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By Hassan El-Shall, M. N. Ahmad, Ponisseril Somasundaran, C. R. Holland, G. M. Walker, N. Iles, R. D. Chandler, Regis Stana, B. Duddy, Patrick Zhang

Phosphoric acid is a major raw material for the production of ammonium phosphate (AP) that is used as an intermediate in fertilizer production. Impurities within commercial grade wet process phosphoric acid are important in producing a fertilizer granule with good handling properties. The impurities identified as being important are; iron (III), aluminium and fluorine-containing compounds. Results show that the viscosity of the AP slurry produced increases by increasing the amount of impurity in the acid. Bench scale tests have been successfully replicated on a plant scale leading to a better understanding of the composition of impurity levels within phosphoric acid required to produce a high quality, free flowing, hard, spherical and non-caking granular fertilizer.

Jan 1, 2002

By D. W. Partridge, W. Lamb, A. E. Lamb, S. Bird

Due to the constant need to improve SAG mill performance and efficiency, extensive research into all aspects of SAG mill optimization has been performed. This paper will review the current evolution of SAG mill shell liner design and their performance at the Copperton Concentrator. The effect of these liner design changes will be discussed with respect to: • Liner configurations • Mill operating performance, i.e., throughput, power draw, mill control • Mill mechanical performance, i.e., liner wear profiles, liner life, liner breakage, liner hardness • Foundry manufacturing considerations • Economic evaluation of throughput versus liner life This paper will discuss the results of Kennecott Utah Copper’s (KUC) and ME International’s (MEI) test work, providing an insight into the past, present and potential future opportunities of SAG mill liner design.

Jan 1, 2002

The Ladolam gold deposit, located on Lihir Island in PNG, is one of the largest known epithermal gold deposits, with a resource of over 37 million ounces. The deposit is characterised by a telescoped porphyry-epithermal system 2-rich sulphidic hydrothermal fluids capable of transporting significant quantities of gold, and the sudden change from porphyry to pithermal conditions caused by removal of the volcanic edifice. As magmatic ore fluids breached the surface, cool surface waters (seawater and/or meteoric) acted as a diluent. Although no other deposit is known with comparable geological characteristics and size, positive features that may be looked for in exploration for other like-deposits elsewhere include magnetite-rich alkalic volcanic rocks, large carbonate haloes, and presence of phreatomagmatic breccias. New discoveries may be recessive or undercover, due to the quartz-poor nature of the alteration.

Jan 1, 2002

By R. J. Sweigard, G. T. Lineberry, B. K. Slone, F. A. James III, D. S. Maggard

The depth at which it becomes more economical to use slope access instead of box-cut access for nearsurface coal reserves is termed the "transition depth." The transition depth can be established for a given coal property by considering cost estimates for those parameters that determine respective access methods. Fourteen parameters that influence access cost were identified, and ranges for these parameters were determined. A transitiondepth formula was developed to permit the determination of which is the better method of accessing a reserve, given information such as high wall slope, road width, total bench width, pit dimensions, road grade, belt component costs, pumping costs and the cost of overburden removal and reclamation. In most cases in Appalachia, especially in eastern Kentucky, the observed transition depth ranges from 20 to 30 m (66 to l00 ft). This indicates that actual practice is consistent with the analytical approach used.

Jan 1, 2002

By J. K. Horbaczewski

The reclamation of an open dragline pit (Pond A3P-2) at the Gibbons Creek lignite mine in east-central Texas required neutralization of acid mine pit water. At the start of treatment with hydrated lime (Ca(OH)2) on March 28, 2000, the pond had partially filled with 913,000 m3 (740 acre ft) of pH 4.9 water. Another 666,600 m3 (540 acre ft) of pH 3.3 water was pumped in from an adjacent pit (PitA3P- 1). By the end of the project (July 5, 2000), a combined volume of 1,579,000m3(1,280ac-ft or 417milliongal) in PondA3P-2 had been successfully treated to pH 8.2 with 431 t (475 st) of lime. This was two to three times more neutralizer than laboratory trials and detailed chemical titration had predicted. The main reasons for the difference are thought to be the inadequate representation in a laboratory setting of some of the chemical reactions that occurred in the field, including incomplete mixing of reactants, reactions with clay minerals in the pit walls, the kinetics of biologically-mediated reactions and the kinetics of aluminum oxyhydroxide polymerization (aging).

Jan 1, 2002

By Jacob Masliyah, Zhiang Zhou, Tshitende Kasongo, Jianjun Liu, Zhenghe Xu, Jeawon Choung

"Slime coating is a recognized challenge in fine particle flotation, not only in decreasing recovery, but also in reducing the selectivity and hence froth quality. In this presentation, a novel method based on electrophoretic mobility distribution measurement to study slime coatings is described. By measuring electrophoretic mobility distribution of individual minerals and their mixtures, the interactions between these minerals can be evaluated.For illustrative purposes, a model system of fine coals, or oil sands with two different types of fine clays was studied. Flotation tests showed a significant decrease in coal (bitumen) flotation recovery with montmorillonite but not with kaolinite clay addition. When electrophoretic mobility distribution of a fine coal/montmorillonite clay mixture was measured, a single modal zeta potential distribution was obtained, in contrast to a bimodal distribution for fine coalkaolinite clay mixture. This finding suggests a stronger adhesion of montmorillonite than kaolinite clays on fine coal surfaces. In the case of bitumen, the bimodal zeta potential distribution was measured for the mixture of bitumen emulsion and kaolinite or montmorillonite, indicating a weak attraction of the clays by bitumen. In the presence of calcium, however, a single modal zeta potential distribution was obtained in the mixture of bitumen emulsion with montmorillonite but not kaolinite clays. These findings are in excellent agreement with bitumen flotation results, demonstrating that the electrophoretic distribution measurement is a powerful tool to study slime coating phenomenon in a complex fine particle flotation system."

Jan 1, 2002

Market forces, particularly iron ore prices, demand that plant operators achieve higher throughput in the worldÆs iron ore beneficiation plants without compromising yields or efficiency. This means that production cost per ton is of paramount importance and that all major pieces of Processing Equipment have come under close scrutiny to improve throughput at their most efficient performance levels and for the longest possible continuous running time. Without doubt the use of modern engineering standards and materials of construction has contributed to matching these throughput, efficiency and availability demands. However, often not enough attention is paid to the so called æinsignificant elementsÆ connecting this metallurgical equipment, such as chutes, pipes or other conveying systems, and particularly to the sufficient protection of their wearing surfaces. The result can be an unplanned and expensive outage caused by the wear related failure of such components. This paper will discuss:the theory of wear and the multiple factors of material and design that contribute to a reduction in wear; and the combinations of modern wear resistant materials available to todayÆs engineer and how, by intelligent selection and correct application, plant availability can be optimised. Examples outlining how these principles have been applied in South Africa showing some improvements leading to increased plant availability.

Jan 1, 2002

By Zenjiro Asaki

The copper concentrate particles dissolve quickly into the molten matte in the smelting furnace of Mitsubishi Process, which indicates that the sulfide smelting is essentially a gas/liquid reaction. In this paper, theoretical calculation has been made on the rate of oxidation of FeS component in the matte to form FeO by rising gas bubbles using the penetration theory. The results showed that all the oxygen in the bubble of 1.2 cm in diameter, which is the maximum stable diameter, is consumed in 3 ms. This time required is sufficiently short, and it results in the actual operation of smelting furnace of 1100% oxygen-efficiency. These calculations indicate that most smelting reactions are completed just under the lance, except slag formation.

Jan 1, 2002

By Edward McHugh

While less than 1% of reported accidents are associated with slope stability problems. slope failures were responsible for about 15% of all U.S. surface mine fatalities between 1995 and 2001. Small rockfalls, which may involve hand-sized rocks weighing only a few kilograms, can cause fatal injuries to workers away from the protection of large machinery. Massive highwall failures containing a million cubic meters of material or more can be fatal even for heavy equipment operators. As part of an ongoing study at the Spokane Research Laboratory of the National Institute for Occupational Safety and Health, several remote-sensing technol¬ogies are being evaluated as tools to monitor slopes for hazards and to assess slope stability. Field tests of a hyperspectral imager were conducted to assess its value for improving geologic maps of poten¬tially unstable alteration zones on mine slopes. An interferometric radar device capable of detecting very small displacements on slopes awaits final assembly and field testing. Computerized moni¬toring methods using images from digital and video cameras are being assessed for application to mine slope surveillance. These and other techniques will eventually provide new tools to augment current methods for monitoring ground control hazards in mines.

Jan 1, 2002

By J. D. Lowell, L. Quevedo

I will talk today about a porphyry copper exploration program now underway in the Amazon jungle in the southeastern part of Ecuador near the border with Peru. The project is unusual for two reasons: first the deposits are of Jurassic age, 153 m.y.o., which is unusually old for porphyry copper deposits and they may be the most significant pre-Tertiary age porphyry deposits known. Second, the district was found only six years ago which makes this the most recent discovery of a totally new porphyry copper district. The new porphyry district, known as the Zamora River Copper Belt, or the Corriente Copper Belt, is a north trending area 50 km long by 10-15 km wide, which is nearly aligned with the axis of the Jurassic age Zamora batholith and with the course of the Zamora river. Gencor in 1994 initiated a regional grassroots gold exploration program based on reconnaissance geologic mapping and geochem sampling which did not find a gold mine, but which identified the San Carlos porphyry copper system in April, 1995. In a later reorganization between Gencore and Billiton the Ecuador project was transferred to Billiton and between the Gencore work and Billiton’s a total of 10 porphyry copper systems were found over the next four years. In the period of 1997 - 1999 Billiton drilled a total of 11,000 meters of wide spaced core holes in the San Carlos, Panantza and Kutukus prospects. In October 1999 Billiton concluded a farm-out, joint venture agreement with Corriente Resources and Lowell Mineral Exploration for additional exploration of the Zamora property. This is funded by Corriente and managed by Lowell Mineral Exploration and a total of 28,000 m of core drilling was completed through August 2001. An immediate result of the Corriente Lowell project was the discovery of potentially commercial ore reserves in two new deposits at Mirador and Warintza. Additional closer spaced drilling was done in the Panantza deposit and additional drilling is planned at San Carlos, in targets related to Warintza, and elsewhere.

Jan 1, 2002

By Y. Q. Zhang, Y. Luo, S. S. Peng

Burrier pillars in underground coal mines could eventually be subjected to a water head due to the build-up of mine water in the old workings. The water head could not only act ns a force to destabilize the pillar, but it could also cause seepage flow through the pillar and its surrounding strata. Excessive seepage flow could induce piping failure that, ill turn, could accelerate the mechanical failure process of the barrier pillars. In this paper, a finite element simulation approach was employed in the evaluation of the barrier pillars. Both the stress distribution and the seepage flow pattern in and around a barrier pillar have been simulated numerically. The effects of ground stress on rock permeability to water seepage has been taken into consideration in these simulations,

Jan 1, 2002

By B. K. Baird, P. C. Satchwell

The application of cutoffs during and after pit optimization is examined for a lower-grade multimetallic copper deposit. Pit optimization requires calculation of the net revenue associated with each mining block. The calculation incorporates parameters such as metal prices, grades and expected recoveries, mining and processing costs, smelting and refining charges, and penalty element and royalty charges. Sensitivity analysis during pit optimization reveals which parameters have significant effects on the total contained resource tonnage and total contained nondiscounted revenue in the optimized pit. The cumulative effects of changing several of the more-significant parameters are investigated The application of a copper cutoff grade to a block inside the optimized pit could result in the less-than-optimal extraction of the resource. A block with a copper grade below the applied cutoff could be economic due to the presence of other metals. Conversely, a higher-copper-grade block may be subeconomic. Also discussed are the merits of applying a copper-grade cutoff, an "equivalent-grade" cutoff and a dollar-per-ton cutoff to blocks inside the optimum nit.

Jan 1, 2002

By K. Morsy, S. S. Peng

This paper deals with the causes and mechanisms of a massive pillar failure in a room-and-pillar mine. The mine employed a nine-entry panel system using supersection technique under a cover ranging from 91 to 168 m (300 to 550 ft). Chain pillar squeeze and large roof-to-floor convergence were first observed at the belt transfer point on the very inby side of the main entries. It propagated out by quickly, and, within 24 hours, it had covered an area approximately 1,250-m- (4,100 ft-) long by 762-m- (2,500-ft-) wide. The failure was caught and stopped by a solid barrier pillar. Using computer modeling, this study indicates that the massive failure was initiated because of a combination of undersized chain pillars in some panels and weak immediate floor. Also, the study shows that the massive pillar failure expanded to a large area because of the absence of barrier pillars between some panels and between mains and panels. Based on computer modeling, alternative mine plans were proposed to avoid such problems.

Jan 1, 2002

By T. J. Toy

The topography reconstructed following land disturbance is the foundation for all other reclamation practices. As the manufactured drainage basins, hillslopes, and stream channels approach a steady-state condition, the amount of adjustment of these landforms by geomorphic processes following reclamation decreases. As the adjustment required to establish a steady-state condition decreases, the prospect of reclamation success increases while the prospect of site maintenance decreases. Careful topographic reconstruction is a good investment.

Jan 1, 2002

By J. A. Organiscak

Data on dust-control practices, mining conditions and occupational exposures were gathered for approximately 80 underground continuous mining units. Despite silica contents on dust samples in excess of 5%, nearly forty units successfully maintained silica concentrations at or below 100 µg/m3 on a majority of occupational dust samples, while the remainder had difficulty maintaining this level. These two sample sets were termed Group A operations and Group B operations, respectively. This data was compared to identify causes of high occupational silica dust exposures. Analyses of dust-control parameters and geologies revealed only minor differences between these two groups. However, subsequent comparisons of face ventilation design showed considerable differences in silica exposure and silica content between Group A and Group B at the continuous mining machine and roof bolter operator occupations. These differences were minimal when using exhaust curtain ventilation with a dust scrubber. This face ventilation system can benefit operations having difficulty controlling silica dust exposure and silica dust content. The collected data also showed that occupational samples from Group B operations possessed generally higher silica exposures and silica content than similar samples from Group A. The single head roof bolter (helper) possessed among the highest silica exposures and silica contents in both groups.

Jan 1, 2002

By Glenn Kosick, Roger Amelunxen, Glenn Dobby

"The variability in flotation response within an orebody is often a significant problem to address during the design phase of a flotation circuit. In addition, for existing operating plants, the reasons for such a variability need to be clearly understood and accounted for if plant performance is to be optimized. MinnovEX Technologies, in collaboration with major mining companies, is developing methodologies and tools to address the issue of variability in ore characteristics (such as ore hardness and flotation response). The tool is used for design and scale-up of flotation circuits from lab flotation data, and for prediction of recovery and final concentrate grades throughout the mine block model for any given circuit design.INTRODUCTIOTNH: EI SSUEB EINGA DDRESSEDThis paper describes the current development of a methodology and software tool for improved flotation plant design and enhanced prediction of froth flotation performance in an operating plant. The need for this tool is attributed to two primary factors: variability of flotation response properties throughout an orebody and related difficulties with scaleup from laboratory tests. Consider these in more detail.It is well recognized that separation performance via froth flotation will vary significantly within a single mineral deposit. This has been enhanced through the wide application of SAG milling. Throughput with SAG mills is more susceptible to ore hardness changes than is the case with crushing-rod-ball circuits; it is not uncommon to see SAG mill throughput to vary by up to 100% on a regular basis, e.g. 1000 tph to 2000 tph.The implication of this on laboratory testing for prediction of metallurgical performance is as follows: it is unlikely that either the plant grind (size distribution) feeding froth flotation or the flotation residence time will be known at the time of laboratory testing for a given block of ore. Hence, the grind used for the laboratory test is not likely to be that which actually occurs once the ore is processed, and the laboratory retention time may not represent the plant conditions."

Jan 1, 2002

By D Brennan, S Jahanshahi, F Jorgensen

The recycling of metals can be very efficient with careful selection of the material being recycled. The volume and value of recycled ferrous scrap has lead to the development of steel mini-mills which in turn has caused major changes to the steel industry. Although much smaller in volume, the recycling of lead is very significant, with battery recycling accounting for 60 per cent of annual world production. This high recycle rate can be attributed to the relatively uniform feed-stock from lead-acid batteries. The recycling rates of other metals are considerably lower due to longer use and non-uniform product usage that results in less efficient segregation and processing. It is clear that recycling of metals has advantages but its sustainability is uncertain. What are the key benefits of metal recycling? Metal recycling has technical, economic and social impacts. It is relatively easy to assess recycling on a technical basis, but the social impacts are harder to evaluate. This paper examines some of the issues in evaluating the sustainability of metal recycling.

Jan 1, 2002

By Ryszard Prajsnar

During copper production in shaft and flash smelting processes at KGHM Polska Miedz S.A., lead bearing material of sulfide, sulfate, and oxide character is generated in forms such as slime from shaft furnace gas handling systems, converter dusts, and dusts from an electric furnace for copper removal from flash smelting slag. These materials are polymetallic concentrates of Pb, Zn, and Cu, with As, Cl, and Cd as impurities. Shaft furnace slime, containing. about 50% PbS and 15% bituminous substances, is the main lead-bearing material. At the Glogów copper mill, a new plant was commissioned in June 2001 to process 80,000 tonnes per year of lead bearing materials to produce 26,000 tonnes per year of crude lead. The plant consists of a feed conditioning system, three (3) rotary rocking furnaces with a capacity of sixteen (16) tonnes of lead feed fired with natural gas and oxygen-enriched air containing up to 45 vol% O2, and a gas handling system. The gas handling system includes a post-combustion chamber, a gas cooling chamber with Cl neutralization, gas mixing chamber, bag filter, and dry limestone scrubbing system for SO2 removal. The lead-bearing feed is smelted with five (5) wt% Na2CO3 and thirteen (13) wt% iron scrap at a temperature of 950 to 1050°C for three (3) hours. The smelting process consists of four (4) stages; feed drying, firing of gaseous hydrocarbons and solid coal from the feed, lead reduction from slag, and separation of molten products. The flow rates of natural gas and oxygen to the burners are controlled to ensure combustion of the bituminous material in the furnace. The process produces crude lead bullion containing (wt%) 0.1 to 0.5% Cu, 0.02 to 0.5% As, 0.05 to 0.07% Bi, 0.1 to 0.5% Sb, and 0.1 to 0.6%Sn. The process also produces a mixture of sodium silicate slag, Fe-Zn-Pb-Cu-S matte, and Fe-As speiss containing (wt%) 5 to 10% Pb, 2 to 6% Cu, 10 to 15% Zn, 1 to 3% As, 10 to 15% S, 0.5 to 3.0% Cl, 2 to 4% K, 4 to 7% Na, 20 to 30% Fe, and 5 to 10% SiO2. The dust is made up of PbO, ZnO, PbSO4, and PbCI2, KCI, and NaCI with a chemical composition (wt%) of 35 to 50% Pb, 5 to 15% Zn, 3 to 6% As, 4 to 8% Cl, 2 to 5% K, and 2 to 5% Na. The construction of the new lead production plant at the Glogów copper mill will process both current lead-bearing materials as well as lead-bearing material that have been stockpiled over the last fifteen (15) years to give a significant improvement in protection of the natural environment.

Jan 1, 2002

By H. Hamza

Oil sand tailings are disposed of in large ponds in which MFT (Mature Fine Tailings, a stable suspension of fine particles in water) forms after many years of settling. Long-term storage of large volumes of MFT is costly to maintain and also poses an environmental liability. The Advanced Separation Technologies laboratory at CANMET Western Research Centre has worked closely with oil sand companies to eliminate MFT generation by applying paste technology to oil sand tailings. In this process the fine tailings are flocculated to produce a thickened material that has the potential to consolidate to a dry landscape, while warm water is recovered and recycled for reuse in the extraction process. This paper presents some results of an extensive technical program involving bench-scale tests for flocculant selection and continuous thickener pilot tests.

Jan 1, 2002

By Steve Kral

For an industry that provides more than half of the nation’s energy needs, the U.S. coal industry still attracts negative publicity. However, the nation’s energy appetite continues to increase. And political leaders and the public are beginning to understand that alternative fuels will not be enough to keep up with that appetite. Does that mean the nation will now embrace the coal industry? No, according to speakers at the Rocky Mountain Coal Mining Institute (RMCMI) meeting. The industry still needs to sell the public on coal’s advantages over other fuels. And the industry must continue to develop technology that will allow coal to meet and exceed strict clean air and clean water regulations.

Jan 1, 2002