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By Katsuyasu Sugawara, Takuo Sugawara, Shin-ji Abe, Tadakazu Kagami

"In order to clarify the mechanism and to obtain the fundamental data for heavy metal recovery from an incinerator ash by chlorination, pure chemical reagents, zinc oxide and lead oxide or the fly ash blended with calcium chloride and silicon dioxide were heated up to 1000°C in a nitrogen stream. Thermogravimetric curves of the samples with the chlorinating reagents indicated that solid-liquid reactions accelerated the chlorination and release of metals from the solid phase. The formation of liquid phase of calcium chloride played an important role on effective recovery of zinc and lead at lower temperatures below 800 °C. Although zinc and lead could be decreased in the incinerator ash without chlorinating reagents, addition of chlorinating· reagents enables the removal of metals in high extent· at lower temperature.IntroductionFly ash is discharged about 3,000 tons/day (about 110 million tons/year) from incinerators of municipal solid waste in Japan and mostly fly ash is disposed in landfills. Fly ash includes heavy metals e.g. zinc and lead. Since untreated fly ash caused hazardous leaching problems, Waste Disposal and Public Cleaning Law was revised in 1992, fly ash being designated 'specially controlled' general waste. Fly ash must be disposed by the following suitable, intermediate four methods: [I] Cement- Solidified Method, [2] Immobilized Chemicals Method, [3] Melting Solidified Method, [4] Acid Leaching Method, permitted by the Ministry of Health and Welfare, Japan."

Jan 1, 2000

By Brian Cochran, C. Edward Eckert

"EXECUTIVE SUMMARYINTRODUCTIONThe commercial incentives for using molten aluminum in casting operations are numerous and substantial. Although these incentives apply broadly to both shape castings (foundry) operations and wrought alloy production, the merit of a particular motive is indeed downstream processing sensitive. Melting cost reduction is a universal incentive that impacts on essentially all aluminum products. At a natural gas burner cost of $4.50 per therm, for example, the reverberatory furnace energy cost is at least $0.01 per pound of aluminum melted, exclusive of melt loss, fixed costs, and other expenses. The Aluminum Statistical Review' cited 3.188 million metric tons of secondary aluminum that was recovered by the industry in 1995. This represents a re-melt energy cost of over $70 million. Other incentives to use molten secondary aluminum include throughput enhancement, metal chemistry assurances, environmental considerations, and the avoidance of an in-house scrap processing operation.A traditional disincentive to use molten secondary aluminum is metal quality. If a particular secondary processing operation was successful in achieving and preserving an acceptable metal quality level prior to shipment, the subsequent metal transfer and ladle delivery events would frequently obviate these efforts. For example, a metal superheat on the order of several hundred degrees is required for an unheated transfer ladle to travel 3 to 4 hours to a customer location. The rate of the y-alumina formation reaction approximately doubles for every 120°F increase in temperature, therefore, the effect of excess superheat on melt loss and metal quality is considerable. Linear oxidation reactions, such as magnesia formation in magnesium containing alloys, are influenced to an even greater extent by temperature.The typical quality detractor events are:"

Jan 1, 2000

By Satyendra K. Singh

If the extraction is beneath massive roof strata, the roof tends to 'bridge' across large spans without failing, the caving behaviour is complex and irregular. Understandably, these give rise to many geotechnical problems with safety implications and involving sometime huge direct and indirect costs. Only two important problems, 'feather-edging' in pillar mining and `severe periodic weighting' in longwalling, are discussed in this paper in the background of geomechanics investigations in Australia at Blue Mountain Colliery and in South Bulga Colliery respectively. `Feather edging'- a major source of injury and fatal accidents in Australia and South Africa in such situations, refers to a phenomenon where the roof, at the goat edge, falls as a thin wafer of rock often suddenly, over-riding conventional timber breakerlines. The results of the first comprehensive, monitored trial in an Australian pillar extraction coal mine, suggests how the roof falls into feather-edging caving (generally) because of multiple shear-planes (interpreted) and how it may be alleviated. Because of complex fracturing behaviour of massive roof strata, periodic weighting at a longwall face is certain to manifest itself as 'yielding supports', heavy conditions', rapid convergence and in the worst case, as a cause of face stoppage. After briefly discussing the programme of instrumentation (in a chain-pillar and over the would-be goal) and results, this paper attempts to improve mechanistic understanding of the related geotechnical issues associated with the weighting behaviour and aims at establishing a 'threshold' value of weighting severity index (suggesting intensity of periodic weighting) with an objective to optimise operational controls before mining through potential (future) weighting areas.

Jan 1, 2000

By Paykan Safe

Computational Fluid Dynamic (CFD) modeling provides a powerful tool to assist with the design of ventilation and fume control systems in smelters and other high temperature metallurgical facilities. For this paper, this tool has been used to analyze the off-gas flow patterns exiting the mouth of a Peirce-Smith converter into a water-cooled hood and drop out box. The effects of various process and physical plant design parameters on process gas and fume capture and potential build up on the converter hoods was examined, and the optimum design and operating parameters were determined.

Jan 1, 2000

By C Katonga

Mindola mine is currently the deepest mine in the Zambian copper belt. Stoping is currently active to 1330 m below surface with long range plans indicating future production from 1590 m level. The orebody is tabular and dips between 55o to vertical. The thickness varies from 8 to 14 m. The vertical crater retreat method of mining was first introduced at Mindola mine in the late-1980s following several trials that helped define the design criteria for its application. Over the last ten years the method has been continually modified to improve safety and maximise ore production. For example, due to the weakness of some rock units within the orebody formation and the instability of the hanging wall, the last VCR slices are usually between 8 - 10 m thick, and efforts are being made to strictly apply shrinkage method in order to reduce dilution. Recent advances in mining technology in the areas of equipment, blasting techniques, rock mechanics and materials handling have been employed to increase the overall productivity of the mine. Large down-the-hole machines capable of drilling 165 mm diameter blast holes, up to 80 m long are used in stoping. Each stope produces up to 20 000 tonnes of ore per month and can last for three months. Heavy systematic ground support of VCR development has significantly enhanced safety for mining crews and equipment. Crater mining has not only improved productivity and enhanced safety, but also overcome various problems associated with conventional sublevel open stoping previously employed at the mine. This paper discusses the technical and operational aspects of vertical crater retreat mining at Mindola mine during the last ten years. The changes in mining method are often accompanied by changes in mine design, blast design, mining equipment, ground support and operating practices.

Jan 1, 2000

By Chikabumi Yamauchi, Mitsuru Tanahashi, Tsuyoshi Taniguchi, Nobuo Furuta, Toshiharu Fujisawa

"It is essential to clarify the equilibrium relations among nonmetallic inclusions of the Mn0-SiO2-CrOx system and molten stainless steel in order to control non-metallic inclusions formed by the deoxidation of stainless steel with silicon. In the present study, the phase equilibria of the MnO-SiO2-CrOx system were measured by conducting the following experiments under controlled oxygen partial pressure, Po2, at 1873 K:1) Phase equilibria of the MnO-Cr20 3 binary system were measured for Po2 = 2 x 10-6 ~2 x 102 Pa.2) Phase equilibria of the MnO-SiO2-CrOx ternary system were measured for Po2 = 2 X 10-6 Pa.Based on the results, the phase diagram of this ternary system was established under the condition of the Si-deoxidation process of stainless steel (Po2 = 2 x 10-6 Pa and T = 1873 K).IntroductionAt the deoxidation stage in steelmaking process, generally multiple deoxidizers participate in deoxidation reactions, and the composition of deoxidation products ""non-metallic inclusions"" greatly varies depending on deoxidizing efoments and their contents. In order to control non-metallic inclusions formed by the refining process of steel, it is essential to clarify the equilibrium relations among non-metallic inclusions and molten steel.Especially, during the refining process of stainless steel, nonmetallic inclusions in molten steel seem to- change as follows. After the oxidation refining, Mn-chromite is formed in molten steel as non-metallic inclusion. By the deoxidation with silicon addition (mainly less than 1 mass%), Mn-chromite inclusions are changed their compositions to Mn-silicate. Segawa et al.[l] have reported the effect of amount of silicon addition on composition and mass ratio· of non-metallic inclusions during the Sideoxidation process of 18Cr-8Ni stainless steel at 1873 K, as shown in Figuri; L At higher silicon content than 0.5 mass%, only Mn-silicate was identified as non-metallic inclusion. On the other hand, at lower silicon content, both of Mn-chromite (MnO Cr2O 3) and Mn-silicate were identified. However, the thermodynamic and the kinetic analyses of the above-mentioned Sicdeoxidation process have not been made due to lack in the thermodynamic data for the non-metallic inclusions· of the MnO-SiO2-CrOx system, such as the phase diagrams, the activities of the components, and the free energy of intermediate compounds. In relation to the phase diagram of this system, those of the MnO-SiO2 [2] and the SiO2-Cr2O 3 [3] binary systems have been only reported"

Jan 1, 2000

By Ken Mills

A program of stress change and roadway deformation monitoring was undertaken to measure the forward abutment load distribution about a retreating longwall panel at Dartbrook Mine. The results of this monitoring allow roadway conditions observed at various stages of mining to be ranked according to the estimated vertical stress they have experienced. This ranking also provides a means to predict and visualise future roadway conditions at various stages of mining. This paper presents the results of the monitoring and describes the approach developed to predict future roadway conditions. The monitoring results show the vertical stress distribution associated with the front abutment from a longwall goal decreases exponentially away from the goaf edge. The vertical stress distribution peaks at the goaf edge at 5 to 6 MPa stress increase and decreases to 1 MPa within 50 m becoming imperceptible beyond 100 m By scaling this measured distribution to reflect the loading environment, the vertical stress can be estimated for different overburden depths and different stages of mining. Photographs of roadway conditions at particular vertical stress levels provide a way to visualise roadway conditions at various stages of mining in the future

Jan 1, 2000

By Carla Lupi

NiMH sealed cells (portable cells) are today widely used in all consumer applications replacing primary alkaline batteries: wireless mobile communication, portable computers and camcorders, are the largest application segments. The Italian market. of NiMH cells is steadily growing, following the impressive penetration rate of the cellular phones. The organization of a national collecting system and correct recycling process are the key factors to prevent environmental impact associated to these wastes, while the metal values recovery can improve the feasibility of the recycling process The University of Rome, Texeco Engineering S.d, and MO.SMO.DE. S.a.s. have developed a combination of mechanical and hydrometallurgical processing to recover Nickel, and Cobalt salable products and rare earths intermediate products. A new plant located in South Italy, designed after this technology, is able to recycle waste Ni-MH batteries collected in the Italian territory, together with other industrial and portable batteries based on different chemistries. The process is able to treat both individual cells and plastic power packs and includes as basic steps an original crushing and elutriation treatment to separate plastic, metallics, and active mass components that are subsequently treated by a hydrometallurgical process to recover Ni, Co, and RE. The hydro metallurgical main steps are: acidic leaching, RE separation, multistage precipitation of Ni, Co and Fe and final solvent extraction on dissolved Ni and Co salts. For each operation the operative condition have been determined.

Jan 1, 2000

By M. Pineau, G. A. Monteith, M. Laliberte, G. Houlachi

Conventional physico-chemical treatment methods, either hydroxide or sulfide precipitation, can hardly achieve a high removal of selenium from the liquid effluents which can be generated in some metallurgical operations. In weak acid solutions, selenium exists mainly as anionic species (selenite Se03-2 and selenate SeCV2) which, therefore, cannot precipitate as metal hydroxide or metal sulfide compounds. At the same time, neither selenite nor selenate form stable precipitates with the common cations (Ca, Mg, Fe, etc.) that are typically used in water treatment. At Noranda Inc., CEZinc Division in Valleyfield, Canada, the introduction of new discharge requirements for effluent toxicity initiated a R&D program which resulted in the full-scale implementation of a new treatment method for selenium removal. The goal of this paper is to present this new method which is now being patented by CEZinc. The process chemistry will be presented along with pilot-scale developments and full-scale operational results.

Jan 1, 2000

By John Brown

Let’s talk about things that you, the driIl boss, the pit boss and the driller can do to eliminate the trend in drilling related accidents that have come to plague our industry in recent years. My paper will focus on reaI issues, problems and solutions that will affect our everyday outlook and attitudes about our jobs and lives. There are some real hard facts we must address if we are going to reverse this terrible killing trend.

Jan 1, 2000

By H. Bai, B. G. Thomas

"A three-dimensional finite difference model has been developed to study the liquid steel-argon bubble two-phase turbulent flow in continuous casting tundish nozzles. Experiments have been performed on a 0.4-scale water model to verify the computational model by comparing its prediction with velocity measurements using PIV (Particle Image Velocimetry) technology. The computational model was developed using CFX and then employed to investigate the effects of various casting process variables. A fast, simple inverse model to quantify relationships between those process variables was developed, based on interpolation of the numerical model results, using Bernoulli's Equation and advanced multivariable curve fitting methods. Predictions using this model compare well with plant measurements. The model has been applied to present trends and observations on the relationship between casting speed, tundish depth, slide gate opening, and argon gas injection rate. The results can also be used to predict .the theoretical steel flow rate through the nozzle, so that clogging conditions can be identified in the plant.IntroductionTundish nozzle geometry is one of the few variables that are both very influential on the casting process and relatively inexpensive to change. Designing an effective nozzle requires quantitative knowledge of the relationship between nozzle geometry and other process variables on the influential characteristics of the flow exiting the nozzle. This relationship depends on the flow pattern within the nozzle components. Most previous modeling studies of flow in the nozzle have focused on single-phase flow [1-4]. Argon injection into nozzle is an efficient and widely employed method to reduce nozzle clogging, even though the real working mechanism(s) are still not fully understood [5]. Argon injection may greatly affect the flow pattern in the nozzle, and subsequently in the mold. Therefore, two-phase flow modeling is needed to improve understanding of fluid flow in the nozzle."

Jan 1, 2000

By D Nicoli, P Feltoe

The operation of grinding circuits are vital to the success of most mineral processing operations in the provision of effective size reduction whilst maximising throughput. However these same circuits, and especially semi-autogenous grinding (SAG) mills, are highly interactive with product re-circulations and long time delays. This makes the optimal control of these difficult by conventional controllers, such as PID, which generally places a heavy reliance upon operations for control. In order to account for the peculiarities (such as ore type changes) and the abnormal situations that continually beset these circuits, it is necessary to adapt linear control techniques to cater for these situations. The Honeywell Hi-Spec Solutions SmartGrindTM controller is a marriage of multivariable predictive control (MPC) with techniques that provide adaptation of the control to optimise the circuit under all conditions. Optimal control is achieved by incorporating pattern recognition techniques to detect and act on discrete events (eg ore type changes) and adaptation of the MPC to account for known process and equipment non-linearities. AlcoaÆs Wagerup Refinery is the first site worldwide to have this technology applied to the SAG milling circuits and this has resulted in throughput increases in excess of two per cent and significant improvements in circuit operations. This paper describes the implementation of the control to the refineryÆs Mill 3 bauxite grinding circuit and the capacity/operational improvements achieved thereof.

Jan 1, 2000

By Robert L. Runkel, D. Kirk Nordstrom, James W. Ball

Low-flow reactive-transport processes in Wightman Fork downstream of the Summitville Mine, south-central Colorado were simulated using the OTIS and OTEQ solute-transport models. The simulation was calibrated using data from a synoptic study conducted during October, 1998. Discharge over the 8-km reach from just below the mine site to the Alamosa River confluence ranged from 0.077 to 0.17 m3/s; travel time was 10.7 hours; pH ranged from 4.6 to 5.7. Simulations revealed that mass balance for SO4 was maintained, and that pH, Fe, and Al were non-conservative. Simulations allowing hydrous ferric and aluminum oxide or hydroxysulfate precipitation matched observed water quality conditions more closely than simulations without precipitation.

Jan 1, 2000

By Ditze A., C. Scharf

Magnesium type 1 - scrap can be remelted without flux in the presence of different sulfur containing protective gases. Beside the draw back in the use of these gases, that either are contributing to the global warming potential (SF6) or are poisonous (S02), residues like dross and crucible sludge are produced. Dross and sludge now a days must be utilized. Partly these byproducts can be used in the aluminum industry and partly for desulphurisation of hot metal and steel. Another possibility is melting of dross and sludge with flux for the production of a secondary magnesium alloy. Then again residues are generated that must be processed. Therefore, the whole material cycle has to be considered to decide which kind of utilization practice is optimum. Based on experiments this question is discussed and the material balances for fluxfree melting, melting with flux and fluxfree melting plus other utilization of the residues are presented.

Jan 1, 2000

By Peter Wells, Gordon Marrs, Dominic Fragomeni, Warren Holmes, Daryl Macnamara

"LocationThe Strathcona mill ofFalconbridge Limited is located in Onaping, Ontario, 50 km northwest of Sudbury.GeneralOre from the Falconbridge mines in the Sudbury Basin (Strathcona, Fraser, Onaping, Craig and Thayer Lindsley mines) is processed through the Strathcona mill with 8500 t of nickel ore and 1500 t of copper ore being treated daily. Current capacity is -3 Mt of ore at 1.8% Ni, 1.9% Cu combined grade. Custom feeds are also processed. The valuable minerals in the ore are pentlandite (FeNi)9S8, chalcopyrite (CuFeS2) with some cubanite (CuFe2S3) and very minor nickel sulphides/ arsenides. Cobalt is present mainly in solid solution in pentlandite. There are small but economically important concentrations of precious metals including platinum, palladium gold, and silver. The common non-sulphide gangue minerals are feldspar, quartz, mica, talc, and chlorite while pyrrhotite (Fe7S8) is the major gangue sulphide. The pyrrhotite contains between 0.6% and 1.2% nickel in solid solution and additional nickel as exsolved pentlandite in micron sized blebs. The nickel and copper ores are batch-crushed in a two stage dry crushing plant and then ground in separate circuits. Concentration by flotation and magnetic separation produces a nickel concentrate assaying approximately 16% nickel plus copper and a copper concentrate assaying 30% copper and 0.4% nickel. The nickel concentrate is trucked as a slurry to the Falconbridge smelter while the copper concentrate is trucked as filter cake to the Kidd Division of Falcon bridge"

Jan 1, 2000

By Tim O’Neil

The search for precious metals opened up the American West. And Nevada was right in the heart of this development. In the mid-19th century, prospectors seeking gold roamed the hills of Nevada and discovered the ComstockLode. The development of this huge silver and gold deposit began in1859 and was responsible for Nevada’s early entry to statehood. Mining was Nevada’s first industry. In more recent years, the Nevada mining industry has led the nation in gold, silver and barite production. Nevada also produces many other minerals. These include aggregates, clays, copper, diatomite, dolomite, gypsum, lime and limestone, lithium and magnesium compounds, perlite, salt and silica. Even today, Nevada’s mining industry continues to be a major economic force in the state. The mining industry has made more than $10 billion in capital investments in Nevada since 1985. And the value of Nevada’s mineral production last year was about $2.7 billion.

Jan 1, 2000

By Douglas Bartley, Robert McClure

This paper discusses the advances in programmable, testable high accuracy electronic detonator technology. The operation and safety of electronic detonator systems are required to meet rigid safety standards and withstand the demanding environment of in-field applications. These requirements are discussed through comments on existing safety requirements in Europe.

Jan 1, 2000

By Ivan Van Herpe

"ABSTRACT NOT AVAILABLEPresentation"

Jan 1, 2000

By Derek H. C. Wilton, David T. W. Evans

"Abstract - The Midas Pond gold prospect, central Newfoundland, is hosted by sheared and altered felsic and mafic pyroclastic rocks of the Tulks Hill volcanics, Victoria Lake Group, and has been trenched and tested by 19 diamond-drill holes. Gold values are sporadic, with the best diamond-drill intersection assaying 7.3 g/t over 0.9 m, and the highest grade channel sample containing 14.7 g/t over 1.15 m. Alteration and mineralization are confined to a 200 m wide brittle-ductile shear zone. This shear zone formed in response to regional D1 deformation, and the shear zone fabric parallels the regional S1 foliation. D2 deformation resulted in broad Z-shaped flexuring of the shear zone. The deformation was probably related to the ca. 396 Ma to 420 Ma Salinic Orogeny.Advanced argillic alteration and an extensive halo of Fe-carbonate and pyrite surround the gold mineralization. Alteration minerals include pyrophyllite, paragonite, quartz, plagioclase, chlorite, fluorite, Fe-carbonate, and pyrite. As such, the alteration seems to reflect combined epithermal (argillic) and mesothermal (carbonate) mineralizing environments. The argillic alteration and fluorite represent a regional hydrothermal effect on the felsic volcanic rocks; whereas, the Fe-carbonate and pyrite represent a mesothermal alteration associated with auriferous quartz veins. The Au, which is spatially associated with pyrite, occurs in three structurally-controlled vein sets. These veins are confined to the contact between a highly deformed breccia (the banded mafic tuff) and structurally overlying, altered felsic tuffaceous rocks. The vein sets include: V1 boudinage veins that parallel the shear-zone fabric (C-shear veins), and V2 and V3 extensional fracture veins which are controlled by an S2 fracture cleavage. V1 veins are the earliest and contain the lowest concentrations of Au. V2 and V3 veins are concentrated within the hinges of the D2 flexures.Pb isotope data for galena separates indicate that the Pb in the vein systems was probably of local derivation. Sulfur, C, and O isotope data for mineral separates are similar to data for typical mesothermal lode gold deposits. Fluid inclusion data suggest the presence of at least three hydrothermal fluid types in the region, viz., (1) an early saline fluid which produced the argillic alteration, (2) a CO2-bearing fluid directly related to the auriferous mineralization, and (3) H2O-NaCl fluids which flowed through the Midas Pond shear zone at a lateral distance from the zone of mineralization. The mineralizing fluids are interpreted to have been CO3 -2-rich types which originated through metamorphic dehydration and decarbonation of mixed island-arc and continental crustal rocks. Gold precipitation resulted from the reaction of these fluids with the Fe-rich breccia unit. Pre-existing and simultaneously crystallizing pyrite served as loci for Au precipitation."

Jan 1, 2000

By Dave Otto, Ron Elliot, Ed Hatch

This paper is a summary of the work carried out by an international team of specialists in the successful explosive compaction of the sand fill core of the Molikpaq offshore oil production structure. The sand fill core is an essential element for the stability of the structure. The sand core must resist liquefaction forces caused by heavy wave action, ice loading, and earthquakes. Explosive compaction methods were used to improve the stability of 220,000 cubic meters of coarse dredged sand placed in the core area. This project was challenging for a number of reasons. It was performed offshore in Russia, seven kilometers off the East Coast of Sakhalin Island. Logistics were a challenge, not just in getting the men and materials to the site, but also working with restricted headroom inside an operating oil drilling platform. This project called for the use of specialty explosives, strict blast vibration controls requiring a complex sequential blast design, and use of custom designed drill rigs. As Russian equivalent explosives were not available, the project involved getting approval for use of North American explosives in Russia, and use of a combined Russian - Canadian blasting crew. The blasting program was carried out successfully, meeting the required densification target _in a safe, effective manner, with no damage to the structure.

Jan 1, 2000