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By D. S. Cronan, S. P. Varnavas

Abstract - Metalliferous precipitates from submarine hydrothermal discharges have been investigated at four inshore locations off Milos in the Hellenic Volcanic Arc. The fine fraction of the sediments shows considerable variability in the concentrations of elements frequently associated with hydrothermal activity. Manganese varies from 30 ppm to 2500 ppm, encompassing the entire range of values found off Santorini also in the Hellenic Arc. Iron occurs in lower concentrations than off Santorini and Yali, while other elements often associated with hydrothermal activity such as Pb, Zn, As, and Cu also show enrichments in sediments from the hydrothermal vent areas. Selective leaching studies have shown that most elements are variably distributed between the different phases of the sediments but with enriched Pb, Zn, and Mn mainly in easily soluble secondary phases. Hydrothermal inputs are strongest at Palaeochori Bay, less at Voudia Bay and lowest at the Airport Springs and Rivari. The weathering of sulfide and possibly other orebodies is also thought to contribute to some of the elements enriched, while background concentrations are largely supplied from detrital sources.

Jan 1, 1999

Mid-ocean ridges host approximately 65 per cent of about 100 known sites of high-temperature venting and polymetallic sulfide deposits; most of them are located at the East Pacific Rise (EPR), while more diverse mineralisation styles occur at the Mid-Atlantic Rise (MAR). Seafloor hydrothermal activity at the EPR are related to MORB while different substrates, including MORB and ultramafic intrusive rocks, are associated with æblack smokersÆ at the MAR. Depth of hydrothermal activity ranges from 0.7 to 4.3 km. High-temperature vents precipitating Cu-Fe sulfides (chalcopyrite and isocubanite, rare bornite), pyrrhotite, pyrite (¦ marcasite), and sphalerite, and low-temperature edifices precipitating marcasite (with pyrite), sphalerite, barite, andsubordinate chalcopyrite (pyrrhotite and isocubanite are absent) occur in both environments. There are considerable differences in Fe, Zn, Cu, Ag, Au and trace element contents in ores and in theFeS contents in Zn-sulfides in these deposits. Acomparison with anhydrite and sulfide minerals precipitating from modern black smoker fluids sulfide reveals many similarities but also some important differences. Fluids with salinity values above and below that of seawater at 400¦C down to 130 - 170¦C deposited sulfide minerals. Mantle-derived He prevails in fluids trapped by sulfides in EPR 9¦N and 21¦N hydrothermal systems. Hydrothermal fluids in MAR and back-arc systems are richer in radiogenic 4He. The sulfur isotope composition varies in the different hydrothermal fields and within zones of a chimney. EPR sulfides display narrower range of d34S values, while MAR and back-arc sulfides can bedepleted and enriched in the heavier d34S isotope. The most important finding is that fluid temperature, salinity, R/Ra ratios and d34S values ranged more significantly in the polymetallic sulfide deposits than when measured directly on venting fluids. An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation.

Jan 1, 2008

By Thomas M. Barczak

A survey of the longwall industry was conducted to examine the performance of modern shield technology. The results of this survey indicate that state-of-the-art shields perform better and last longer than ever before, but premature failures do still occur. In addition, longwalI operators are now using shields longer than ever before and a greater number of fatigue related failures on aging shields are now occurring. A generic assessment of these shield failures is provided, describing the nature of the failures and how widespread they are throughout the industry. An engineering assessment of shield design and factors that cause shield failures is made using both strength of materials and fracture mechanics principles. From this analysis, design practices to improve structural margins of safety and extend the life of the shield are proposed. The existence of unexpected shield failures indicate that current shield performance testing is at times inadequate. Recommendations are made relative to improved shield performance testing protocols including the benefits of testing in an active load frame such as the National Institute for Occupational Safety and Health's (NIOSH) Mine Roof Simulator. Even the most rigorous shield testing procedures, which strive to simulate in-service loading conditions, fail to consider key environmental issues, such as corrosion which is often the cause of structural fatigue failures in modern shields. The survey also indicated that hydraulic failures occur much sooner in the life cycle of a shield than structural failures, and although they can significantly degrade support capability, often go undetected for long periods of time. Methods to detect the hydraulic failures are also provided. The paper concludes with key points to maximizing shield design and life expectancy and ideas for future generation shield designs.

Jan 1, 1999

By J. Olsson

The paper describes and discusses the use of stainless steels for leaching plants emphasising the duplex family, i.e., austenitic-ferritic stainless steels. This group has generally twice the proof strength of the more common 300-series austenitic grades, which implies possibilities to reduce the gauge at construction of pressure vessels and atmospheric tanks and vessels and thereby possibilities to reduce the weight. The duplex grades have also higher surface hardness resulting in better resistance to mechanical wear, i.e., abrasion and erosion corrosion. The lower contents of nickel and molybdenum imply lower cost and a more stable price considering the present market situation for these alloying elements. Corrosion data from laboratory and pilot plant tests, as well as examples of applications of duplex and highly alloyed austenitic grades, are presented. Cu2007 - Volume IV (Book 1) The John E. Dutrizac International Symposium on Copper Hydrometallurgy Edited by P.A. Riveros, D.G. Dixon, D.B. Dreisinger, M.J. Collins Toronto, Canada,

Jan 1, 2007

By C. L. Clark

EVERY user of steel should ask himself whether or not he is taking full advantage of the discoveries of the steel metallurgists during the last few years, or is merely buying grades that looked to be the best five or ten years ago for various specific purposes and have since proved perfectly satisfactory in his plant. If he has not kept abreast of the times, then it is probable that something better has been developed, or something just as good that costs less. Though this article will have to do with steel for high-temperature applications primarily, marked advances have been made in steels for other purposes as well.

Jan 1, 1940

By C. McCulloch

OPEN-PIT mining of coal is relatively a recent innovation; men still active in the industry can trace its development. Re- viewing the growth of operations from the original horse-drawn scrapers, through the various stages of power equipment to the huge strip- ping shovels of today, one also notes changes in the methods of what the coal man calls preparation at the face. We really should not call it face preparation because, in contrast to underground mining, a face does not exist in strip mining. Further, preparation of the coal for market at the loading point has already, in but a few years, become largely of historic interest only and modern mines as well as old mines recently modernized rely almost entirely on separate and elaborate preparation plants to produce marketable coal. This practice was not voluntarily adopted by the producer but was forced upon him by the inadequacy of previous

Jan 1, 1939

By D. W. Hoey

Eight years use of the ISA Process is reviewed and current design and operations described. Nodern Technology used for impurity control and disposal as well as the use of mechanised electrode handling equipment, cell voltage monitoring, cell insulation and an efficient contact bar system are described. Improvements achieved in terms of energy usage and plant productivity are detailed.

Jan 1, 1987

By John Pew

PRIOR to the development of the bulk-oil carrier, practically all transportation of oil was in barrels and in cans contained in wooden cases; the latter was known as case oil. In the year 1885, approximately two hundred million gallons of petroleum were exported from this country in barrels and about one and three-quarter millions in bulk; less than twelve years later, the shipment in barrels had decreased to nearly one and three-quarter million gallons, while the transport of bulk oil had increased to four hundred eighty-four million gallons. The first modern tanker, the "Glückauf," was built in England in 1886. Her hull, which was 300 ft. long, was divided into compartments by transverse bulk-heads, these compartments being divided by longitu-dinal center-line bulkheads extending throughout the oil spaces. There was a pump room forward of the boiler room, thus providing a cofferdam or safety space. Between the main and upper decks, a narrow trunk extended the full length of the' oil spaces, the trans-verse and longitudinal bulkheads being carried to the upper deck. This allowed for the expansion of the oil from a rise in temperature, and if the tank below the main deck was kept full, the danger of the oil moving with the roll and pitch of the vessel was considerably reduced. Spaces for the carriage of light oil were provided on each side of the vessel outboard of the expansion trunk, while water ballast was carried under the machinery compartments fore and aft. Although vessels previously had been built to carry oil next to the skin of the ship, it is claimed that the "Glückauf" was the first one constructed on the new principle outlined.

Jan 12, 1922

By J. de Villiers

Through the application of the Rietveld method, X-ray diffraction analysis has developed into a fully quantitative method for phase analysis. The Rietveld method itself has progressed from an unstable method that required constant operator intervention to a stable and robust method suited even for routine analysis. The method, however, requires a good initial calibration and periodic checks on its precision and accuracy. Several examples from minerals processing, pyrometallurgy, and materials science show the strengths and applicability of the method. The limitations and sources of error are also discussed.

Jan 1, 2007

By Sabine Verryn, Johan de Villiers

"Through the application of the Rietveld method, X-ray diffraction analysis has developed into a fully quantitative method for phase analysis. The Rietveld method itself has progressed from an unstable method that required constant operator intervention to a stable and robust method suited even for routine analysis. The method however, requires a good initial calibration and periodic checks on its precision and accuracy.Several examples from minerals processing, pyrometallurgy, and materials science show the strengths and applicability of the method. The limitations and sources of error are also discussed.1. IntroductionDiffraction of X-rays by matter has been used for more than 80 years, initially to elucidate the structure of crystalline matter, and to investigate the bonding between atoms. The first development of powder diffraction cameras and the later development of X-ray diffractometers saw the development of methods to identify phases and to try to quantify them in mixtures. A comprehensive database and search-match techniques have been developed over the ensuing years. Effective and accurate quantification had to wait for the so-called Rietveld' analysis where the total diffraction pattern is used and where the crystal structure data for the constituent phases are needed as input. Overlapping of diffraction peaks of different phases is handled without difficulty and reliable results can be obtained in spite of this occurrence.The development of methods for structure analysis from powder data has also progressed rapidly and more and more complex structures are being solved from first principles, i.e. without knowledge of unit cell or space group data. Because of the ease of use of the Rietveld method, it is finding increased application in metallurgy, especially in the quantification of phases of importance in minerals processing, in pyrometallurgical processes, and in materials characterization. This study will examine the principles of the Rietveld method, its application in metallurgy, and finally also the common pitfalls that need to be avoided.2. Rietve1d AnalysisAs the Rietveld method compares the experimental diffraction pattern with one calculated from known crystal structure data, the following data are needed:•,An XRD Pattern with as Iowa background as possible. This should have good resolution and high diffraction peak intensities. With modem X-ray detectors, this can be achieved in minutes rather than hours.•,Instrumental parameters such as goniometer radii and slit sizes are needed. These are the so-called ""Fundamental parameters"". They are used to calculate the shapes of the resultant diffraction peak profiles that are caused by the instrument. The parameters are used to correctly separate the instrumental effects on the diffraction pattern from the sample effects."

Jan 1, 2014

The past decade has seen revolutionary advances in communications and information-handling techniques which have been stimulated by "cold war" military requirements and by current programmes for probing into outer space. The tools used in exploration for petroleum and minerals have been improved significantly as a result of this new space age technology and even greater improvements are on the way.Two areas of technical activity have been particularly fruitful in enhancing the effectiveness of exploration methods. These are1. the development of new approaches, based on information theory,for extracting signal from noise more efficiently than before, and2. the use of high-speed digital computers for storing and processing all kinds of exploration information, not only geophysical but geological as well.In seismic prospecting, use of information theory has led to new techniques such as time-domain filtering, wave-number filtering and correlation methods which have made it possible to obtain usable reflection data from areas which were previously considered non reflective. Complex playback and other data processing facilities have been developed to apply these approaches.Digitization of geophysical data for handling by high-speed electronic computers facilitates many of these techniques for signal-to-noise improvement. Direct digital recording of seismic data in the field is now being d'one on an experimental basis in the United States, and this should become a standard procedure, at least for problem areas.The increased dynamic range, flexibility of filtering and other data processing, and convenience of information storage and retrieval make digital recording attractive in spite of its high cost compared to conventional analogue methods. Digital computers are being programmed to carry out many operations in data reduction and interpretation with substantial savings in time and cost over conventional procedures.INTROPUCTIONIn the years that have passed since the end of the Second World War, the western world has witnessed a technological revolution which may be as far reaching in its ultimate impqct as the Industrial Revolution of the last century.

Jan 1, 1963

By Hunter T. C

The wirebar furnacing and casting facility commissioned in 1970 at Copper Refineries Pty. Ltd. (CRL), Townsville, comprising a 70 tonne/ hour ASARCO shaft furnace and a Walker type casting wheel, contained several unique design features. Since commissioning, effort has been directed at improving metallurgical control of the casting process. This has resulted in the identification of optimum mould lubricant properties and the use of continuous on-line measurement of molten metal oxygen content. Casting defects such as cracks and surface porosity are readily explained and controlled using these techniques.

Jan 1, 1977

The large rotary blast hole drills for hole sizes of 250 to 375 mm in diameter have been utilized by large open pit metal and coal mines for production drilling all over the world. The design of such rotary drills is in most cases about two decades old and it has not been done much in order to apply a modern technology on rotary drilling. The most modern large rotary drill, Tamrock RI 10, consists of an advantageous rotary head with a squirrel cage AC motor controlled by a frequency converter, a beneficial mast structure with a possibility for inclined drilling, hydraulic driven, independent crawlers, and a modern ergonomic cabin to provide a comfortable working condition for the oper- ator. Several automatic features are available as options. The rig has been designed to be operated by one man only. With this modern rig the produc- tion rate can be increased and production cost kept on a low level.

Jan 1, 1989

By C. K. McArthur

THE subject of classification is so broad that this discussion is con-fined to what the author believes is of prime importance in connection with proper grinding and classification. The years passed have witnessed many noteworthy changes in fine grinding and classification, which have been accompanied by a readjust-ment of ore-dressing flowsheets for the preparation of better ground and/or sized products at an expenditure of less. power, steel and main-tenance than formerly. Nowhere in the industry is more being done in the way of experimental work to lower costs than in grinding circuits, because, at best, grinding costs are high. Recent years have indicated that, on the average, finer grinding has a real application. Without careful preparation of the process feed, no operation can be highly efficient or successful. In an earlier paper, the findings of an extensive survey at representa-tive concentrators were presented1. Also, in the year of 1935, a technical discussion was given by Dr. J. V. N. Dorr (Some Notes on Classification Trends in America) before the Chemical, Metallurgical and Mining Society of South Africa. In both papers mentioned, much has been said regarding flowsheets, grinding and classification. The author is very familiar with these papers, having had considerable to do with the actual operation of the flowsheets, as well as large mills and classifiers in the work described. Some data from the second paper have been included in the following discussion.

Jan 1, 1937

By C. K. McArthur

THE subject of classification is so broad that this discussion is confined to what the author believes is of prime importance in connection with proper grinding and classification. The years passed have witnessed many noteworthy changes in fine grinding and classification, which have been accompanied by a readjustment of ore-dressing flowsheets for the preparation of better ground and/or sized products at an expenditure of less power, steel and maintenance than formerly. Nowhere in the industry is more being done in the way of experimental work to lower costs than in grinding circuits, because, at best, grinding costs are high. Recent years have indicated that, on the average, finer grinding has a real application. Without careful preparation of the process feed, no operation can be highly efficient or successful. In an earlier paper, the findings of an extensive survey at representative concentrators were presented1. Also, in the year of 1935, a technical discussion was given by Dr. J. V. N. Dorr (Some Notes on Classification Trends in America) before the Chemical, Metallurgical and Mining Society of South Africa In both papers mentioned, much has been said regarding flowsheets, grinding and classification. The author is very familiar with these papers, having had considerable to do with the actual operation of the flowsheets, as well as large mills and classifiers in the work described. Some data from the second paper have been included in the following discussion. Circulating Load In this particular paper it seems advisable to deal with the classification phases of the work that to a major extent govern the success of any closed-circuit grinding unit. The question has often been asked in connection with a closed circuit: "What circulating-load ratio should be carried?" This is really an

Jan 1, 1937

By B. M. Hamilton

"IntroductionTHE PROCEDURE and technique for drilling holes has probably undergone as great a change during the past ten years as any one of the other operations conducted in hard-rock mining. During this period, we have seen a change from the heavy leyners and drifters to the light jackleg type of drill machine; from steels that were forged and hardened on the bit end to the inserted •carbide-tipped rod, from the necessity of providing special bit-end fabrication and beat treatment of shank steels to the simple grinding or turning of a plain section on a shank with no heat treatment required for bit attachment.When the steel maker was first called upon to manufacture a hollow drill rod, it was required that the steel must not only have sufficient strength and fatigue resistance to cope with the stresses of service, but also must be capable of being heat treated on the bit end to a high hardness for resistance to wear and abrasion . Little was known at that time about alloy steels and the beneficial effects to be gained from additions of chromium, nickel , and molybdenum. So it was that the plain 0.80 per cent carbon analysis was selected, since it had already proven to be a suitable grade for chisels, hammers, and other such shock tools. This grade has long endured the test of time and is still used in considerable tonnage today, particularly by the construction industry.As the metallurgist learned more about the influence of alloying elements, a new hollow drill analysis was placed on the market in the early 'thirties'."

Jan 1, 1954

By T. L. McCall

CHANGES in mining practices have evolved so quietly and unobtrusively that perhaps we scarcely appreciate how truly startling these changes are unless we cast our minds back so as to compare the past with the present. Such retrospection is, indeed, necessary when attempting to forecast the future, for it is only by carefully reviewing the past that we can hope to obtain an indication of what the future may hold in store. In this instance, it is not necessary to delve into the very early history of . coal mining, as our purpose will be served if the last three or four decades are reviewed, a period that is still fresh within the memory of many of us. These earlier days might be termed the selective period of mining, for at that time the coal resources of the world had not been tapped to anything like the extent they are at present and this condition enabled the owners and operators to exercise selective powers and only mine such seams of coal as could be most easily reached an worked at the lowest possible cost and which, at the same time, would suit the requirements of the market. Carrying this thought of selective mining still further, the miner, who was then an artisan skilled in all the branches of his calling, was able to select or discard such parts of the seam he was working that the co al sent out of the mine was acceptable to the consumer with just the barest minimum of preparation. Compare these conditions with the? conditions prevailing today, when coal seams of medium height, good quality, and readily accessible have been largely depleted and the operator has been compelled either to carry on his operations under much greater depths of cover where the coal is more costly to win, or else to work seams of lesser height or of poorer quality.

Jan 1, 1938

By C. K. Jankousky

The midwestern area referred to is the Illinois basin. The coals presently worked are mainly the No. 5 and No. 6 coal seams which vary in thickness from five to eleven feet. Present average of the more important No. 6 id about nine feet. The coal can vary considerably in toughness within the same mine with some coal perhaps rashing very easily and other coal being extremely difficult to cut. Top is generally well laminated shales with some fortunate areas having limestone roof. There are local areas with troublesome top of poorly laminated shales, shale with slickensides and shale intermingled with small partings and traces of coal. The bottoms are generally one to three feet of clay which softens readily on exposure to moisture. The mines are dry although some water is released and collects from rapid penetration of the seam by continuous miners. However, there are locally wet areas. Most of this material refers to mines of the Freeman Coal Mining Corporation. The mining operations written about are underground mines in southern and central Illinois.

Jan 1, 1962

By R. S. MACPHERRAN

TRENDS in the manufacture and use of cast iron are decidedly toward specialization, alloy iron, and increased strength. Old handbooks list only one kind of cast iron, with a tensile strength of 15,000 lb. Recent A.S.T.M. specifications show that from 50,000 to 60,000 lb. per sq. in. can now regularly he guaranteed. The use of alloy iron, heat-treated iron, and even nitrided cast iron, is rapidly growing and all kinds are improving in quality. Iron for operation at high temperature and corrosion-resisting irons have also been developed. Only a few years ago cast iron was "cast iron," but now there are almost as many kinds of cast iron as there are foundries making it

Jan 1, 1936

By Leo G. Martin, Richard G. Sherman

Recent sewer construction in downtown New Haven, CT required avoiding open trench methods because of near surface utilities and traffic congestion. The .73 km long alignment is in sands with the water table at the tunnel's springline. The designers felt the situation was ideal for an EPB machine; however, the tunneling method was left to the Contractor. The winning bid surprised everyone. The tunnel is being excavated by hand using an open face shield with breasting boards. The review of the bids indicates hand mining was approximately 1/2 the bid price of TBMs. Currently, excavation rates average 14 m/day with no excessive settlements.

Jan 1, 1993