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Novel flotation reagents were developed to improve the flotation of coarse particles. Laboratory tests conducted on an anthracite coal sample from Kyung-Dong Coal Company, Korea, showed that the reagents can successfully clean 2?3 mm top-size materials. Pilot-scale tests conducted on a 1.41 mm x0 coal gave substantially better results than those obtained using kerosene as collector. The pilot-scale test results were used to develop a flowsheet, in which the 1.41 mm x0 fraction is cleaned by flotation and the 4 x1.41 mm coal is cleaned by single-stage spirals. The performance of this circuit was compared with another flowsheet, in which the 0.5 mm x0coal is floated using the conventional flotation reagent, with the 4 x0.5 mm material being cleaned using two separate spiral circuits. The performance of the two flowsheets was compared by computer simulation. The results showed that the flowsheet consisting of the coarse particle flotation circuit can give substantially higher yield sat a given product grade. Keywords: coal flotation, coarse particle flotation, collector, spirals, computer simulation.

Jan 1, 2002

Over years of exploration the massive and tabular orebodies in the area to the South West of Western Areas Gold Mine had been assessed as containing about 50 million ounces of gold û a world class orebody. Planning initially was for a surface and subvertical shaft system to exploit this area but because of cost, a single lift shaft to an area which could be accessed ex Western Areas was planned to intersect the reef at 2760 metres. It was also planned to mine out the shaft pillar area long before the deep shafts would reach that position. This is not the normal practice in South African Gold Mines. The stoped out shaft pillar was backfilled to minimise movement in the shaft sites. The result of a competitive tender/adjudication process was that Cementation Mining û Skanska won and was awarded the R192 million contract to sink the Main and Ventilation Shafts on 15 June 1995. On 1 April 1999 Western Areas and Placer Dome SA formed a Joint Venture, which now owns and operates the mine on which the South Deep Shafts are situated. This situation prevails today.

Jan 1, 2002

By V Lickfold, A J. Crawford, A J. Wilson

A total of 12 alkalic porphyry centres of Late Ordovician age have been discovered in two mineral districts within NSW. The alkalic porphyry deposits are hosted within shoshonitic volcanic centres that formed where a major cross-arc basement structure (the Lachlan Transverse Zone) cut the Ordovician Macquarie Arc. The Macquarie Arc was amalgamated with the back-arc basin sediments of the Wagga Marginal Basin and with the proto-Pacific margin of Gondwanaland to form the Lachlan Fold Belt after the cessation of arc magmatism in the Late Ordovician. Within the Ordovician volcanic belts of NSW, the alkalic porphyries are the most significant mineral deposits economically. The combined resource of the Cadia district porphyries (729 Mt @ 0.79 g/t Au and 0.30 per cent Cu) makes Cadia the worldÆs seventh largest known porphyry gold system and the largest known gold resource in an alkalic porphyry system (574 t Au). Hydrothermal alteration in the alkalic porphyries comprises a complex sequence of potassic, calc-potassic, sodic, calc-sodic, propylitic and late-stage, typically fault-controlled phyllic assemblages. Hematite dusting is common in many of these alteration assemblages, giving the intrusions and the altered volcano-sedimentary host sequences a distinctive pink-orange colouration. Intensely developed hydrothermal alteration assemblages are localised to within a few hundred metres of the composite intrusions that sourced the mineralising fluids, making these deposits difficult exploration targets. Sulfides are typically zoned, with several of the deposits having bornite-rich cores, chalcopyrite-dominant annuluses and pyritic outer haloes. Gold is well correlated with bornite in most of the deposits, and with chalcopyrite at Cadia Hill.

Jan 1, 2002

By Kokichi Iizasa

Kuroko-type deposits exist in Japanese EEZ. Some of them are present in the Izu-Ogasawara oceanic island arc south of Tokyo. Major two Kuroko-type deposits occur in the area. One is the Sunrise hydrothermal field occurring on the caldera floor of Myojin knoll, which is likely to be the developed stage in sulfide mineralization. Another is present in the crater of Suiyo seamount that is the early stage of sulfide mineralization. The two deposits are here presented on the growth history based on samples recovered by Benthic Multicoring System (BMS).

Jan 1, 2002

By Dominique Vié

Standards methods covers the procedures for testing deep foundation to determine the force and velocity response to an impact of a pile driving hammer or similar device. The results of analysis generally include an assessment of pile integrity and the value of maximum dynamic stresses. But evaluation of static bearing capacity remains a matter of individual engineering judgment. A new 1D finite elements model has been developed for dynamic stresses and velocity analysis. Following an international benchmark of bearing capacity prediction organised by the Belgium Building Research Institute (BBRI), 12 piles in a site of fissured stiff tertiary clay tested in 1999, and 12 piles in a site of dense sand tested in 2001, comparison are proposed between analysis of dynamic tests and static tests results. A procedure is proposed to take in account the results of dynamic test for evaluation of bearing capacity.

Jan 1, 2002

By Frank S. Hicks, Y. Charles Guan, Glenn A. Gruber

This paper describes a two-part program funded by the Florida Institute of Phosphate Research and performed by Jacobs. The first part of the program was to examine the application of ultrasonic treatment to clean phosphate particle surfaces. Florida phosphate pebble and rougher flotation feeds were treated in an ultrasonic trough to remove clays. Also, the de-oiling of rougher concentrates by ultrasonic treatment was tested. In order to improve the clay removal efficiency, viscosities of primary cyclone overflow from six beneficiation plants were studied in the second part of the program. Viscosities for different samples at the same clay % solids vary significantly, and increase exponentially with clay % solids content for the same sample. A method of controlling cyclone operation using on-line viscosity measurements and pump box level sensors is proposed to logically improve primary cyclone performance.

Jan 1, 2002

By H. Arima, T. Fujita, W. Yen

The copper catalyzed gold oxidation and reduction mechanisms in ammonium thiosulfate solution were investigated by Eh-pH diagram based on the optimum reagent combination for 60 mass% -75 µm silicate ore at 16g/t Au with the maximum gold extraction of 92% and the minimum ammonium thiosulfate consumption of 23 kg/t-ore for 24 hour’s leaching at ambient temperature. The gold recovery by cementation was nearly 100% by Zn and Al powders at Metal/Au mass ratio of 30, and around 95% by Cu powder at Cu/Au+ mass ratio of 50. In order to oxidize the gold efficiently with the less thiosulfate consumption, the stable region of [Cu(NH3)4]2+ should be as wide as possible in the region, where [Cu(S2O3)2]3- was more stable than [Cu(NH3)2]+. In order to reduce gold from the pregnant solution with the less metal powder’s (Zn, Cu, Al) consumption, the stable region of [Cu(S2O3)2]3- should be wider than [Cu(NH3)2]+ on copper precipitation. Zinc powder may recover gold more efficiently than copper powder with the similar trend on the effect of ammonia, copper and thiosulfate. However, the large amount of copper will be co-precipitated along with gold since the stability of zinc ammine and thiosulfate complexes are higher than that of copper’s. Aluminium may reduce gold efficiently at higher thiosulfate concentration and pH. These results were confirmed and compared with the optimum reagent combination for finer grind sample at 100 mass% -75 µm, which is the optimum ore size for the standard cyanidation at 1.0 g/ l NaCN to obtain about 95% gold extraction. The optimum reagent combination was concluded as 0.5 mol/l NH4OH, 0.0001 mol/l CuSO4*5H2O and 0.05 mol/l (NH4)2S2O3 with the result of 94% gold extraction and 3kg/t-ore of ammonium thiosulfate consumption. Gold and copper stabilities were well agreed with the result of coarser grind ore thermodynamically. The lower reagent combination will reduce gold oxidation power, but significantly minimize the reagent consumption. From this pregnant solution, nearly 100% of gold was successfully recovered by zinc precipitation at Zn/Au+ mass ratio of 30. Aluminium and copper precipitations resulted in less than 40% of gold recovery at Metal/Gold mass ratio of 30. The reagent consumption cost on this lower reagent combination followed by zinc precipitation was $1.6/t-ore, while the cyanidation was $3.1/t-ore. Thiosulfate oxidation mechanism indicated the similarity to Belousov-Zhabotinsky reaction.

Jan 1, 2002

By R. Codell, D. L. Hughson

The authors benchmarked the integrated finite-volume code MULTIFLO against the analytical solution of Philip et al. (1989) for cylindrical underground openings. They found that the numerical simulation of dripping threshold flux was consistently higher than the analytical solution for rectangular and unstructured grids. The magnitude of this error was proportional to the alpha parameter characterizing capillarity. This error may bias estimates of seepage into drifts for repository performance towards nonconservatism.

Jan 1, 2002

By R. W. Schutz

"Titanium possesses an exceptional and wide-range resistance to chlorides and their compounds when compared to most corrosion-resistant engineering alloys (CRAs) used in the chemical process industry. This natural resistance to chlorides stems from titanium’s protective, tenacious, and readily rehealable titanium oxide surface film, which is chemically stable over a wide range of pH and redox potentials in aqueous environments. This passive film explains titanium’s elevated resistance to anodic pitting, crevice and stress corrosion, and erosion-corrosion in aqueous chloride environments.Guidelines for successful selection and application of industrial titanium alloys are derived from an extensive laboratory test database and more than forty years of industrial/chemical service experience. These guidelines are simplified, and alloy corrosion performance is assessed with respect to four basic aqueous chloride service categories where selection or consideration of titanium is highly merited. An overview of historical titanium alloy applications in chloride-rich environments in a wide variety of process industries substantiates their exceptional chloride tolerance. These industrial titanium alloys are cost-competitive with stainless steels and nickel alloys, readily commercially available, and routinely fabricated and welded in the shop and field via well-established methods."

Jan 1, 2002

By Graham Davey

"Ultrafine grinding of minerals has been in wide spread use in the industrial mineral field for over 30 years. Within the last 10 years the metalliferous industry has shown interest in the ability to produce ultrafine particles, as chemical, physio-chemical and physical separation processes have advanced to be able to treat ultrafine metalliferous particles. Also as the primary mineral deposits are depleted, new more difficult deposits must be mined. Existing operations are also looking to maximize economic return from existing deposits, requiring new thinking and technologies.The recent development of industrially proven and cost efficient technologies for ultrafine grinding has opened up another processing option for the treatment of finegrained metalliferous and refractory gold ores. The current commercial designs are variations of stirred mills used in the industrial minerals sector for the past 30 years. For the purposes of this paper ultrafine grinding is considered to be P80 of less than 15 microns.Attrition milling to fine grind sizes presents some challenging issues relating to scale-up including the dearth of information on the quantitative impact of feed and operating conditions, as well as the precise and accurate measurement of particle size distributions. Two examples from recent installations will be analyzed including Thalanga Copper and Century Zinc Mines. Both have diverse grind size targets for the SMD, yet both have realized significant metallurgical gains."

Jan 1, 2002

By K. Terhaar, K. Prisbrey

The objective was to determine operating protocols for a lead and silver column flotation cleaner being considered for installation at Sunshine Precious Metals Inc. 's Kellogg mill in Northern Idaho. In this column, tetrahedrite and galena were floated, and pyrite and other gangue minerals, including siderite and silica, were depressed. The procedure was to develop a dynamic simulation using a linear transfer function approach. The transfer function related cause-and-effect variables such as the influence of collector and depressant dosages on recovery and grades. Bench-scale flotation tests followed by pilot column testing provided the data used to develop a linear transfer function. The transfer function was derived using a spreadsheet. This model was applied to simulate how the flotation column could be made to respond to disturbances in feed grade. The results were that xanthate, zinc sulfate and sodium cyanide were found to be suitable controls for grade and recovery. Simulations showed the best sequence of manipulations of these reagents, and these sequences are useful for future operator training. The conclusion was that linear transfer functions were able to simulate lead and silver recovery, develop scenarios for operator training and provide a foundation for future on-line control.

Jan 1, 2002

By Y Zhuang, S La Brooy

The selection of the optimum process route for a new project has traditionally consisted of investigating existing options and ranking them in terms of cost, technical risk and environmental acceptability. With the current focus on sustainable development other factors now need to be considered. Life Cycle Assessment (LCA) of the process options can be used to extend the assessment in terms of their potential for earning renewable energy credits and in judging their ability to achieve greenhouse gas emission reductions. A rigorous life cycle assessment is demanding in terms of setting the baseline for comparisons and evaluating the elements that make up the emission profiles of the process options. However, a simplified LCA can provide a useful tool for comparing different process options. This approach can be combined with traditional assessment criteria to rank the options available to the project. GRD Minproc has been intimately involved in executing LCA calculations for different municipal waste treatment options. This paper applies a similar LCA methodology to investigate the greenhouse gas implications for different options for copper processing. The process options considered are:concentrator û sale of concentrate to smelter, concentrator û on-site mini smelter, and concentrator û leach SX/EW. The paper then goes on to consider the operating cost implications that could arise with the introduction of carbon taxes or carbon credits and how these might impact on the future choice of flowsheet.

Jan 1, 2002

By Henk Dijkman

Existing metallurgical operations can be optimized by implementing engineered bioreactor systems in the process configuration. For instance, metals can be recovered safely and economically from process and waste streams using biogenic sulfide. This paper focuses upon possible applications of high rate biotechnology in metallurgy and mining. Metal recovery from liquid streams (process bleed streams, leach water, waste streams), integrated removal of (fugitive) SO2, treatment of acid blowdown and other options will be described. Practical examples are given. A large-scale application of biotechnology at Pasminco's Budel Zink refinery is described. Here, acid plant blowdown is treated together with electrolyte magnesium bleed. Concentrated zinc sulfide (10 tpd) is produced biologically, eliminating the production of gypsum and closing the refinery sulfur cycle. Recovery of metals from solution at Kovehute Pribram in the Czech Republic is the second practical example. In this case, H2S is produced on-site for metal removal from an alkaline slag dump leachate. At the Caribou mine in New Brunswick, Canada, acid mine drainage is treated with biogenic sulfide. This plant is situated upstream of a lime neutralization plant. As a result, reusable ZnS is produced, the volume of the sludge (gypsum and hydroxides) from the lime plant is reduced by 50%, the sludge is free of heavy metals and the final effluent concentration of heavy metals is in the ppb range. In the second phase of this project, metals will be recovered from stored tailings, resulting in significant revenues.

Jan 1, 2002

By J. Wagner, P. Eger

Although lifetime estimates for sulfate reduction based on total substrate carbon typically range from 20 to 30 years, field and laboratory experiments showed that rates of sulfate reduction decreased over time as readily available organic material was consumed. When the rate of acid input exceeded the rate of sulfate reduction, alkalinity was removed from the substrate, the pH decreased and metals increased. Output pH increased from 4 to more than 6 after the system was shut down for several weeks and the rate of acid input was reduced. Successful long-term treatment requires a design based on the input pH and the long-term organic decomposition rate.

Jan 1, 2002

By J L. Mauk

The Favona low-sulfidation epithermal deposit in the Hauraki Goldfield is less than one kilometre southeast of the world-class Waihi deposit. The veins are hosted by Miocene andesite of the Waipupu Formation, have a total strike length of over 900 m, a vertical extent of at least 350 m and are on average 1-3 m wide. Individual veins have been traced for 200 m with vein widths up to 25 m. The dominant vein textures are massive, crustiform and colloform banded veins and vein breccias, with subsidiary textures including comb, zonal, flamboyant, lattice-bladed, ghost-bladed, microbotryoidal, feathery, ripple and dune, and mosaic. Quartz is the dominant gangue mineral in the veins at Favona. Accessory gangue minerals include pyrite, chlorite, adularia, illite, calcite, and apatite. Electrum is the only gold-bearing mineral and is associated with acanthite, tetrahedrite, pyrite, sphalerite, chalcopyrite, and rare galena. Whole rock geochemical analyses indicate that gold grades correlate with textures/vein types. The highest gold and silver grades are associated with vein breccias and banded veins, with the former containing 28 g/t Au and 136 g/t Ag on average. To date, veins with significant base metal sulfide minerals, and massive and crystalline quartz veins lack significant precious metals (Au and Ag), except for one banded base metal sulfide-rich vein at Favona. An overall zonation of the veins exists, with base metal sulfide minerals dominant at depth (1050 m RL) of the system are characterised by massive quartz veins.Fluid inclusions from a total of 31 quartz, amethyst, and platy calcite veins reveal homogenisation temperatures of ~190-250¦C, with final ice melting temperatures between 0.0 and -0.8. Ice melting temperatures correspond to apparent salinities of 18O value of the water that formed these veins is approximately -4.3 per mil, which is similar to meteoric water-dominated, near neutral chloride fluids in geothermal systems in the Taupo Volcanic Zone.

Jan 1, 2002

By N Davies, M J. Coward, P L. Hissey

Mount Isa Mines has four mining operations in Mt Isa with the X41 and Enterprise Mines producing copper and the Lead Mine and George Fisher producing lead zinc and silver. Each stream contributes ore to their respective concentrator at a feed rate and therefore metal ratio set out by the monthly schedule. Mine Planning and scheduling lead to a sales and operating plan (S&OP) and revenue projections which ultimately derives actual revenue /tonne and therefore cost/tonne. At Mount Isa, both the copper and lead/zinc streams produce ore from relatively new operations to be blended with material from more mature operations. It is critical to accurately predict the metal contribution from each operation in order to gauge the relative performance of each mine. Development mining ore contributions are estimated and reconciled, as are stope and bench sources. Performance is continually measured and assessed during extraction and grade adjustments are made to account for underbreak, overbreak and design modifications. It is critical to not understate or overstate the contribution from one operation relative to the other as this can produce a false picture of operational performance. Identifying process improvements are key to improving the business overall. Ore from the lead stream passes 17 measurement stations and two midstream reconciliation points before delivery to the heavy media plant (HMP), where the metallurgical circuit begins. From this point two concentrates are produced. A zinc concentrate for treatment off site and a lead concentrate for further on site processing. The lead smelter takes 100 per cent of Isa concentrates as well as a contribution from BHP-BillitonÆs Cannington Mine.

Jan 1, 2002

By D. D. Tannant

An experimental and numerical study was conducted on the geomechanical behaviour of oil sands during penetration tests in which a steel wedge with an apex angle of either 20 degrees or 30 degrees was forced into compacted oil sands. The boundary conditions simulated in the laboratory tests are similar to shovel penetration into oil sands. The objective of the laboratory tests was to measure the force required to push a steel wedge into compacted oil sands. A wedge penetration test differs from conventional triaxial tests in that much more shear is generated. The laboratory data was needed to improve calibration of micro-mechanical input parameters for a two-dimensional discrete element model of oil sands constructed with Particle Flow Code (PFC). Initial model calibration was performed with triaxial test data and then a PFC model of the wedge penetration test was constructed. The measured force-displacement behaviour of the steel wedge was compared with PFC modelling results. It was found that different combinations of PFC particle and bond parameters could equally well replicate the laboratory triaxial compression data for bitumen-rich oil sands. When the wedge model was run, it was found that the resulting force required to penetrate the wedge into the oil sands was about four to six times higher than that measured. This clearly indicates that further research is required to improve the predictive capability of PFC models of oil sands.

Jan 1, 2002

By M Nombe

Based on the analysis of a case study at POWELTON No.2 MINE, it was determined that mine stability problems had occurred due to floor softening. A fireclay (underclay) layer in the immediate floor was softening after coal extraction and failing under pillars load. The thickness of soft floor was considered as the governing factor in the determination of the magnitude of floor displacement. The effect of floor thickness on floor displacement was evaluated by creating seven models that were input into the LAMODEL program. The properties of the soft floor were determined from a bearing capacity test performed in the Mains close to the area where mine stability problems had occurred. Moisture increase was considered in the reduction of floor bearing strength. Various strain-softening properties were allocated to the materials representing the soft floor. The LOW GAP POWELTON No.2 MINE was modeled and LAMODEL program was used to determine stress and convergence on both the coal seam and the fireclay seam. The results of critical stress and convergence obtained from modeling were compared with the actual floor failure area in the mine.

Jan 1, 2002

By J. P. Constantinea

The use of fluidized beds for the roasting of zinc sulphide concentrates marked a milestone in the electrolytic production of zinc. Stable operation of a fluidized bed for zinc roasting requires a particle size distribution that minimizes the risk of defluidization and helps control carryover to manageable levels. However, the understanding of the roasting process is limited, and changes in operating conditions mainly rely on intuition, experience, and trial and error. A research program has been initiated at UBC to study the phenomena that influence the particle size distribution of fluidized bed zinc roasters. In preparation for the experimental phase, this paper reviews the current literature on the phenomena that affect the particle size distribution during fluidized bed roasting and other fluidized bed processes.

Jan 1, 2002

By S. A. Osterberg, J. L. Breckenridge, R. S. Popielak

Multidisciplinary investigations were completed to prove the availability of water resources for the proposed San Cristóbal silver-lead-zinc mine in the arid Altiplano of Bolivia. Surface water resources are scarce, of poor quality, and unsuitable for development. Therefore, hydrogeological reconnaissance targeted alluvial aquifers for development. Follow-up resistivity, refraction, and water quality assessments were used to prioritize areas with prolific production potential. Pumping tests and regional water balance analysis indicate an alluvial aquifer can sustain the required approximately 40 000 m3 per day production for the life of the mine and predict no significant negative environmental effects on local groundwater users and the environment.

Jan 1, 2002