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By J. C. Purcupile

In this time of increased coal demand, a faster and safer method for roof support is needed. This report outlines the preparation and testing of a machine which we feel will help answer this need. The results of the tests are encouraging, and indicate that further exploration of the method should be continued.

Jan 1, 1975

By J. C. Purcupile, R. L. Morris

Present methods of roof support require that first a hole must be drilled, and then a toggle belt or grouted resin bolt be set. Automating this system is very difficult. Therefore, we decided to develop a system which would insert pins into the roof in one step. We think that this type of system can be automated much easier. It would then speed up the roof bolting operation and eliminate the need for a man to work under unsupported roof, making roof bolting a much safer job. There are two ways that a pin can be inserted in a mine roof without drilling a hole. It can either be pushed in, using a very high, constant axial force; or it can be hammered in like a nail. The former method involves very high compressive stresses in the pin, and requires complicated machinery to prevent buckling. Since hammering the pin does not require high axial forces buckling is not as likely. Also, experiments have shown that there are no problems associated with getting the pin to go in straight. We chose to develop the second method. While investigating methods for hammering a pin into a mine roof, we learned that piles were being driven 10 times faster than by conventional methods with a method called "orboresonance." We decided to turn the pile driver upside down, and drive pins up into the mine roof. Sonic Pin Setting Machine The machine consists of a steel bar supported at the nodal points of its first mode of transverse vibration (Fig. 1). A mechanical oscillator, driven by a hydraulic motor, is attached to one end of the bar. This provides the forcing function for the vibrations in the bar. The hydraulic power is supplied by a portable unit. When the forcing function is near the natural frequency of the bar, large amplitudes of vibration occur and require little power input. An anvil is attached to the bar at a point of maximum deflection, providing a means for striking the pin. Since the bar is being driven near its natural frequency, it takes little energy to accelerate the bar back and forth between each hit. This means that most of the power being put into the bar is going into driving the pin. This is unlike conventional pile drivers which use most of their power to accelerate the hammer back and forth between hits. The resonant frequency of the bar we used is about 250 Hz, which is in the audible range, hence the term "sonic pin setting machine." The system benefits are: (1) elimination of the two-step drilling and pin-setting roof bolt operation, (2) increased speed, (3) more intimate contact between the formation and bolts, (4) less expensive roof bolts, (5) higher integrity, (6) potential for automatic operation. Modifications During the months from Oct. to Dec. 12, 1974, under U.S. Bureau of Mines grant No. 00144104, "Projects on Coal Extraction," six members of the senior class at Carnegie Mellon University designed and built the experimental machine. They drove three pins into the Safety Research coal mine at Bruceton, Pa., and determined that the project was worth continuing. In January 1975 we began making modifications and repairs in preparation for a more extensive program of testing at Bruceton. The major items were: 1) Design and build a collapsible pin guide to keep the pin parallel with the line of travel of the lift table. 2) Move the anvil to the center of the bar. 3) Refinish the nodal holes and install new node pins and bushings. 4) Realign the bar in its frame. 5) Install a relief valve on the lift unit to control the upward force. The upward force that we exert on the pin is relatively small, so there is no tendency for it to buckle. This means that all we need to do is hold the pin straight during its initial penetration. This allows the bushing to travel up and down in a straight line. At the beginning of penetration, the bushing

Jan 1, 1977

By Wantae Kim

Ultrasonic stimulation of constituent suspension (metakaolinite/NaOH) can improve the rate of synthesizing reaction for zeolite Na-A. Zeolite Na-A can be synthesized from the suspension by sonicating treatment at comparatively shorter exposing time than conventional heating treatment. The main effect of ultrasound for the production of zeolite Na-A in the present heterogeneous solid/liquid reaction is intense stirring the solid and liquid substances to produce relatively narrow-sized zeolite Na-A particles with higher CEC value.

Jan 1, 2006

By Árpád B. Palotás, Adel F. Sarofim, John B. Vander Sande, Lenore Rainey Christian, J. Feldermann

"Interest in the fine structure of soots and carbon blacks is motivated by a variety of possible applications. The structure provides information on the origins of the particles and on their adsorptive and reactive properties. This paper describes a method for quantification of the structure of soots and carbon blacks based on direct electron microscopic observation followed by image analysis of these materials. High-resolution transmission electron microscopy (HRTEM) provides a very detailed observation of particle structure. The differences in soot structure, because of its complexity, may not be easily quantifiable with the human eye; therefore, high-level computer software has been used to manipulate HRTEM images. This technique involves the application of fast Fourier transforms (FFT) to single particles and the measurement of characteristic parameters such as interplanar spacings and crystallite sizes from these particles. The methodology and application of this characterization technique are presented here. Results are shown for dif¬ferent samples obtained from soot and carbon black particles selected to illustrate the capabilities of the methodology. Quantitative information can be obtained on structural characteristics, e.g., interplanar spacing, circularity, orientation, elongation, and length distribution of lattice fringes, as well as on the fractional coverage of the extracted pattern. c 1996 Wiley-Liss, Inc.This paper presents a combination of techniques for recognizing and classifying different carbonaceous materials, using their structural morphology. A new method to assess and quantify the parameters which define such structures is proposed and discussed. The technique is based on the use of HRTEM (high-resolution transmission electron microscopy) and computational image analysis.It is well-known that carbonaceous materials like graphite, soots, coals, cokes, chars, etc. possess characteristic structural appearances which can vary from mostly random or amorphous to a perfectly ordered graphitic crystalline structure (Buseck and Bo-Jun, 1985; Buseck et al., 1987). The carbon structure has been variously described as turbostratic (Oberlin, 1989) or as crumpled sheets (Rouzaud et al., 1991) to indicate that parallel layering, reminiscent of graphite, is observed over dimensions of nanometers, but that these planes or crystallites show disorder over larger scales. The degree of order of such structures is strongly dependent on the thermal treatment of the material as well as on the composition of the source of the carbonaceous material. The value of the electron microscope in studying the morphology of such materials has been well-established, and abundant information is available (Ishiguro et al., 1991; Lahaye and Prado, 1978; Buseck, 1992).The use of HRTEM has brought further insight into this matter. Qualitative assessment of the structural order of such materials has been attempted over a long period of time in order to differentiate between various sources or treatments. There is, to date, no successful method available for quantifying the structural characteristics of various carbonaceous materials. This paper presents a technique which is able to recognize dif-ferent materials and to quantify the structural parameters of those materials using HRTEM and computational image analysis, including pattern recognition techniques.In the case of perfectly ordered graphitic crystals, electron diffraction is widely used for obtaining details on structure. Analysis of diffraction patterns can reveal parameters such as interplanar spacing, d002, crystallite size along the c-axis, Lc, crystal size in the plane of the layers, L., mean number of crystallites, Nc, etc.Complicated electron microscopy methods such as defocusing, tilted illumination, axial illumination, etc., often have to be used in order to characterize complex materials such as randomly oriented crystals in soots and carbons. Obtaining the right fo"

Jan 1, 1998

By Maarten van de Vijfeijken, Marco Rufli

"By using the latest generation of medium voltage frequency converters, new possibilities have arisen to improve the grinding process. Beside all the direct and indirect advantages, several dedicated functions have now been implemented for ring geared grinding mills in the minerals industry. The advanced operational functions ensure a smooth, safe and reliable operation with minimum stress for the mechanical equipment and therefore highest availability of the mill. Several papers have already been presented concerning the benefits of using this state of the art technology for mill drives (Ravani von Ow and Bomvisinho, 2010; Ravani von Ow and Gerhard, 2010). However this paper will not only show and explain the operational benefit of these functions, but will focus on the experiences gained with this kind of sophisticated ring geared mill drive system. Several measurements of different operating conditions (starting, frozen charge remover, controlled roll back, backlash, etc.) made on an installed and commissioned 2 x 5 MW dual pinion ring geared mill drive system will be shown and discussed. Also the accuracy of the load sharing between the two 5 MW motors during starting, normal operation and stopping will be demonstrated using real measurements from an operating system. Finally the inherent features of these drive systems are briefly discussed.INTRODUCTIONLooking at the demands of grinding mills, we can split them into operational, maintenance and protective demands. For smooth and safe operation, it is important that critical situations are avoided as much as possible. Maintenance functionality must be quick and easy to execute, while protection of the system is important during all operating conditions. ABB has considered all these demands during development of their dedicated mill functions. By adding an additional controller (mill controller), not only a lot of application related functionality and protection is included, but also the interface between the mill drive system and the customer’s distributed control system (DCS) is simplified."

Jan 1, 2011

By Jaime Rebolledo, Carlos Toro

Muchas situaciones pueden ocurrir durante el cambio de turno en una operación minera y relación a la información que se genera, como por ejemplo: i) Silos de información, ii) uso de herramientas no estándar para compartir eventos de seguridad, iii) Necesidad de movilizarse a un centro de mando para declarar un evento peligroso detectado durante el cambio de turno y iii) la existencia Información dispersa El presente artículo propone la creación de una herramienta basada en Gemelos Digitales que tiene por foco, el apoyo a la actividad de cambio de turno. Los Gemelos Digitales poseen una característica innata de poder ser aglutinadores de información y por ello representan una excelente oportunidad de implementación.

Sep 29, 2023

By T. Lang

Clay sorbents from the North Bohemian Brown Coal Basin represent important but still some-what neglected accessory raw material. Submitted paper is concerned with relation between mineral structure, sorptive efficiency and reclamation exploitation of these rocks. Characters and localities of main clay sorbents from the North Bohemian Brown Coal Basin are shortly evaluated in an introduction. In next part, methodology of mineralogy survey for these accessory raw materials is stated, it is based on diffract analyse with D 5000 Siemens X-ray diffracto-meter. At the conclusion results are stated of mineralogy analyses from several clay sorbents. The determination of the zeolite and montmorillonite localities was accentuated. The paper presents also possibilities of practical clay sorbents utilization, especially by reclamation works.

Jan 1, 2014

By N. Graham, C. Walker

The SORD Miner is a patented mining principle being developed to exploit mineral and energy resources that current technology can not access. SORD Miner is designed to operate in underground wet, granular, continuously collapsing geological environments such as alluvial and marine deposits. It is somewhat like a cutter suction dredge and should be capable of mining its way through any fine granular material like sand or gravel, pumping the slurry back to the surface. In areas where the target layer is covered, the SORD Miner is inserted below the water table and will tunnel its way to the mineral deposits at depth. This paper describes the development, concept testing and prototype construction of the SORD Miner.

Jan 1, 2007

By G. O. Onyedika, M. U. Obidiegwu, G. C. Onuegbu

The effect of kolanut (KN) filler and compatibilizer (maleic anhydride) contents on the transport of toluene through low density polyethylene (LDPE) and low density polyethylene composite were studied at the temperatures 40, 60 and 80 °C.The kolanut powder used was ground to 25 μm particle size. In preparation of composite 0–5 wt% of kolanut powder and 0–2.5 wt% of the compatibilizer were mixed with 200 g of low density polyethylene in an injection moulding machine. The injected polyethylene and polyethylene/kolanut composites (LDPE/KN) were taken for sorption test. The sorption data obtained for low density polyethylene and kolanut powder filled low density polyethylene at the different temperature investigated were expressed as the molar percentage uptake (% Qt) of toluene per gram of the kola nut composites. Results show that the uptake of toluene at the five filler content (0–5 wt%) generally increased with increase in sorption temperature but decreased with increase in compatibilizer and filler contents. This can be seen at 80 °C and 0, 1, 1.5 and 2.5 wt% of compatibilizer respectively. The molar percentage uptake of toluene at 1 wt% of filler yielded the following values; 8.6789, 8.4768, 8.3476 and 8.2679 respectively. At 2 wt% it yielded 8.6224, 8.1333, 7.9525 and 7.9042 respectively, at 3 wt% it gave 8.4336, 7.9450,7.8900 and 7.7823 respectively, at 4 wt% it yielded 8.0263,7.9614,7.8218 and 7.6800 respectively and at 5 wt% it gave 7.9635, 7.8630, 7.6256 and 7.5013 respectively.

Mar 1, 2017

By Andrew Shabalin, Vladimir Skorohodov, Svetlana Babaeva, ?lga Makovskaya

"At processing of some kinds of wastes (electronic scrap, secondary materials, spent nuclear fuel) in nitric acid solutions, and also in technology of silver refining, the significant amounts of palladium and platinum passes into a solution. The ion-exchange concentration of palladium and platinum in nitric acid solutions (5-500/dm3) are investigated. More than 30 various classes of ionites are tested. The most chemically resistance resins at the given conditions are identified. It is shown, that the maximum sorptive capacity to studied metals at high acidity the complexing, synthetic and inorganic sorbents possess. To definition of platinum metals sorption optimum conditions the kinetics is studied, isotherms of a sorption at various parameters from nitrate solutions are obtained. The conditions of the platinum and a palladium desorption from the pregnant sorbents and its regeneration with the subsequent reuse of materials were defined. The raw materials containing precious metals have very diverse composition and physical properties. Commonly the materials are processed by hydrometallurgical way. If gold or PGMs there are in raw materials to its opening hydrochloric acid solutions are applied. As an oxidizer nitric acid, hydrogen peroxide, gaseous chlorine, etc are used. Nevertheless, at processing of argentiferous materials and preliminary treatment of a waste including the spent nuclear fuel, nitric acid solutions are often used and the specified metals in some extent pass into solution [1]. Therefore selective extraction of PGMs from nitrate solutions is an actual problem. In the present work the ion-exchange concentrations of palladium and platinum in nitric acid solutions (5-500 g/dm3) are investigated. At the testing more than 30 various classes of ionites the most chemically resistance resins at the given conditions are identified. These resins are synthesized on the base of polyacrylate, styrene-divinylbenzene and vinylpyridine. For a selection of the most effective resin among what are made in Russia and overseas, a number of ionites with various functional groups were studied. Influence of functional groups type on a PGM sorption is shown for extraction of a palladium as an example (table 1). The presented data shows, that palladium concentration in a phase of ionites depends on sorbent type. If the increasing of solution acidity essentially reduces palladium sorption by sulfonic cation-exchange resins (KU-2×8) than its sorption by strongly basic anionites is approximately equal. Intermediate position is occupied by complexing sorbents. The latter (AN-31, SN-3, ANKB-35, Lewatit TP 207, Purolite S 930) are the most effective for extraction of PGMs from nitrate solutions from the point of view of capacity value. According to [2], solution behavior of Pt (II) and Pd (II) are similar. As is known from coordination chemistry, ligand environment of the metal ions substantially impacts to character of electronic spectra. The figure 1 shows the results of measurements of optical density of platinum bearing solutions with various concentration of nitric acid at ?=400 nanometers"

Jan 1, 2008

By J. H. Perkins

The Bureau of Mines has conducted desorption work on fine coal particles at near atmospheric pressure. An apparatus Iris been developed that uses a capacitance manometer to measure desorption of methane from coal particles up to, 2 inches in diameter and pressures up to 1,000 psi. This will make it possible to duplicate the desorption process as it occurs in its natural underground environment.

Jan 1, 1969

By D. Haraguchi, S. Izawa, C. Tokoro, S. Owada

"Arsenic is widely known as a toxic element for humans, animals and plants. Because of more stringent wastewater standards not only in Japan but also around the world, research for appropriate and efficient treatment method for arsenic is becoming increasingly important. Coprecipitation or adsorption process using ferrihydrite is widely implemented for dilute As(V) removal from wastewater. In this study, the sorption mechanism of dilute As(V) with ferrihydrite in coprecipitation or adsorption process was investigated. To accomplish this, we conducted batch experiments of coprecipitation or adsorption and compared these results for sorption isotherm and zeta potential. These experimental results showed that sorption mechanism in coprecipitation process depends on the initial As/Fe molar ratio; simple twodimensional adsorption onto the surface of ferrihydrite when the initial As/Fe molar ratio was < 0.4, and some three-dimensional uptake with ferrihydrite when it was = 0.4. We also evaluated the sorption mechanim by analysis of X-ray diffraction (XRD) and X-ray Absorption Fine Structure (XAFS). XRD or XAFS spectra showed that surface precipitation of amorphous ferric arsenate was formed when the initial as/Fe molar ratio was = 0.4, beyond the thermodynamic bulk precipitation range for ferric arsenate.INTRODUCTIONArsenic is toxic to animals, including humans, and long-term exposure to arsenic via drinkingwater causes cancer of the skin, lungs, urinary bladder, and kidneys, as well as other effects on the skin such as changes in pigmentation and thickening (Ghosha et al., 2008). Elevated levels of arsenic are often present in the environment as a result of the weathering and dissolution of minerals as well as in response to numerous anthropogenic sources including the discharge of mine wastes, coal fly ash and the use of pesticides that contain arsenic (Nriagu, 1994; Singh et al., 2007). Indeed, the potential for arsenic exposure affects many people, as evidenced by several million people in Bangladesh and India being at risk of exposure via drinking water obtained from contaminated groundwater sources (Ahmed, 2001).Acid mine drainage (AMD) containing arsenic is a global environmental problem (Dold, 2008; Liang and Thomson, 2008) that also affects Japan, which has many abandoned or closed mines that have been generating AMD for the last few decades (Masuda et al., 2008). Several such facilities in Japan produce AMD containing dilute concentrations of arsenic that exceed Japanese effluent standards (0.1 mg/dm3) (METI, 2006). For example, AMD from the abandoned Horobetsu sulfur mine, the largest AMD source in Japan, contains approximately 10 mg/dm3 arsenic."

Jan 1, 2012

By G. Roy Chaudhury

Adsorption techniques are comparatively low cost and effective for treatment of arsenic contaminated drinking water. Various adsorbents such as alumina, ferrihydrite and manganese ores have been used, but there has been little investigation of modifying the structure of ferrihydrite to improve its adsorptive efficiency of As(III) and As(V). In the present study the incorporation of manganese oxide into the ferrihydrite structure was carried out and the prepared materials used in arsenic adsorption experiments. The compounds were X-ray amorphous, but TGA/DTA and FTIR analysis showed some structural characteristics. Sorption studies reported in this paper indicate the excellent arsenic removal properties of the manganese/iron compounds with a loading capacity of 0.3 mmol/g. Adsorption follows first order kinetics and the results fitted to adsorption and mass transfer models. Arsenic levels in water containing 1 mg/L As(V) were reduced by 50% in 20 minutes and 90% in 60 minutes using 1 g/L manganic ferric oxyhydroxide.

Jan 1, 2003

By Ivo André

Sorption of copper ions from aqueous solutions by dried biomass of the aquatic plant Potamogeton luscens was studied at laboratory scale. The aquatic plant was collected in water resources in Brazil, washed, dried at 60°C and ground in a bladed mixer. Sorption experiments were conducted in agitated flasks and in a packed bed column. Maximum copper removal was obtained between pH 5.0 and 6.6 when copper was present in the ionic form Cu&apos;. Sorption followed the Langmuir isotherm with saturation attained at 35 mg/g. Free energy of sorption was found, to be of the order of -25 kJ/mol. Sorption kinetics data were better described by a second order reaction and rate constants were calculated in 0.030 1/(min.mg) for - 4.0 mm particles and 0.081 1/(min.mg) for - 0.59 mm particles. Removal of metal ions in a packed bed column showed that Potamogeton luscens biomass can be used in several sorption/dessorption cycles. After sorbent saturation, copper ions can be recovered from the loaded biomass by elution-with H2SO4, solution. Main mechanism responsible for heavy metal uptake was found to be ion exchange. Results are discussed in terms of the surface properties of the biomaterial, solution chemistry of copper ions and thermodynamics parameters.

Jan 1, 1995

By R. K. Mehta, U. Cetin

The Nevada Test Site is located approximately 100 km (65 miles) northwest of Las Vegas, NV. The site was primarily used by the Department of Energy for the field testing of nuclear weapons and has been contaminated by several million cubic feet of low-level radioactive wastes, heavy metals, explosive materials, and volatile and nonvolatile organics. The transportation and leaching of these contaminants are creating serious environmental problems. The purpose of this study is to examine pozzolan, a natural alumina-silicate mineral, as a possible replacement for the existing impermeable clay barriers. In the first phase of this study, radionuclide sorption characteristics of pozzolan were investigated. This paper presents the results of the adsorption tests for the target radionuclides.

Jan 1, 2000

By U. Cetin

The Nevada Test Site is located approximately 65 miles northwest of Las Vegas, NY. The site was primarily used by the Department of Energy for the field testing of nuclear weapons and contaminated by several million cubic feet of low-level radioactive wastes, heavy metals, volatile and non-volatile organics, and explosive materials. Leaching and transportation of these contaminants are creating severe environmental problems. The purpose of this study is to examine pozzolan, a natural alumina-silicate mineral, as a possible replacement of the existing impermeable barriers (clays). In the first phase of this study, radionuclide sorption characteristics of pozzolan were investigated. This paper will present the results of the sorption tests for the target radionuclides.

Jan 1, 1998

By Lars Lövgren, Jörgen Jönsson

Heavy metals may be retained within deposits of sulfide minerals under oxidation and in the nearest recipients of drainage water by sorption to secondary iron precipitates. The extent of sorption is strongly influenced by solution pH and presence of complexing ligands, such as sulfate and natural organic acids. Desorption of metals and organidinorganic anions to recent secondary Fe precipitates, collected at the Kristineberg mine, Sweden, has been investigated under different geochemical conditions. Elemental composition and structural characterization (X-ray powder diffraction) indicate presence of schwertmannite. While metals such as Ni and Pb were fractionally desorbed from the precipitates under acidic conditions, oxyanions, e.g. arsenatdarsenite and sulfate were desorbed preferably under alkaline conditions. In a separate study the adsorption of NOM onto synthetic goethite was investigated. NOM adsorption showed a strong pH dependence, 95% was adsorbed at pH 3 and 40 % was adsorbed at pH 9. Addition of 2 mM of sulfate desorbed about 10 % of the adsorbed NOM.

Jan 1, 2000

By Gabriela Pino, Maurício Torem, Diego Veneu

Because of its simplicity, economy and biocompatibility, research regarding the use of microorganism for decontaminating heavy metals produced by many industries is an area of growing interest. Also, there is a stringent need for the control of toxic metals produced during various production processes and released into the aqueous environment in order to avoid damage relevant to soil or groundwater contamination. Among the available treatment technologies, sorptive flotation has been considered as a promising alternative for the wastewater treatment. In the present study Streptomyces lunalinharesii strain was applied as bioreagent for the removal of copper, cadmium and zinc. The removal of those metal ions depends mainly on the respective pH value, influencing the aquatic speciation during the process, as well as the zeta potential of the system and biomass concentration. Langmuir and Freundlich isotherms have been depicted. Dispersed air flotation was applied as the subsequent separation method for harvesting the suspended metal laden microorganisms, following the biosorption of copper, zinc and cadmium. The investigated parameters (in batch mode, laboratory scale) were in this case the saturator pressure, the coagulant concentration and the recycled flow. Applying the optimum defined conditions, over 60% removal of metal ions have been achieved in one stage and simultaneously, quantitative separation of the used (metal-loaded) biomass has been obtained.

Jan 1, 2014

By H. Sipilä, H. Vartiainen, H. Paarma

"The carbonatite massif of Sokli includes several low-grade Nb showings composed of ores and wastes as identified by routine analyses. More detailed lithologic proportions were determined in two orebodies in the Kaulusrova Nb-mineralized area by a careful geological study and by thorium radiation measurement on 10 cm-long drill core cuttings with a total length of 460 metres. The distribution of Nb in eight X-ray spectrometrically analyzed drill core sample intervals (totalling 35.8 m) was determined by analyzing the intervals semi-continuously by an X -MET analyzer. The geological studies suggest that Nb-mineralized bodies are feasible fo r the sorting of are and waste. This was confirmed by the semi-continuous determination of Nb on the X-MET analyzer.IntroductionThe Sokli carbonatite complex is located in eastern Finnish Lapland. The main ore of the carbonatite massif is a regolithic phosphorus ore in the weathered crust. Large-scale geophysical measurements and diamond drillings have also established several niobium showings within the magmatic carbonatites. Owing to the complicated geology of the massif, the niobium showings occur as irregular zones o r areas displaying complicated structure, texture, mineralogy and geochemistry (Vartiainen and Paarma , 1979; Vartiainen , 1980). The tonnages in areas such as this are large but the grades in-situ are low . The most intensely studied niobium showing is the Kaulusrova area.The exploitation of these showings depends on the feasibility of applying a sorting technique to upgrade the feed and to minimize the amount of material to be treated in the concentration plant. These possibilities o n the Kaulusrova area have been viewed by a detailed geological and X-MET an analyzing study."

Jan 1, 1985

By A. Rosenfeld

The feasibility of applying laser induced optical emission spectroscopy to the high speed sorting of mixed alloy aluminum scrap is investigated. The basic spectroscopy for analysing aluminum alloys for the major alloying elements over their full concentration ranges is established. Materials handling issues are also described and the components of an overall sorting system are presented.

Jan 1, 1995