it, ferrite formers such as Mo, V and Ni are added in the sample. Then, the longitudinal length of the fine columnar grain extends in the sequence of the no addition, Mo, V and Nb.

Jan 1, 2000

By Kathleen S. Smith, Katherine Walton-Day, James F. Ranville

Four different scales of observation were used to evaluate the potential effects of a fluvial tailings deposit on water quality along the flood plain of the upper Arkansas River south of Leadville, Colorado. First, we collected surficial material and subjected it to batch water-leaching test. Second, we excavated and leached an intact eight-inch diameter core. Third, we examined the water quality of the shallow ground water beneath the fluvial tailings deposit, and fourth, we monitored water quality along a 5-km reach of the adjacent Arkansas River. Leaching of surficial samples indicates that there is a reservoir of readily water-soluble material yielding elevated metal concentrations and high acidity. However, there are minimal measurable water quality effects of the fluvial tailings deposit on the adjacent reach of the Arkansas River.

Jan 1, 2000

By R. L. Guerguerian

Nowadays, most grinding mills driven by a wrap-around ring motor are operating successfully. Some of the earlier problems could be attributed to the lateral stiffness and stability of their bearings. As a result, modifications to the bearings included the rearrangement of the shoes, or the addition of more shoes, closer to the horizontal centerline. This technical paper reports a study of the effects of bearings on the lateral stiffness of grinding mills driven by a wrap-around ring motor. The discussions cover the design of the four shoe trunnion bearings and examine the effects of the angular location of the shoes.

Jan 1, 2000

Mobile mining equipment presents only a small portion (ten per cent mining project costs but the selected technology will determine to a large extent the mining performance and mine profitability. The actual performance of the selected mobile equipment technology will rely on the support functions, infrastructure, user interface and user acceptance. Optimising the technology to match the circumstances is an increasingly important phase in a mine feasibility study. Smartly done feasibility studies include the possible future needs of changing or building-up of the selected technology. In massive mining applications the machinery faces quite different challenges than in selective or small-scale mining applications. In massive mining applications the efficient and continuous move of large amounts of material has led to the use of increasing degree of automation. This higher degree of automation in a mining application, on the other hand, will be best applied to a smooth and streamlined mining process and operation. Mining methods like block caving support automated operation. Automated mobile equipment needs supportive infrastructure, monitoring and information transfer systems as well as well established working procedures. Too often the user interface and human factor is disregarded during the consideration of automation. Through the available supplier programming tools it is possible to see how much the selected technology provides flexibility in changing production or economical situations, when major rebuilds or replacements are necessary, and view the effects of all these on the mine economy. When adequate technology is available from various sources, the difference becomes from preparing for the future, managing costs and combining the best layout with the most suitable technological solutions.

Jan 1, 2000

By S Vearncombe

SpaDiSÖ is a revolutionary approach to the spatial analysis of point data using geometry to analyse geometry! SpaDiSÖ uses each and every spatial relationship and is not dependent on mathematical models. For n points there are n2 û n spatial relationships and, because of the square function, the method yields interpretable results for both small and large data sets. SpaDiSÖ is an alternative to variography for directional studies. At the regional scale, the analysis can assess distribution patterns of mineralisation and potential controlling structures. At the deposit scale, the characteristics of zones of mineralisation such as direction, spacing, high-grade ore direction and grade distribution can all be deduced.

Jan 1, 2000

By E. J. Beckman, R. M. Enick, C. Shi

A novel liquid-liquid separation for the recovery of free or liberated gold from mixtures of fine particles was evaluated. Two inexpensive and environmentally benign fluids were selected for the study, water and carbon dioxide. The separation, which is conducted at 295 K and at the vapor pressure of carbon dioxide (6.0 MPa), is based on differences in wettability between the precious metals and other minerals. Contact-angle results indicated that, in the presence of water and liquid CO2, gold is slightly hydrophobic. The addition of CO2-soluble fluoroalkyl thiols or f uoroetherthiols increased the hydrophobicity of gold exposed to water and CO2 to a greater extent than alkylthiols. Minerals, including quartz, pyrite and magnetite, were hydrophilic. During the separation, an aqueous slurry of fine mineral and gold particles was mixed with liquid carbon dioxide. Pure gold particles (-325 mesh) were found to agglomerate at the H2O-CO2 interface. The minerals tended to remain in the aqueous phase. Despite these promising preliminary results, very poor gold recoveries were obtained when applying the procedure to an Australian gravity concentrate. This was attributed to the native gold particles in the concentrate being either too large, agglomerated in slimes or coated with minerals. Although this particular application was unsuccessful, this water-CO2 biphase technique may be applicable for other separations that require the removal of very fine, hydrophobic particles from an aqueous slurry.

Jan 1, 2000

By P Cavieres, R Dunlop, S Gaete

El Teniente Mine started the exploitation of the primary rock in the beginning of the 1980s decade, using caving methods. Since the beginning the mining activities have induced seismicity including some occasional rockbursts. Owing to the relevant damages, the mining operations were stopped in some production sectors. This paper describes the concepts that have been used in order to control the induced seismicity based on the strategies for controlling the rockmass breaking process, which depend on mining parameters. It also presents the main concepts applied in the Teniente Sub6 sector design and the experience collected during its sector exploitation.

Jan 1, 2000

By P. Meyers, F. DeSilva, L. Gottlieb

A number of tests looking at lead removal using ion exchange resins of various types from various aqueous streams have been undertaken. The tests focused on strong acid cation (SAC) and weak acid cation 0N AC) resins. It was found that the mechanism of lead removal is partly by lead filtration rather than solely by ion exchange in a large portion of the applications studied. This is not surprising since lead carbonate is essentially insoluble and almost all water supplies contain at least some carbonate alkalinity. Regeneration of lead from exhausted resins containing significant amounts of lead may not be practical in some cases because of the large chemical and waste volumes involved. Since lead, .·along with many other very insoluble metals, is often present as a suspended solid rather than in ionic form, ion exchange is probably not always the best technology for bulk lead removal.

Jan 1, 2000

By T. L. Owen

Since 1993 Cyprus Amax has brought $2.5 billion dollars of greenfield and expansion projects into production, taking it from a mid-sized domestic minerals company into a major international minerals organization. The near simultaneous development of these multiple mineral projects in different locations around the world provided the opportunity for Cyprus Amax to develop a formal project management approach based, in large part, on an outsourcing philosophy. This formal project management system along with its outsourcing philosophy has served the growth agenda of Cyprus Amax extremely well. These preceding factors, coupled with the in-house retention of a core project group that fully understands the breadth of skills and abilities needed to undertake development of multiple large projects successfully, have been the cornerstone of Cyprus Amax’s project development success.

Jan 1, 2000

By Paul Schmiesing, Matt Higgins

Central Oregon is a fast growing resort community centered in Bend, Oregon. Bend is bordered by the Cascade Mountains to the west and the high dessert to the east. Central Oregon is blanketed with lava rock with little topsoil. Ditch blasting is a staple in the area. Almost all utilities excavation (gas lines, sewer lines, water lines, and electrical lines) requires blasting. There is also a considerable amount of blasting required for site excavations and drywells. On average, there are over 500 blasts per year in Bend alone. All of this blasting is done using small holes, generally 2.5 inches in diameter. Typical ditches will have 200 holes, between 2-3 rows wide, with an average depth of 8 feet, and on 36 inch centers. Almost all shots are dry. Successful blasting requires careful control of drilling and loading. The vesicular basalt contains numerous lava tubes and caves making drilling and loading difficult. The rock conditions vary greatly from one side of town to the other requiring different powder factors and different scale of distances for vibration control. Caret%1 calculations of vibration predictions and use of site-specific seismic info is necessary. Marry shots will require deck loading and careful timing to ensure one-charge per delay. It is an every day occurrence to be blasting near residential and commercial structures or high pressure gas lines. Many times ditch blasting will incorporate excavation blasting. The different hole patterns used for the ditches and the excavation shots presents challenging timing sequences.

Jan 1, 2000

By H. Roberts, C. Hassall

The opening years of the new millennium will be characterised by the closure of many lead and zinc mines because of reserve depletion. However, weak commodity prices through the second half of the 1990s have slowed project evaluation and have made it difficult to raise finances for the development of new mines required to replace lost output and to meet increasing demand for metal in the future. Growth of lead and zinc demand will be determined by the pace of global economic activity, especially in the emerging economies. How rapidly demand grows will have a key bearing on the possible shortfall in mine output and the response of prices to the implied tightening of metal supplies early in the new millennium. These issues are the focus of a discussion of the critical lead and zinc supply developments which will unfold post 2000, taking into account project lead times and the role that recycled metal plays in meeting market demand.

Jan 1, 2000

By S M. Denn

The Cawse nickel-cobalt operation is situated 50 km NW of Kalgoorlie in Western Australia, at latitude30o22'30'' south and longitude 121o08'30'' east on the Kalgoorlie 1:250 000 geological map sheet (SH 51-9) (see Figure 1). The project is owned and operated by Centaur Nickel Pty Ltd (CTR) and was the first in Australia to commercially produce nickel metal and cobalt sulphide through pressure acid leach (PAL) technology. Cawse has a total resource base (all categories of resources + reserves) of 213 million tonnes Mt at 0.7 per cent Ni and 0.04 per cent Co, comprising 127 Mt at Cawse Central which is 100 per cent owned by CTR and 86 Mt at Cawse Extended where CTR has a 80 per cent equity. Cawse Extended is located immediately to the northwest of the Cawse Central leases. All current reserves (proved and probable) of 30 Mt at 1.0 per cent nickel are contained within Cawse Central. In addition the Siberia project area 20 kilometres to the NW has a resource of 63 Mt at 0.7 per cent Ni. Cawse is a dry laterite deposit, with nickel and cobalt hosted by iron and manganese oxides. Cawse Central mineralisation extends over a ten kilometre strike length, with three pits currently being mined. The Bunyip pit has the premier nickel and cobalt grades within Cawse Central. There are seven dominant lithology types forming mappable units within current pit exposures. Four of these units are host to nickel and cobalt mineralisation. Ore types are defined as Upgrade, Grind and Non-upgrade, depending on their physical characteristics with respect to the treatment route. Mining commenced in February 1998. To the end of calender 1999 the operation has produced 2100 tonnes nickel plate and 470 tonnes of cobalt as a cobalt sulphide product. Future production will target 9000 tonnes per annum Ni metal and up to 2000 tonnes per annum Co, based on processing 500 000 tonnes of ore per annum.

Jan 1, 2000

By G. R. Dunning, M. R. Wilson

"Abstract - The early Paleozoic accretionary tectonic regime that was established along the Laurentian margin of the Newfoundland Appalachians provided a favorable setting for shear-hosted gold mineralization along a major terrane suture, the Baie Verte-Brompton Line. The Stog’er Tight prospect is one of several mesothermal-style gold occurrences hosted by shear zones within accreted ophiolites and oceanic arc terranes on the Baie Verte Peninsula. It is an epigenetic, stratabound deposit that is confined to shallow-level gabbro sills within the volcanic cover sequence of the allochthonous Point Rousse ophiolite complex. Gold mineralization at Stog’er Tight is associated with hydrothermal mineral assemblages represented by chlorite-calcite, sericite-ankerite, red albitepyrite (±Au) and chlorite-magnetite alteration zones. Gold occurs with pyrite within the intensely altered gabbro, along the margins of syn- to late-shear, quartz-rich, replacement veins.The Stog’er Tight gabbro served as a rigid body conducive to shear deformation and fluid penetration, whereas, its high Fe-Ti oxide content induced fluid oxidation and gold-pyrite precipitation. Hydrothermal alteration involved progressive CO2, S, Na, and LILE metasomatism, along with significant enrichments in the REE, HFSE, and Th in the high-grade ore zone. Temperatures of vein formation and alteration are constrained by oxygen isotope thermometry to be between 250°C and 480°C. Isotopic compositions of vein quartz from the Stog’er Tight prospect are uniform (??O = +12.5 ± 1‰) and fall within the range cited for many shear-hosted, auriferous quartz veins.A U-Pb zircon igneous age of 483 +3/-2 Ma for the Stog’er Tight gabbro is consistent with its stratigraphic correlation with other Ordovician ophiolitic and volcanic arc/back-arc assemblages in Newfoundland. The U-Pb age of a rare variety of hydrothermal zircon recovered from the high-grade ore zone directly constrains the timing of gold mineralization to 420 ±5 Ma, in accord with a major orogenic episode of Silurian age that produced many of the magmatic and metamorphic rock suites in north-central Newfoundland. Our results are consistent with a post-peak metamorphic, late-magmatic model for gold mineralization that occurred during the waning stages of Silurian orogenesis, driven by emplacement of I-type granitoid intrusions into the crust."

Jan 1, 2000