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By O. H. Tuovinen, T. M. Bhatti

Microbiological leaching has been used as an alternative approach to conventional hydrometallurgical methods of uranium extraction. In the microbiological leaching process, iron-oxidizing bacteria oxidize pyritic phases to ferric iron and sulfuric acid, and uranium is solubilized from the ore due to sulfuric acid attack. If uranium in the ore material is in the reduced, tetravalent form (UIV), a red ox reaction is involved whereby uranium is oxidized to the hexavalent form (UvI) upon dissolution. In acid-leaching systems, the primary oxidant is ferric iron, which is reduced to ferrous iron by its chemical reaction with UIV. The ferrous iron thus formed is reoxidized to ferric iron by iron-oxidizing bacteria such as Thiobacillus ferrooxidans and Leptospirillum ferrooxidans. Nutritional requirements and responses to environmental extremes of acidophilic iron-oxidizing bacteria are appraised. The S-entity in Fe-sulfides is oxidized to sulfate by bacteria similar to Thiobacillus ferrooxidans and Thiobacillus thiooxidans. Pyrite and marcasite oxidation is a sulfuric acid forming reaction. Heap, dump and in situ leach techniques are feasible as bacterial leaching systems.

Jan 1, 2000

As the world continues to face the turmoil of the economic environment, legislative prerequisites and physical conditions the intervention of technological development is vital for the continuation of the ancient source of revenue: mining. The Palabora underground mining project is a state-of-the-art shaft mining system that will prove to be a benchmark in its field for years to come. An integration of modern technology?both in application and development?has resulted in a shaft system that is intrinsically holistic. Every aspect of the mining and production process has undergone thorough investigation, simulation and innovation to ensure that every component is selected by design and not simply conforming to past practice or trends. The process philosophy includes proven technology such as to promote the lowest operating cost and process time with the highest yield. The underground mining system is in the final stages of commissioning and will shortly be producing a nominal 30 000 tons per day with a predominantly automated system. This paper discusses the complete state-of-art shaft system developed for the Palabora underground mine, and refers particularly to the headgear, the winders, the conveyances and the shaft guide system, as well as the loading system developed specifically for the high performance requirements of the mine.

Jan 1, 2000

By Robert M. Leary

The Kennecott Utah Copper smelter operates two Outokumpu flash furnaces: a smelting furnace for production of high-grade matte and a converting furnace for production of blister copper. Flash furnaces typically possess several characteristic features that must be considered in process control development such as long lag times associated with settler volume, non-linear input and output responses, large process gains, and unmeasured disturbances. Additionally, the Kennecott smelter possesses certain unique characteristics which must be considered such as single mine concentrate source, limited concentrate blending capacity, and feed preparation facilities that inevitably cause significant lags between furnace control parameters and manipulated set points. In order to improve furnace control and on-line time, a process control system was developed to address these issues. The feed forward control module provides predictive control and operates in response to furnace feed input changes. The feed back control module provides responsive control and is based on furnace output deviations. To provide regular feed back information to the control room supervisors, new sampling methods were developed which provide the operators with molten metal and bulk material samples at regular intervals to provide information for control. The control system was implemented on the Flash Converting Furnace in May 1999 and on the Flash Smelting Furnace in August 1999.

Jan 1, 2000

By W. K. Connor, O&apos

Thermal Treatment Technology Division Albany Research Center, U.S. Dept. of Energy Oregon. This evaluation included a characterization study and direct smelting tests conducted in a bench-scale electric arc furnace (EAF). In contrast to other thermal treatment technologies considered for these wastes (i.e., fluidized bed combustion), direct smelting in the EAF can process 100% of the wastes without prior beneficiation, and utilizes solid oxidant additions (in this case iron ore) rather than air to oxidize the carbon. This solid oxidant addition is advantageous because it results in the production of several value-added furnace products. These products include cast iron resulting from the reduction of the iron oxides, baghouse dust containing virtually all of the zinc from the residues, and a clean (nonhazardous) slag product suitable for recycle as concrete aggregate or construction fill. Offgas from the smelting furnace also holds potential as fuel gas for cogeneration. The direct smelting tests conducted thus far were successful at producing the desired furnace products, exhibiting the potential for complete recycle of the waste pile. A cast iron product of comparable quality to conventional cast irons was produced, at nearly 80% iron recovery to the metal. The slag product was determined to be nonhazardous, based on the EPA TCLP. Lead and zinc partitioning to the dust product was greater than 99%. The material balance over the furnace indicates that for every ton of feed processed, 540 lb. of cast iron, 600 lb. of slag, and 150 lb. of dust would be produced. Energy consumption was roughly 1.10 kWxh/lb of feed material. Prior experience suggests that these figures measured in the bench-scale furnace would translate to 0040 to 0.50 kWxh/lb at the industrial-scale.

Jan 1, 2000

By John Drobe, Robert M. Cann

"Abstract - The Minas de Oro Cu-Au skarn and replacement deposits are located in the highlands of central Honduras, 90 km north-northwest of the capital of Tegucigalpa.The deposits formed in Cretaceous volcano-sedimentary rocks following the emplacement of an early Paleocene granodiorite to dacite intrusive complex. Three types of skarn (Type IA, IB, and IC) and a low-temperature replacement mineralization (Type II) are recognized. Type IA skarn consists of massive brown-green andradite and lesser magnetite and pyroxene. Type IB skarn has magnetite + hematite as the main constituent and garnet <50%. Type IC skarn comprises >50% pyrrhotite + chalcopyrite with interstitial garnet or pyroxene. Au and Cu occur in potentially economic concentrations in all skarn types while other metals such as Ag, Pb, Zn, and Mo are locally present in significant quantities. The highly variable distribution and nature of the skarn deposits is controlled by: (1) intrusive activity, (2) composition of host rocks, (3) faulting and fracturing, and (4) attitude of host carbonates.Type II Au-Cu-As mineralization occurs in calcareous sandstone and conglomerate 2 km distal from skarns and comprises clots of Cu sulfides hosted within a zone of brecciation and quartz flooding. Garnet and/or magnetite skarn is not present and the mineralizing event appears to have been a low-temperature replacement type.The similarity of coeval Au-Cu-Fe skarns in central Guerrero, southern Mexico to Minas de Oro skarns, and the similar local stratigraphy is consistent with the generally accepted theory that the Chortis block originated from southern Mexico and during the Tertiary moved southeast to its present position."

Jan 1, 2000

A review of the factors controlling stope wall behaviour such as excavation geometry, rockmass strength, induced stress, ground support, blast damage and drill drive layout is undertaken. In addition, the advantages and disadvantages of single lift stope geometries linked to vertical crater retreat are also analysed. Finally, key components of multiple lift stoping such as cut-off slots, production rings, stope undercuts and drawpoints are studied in detail.

Jan 1, 2000

By Herryal Z. Anwar

In recent years, many both mining and civil engineering projects are developed in the area which may be categorized unstable, such as fractured and jointed rocks or "water sensitive rocks". For example, in underground coal mining, in which the floor strata normally consist of weak shale, the problem that may arise in roadway is floor heaving. In this case cement injection in borehole appears to be an economically effective method in order to make roadway more stable. This method may be also applied in the projects in which the constructions are laid on fractured and jointed rock. Nevertheless, the successful cement injection is much dependent on the water-cement ratio and the injection technique. This paper discusses the application of cement grouting to improve the ground stability in longwall mining, the laboratory experimentation of cement grouting and the method of floor injection.

Jan 1, 2000

By T. T. Chen, J. E. Dutrizac

Noranda Inc., CEZinc presently employs a cement-stabilization (jarofix) process to stabilize its jarosite residues for direct disposal. In this process, Portland cement partly decomposes Na-jarosite to form Ca6Fe2(SC>4)3(OH)i2.nH20, ferric hydroxide and sodium sulphate which further reacts to form gypsum; approximately one-third of the Na-jarosite reacts in the current commercial product. The cured jarofix products also contain minor amounts of various Ca-Al-Fe silicate-sulphate-hydrate phases and traces of calcite. Together with gypsum and a Ca-Fe sulphate phase, these species bond the various particles together, imparting mechanical strength and reducing the permeability. Water-soluble Zn and Mg are stabilized in the Ca-Al-Fe silicate-sulphate-hydrate phases. The freshly cured products usually contain small amounts of moisture and traces of residual Portland cement, which provides additional alkalinity for the neutralization of any residual acid species. Jarofix products stored for more than six years in the laboratory, after curing, are usually dry and exhibit the same micro-textures as those of the freshly cured products. However, the stored products are depleted in the Ca6Fe2(S04)3(OH)i2.nH20 and Portland cement phases, and are enriched in gypsum and calcite which reflects the highly alkaline environment of the jarofix products. The aged products also have increased amounts of the Ca-Al-Fe silicate-sulphate-hydrate phases which have elevated Zn and Mg contents. This implies a further immobilization of residual water-soluble Zn and Mg during stora

Jan 1, 2000

By Mel Febesh

Working in New York City has become the graveyard of many Foundation Contractors. Varying subsurface conditions require Foundation Contractors to be aware of the conditions at each particular site and have the knowledge and equipment to successfully complete the project. Looking back, we can see that many of the methods and much of the equipment that were commonly used in the past have been replaced with newer methods and equipment, but sometimes the old methods prove to be the most reliable. This paper will describe examples of varying conditions and construction methods in sites that are close to each other. It will also show different construction problems that are encountered when working adjacent to existing subway structures, when excavating below the foundations of adjacent structures and when ground water is encountered.

Jan 1, 2000

By Shawn Benner, David Blowes, Carol Ptacek

A full-scale reactive barrier was installed into an aquifer impacted by acid mine drainage in August 1995 at the Nickel Rim mine site near Sudbury, Ontario. The primary mechanism of water quality improvement is bacterially mediated sulfate reduction and metal sulfide precipitation. Dramatic changes in the groundwater chemistry are observed with up to 90% decline in Fe (from >18 to <2 mmol L-1) and increases in alkalinity from <1 to >10 mmol L-1 (as CaCO3). Over a 3 year period, the rate of Fe removal declines by approximately 35%. Primary controls on barrier performance are organic carbon reactivity, groundwater temperature, and variable residence time within the barrier.

Jan 1, 2000

By O Ostrovski

Iron ore reduction and iron cementation by CH4-H2-Ar gas was investigated in a laboratory isothermal fixed bed reactor. Iron ore was first reduced to metallic iron by hydrogen, then carburised to cementite by methane. Increasing temperature and hydrogen content accelerated the reduction process. Methane had almost no effect on the reduction process. Meanwhile, higher temperatures increased the rate of cementation and also the rate of free carbon deposition. The optimal temperature for cementite formation was found to be 750¦C. At this temperature, reduction of iron ore to cementite by gas containing 55 vol per cent hydrogen, 35 vol per cent methane and 10 vol per cent argon was completed in about 15 minutes. Addition of sulphur into the reducing/carburising gas strongly retarded the process of cementite formation and free carbon deposition. Cementite is an unstable phase which decomposes to iron and carbon. The rate of cementite decomposition increased with temperature up to 600¦C and above 750¦C . In the temperature range from 600¦C to 750¦C the rate of cementite decomposition decreased with temperature. Cementite was the most stable at 750¦C and least stable at 600¦C. The two-interface grain model was used to describe the process of iron ore reduction and the volume reaction model was employed to model the iron cementation process. The simulated results for both reduction and cementation are consistent with the experimental data.

Jan 1, 2000

By W D. Ortlepp

Seismicity associated with deep block cave mining operations in hard rock can give rise to dynamic loading of the mining openings. A description is given of the source and damage mechanisms associated with such seismic events, and the possible demands placed on the rock support by the resulting dynamic loading. In addition, production level drifts are often subjected to large static deformations during mining. Appropriate support, able to sustain large static deformations, and capable of absorbing the energy released during dynamic loading, is described. The performance of these support types has been determined by means of large-scale dynamic loading tests, and large deformation static laboratory tests. Finally, a support system which is considered to be appropriate for extraction drifts in block cave layouts subjected to dynamic loading is described.

Jan 1, 2000

By Akira Yazawa, Kazuo Koike, Mitsuhisa Hino

"The vapor pressures of MS (PbS, SnS and Sb2S3) in the molten Cu2S-MS, FeS-MS pseudo-binary and Cu2S-FeS-MS ternary systems were measured by means of a transportation method in the temperature range of 1323 and 1423K to calculate MS activities in the sulfide melts. The activities of MS in these systems show negative deviation from ideal behavior except the FeS binary systems which exhibit nearly ideal behavior in the homogeneous melts. The activities of the Cu2S-FeS pseudobinary system, which is fundamentals of the copper matte, were estimated from the activity values in the ternary systems and exhibit negative deviation from ideality.The distribution behavior of tin between the ·matte and silica saturated fayalite slag was investigated under the controlled partial pressures of S02 at l 523K. It was found that, in general, tin is distributed in the both phase, while tin is concentrated to the slag phase with increasing copper content in the matte. The activity coefficient of SnO in the slag was calculated based on the distribution ratio combined with the activity coefficient in the Cu2S-FeS system.IntroductionThe thermodynamic properties related to the Cu2S-FeS system and the Cu2S-FeS-MS systems (where MS can be PbS, SnS, Sb2S3, As2S3, Bi2S3, etc.) is required to be better understanding of the copper smelting process. However, thermodynamic analysis such as the distribution of impurities among the gas, slag and matte phases is difficult due to lack of thermodynamic data. In this study, the vapor pressures of MS (PbS, SnS and Sb2S3) in the Cu2S-MS, FeS-MS. and Cu2S-FeS-MS systems were measured by a transportation method. The distribution behavior of tin between the matte and silica saturated fayalite slag was also investigated. The results in the present experiments are useful to analyze thermodynamically the behavior of component in the copper matte smelting."

Jan 1, 2000

Metal smelting is seeing a continual increase in intensity and throughput in recent years. This is done with increasing demand for cost/capital efficiency, higher recovery, and managed environmental impact, among other things. With the development of more intense smelting processes, the issues of refractory wear, mixing and separation of reacting phases and the nature of the reactions between them become more prominent. Understanding of interfacial phenomena is in growing need, in addition to knowledge of the bulk properties of equilibrium and transportation. The GKW CRC has a suite of projects aimed at developing various techniques and expertise to provide information of interfaces in metallurgical systems. This article illustrates some recent development in this area, particularly in studies of melt/refractory contacts, the determination of surface and interfacial tension of metal/slag/matte melts, modelling slag-metal mixing and studies of kinetics of the smelting reactions.

Jan 1, 2000

By H. U. R. Kattentidt, W. L. Dalmijn, T. P. R. de Jong

Sensor controlled sorting is a promising technique for the upgrading of scrap aluminium alloys. In a universal detection system of Delft University characteristic features are extracted · from the material particles by means of cameras. Examples are size, texture, edge-structure, homogeneity, and colour pattern. Additional sensors are added for higher selectivity: electromagnetic detection, light transmission, spectral reflection and more. Signal processing theory learns that a classification of particles fundamentally improves as the number of independent features increases. At the laboratories of the Delft University a test bench is available for the development of advanced multi-sensor quality control and sorting systems. It is based on a software system for detection, segmentation and classification of particles, which was especially developed for this application. Work is now in progress for high-speed detection and sorting of non-ferrous alloys, including aluminium casting and wrought alloys. A recently developed actuator design enables positive sorting into more than 3 fractions of particles that are randomly orientated on a flat conveyor belt.

Jan 1, 2000

By A. C. T. Bigg, Y. Kocak, N. K. Bodur

The Gumuskoy silver mine, owned by the Etibank, in the province of Kutahya, Turkey, has been operating since 1987 with primary, secondary and tertiary crushers, and two parallel single stage ball mill circuits. Continuing problems with crushing and feeding of the ore to the ball mills, because of the moisture retaining and sticky nature of the ore, prompted an investigation into the possibility of converting the grinding circuit to an autogenous or semiautogenous grinding circuit. This would remove the bottleneck associated with the secondary and tertiary crushing. At the same time the target feedrate is to be raised from 140 t/h to 175 t/h. This paper demonstrates the response of five ore types, and blends of ore types in an onsite pilot plant test program, and also suggests how the variations can be handled in a SAG mill/ball mill circuit incorporating just one of the present ball mills.

Jan 1, 2000

By Winfield G. Wright, Philip L. Verplanck, Philip L. Hageman, Douglas B. Yager, Dana J. Bove, M. Alisa Mast

Geological, hydrological, and geochemical information synthesized in a Geographical Information System (GIS) for water and rock surrounding South and Middle Forks of Mineral Creek, northwest of Silverton Colorado, was analyzed to distinguish between the natural and the mining-related sources of metals to dace waters in the watershed An important natural source of metals to surface water emanates from a porphyry molybdenum deposit south and upslope from the Middle Fork of Mineral Creek. Interaction of surface and ground water with fractured, altered rocks and permeable, Quatemay-age surficial deposits produces downstream water quality that does not meet current State of Colorado water quality standards for metals and pH. GIS site characterization and three-dimensional modeling distinguish surficial deposits as volumetrically substantial, significant sources of naturally occurring metals that strongly influence water quality and complicate ongoing mine-site mitigation efforts. Our findings indicate that regional hydrologic and geologic information needs to be evaluated before realistic water quality guidelines are established and mitigation recommendations are confidently implemented.

Jan 1, 2000

By T S. Giraudo

The Macraes Gold Project, operated by GRD Macraes Limited, engaged GRD Minproc Limited to assist with the evaluation of a pressure oxidation circuit, this being the key component of a recovery enhancement project. The initial study gave sufficient confidence in the process to enter into project execution. GRD Macraes Limited was the first company to license Newmont Mining Corporation&apos;s pressure oxidation technology, which aims to improve gold recovery from the carbonaceous sulfidic flotation concentrate. This paper outlines the fundamental chemistry of the process followed by a description of the plant that was ultimately installed. A summary of the commissioning is given together with an overview of the production results to date. The project ramp-up was rapid, with design temperature and throughput being achieved within days of hot commissioning. Gold recoveries have exceeded expectations, improving from around 70% prior to the installation of pressure oxidation to above 84%. The project has increased the nominal gold output at Macraes from 120,000 oz/y to 170,000 oz/y. On-going plant optimisation for process parameters is discussed, giving rise to flexibility in gold production, with key controlling parameters exceeding design.

Jan 1, 2000

By Lars Olaf Höglund

MiMi has been set up to be i) visionary, ii) strategic and iii) long-term. The planning as well as the executive phases involves industry, academia and authorities in close co-operation. MiMi focuses on improved, economically efficient management of mining waste, a challenge that requires combined and integrated research efforts across discipline boundaries. The MiMi programme is financed by the Swedish Foundation for Strategic Environmental Research (MISTRA) with support from the mining industry. The first programme phase covers the period 1997 - 2000, with intentions for additional phases. Planning, experience and results from the first programme period are highlighted. INTRODUCTION Most of the mining activities in Sweden takes place in the No

Jan 1, 2000

By Toshihide Ito, Jie Liu, Takashi Nishiyama

"Human society evolved from an agricultural to industrial and, subsequently, to a service society. As the resource requirements for each stage of this development differ, trends of metal and energy consumption are related to shifts in society. The increase pattern of supplemental energy is similar to that of mineral production throughout the world. Low positive and stable long-term increasing occurred before 1950, whereas they increased quickly after 1950, especially between 1950 and 1973. A substantial decline in· the growth of energy and mineral production began in 1973 and lasted until the early 1980s. Production of energy resources has recently begun to increase again at a high growth rate in the world. Observing the consumption trends of energy and key metals, it is clarified that increasing patterns can be thought in three stages.IntroductionHuman society evolved from an agricultural to industrial and, subsequently, to a service society. As the resource requirements for each stage of this development differ, trends of metal and energy consumption are related to shifts in society [1-3]. Humphreys [4] described that both the non-ferrous metal consumption and the construction material consumption showed a similar trend dropping markedly in the UK over the period 1960-1992. On the other hand, per GDP (Gross Domestic Product) consumption, that is, the intensity of use of construction materials has declined sharply over the past 30 years, more so than the intensity of metal use in the USA [5]. Nishiyama [6] observed that increase pattern of supplemental energy is similar to that of mineral production throughout the world."

Jan 1, 2000