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By M. Reda

Because of the adverse environmental effect of Chromate, Molybdate ions had been investigated as replacement for Chromate and the results had shown not to be encouraging. Film deposited from peroxopolymolybdate (from reaction of Molybdenum meta, with excess Hydrogen Peroxide), are more robust than that deposited from molybdate solutions. This was shown to be due to higher fraction of Mo (IV) and Mo (V) that form from Mo (VI) in the peroxopolymolybdate deposited film than the film deposited from Molybdate solutions. The peroxopolymolybdate film contains 40% un-hydrated molybdic acid, tetraperoxodimolybdate and tetra peroxo tetra molybdate. The protective properties of peroxopolymolybdate were shown to be due to the effectiveness of the un-hydrated molybdic acid.

Jan 1, 2010

By David Shatwell

Recent epithermal gold discoveries in Chile and Bolivia provide increasing evidence of a belt of intermittent, epithermal, precious metal mineralization east of the main Andean porphyry copper belt. This relationship may be the result of an easterly decrease in the age of magmatism and erosional levels, in¬crease in depth above the underlying Benioff zone and consequent changes in magma chemistry, or some other unrecognized factor. Examples are: • The Choquelimpie gold-silver mine in Chile and numerous other epithermal prospects (such as La Riviera, Bolivia) in late Tertiary volcanics along the Chile-Bolivia border. These lie east of the belt that contains the Toquepala, Quellaveco and Cuajone porphyries in southern Peru and the Cerro Colorado, Copaquire and Quebrada Blanca porphyries in northern rhila

Jan 1, 1990

By Abouzar Vakili

Longwall Top Coal Caving (LTCC), as the most attractive method for thick coal seams, has been suffering from insufficient geomechanical understanding for the past few years. Cavability without doubt is the most critical geomechanical issue associated with the top coal caving method. A discontinuum method has been used for comprehensive modeling of LTCC operation by using the Universal Distinct Element Code (UDEC). In addition Particle Flow Code (PFC) and Phase2 were used as support for the caving mechanics analysis. Although the previous researches of gravity flow in caving operations neglected the effect of continuous span expansion, it has been observed in this study that face advancement has a great impact on roof symmetrical behavior. The amount of symmetry fluctuates between different face distances. Horizontal displacement seems to be the best indication for roof symmetrical evaluations. Two critical caving conditions have been modeled and parameters such as horizontal displacement, caving angle and recovery rate have been compared thoroughly. Results show that unsymmetrical behavior on the roof is closely related to face stability.

Jan 1, 2007

By Andrew Howard

As the mining industry moves further into developing countries in search of new resources, its role in international development is coming under increasing scrutiny. This is a trend that is likely to accelerate, along with the potential for headaches among managers in the industry. Public interest in development and environmental issues is rising as faith in “big business” falls. This has strengthened nongovernmental organizations (NGOs) campaigning for sustainable development. And it has put more pressure on banks, governments and development agencies to curb corporate misdemeanors. Developing world governments are also becoming emboldened to reject previously agreed terms they do not consider equitable. The mining industry has begun to formulate a response to these pressures but must go much further. Societal and environmental issues must move from public relations to core strategic thinking. Abiding by rules or codes is not a relevant response. Instead, genuine support for sustainable development is required. This will involve delegating the responsibility for engaging with local communities to on-the-ground staff and developing a dialogue with local stakeholders rather than conducting an initial assessment and disengaging.

Jan 1, 2006

During the past three years Lurgi's Circulating Fluid Bed (CFB) technology has been successfully applied to roasting of refractory gold ores and con- centrates. In comparison with the so-called Stationary Fluid Bed roasting systems, a considerable improvement of gold recovery, to around 95 per cent, has been demonstrated and achieved on many occasions in pilot CFB units and in commercial CFB roasting plants as well. The major reason for such improved gold recoveries is the excellent controllability of the roasting process in the CFB reactor system. Here, temperature, gas atmosphere and solids residence time are more precisely controllable at optimal values during roasting operation in order to achieve the highest possible gold recovery in the subsequent leaching process step. Further dominant benefits of CFB roasting systems are their flexibility with regard to feed material, throughput capacity, dry or slurry feed, almost unlimited oxygen enrichment, direct fuel addition and in situ capture of SO2 in the presence of limestone and dolomite. The system will accept 50 per cent turndown ratio, large variations in feed composition and particle size, as well as a variety of different fuel types. The commercial applications of CFB roasting systems for gold con- centrates have been realized so far at Fimiston, Kalgoorlie/Westem Australia and for whole ores at Cortez, Nevada/USA.

Jan 1, 1991

By N. Schreithofer

Varying flow regimes, particle populations and consequently different types of bubble-particle interactions characterize the different zones of a flotation cell. The understanding of the role of the different zones of turbulent intensity on the particle-bubble interactions is of primary importance to optimization and scale-up of flotation processes and machinery. In order to study particle-bubble interaction in turbulent flow a completely new approach was taken. A laboratory scale stationary turbulence device was developed and built. The set-up allows the observation of particle-bubble interactions in various turbulence intensities, particle and bubble sizes and surfactant concentrations. The experimental set-up consists of a transparent, specially designed tank in which liquid flows between carefully designed and placed obstacles that create different turbulent flow fields. Bubble-particle aggregates are introduced into this turbulent zone. The behaviour of the aggregates, such as attachment /detachment of particles to/from air bubbles is recorded by a High Speed Imaging (HSI) system (5400 fps). The images are then analysed and the dependence of attachment/detachment process is described as a function of turbulent intensity in different conditions for different surfactant concentrations. This paper introduces this method to study particle-bubble interactions in turbulent flow and correlation to Computational Fluid Dynamics (CFD) simulation. CFD modelling is validated for two and three phase systems; liquid-gas with liquid and solid tracers respectively. The CFD simulations using the RANS k-S turbulence model showed good correlation to the experimental data and the experimental method is a promising tool for investigation of particle-bubble interaction in turbulent flow.

Jan 1, 2014

By A. Jakobsson

Studies of the rate of interdissolution in oxide systems in the solid state are of importance in materials processing through the powder-metallurgical route. As there is a need for following the rate of the such reactions continuously, a new method based on high temperature X-ray diffraction was developed. Mechanical mixtures of the oxides were placed in a high-temperature X-ray diffraction unit and the changes in the intensity and position of the peaks with highest intensity for both the components were followed as functions of time. A suitable theoretical model has been developed in order to interpret the experimental data and evaluate the diffusion coefficients. The method was applied in the case of the system MgO-NiO. The results obtained are compared with those obtained by another new method, based on solid-state galvanic cell technique with calcia stabilized zirconia electrolyte, developed in the Department of Theoretical Metallurgy. The advantage of the present techniques to monitor the progress of the reaction continuously make them suitable for computer control of such processes.

Jan 1, 1995

By James M. Franklin

Research on modern hydrothermal systems provides quantitative measures of the processes of formation of hydrothermal fluids and of precipitation mechanisms from them. Studies of ancient deposits provide new information regarding volcanological processes that are related to the deposits, as well as data on their spatial and temporal compositional variations. Mew exploration guidelines result from both aspects of research. The most fundamental requirement for large metalliferous hydrothermal systems is an abundant heat supply for the upper two kilometers of the crust. This heat may come from a focused heal source (shallow-level subvolcanic intrusion), but ambient heat also may have provided enough energy for the reactions necessary to effect leaching of metals, especially where heat flow is particularly high (i.e. very large or high-temperature magmatic source, such as ultramafic environments). For most VMS systems, the majority of the metals were derived through leaching from footwall strata; in addition interstratal fluids may enter subvolcanic intrusions during episodes of magma a chamber "cracking," engendering some '?magmatic" component in the hydrothermal system. Direct contributions of metalliferous magmatic fluid also may be significant from arc-related or back-arc felsic or alkalis systems. These latter contributions may form exceptionally high - grade portions in some deposits. Subvolcanic intrusions, which are excellent indicators of high heat flow and may have been the direct driving mechanisms for some stems undergo two stages of alteration: On intrusion emplacernent. fluids may rapidly enter and react with their mesostatic portions, evident in the sills in the Middle Valley. High temperature interactions caused albitization and destruction of oxides and sulfides, releasing metals. During terminal hydrothermal stages, the metalliferous fluid collapsed into the intrusions, forming disseminated and vein sulfides.

Jan 1, 1998

The Epithermal and Mesothermal Gold Prospectivity modelling projects carried out by Crown Minerals provided explorers in New Zealand with a new compilation of historical exploration data combined with new geological information from the GNS QMap 1:250,000 scale mapping project. These data were used to produce predictive mineral potential maps for gold mineralisation in New Zealand. The aim of these projects, to stimulate mineral exploration and investment in exploration, has been successful with eight new companies acquiring new tenement positions and committing significant exploration expenditure to exploring in New Zealand in the coming years. The projects were done at a national scale and consequently not all exploration data were compiled into the prospectivity models. Several of the new companies recognised the value of the prospectivity modelling work and committed exploration funds to continue the modelling process. They recognised a need to compile the remaining data and run the models again to allow detailed exploration targeting. Detailed data compilations including digitising historic exploration stream sediment sample, rock chip sample, soil sample and drilling data has been completed. New models have been completed in Otago for mesothermal gold mineralisation and in the Coromandel and Northland for epithermal gold. The new models have been compared with the original regional scale models and used to target prospect scale exploration. This work has allowed exploration models for epithermal and mesothermal mineralisation in New Zealand to be refined. More importantly this work has identified significant areas with potential to host gold mineralisation with little or no systematic geochemical data including soil sampling or drilling. Exploration work programs have been designed to acquire these missing data and exploration funds have now been committed to test the areas highlighted by the prospectivity modelling. In summary, the Epithermal and Mesothermal Gold Prospectivity modelling work has successfully attracted new investment and ideas to the exploration scene in New Zealand. The projects had an estimated cost of NA$250 000 and will in the next two years, just through exploration expenditure, attract more than NZ$10 M in investment. If a mine is discovered the return on investment will be considerably greater.

Jan 1, 2004

By Stefano Baf

This paper describes the main technical and process solutions applied to the extrathick and wide slab caster built at Yingkou (Liaoning, P.R. of China), as well as all the features required to achieve the surface and internal quality targets.

Aug 16, 2017

By A. T. Yu

As the first year of full-scale shiploading operations nears completion, Chile's twin ports of Chafiaral and Caldera have proved instrumental in promoting the growth of that nation's iron ore industry. Located on the Iron Coast several hundred miles below Antofagasta, the two ports boast of new conveyor shiploading facilities uniquely adapted to their coastal environment. Until recently, iron ore producers in this region of Chile have been hampered by antiquated methods of loading crushed ore on ships for transportation to foreign buyers. Use of the "truck-to-lighter- to-ship" method, which dominated heretofore, was too slow and costly to permit expansion of productive mines and exploitation of new high-grade discoveries to meet the growing world demand for such ore.

Jan 8, 1960

By P. G. Killeen

Proper calibration of portable gammaray spectrometers and spectrometric logging equipment is essential if they are to be used for accurate quantitative determinations of radioelement concentrations. In the case of both types of equipment, it is necessary to determine the system calibration constants (stripping factors and sensitivities). In the case of borehole logging equipment, it is further necessary to determine the system response characteristics if the data are to be computer processed to improve the accuracy and resolution of the logs. Facilities are now available near Ottawa for the complete calibration of portable gamma-ray spectrometers and spectrometric logging equipment, in addition to already existing facilities for calibrating airborne gamma-ray spectrometers. Limited additional facilities are also available or planned in several other areas of Canada.

Jan 1, 1978

By Rich Perry

HARRY HINDS: Our second speaker today is Rich Perry. Rich is the manager of leach and dewatering at Newmont Gold Company's Carlin operations. He has been the operator of Newmont's refractory leach development program for the past three years. Prior to joining Newmont in 1994, he was plant superintendent at the Big Springs and Jerritt Canyon Roasting Mills for Independence Mining Company. He graduated from the University of Nevada's Mackay School of Mines, and has lived with his wife and three children in Elko, Nevada, for the past 12 years. Please welcome Rich as he presents "New Facility Design Engineering: On-Site Versus Engineering Companies' Offices." RICH PERRY: Newmont Gold Company has been mining and processing gold ore at its Carlin, Nevada, operations since 1965. Processing is done using oxide milling, heap leaching, and whole ore roasting methods. Newmont began development of refractory leach processing technology at its research and development facility in 1988. The R&D staff focused on developing processing methods for low-grade refractory gold resources at Carlin that could not be economically processed by refractory milling methods. The term refractory ore refers to those ores that contain quantities of sulfides and/or organic carbon that result in low recoveries using conventional cyanide leaching. The R&D staff developed two potential processes deemed worthy of further testing: heap biooxidation to liberate gold occluded by sulfides and ammonium thiosulfate leaching for gold recovery from carbonaceous preg-robbing ores. These were piloted in small heaps by the staff of the R&D and Carlin metallurgical labs from 1990 through 1994. By 1994, Newmont's R&D and metallurgical staffs had unlocked the chemistry and kinetics of the two processes, and it was decided that the operations group would be brought in to begin development of a commercial plant. A project manager at Newmont's Denver office was assigned to the project. Scale-up issues such as biooxidation leach pad design; on/off heap heights; handling of various ore types during stacking and reclaiming; operating costs; and environmental, health, and hygiene concerns using a new process chemistry remained unanswered.

Jan 1, 1998

By D. Milne, G. Snell

"A new method to predict stope hangingwall failure in underground excavations is proposed. This method compares movement rate for stope hangingwalls, determined from changes in strain or deformation, with changing opening geometry. This geometry is represented by the effective radius factor (ERF), a measure of relative distance to supporting abutments from an opening surface point. This strain-ERF (SERF) approach is applied to an instrumentation program for Brunswick mine near Bathurst, New Brunswick. The SERF method for this case study predicted failure at an ERF of 13.9 m and hangingwall failure actually occurred at an approximate ERF of 12.4 m.RÉSUMÉ Cet article propose une nouvelle méthode permettant de prévoir la rupture de l’éponte supérieure des chambres d’abattage dans les excavations souterraines. Cette méthode compare la vitesse de mouvement des épontes supérieures des chambres d’abattage, déterminée à partir des changements aux niveaux des contraintes ou de la déformation, à la géométrie variable de l’ouverture au jour. Cette géométrie est représentée par le facteur du rayon effectif (ERF, de l’anglais Effective Radius Factor), une mesure de la distance relative jusqu’aux appuis latéraux de soutènement à partir d’un point de la surface d’ouverture au jour. Cette approche contraintes-ERF (SERF, de l’anglais strain-ERF) est appliquée à un programme d’instrumentation pour la mine Brunswick située près de Bathurst, dans le Nouveau-Brunswick. Pour cette étude de cas, la méthode SERF prévoyait une rupture à un ERF de 13,9 mètres (m); la rupture de l’éponte supérieure s’est effectivement produite à un ERF d’environ 12,4 m.INTRODUCTIONUnderground stope design can be improved with the installation of field instrumentation. The most commonly used instrumentation for monitoring rock mass behaviour around open stopes is extensometers. The y-axis of Figure 1 represents how the changing rate of movement, measured using either displacement- or stress-type instruments, can be observed over time. The magnitude of movement measured by extensometers can give an approximation of the load on installed support (Milne, Pakalnis, & Lunder, 1996) and a changing rate of movement can indicate approaching instability."

Jan 1, 2018

By Gerhard Melcher, Hermann Hilbrans, Michael Gamroth

"IntroductionSeveral new smelting processes have been proposed and developed during the last 20 years. This has been true, in particular, for copper smelting technology. The important impulses for the advances in this field have been the recent demands regarding the environmental protection, energy saving and improved utilization of the metals contents of deposits, in particular that of complex raw materials.The methods developed more recently for pursuing these objectives have been outlined in several papers. In some of them the advantages and drawbacks of certain developments have been stressed. These documents are of great importance for assessing the different processes. The following paper tries to explain some details of the cyclone smelting process taking into consideration a few of these well-known presentations. The effectiveness of operation of the cyclone smelting process indicates that this process presents a significant achievement when compared with other conventional methods.The application of the CONTOP smelting cyclone range s beyond the field of copper metallurgy or the smelting of sulphide concentrates with the aid of oxygen. The research work carried out in the pilot plant of KHD Humboldt Wedag AG in Cologne-Porz also includes the recovery of the metal contents of intermediate products and processing of smelter residues which have to be converted in a disposable stat e, free of environmental pollution. This paper explains a few examples in this regard."

Jan 1, 1987

By James Kemp

IN earlier years, the custom prevailed of regarding the anthracite basins as cases of folding with slight development of faulting. Folding is so pronounced and, in the eastern and western Middle Fields, at times so violent, that the inference was a natural one and led to the widespread impression that practically all the disturbances of the seams could be explained in this way. The cross-sections-and maps prepared forty or more years ago for the Second Geological Survey of Pennsylvania, by Mr. Ashburner under Prof. J. P. Lesley, exhibit little else than folds.1 So far as I can discover faults fail in the charts, except in one small case in the Henry Colliery near Plainsville on the outskirts of Wilkes-Barre. Some years ago, while spending a day or two in Wilkes-Barre, under the guidance of R. V. Norris, I looked over some recent and accurate cross-sections of a number of the large collieries and was deeply impressed with the peculiar behavior of some of the seams and the intervening shales. Thus, a seam might present a small, more or less overturned fold, rising 30 to 50 ft. (9 to 15m.) above its general course, and yet the movement would be taken up in the overlying shales, so as hardly to be noticeable in the seams next above or below. These and similar anomalies, especially when shown with the accuracy of engineer's surveys, possess great scientific and practical interest, bearing as .they do, not alone on coal mining, but on theoretical geology and the actual behavior of strata under great compressive stresses. In preparation for the semicentennial meeting of the Institute, an, effort was therefore made to secure some of the most interesting sections for presentation to the members. The collection of illustrations here shown is mainly due to, Mr. Douglas Bunting of the local committee, to whom and to the contributing companies acknowledgments are due.

Jan 1, 1922

By Vincent P. Gi. ccnella

GOLD was discovered in Gold Canyon on May 15, 1849. Following this discovery placer miners worked the gravels in the canyon for-ten years, finally discovering the outcrop of the Comstock lode at Gold Hill in May, 1859, and in Ophir ravine on June 12 of the same year. Before long large quantities of gold and silver, were taken from the lode and one of the West's most spectacular mining booms drew thousands of fortune seekers to Nevada. After a long period of production activity waned and in late years little mining was done. The recent reopening of the old mines and the discovery of ore in other parts of the vein, and in other veins of the district, has led to a revival of interest in the Comstock. Virginia City, Gold Hill, and Silver City, situated along the great vein system, are enjoying a period of prosperity and a large influx of people.

Jan 1, 1934

By Robert B. Parsons

"It is quite likely that more than a handful of junior exploration companies will receive some startling news from their accountants this spring when 1989s tax returns are being prepared. These companies could find that, for the first time ever, they will have to write a cheque to the federal government on account of a new federal capital tax which became effective July I, 1989IntroductionMany mining companies which have never had to pay a federal income tax are finding that they indeed have a tax liability for 1989. Non-producing companies, such as junior exploration companies, almost automatically assume that they don't have to pay any income tax. But, a new tax imposed under the Income Tax Act catches especially the company that has no income.Effective July 1, 1989, a federal capital tax (some call it a corporation minimum tax) is payable by any corporate carrying on business in Canada where the corporation has ""taxable capital"" exceeding $10 million. As a result of the popular use of flow-through shares in recent years, many junior exploration companies are finding that their balance sheets show capital stock over $10 million, and that they are consequently caught by the new tax. Further, some of these companies are finding, to their chagrin, that the tax for 1989 was due on February 28, 1990, and that non-deductible interest is ticking away on unpaid taxes."

Jan 1, 1990

By A. V. Roschin, N. V. Malkov, V. N. Karnoukhov, V. E. Roschin

Reduction interactions in solid phases are widespread and occur in most complex metallurgical processes. Among these processes, reactions between oxides and carbon have a special importance. The authors conducted experiments for comparison of reduction by different reducing agents of impregnated chromite ores, in which grains of the reducible chromite spinel are isolated from direct contact with the reducing agent by layers of non-ore material. The results of the experiments have revealed that the beginning of reduction is preceded by thermal and impurity order-disorder transformation of the oxide lattice whilst the transformation of the oxide lattice into the metal lattice takes place as a result of removal of oxygen anions from the zone of metal germ nucleation. Since anions are charge carriers, increase of their mobility can be monitored by changes in electrical conductivity of oxides. Respective measurements of electrical resistance of ores of different metals and a number of pure refractory oxides under heating have indicated that the beginning of reduction coincides with the time of drastic (tens of thousands times) increase of conductivity of the oxides. Besides, the temperature of the beginning of carbon-thermal reduction is in line with the Tammann temperature, i.e. the temperature of transition from the predominantly surface diffusion to volume diffusion. Segregation of metals from the oxide lattice occurs as a result of merging of anion vacancies with defect electrons on defects of the oxide lattice. The transformation of the oxide lattice into the metal lattice requires a certain concentration of anion vacancies and inflow of electrons from the reducing agent to the site of metal segregation. Such inflow has no difficulties due to the mixed anion-electron nature of high-temperature conductivity of oxides. Thus, the reduction is not determined by oxygen diffusion, it is determined by oxygen vacancies diffusion whose speed exceeds the speed of oxygen diffusion by orders of magnitude. This determines that the kinetics of reduction considerably exceeds the kinetics of oxidation at similar temperatures since oxidation proceeds by means of mass transfer of oxygen through the layer of the generated oxide.

Jan 1, 2004

By João Veludo, Eduardo Júlio, Helen D. Robinson, Jesús E. Gómez

"Utilization of micropiles for structural retrofit requires connection of the micropiles to the footings of the existing structure. Almost ten years ago, an experimental research effort was carried out in the US to investigate the magnitude and mechanism of development of the bond strength between micropiles and existing concrete. The study resulted in important conclusions on the mechanism of connection capacity development and provided specific recommendations for practical design of micropile-to-footing connections. In the last five years, the original study was complemented by an intensive experimental effort in Portugal aimed at answering many of the questions still remaining on this topic. This paper is a summary of the knowledge that is presently available on the capacity of micropile-to-existing footing connections. It presents the results and observations of model tests performed in the US and Portugal, as well as some tests from actual construction sites. The paper presents clear evidence that friction may be the most important component of connection capacity. It also presents a clear correlation between confinement and connection capacity.IntroductionUtilization of micropiles for structural retrofit requires connection of the micropiles to the footings of the existing structure. This is often accomplished by drilling through the footing and developing the connection by direct bond between the micropile grout and the existing concrete. Almost ten years ago, an experimental research effort was carried out in the US to investigate the magnitude and mechanism of development of the bond strength between micropiles and existing concrete. Smooth and textured micropile inserts of varying lengths were tested to failure inside pre-drilled holes of varying diameters. That investigation led to several publications (Gomez et al. 2005, Wilder et al. 2005, Cadden 2009) on the mechanism of development of bond strength between micropiles and concrete, which included a chart for preliminary bond value selection depending on the diameter of the hole and texture of the micropile.An intensive testing program was carried out in Portugal in the last five years. The program focused on answering questions posed by the original investigation and on finding the relationship between connection capacity and level of confinement. Both investigations, and especially the testing performed in Portugal, provided an invaluable amount of information on the mechanisms of failure of micropile-to-footing connections. This information should be the basis for development of design procedures that, until now, were not available."

Jan 1, 2015