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By James R. Gage

THE lead deposits of Missouri may be divided into three districts, the southwest, middle, and southeast. As too much time would be required to devote a detailed account to each district, only a description of the modes of occurrence of the lead ores in the southeast district will be given. The lead mining region proper of Southeast Missouri is embraced in an area of about twenty-five miles in width by about one hundred in length. The country embraced in this district is very broken, and traversed by ridges from one hundred to three hundred feet in height, with an occasional knob rising higher. Porphyry forms almost the entire substructure of the region, with here and there outcrops of granite. The crystalline rocks were eroded into ridges and valleys before the deposition of the limestone took place. These porphyries are older than the Silurian limestones, and "belong (according to Pumpelly) to the Archaean (Azoic) formation, of which they may be the youngest member in Missouri. They are the near equivalents, in point of age, to the great iron-bearing rocks of Lake Superior, New Jersey, and Sweden."12/02/2007

Jan 1, 1875

By S. Utili

"The optimal profile of a rock slope under given geometry constraint is investigated by means of the upper bound method of limit analysis. The optimal condition corresponds to maximizing stability factor. It is assumed that rock failure condition is suitably described by the Hoek-Brown criterion. Genetic algorithm is applied for locating the optimal profile. The optimal profiles turn out to be concave profiles but there are heaps around the toes of the slopes. Compared with plane profiles, the percentage of increase in stability factor can reach up to nearly 50%. The key geometry parameters of the optimal profiles are provided for practical use. The new upper bound formulation is capable of computing the stability factors of slopes of any shape, thus the stability status of a slope under man-made excavation can be monitored during the whole construction period.INTRODUCTIONIn mining industry, man-made slopes are excavated to create working surfaces. It is important to optimize the slope profile in order to maximize slope stability under certain geometry constraint. For instance, when the height and width of an excavation are assigned, a plane profile AC (see in Fig. 1) is widely applied in engineering practice, but it has been proved not the best one in terms of safety (Utili & Nova, 2007; Cala, 2007). A vertical profile ABC is the one with least stability. Thus, it can be deduced that there is a profile within the domain of the rectangle ABCD providing the highest stability. Cala (2007) compared the difference of convex and concave profiles in stability using strength reduction technique. According to Cala (2007), circular concave slopes can increase the maximum slope inclination under given factor of safety. Besides, based on upper bound theory of limit analysis, Utili & Nova (2007) assumed a logarithmic spiral profile to prove it is more stable than a plane profile in terms of the stability factor. Although the above studies attempted to seek the best circular or logarithmic spiral profiles, none of them considered the arbitrary shape of the optimal profile and its contribution to enhance slope stability."

Jan 1, 2015

By L. A. Wrigglesworth, A. S. Dadson

The orebodies of the Giant Yellow-knife mine occur in zones of schist, in an assemblage of typical Precambrian greenstones which form part of the Yellowknife Greenstone Belt. One of the most interesting problems at the mine concerns the fold-like attitudes assumed by the schist zones. The internal structure of the zones and orebodies provides much evidence of folding. A logical conclusion would be that the zones represent a single horizon which has been folded and drag-folded in the ordinary course of mountain building. However, surface mapping, and correlation of certain marker horizons, in underground work, indicate a homo-clinal succession of steeply dipping flows. If this concept of the geology is correct, the zones must cross-cut the regional strike at a small angle and, in the over-all aspect, the regional dip at a large angle. A mechanical interpretation of the zone structure is presented as a suggestion for the present until new evidence is found.

Jan 1, 1959

By W. H. Emmons

IN 1922 Morey made a series of experiments in which he observed the cooling of a molten system containing H20, 9.1 per cent; K20, 17.3 per cent and Si02, 73.6 per cent. This system was confined in a bomb; it was fluid at 500° C. and exerted no vapor pressure. In cooling to 420° C. a large part of it crystallized and at that temperature much of the water had separated from the crystals and remained as steam, which built up a pressure of 4998 lb. per sq. in., a force sufficient to lift nearly one mile of granite.1 If granite, cooling at 600°, expels vapor in the process of crystalliza-tion it is reasonable to suppose that a considerably greater vapor pressure would result, and it is thought that the vapor expelled from crystallizing granitic batholiths probably has a pressure sufficient to lift two or three miles of granite. This vapor, collecting near the tops of cupolas of batholiths, is believed to exert sufficient pressure to fracture the hoods and roofs of batholiths above the cupolas. If that is true, one would expect to find that the fracture systems above cupolas are arranged in patterns that depend in part on the shapes of the cupolas. The mechanics of the situation seem to require that conical cupolas should have radial fracture patterns, that bluntly rounded cupolas should have fracture systems that are either irregular or rudely conjugated in plan, and that elongated stocks or cupolas should have fracture systems in which the fractures lie nearly parallel to the direction of the elongation of the cupolas.

Jan 1, 1934

By Bruce B. Hanshaw

The Tertiary carbonate aquifer of central Florida is composed of about 2/3 calcite and 1/3 dolomite with minor amounts of quartz and apatite. The Mg content of the calcite is lower in the recharge areas than in the deeper confined parts of the aquifer system. Various geochemical lines of evidence indicate that much of the dolomite is of penecontemporaneous origin but that some may have been formed much later, possibly by ground water. Theoretical studies indicate that the Mg/Ca ratio in solutions is about unity for the three-phase equilibrium, calcite-dolomite-water. Solutions, such as ocean water and some subsurface brines, have Mg/Ca ratios higher than one and should represent dolomitizing solutions. In the areas of principal recharge to the Floridan aquifer, ground water is undersaturated with respect to both calcite and dolomite, and the Mg/Ca ratiois as low as 0.05. As the water moves downgradient, the Mg/Ca ratio systematically increases and approaches unity; saturation of the solution with respect to both calcite and dolomite also increases with length of travel in the system. Thus, in the zone of active potable-water circulation, the chemical process is one of dissolution of minerals until saturation is reached or exceeded. However, in the deeper brackish-water zones that underlie peninsular Florida, dolomite may be forming where the Mg/Ca ratio is greater than one. The necessary Mg may be derived from ocean water or brines recycled through the system as the hydrologic regimen is changed. The driving force may be simple mixing, relative fluctuations of sea level, or a combination of mechanisms.

Jan 1, 1972

By T. Crivits, I. Bellemans, V. Cnockaert, K. Verbeken

It is well known that slag foaming can significantly complicate copper smelting processes. This is especially true for unpredictable events that generate large amounts of slag foam during a small period of time. These events are here referred to as eruptions and are typical for certain types of liquid bath furnaces such as modern top submerged lance (TSL) furnaces. A few authors already made the link between over- oxidation of the slag phase and slag foaming. In this work, the mechanism is studied in more detail and explained using the smelter chemistry and the behaviour of dynamic foam formation. Finally, the most influential parameters on the foaming behaviour of the process are presented. INTRODUCTION Copper remains one of the most important metals used in our modern society. In 2017, the annual amount of copper produced worldwide was about 23.5 million metric tons. This makes copper the third most produced metal in the world after steel and aluminium. The majority of this copper was produced by copper smelting, about 19 million metric tons, both from primary concentrate and secondary feed material as reported in ICSG’s World Copper Factbook 2018. In the past, copper smelting was mainly performed using Flash smelting, a technology developed before 1949 (Kojo, Jokilaakso & Hanniala, 2000). Nowadays, this type of smelter is being complemented by other smelter types such as ISASMELT and Ausmelt technologies. These are two types op smelter furnaces, based on the concept of a top submerged lance (TSL) furnace. These two technologies were both commercialized around 1990 (Arthur & Hunt, 2005). It is estimated by Wang et al. (2016) that at this time, both flash and TSL smelters contribute equally to the total amount of annually smelted copper. Flash smelting stays the most important technology for extracting copper from primary sources. TSL furnaces, on the other hand, are more suited than Flash smelters for the recovery of copper from secondary materials. This is because of the different ways that the feed material is inserted in both furnaces. In Flash smelters, the ore and fluxes needs to be fine and completely dry in order to be able to blow the mixture inside the burner area of the furnace. The feed material for TSL smelters show less constrains concerning humidity and particle size. The material is dropped from the top inside the molten bath. As a result, a more complex and flexible feed stream can be processed using TSL smelting (Wood, Hoang & Hughes, 2017). This feature will become more important in the future as primary copper sources gets more scarce and the need for a fully sustainable material cycle increases.

Jan 1, 2019

By Albert H. Chester

DURING the summer of 1875 I visited some of the iron mines of Houghton County, Mich., and was quite interested to observe the progress made there within a. few years. Working in open pits is gradually giving place to underground work in most of the mines where this system is practicable. In some cases, as in the Lake Superior Mine, the body of ore is so irregular, and the deposit so liable at any time to be pinched out, or nearly so, that it has been found impractical, if not impossible, to lay out any plan for systematic underground work. But in many other mines the deposit is so regular in character, that the work can be laid out in shafts at regu¬lar intervals, and a series of 60 feet levels. The Michigammi Mine, opened in 1872, and first worked in 1873, is arranged on this plan, though some quarrying is still done. But the men are being put at overhead stoping as fast as it can be got ready for them, and before long it will all be worked in this way. The New York Mine is undergoing a similar change to the pillar system, and several others have either been changed, or it is about to be done. My principal object in visiting this region was to obtain samples from some of the important mines, so as to be able to answer the question : "What is the average percentage of iron in the Lake Superior ores?" Most iron furnaces work on mixtures of ore, so that it is impossible to tell, from their records, just the percentage in each one.

Jan 1, 1876

By James J. Bailey

Percussive drills have been in commercial use for many decades. Until relatively recently there was little serious effort to analyze the stresses in such devices in any detail. Within the last few years such analyses have been developed and have been reported by a number of authors.1-4 We present here an investigation of the impact systems of a family of conventional down-hole drills with optimization the objective. We have assumed that maximum drilling speed was the quality most desired and that this was to be achieved within conventional practice. In fact the methods that are demonstrated in principle below can readily be adapted to other percussive devices, whether conventional or not, and to other constraints. SOME PERFORMANCE PARAMETERS FOR PERCUSSIVE DRILLS Consider a percussive drill with an air motor operating with the following parameters: p-supply air pressure a-effective piston area W-piston mass S-piston stroke If we consider a simple (constant pressure) cycle, the following relationships can be derived. The blow frequency [N~ pa lie WS 377]

Jan 1, 1968

Tokyo Metropolitan Government designs the stormwater storage plans in underground, as a measure of flood control in completed urban district and improvement of combined sewarage system. This time, introducing those plans, we report about IKEJIRI and SIN-KOMAZAWA STORAGE TRUNK LINEs design and construction. They are located in Meguro river basin of the Morigasaki drainage area. Both storage trunk lines have capacity to store 15O,000m3 of stormwater. They are in use for countermeasure of flood till Meguro river's strengthening (intensity 50 mm/h) is ended. And after the strengthening, they will be in use for improvement of river water quality, through the storage of combined sewage and first runoff, which, otherwise overflows weirs and flows to river in a rainy day. These storage trunk line's full length is about 5700m. Boring diameter 66140 mm (f = 2672m) and 47800 mm (I = 2866m) of these tunnels are constructed by Mechanical Shield tunnelling method. And boring diameter 3600 mm x 4000 mm (R = 180m) is constructed by NATM tunnelling method. We began works in 1983, and have a mind to complete in 1987.

Jan 1, 1987

By S. I. Nozhko, V. N. Guliy, A. A. Zolotarev, L. M. Luyshnia

The study of the apatite deposits of the Aldan Shield shows wide spread of the Precambrian apatite-carbonate ores and possibilities of using them for extraction of apatite. Dependency of flotation on ore minerals was studied according to the following scheme: preparation of the monomineralic samples of anhydrite, gypsum, chlorite, serpentine, phlogopite, apatite; mixing them in apatite ore of the average composition; followed by flotation. Another series of the experiments was conducted to ascertain a dependence of flotation activity of the different minerals on the different flotation reagents, which were used as collectors. It has been shown that apatite from silicate-carbonate ores is most extractable because it has the biggest size of grains and is the most free of inclusions. Beneficiation of the sulphate-containing apatite-carbonate rocks is possible when flotol - 7.9 is used as a collector. Meanwhile, the use of the tallaktam leads to an increase in the sulphate recovery. The estimation of individual technological features of the layered Mghydrosilicates and their influence on the process of beneficiation has been examined using samples of apatite-dolomite ore (P205-8%) with the addition of the phlogopite, serpentine and chlorite. The results show that there is little influence of the chlorite presence on the flotation while the serpentine presence leads to a decrease of the flotation, because of its high specific surface area.

Jan 1, 1993

By P. U. W. Appel

Despite the very large offshore Exclusive Economic Zone (EEZ) area of Greenland (in excess of 2 mill. km2) virtually no work has been carried out on marine minerals on the ocean floor. Apart from a single reconnaissance survey by a mining company, major activities have been those of oil companies exploring the West Greenland shelf in the early seventies. The West Greenland shelf and its extensions is the most obvious area for year-around accessability when looking for marine mineral deposits. So far, only one onshore placer deposit has been found - ilmenite deposit near Thule, NW Greenland, whereas a gold placer in South Greenland presently is being evaluated.

Jan 1, 1988

By R. V. Kumar, F. Tailoka

In order to use ZnO laden dust as a possible desulphurization reagent, it is important to evaluate thermodynamics of the Zn-O-S system. At temperatures greater than 1450 K, there is an uncertainty in the thermodynamic data for the reaction of zinc with sulfur to form Zinc sulfide. In this work, the standard free energy has been determined using an electrochemical cell: Pt, Mo, MoO2/YSZ/ZnO, ZnS, S02, Pt., between 1198 and 1602 K. AG° varies from -145,880 to -88,100 J (± 2500) , with a phase change to ZnS (g) by sublimation occurring between 1450 and 1460 K. This is supported by thermogravimetric analysis which shows about 80% weight loss in ZnS from 1273 to 1473 K. Feasibility reactions were also performed and confirmed that ZnS (g) is formed when ZnO reacts with FeS (1473 to 1653 K) or with Fe-Csat-S(1473-1673 K). There is therefore potential for the utilization of ZnO laden waste as an additional or alternative reagent for desulfurisation.

Jan 1, 2004

By L. H. Chen, Y. C. Chen, Leo Benyamin, W. C. Chen

"To investigate the evolution of fluid-driven fracture of rock-like material subjected to borehole fluid pressure and its consequential damage with regard to post-peak stabilization, micro-seismic activities have been monitored using nondestructive technique of acoustic emission (AE) corresponding to the macro-scale complete history of loading curve by setting the hollow cylindrical external circumferential strain to be a closed-loop feedback signal during servo-fluid-driven tests. Development of a novel fluidinduced loading system injected from internal borehole as well as monitoring system were equipped such that the initiation and propagation of micro-cracks enable to analyze experimentally. By programming/controlling either injection rate or fluid pressure, synthetic sandstones with low-permeability made by cement mortar were conducted in this study. It found that both the growth of macro-crack initialized intensively as reaching the breakdown pressure and the micro-seismic activities represented by AE locations show nice agreement. The experimental results in this paper provide better understandings of fluid-driven fracture mechanism.INTRODUCTIONFluid-driven fracture is a process of generating cracks by injecting viscous fluid into solid material. Conventionally, fluid-driven fracture tests have been performed by mining industry to measure the in situ stress (Haimson & Fairhurst, 1969) and fluid-driven fracture has been employed by the petroleum industry to recover oil and gas. Additionally, the mechanism of crack growth or the extension of existing cracks is important to the evolution of volcanic dikes over distances of a few kilometers (Lister & Kerr, 1991; Rubin, 1995), crack propagation in dams (Bolzon & Cocchetti, 2003) and the disposal of radioactive waste (Sun, 1969)."

Jan 1, 2015

By Clarici E, Marsden J. R, Calderbank P. A

Evaluation of previous studies of multi-layer perceptron type artificial neural networks in the modelling of the deformability behaviour of rock have suggested that a deviation from the standard method of laboratory testing of rock under triaxial loading at constant confining stresses and constant axial strain rates may be inappropriate when the data produced are used to train an artificial neural network. In this paper, preliminary results of adopting such a strategy are reported. Of specific concern is the establishment of a suitable schedule for the stress path during testing. Furthermore, the training element of back propagation optimisation was directed towards prediction of new stresses given old stresses and old strain increments. Adoption of this method of supervisation in artificial neural network training facilitates the integration of the trained neural network within existing numerical methods used in rock mechanics. The target code was a finite difference Lagrangian formulation for the analysis of continua. Sandstone rock taken from a quarry in the UK was used in the study which showed that the method has great potential.

Jan 1, 1995

By George P. Demopoulos

In this paper the production and stability of crystalline scorodite (FeAsO4·2H2O) is discussed both on the basis of previously published work as well as recent work performed in our laboratory. The production of scorodite, especially from arsenic-rich and iron-deficient sulphate solutions offers a number of operational advantages such as high arsenic content, stoichiometriciron demand, and excellent dewatering characteristics. In addition to hydrothermal production of scorodite the work done over the last 10 years in our laboratory has determined that it is feasible to produce scorodite by step-wise lime neutralization at 90°C. The atmospheric scorodite possesses the same structural and solubility characteristics with the hydrothermally produced scorodite. Long term equilibration tests (up to 66 weeks) in the pH range 5 to 9 and temperatures from 22 °C to 75 °C revealed scorodite to undergo slow incongruent dissolutionyielding a highly metastable nano-sized 2-line ferrihydrite phase. The equilibrium arsenic concentration with this phase was 0.35, 0.96 and 5.87 mg/L at pH 5, 6, and 7 respectively at 22°C. In the presence of gypsum slightly lower concentrations were measured, this being more pronounced at pH>7. It was tentatively deduced that a Fe-Ca-AsO4 association (in the form of a phase resembling the mineral yukonite) contributes to the lowering of As concentration. Finally thermodynamic calculations determined that scorodite is stable in the presence of ferrihydriteunder oxic conditions up to pH 6.75 at 22 °C or higher pH at lower temperature and gypsum-saturated solutions. Keywords: Scorodite, Crystallization, Arsenic, Solubility, Stability, Precipitation, Disposal, Extraction, Processing, Metals, and Environment.

Jan 1, 2005

By X. L. Wang

Hydrothermal method was applied in the preparation of calcium sulfate whiskers in airtight re-actor using gypsum as primary materials. The optimum conditions of preparation are as follows: pH value 9.8~10.1, concentration 5%, material size 18.1µm, which were determined by the analysis of the diameter of CaSO4 whiskers through SEM. On these conditions a product of ultrafine CaSO4 whiskers with diameter of 0.19µm and aspect ratio of 98 is obtained. Ultrafine CaSO4 whiskers with different concentrations, modified by titanate NDZ-401, were added into polypropylene as intensifier and composites of Ultrafine CaSO4 whiskers/ polypropylene were prepared by melting-extruding method. Mechanical performance of the composites was tested and surface morphology of the composites was observed by SEM. The results indicated that impact notched izod of the composites was enhanced by 49.5% compared with pure polypropylene when 10.0% Ultrafine CaSO4 whiskers were added into polypropylene and toughening effect was very remarkable. Dispersion behaviour and interface phenomenon of Ultrafine CaSO4 whiskers in polypropylene matrix were investigated by SEM. The results indicated that Dispersion performance of Ultrafine CaSO4 whiskers modified by titanate NDZ-401 in polypropylene matrix is good, which improved mechanical performance of composites to some extent.

Jan 1, 2014

By B. Prof. Silliman

THE occurrence of diamonds of some size in the gold-fields of California is by no means uncommon, and was noticed by me in a communication, to the California Academy of Science in 1867, when specimens of this gem, from at least five different localities, were exhibited. I then suggested that a more attentive examination of the heavy sands left in the sluices of hydraulic washings would in all probability detect diamonds, mingled with other rare species not commonly believed to have occurred in these sands. Mr. George A. Treadwell, of San Francisco, has lately sent me a small package of these sands, collected by him from the sluices of the "Spring Valley Gravel Mining Claim," Cherokee, Butte County, California. A microscopic examination shows these sands to abound in beautiful colorless zircons (hyacinths), of the form well known in the hyacinths of Expailly (France), associated with crystals of topaz, quartz in fragments, rounded grains 'of chromic and titanic iron, and

Jan 1, 1873

By Takeshita. Takuo

"In this work, the progress of the HDDR process is discussed mainly on the Nd-Fe-B magnet system. There are three technologies being used for the Nd-Fe-B permanent magnet production; the sintering technique, the rapid quenching annealing and the HDDR process. The HDDR process utilizes· the HDDR phenomenon, in which hydrogen absorbing intermetallic compounds go through as they are heated in hydrogen atmosphere, Hydrogenation - Decomposition Desorption - Recombination. In the HDDR process, these four steps in the HDDR phenomenon are processed by choosing suitable reaction conditions regarding to hydrogen gas pressure, temperature, rate ·of desorption and etc., and we can produce permanent magnet powders of good magnetic properties with microstructures consisting with sub-micron size crystalline grains. In the anisotropic magnet powders, the sub-micron size crystals are being mostly aligned in the crystallographic c-axis direction. Possible applications of the HDDR process to other systems are also discussed.Microstructures of the Nd-Fe-B Permanent MagnetsIt is well known that magnet properties of magnetic materials are very sensitive to their microstructures [l]. This is seen in almost all magnet materials from soft magnetic materials and hard magnetic materials to magnetic memory materials. In this regard, the production technology is very important for the control of microstructures of permanent magnets The Nd-Fe-B magnet is the most powerful permanent magnet as a practical permanent magnet, and its coercivity force is much dependant on the microstructure as is the case for other permanent magnets."

Jan 1, 2000

By R. Stefaniuk, T. Le, J-Y Huôt, H. Henein

"One of the most important process variables in gas atomization is the gas to metal (G/M) mass ratio as it has a direct effect on the mean particle size of the atomized powder. If this ratio can be controlled during the atomization process, the powder produced would be more uniform and the d50 more predictable. Thus, atomization using a tundish or gravity feed from a crucible would be more stable. In gas atomization, the gas flow rate can be easily monitored; while it is very difficult to determine the molten metal flow rate. This research paper presents a new method of recording the molten metal height with time using a conducting metal height detector. The metal height recorded in real time during atomization was used to characterize using a model the friction losses in the metal delivery system. It is found that the integrity of the metal delivery tube and the cleanliness of the melt play a key role in the maintaining a stable metal feed.IntroductionIn the gas atomization process, molten metal is normally fed to the system either continuously using a tundish or in most cases a certain amount of metal is melted in a crucible and flows into the atomizing chamber under gravity. In the first case, the metal flow rate is believed to be constant during the atomization process despite the presence of slag or dross on the molten metal surface. In the second case, the amount of molten metal is depleted with time and the rate at which the metal flow decreases with time varies from test to test in a seemingly unpredictable fashion.' Furthermore, most atomization systems are confined units and the metal level in the crucible cannot be detected by a visualization method. In industry as well as in laboratories, the metal flow rate is normally calculated on either the mass of input material or the mass of total production divided by the duration of the test. This figure is not accurate enough and obviously cannot be used as a control parameter for the gas to metal ratio as it is only determined after the completion of an atomization run. The need exists for a metal flow rate measurement and control methodology; thereby the d50 of the powder produced may be estimated and controlled in real time. Clearly, the smaller the variation of the G/M ratio during the atomization process the more uniform the powder produced and hence the size of the particles can be predicted."

Jan 1, 1994

By K. Fagerlund

Methods for simulation of settler reactions, matte-slag separation and matte settling in copper flash smelting have been examined. The reaction, separation and settling phenomena of slightly oxidized chalcopyrite samples and cuprous sulfide-magnetite mixtures in fayalite type slags were examined at about 1300°C under inert atmosphere. Two methods based on introduction of molten samples of oxidized chalcopyrite concentrates or synthetic matte-magnetite mixtures onto the surface of molten iron silicate slag were tested. In the first method the samples were water quenched and polished specimens were studied and analysed using light optical microscope, scanning electron microscope, energy dispersive spectrometer. In the second method processes taking place after the introduction of samples onto the slag are followed "in situ" using X-ray transmission image monitoring. Great differences were observed in separation and settling behaviour of low and high grade copper mattes produced as a results of interaction of initial samples and slag.

Jan 1, 1997