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In his account of the Thackaringa sulphide ore, Lawrence (p. 92) reports the presence of valleriite as a minor accessory in chalcopyrite. He says that it is readily identified by its intensive anisotrophy and reflection pleochroism. He also gives (p. 87) the chemical formula as Cu8Fe4S7 Recent work by Evans et al. (1964), Chamberlain and Delabio (1965), and Schidlowski and Otteman (1966) suggests that most material identified as valleriite is, in fact, mackinawite. Mackinawite and valleriite are both extremely anisotropic and strongly reflection pleochroic, and so with fine-grained material it would be hard to distinguish them optically.Mackinawite, according to Evans et al. (p. D66) is a copper-free iron sulphide (PeS) with small quantities of nickel, whereas valleriite is considered to be a dimorph of chalcopyrite (CuPeS2 ). They found that mackinawite is much more widespread than valleriite, and, unlike the latter mineral, is commonly included in other sulphides, particularly chalcopyrite.Lawrence (p. 92) states that the valleriite inclusions are up to 0·01 mm long, so that an electron probe microanalysis should be quite feasible and provide a ready answer to this query.L. J. Lawrence: I thank Dr Townend for his comments on the occurrence of a valleriite-like mineral embedded in chalcopyrite from Thackaringa. The problem of distinguishing valleriite from mackina...

Jan 1, 1967

By T Mizuta, D Ishiyama

The Vienna Wood hydrothermal is hosted by mid-oceanic ridge type basalt in graben morphology and is located in the Central Manus Basin. The hydrothermal field is about 300 metres in diameter and consist of a sulphide mounds and tall huge death and active chimneys. From the three distinct ore types collected from the Vienna Wood site, the dominant ore minerals recognised are pyrite, wurtzite, sphalerite, chalcopyrite, Fe-oxide and gangue minerals of anhydrite, gypsum, barite and silica. The consistencies in the paragenetic sequence and in the spatial distribution of the sulfides across the three ore types suggest that similar hydrothermal process exist across active and death chimneys. Fluid inclusion studies reveal a homogenisation temperature of 190-260¦C and an average salinity of 5.1-5.4 wt per cent NaCl equiv. The pH of the hydrothermal fluid ranges from 4.2 to 6.1. Bulk chemical analyses indicate that the mineralisation in the Vienna Wood can be classified into the Zn-(Cu-Pb) type of mineralisation. The tenors of the ore and mineral assemblage resemble those of the Mid-oceanic ridge system and ancient ophiolite hosted massive sulphide deposits of Cyprus and Oman.

Jan 1, 2002

By Thomas Kuhn, Anna Wegorzewski

"INTRODUCTIONPolymetallic nodules from the Clarion and Clipperton Zone (CCZ) within the equatorial NE Pacific Ocean show high concentration of economic important strategic metals such as Ni, Cu, Co, Mo and Rare Earth Elements (REE). The content of those metals in nodules is depending on (i) the supply during individual growing periods, (ii) the environment conditions as well as (iii) on different manganese minerals, which occur in nodules. The incorporation of the metals can vary within the structure (incorporated into the structure / over vacancies of the structure) and this can be relevant for the further metallurgical treatment.Mineralogy of Mn-nodules from the CCZ and the incorporation of metalsManganese nodules consist of nm to µm thick layer growth structures (LGS) of different genetic origin (hydrogenetic/suboxic-diagenetic). Those LGS form due to the precipitation of Mn-and Fe-(oxy) hydroxide colloids from the oxygen rich near-bottom water and/or pore water (hydrogenetic growth; Halbach et al., 1988) or from suboxic (depleted in O2 <5µmol O2/l; Hein and Koschinsky 2013)) near-bottom water/pore water (suboxicdiagenetic growth; Halbach et al., 1988; Wegorzewski and Kuhn, 2014).In general, metals dissolved in seawater will be adsorbed and complexed on the oxide surfaces according to their different surface charge. The surface charge of the Mn-Fe (oxy) hydroxides depends on the pHzpc (zpc: zero point of charge). In seawater dissolved hydrated cations (Ni2+, Cu2+, Co2+) are adsorbed preferentially on the negatively charged Mn-oxide (MnO2 -) surface (pHzpc 2.8). In contrast, negatively and neutrally charged complexes (e.g., Ti(OH4); REE(CO3)2 -, MoO4 2-) are adsorbed on the surface of Fe-oxy hydroxide colloids (FeOOH+) which have a slightly positively charged surface (pHzpc 8.5; Stumm and Morgan, 1981; Koschinsky and Halbach 1995)."

Jan 1, 2017

By SH. Shahsavari, H. Akbari, M. Noaparast, M. Oliazadeh

Mejel valley zircon ore in Iran is located in north part of Iran and was sampled to evaluate its concentration. The aim of this project was to define the mineralogy of this zone and separating zircon from other minerals using gravity concentrators and magnetic separators. It is constituted of various valuable minerals, mainly zirconium, niobium-tantalum, titanium, rare earth elements particularly cerium-bearing minerals namely zircon, sphene and rare earth elements oxides. We used statistical method for designing of experiments. Yates method used for analysis of basic experiments results. The grade of zircon in primary sample was 1.1%. Different experiments were designed to optimize all required parameters. The final concentration with 75% zircon was produced and final recovery was 79%. Finally, lab-scale based flow sheet was prepared using experiments results.

Jan 1, 2005

By LeoJ. Miller

Exploration for an ore deposit commences with an outline of the regional ore controlling environment and is followed by the application of tools to focus the target area. One of the most essential focusing is the mapping of the mineral assemblages within the area of the ore. Key elements of mineralizing fluids, either epigenetic or syngenetic, enter into mineral assemblages that extend far beyond ore deposits. Portions of these assemblages may consist of new matrix minerals or alteration of previously existing minerals. Today, ore deposits are divided into genetic classes and each class is d8fined by a specific geological environment. Ore deposits within a given class are associated with a mineralogy, that is characteristic of the ore deposit class. So faithful is the mineral assemblage surrounding, or within an ore deposit, that recognition of the assemblage may be sufficient to define the class. Porphyry copper deposits have long been noted for their halos of alter-ation minerals. The outermost ring of chlorite, epidote and calcite extend thousands of feet away from the main ore zone. The mineral associated with porphyry copper deposits have been well documented by our distinguished speaker Paul Kerr, at Santa Rita (1), and Silver Bell&apos; (2), and by excellent papers from S. C. Creasey, 1959 (3), Sales, 1948 (4), T. S. Lovering, 1949 (5), our Co-Chairman John Guilbert, 1970 (6), and many others. Several recent porphyry copper mines have been discovered in recent years by utilizing the mineral assemblage model described by Lowell and Guilbert, 1970 (6). Dave Lowell applied his own model of mineral halos for the discovery of Kalamazoo at San Manuel (7), Arizona, and Casa Grande West, Arizona. The purpose of this paper is to outline the application of mineralogy for discoveries of deposits other than porphyry copper mines and in particular, to ore discoveries in which mineralogy has played a key roll.

Jan 1, 1981

By Barns K. E, Munro P. D, Brindley S. K

Ernest Henry Mining Pty Ltd started production in August 1997. The Ernest Henry orebody consists of two distinct parts, a complex supergene ore zone overlying a primary ore zone. The economic copper minerals in the supergene ore are chalcocite

Jan 1, 1998

By S Strohmayr, R Harvey, A See

Ernest Henry Mining Pty Ltd started production in August 1997. The Ernest Henry orebody consists of two distinct parts, a complex supergene ore zone overlying a primary ore zone. The economic copper minerals in the supergene ore were chalcocite, bornite, secondary chalcopyrite and native copper while the primary zone has only chalcopyrite. The variability of the supergene zone made concentrator operation difficult and predicting metallurgical performance using mineralogy essential to establish the capabilities of the concentrator. A paper presented at the 1998 Mine to Mill Conference entitled Mineralogy Controlling Metallurgy at Ernest Henry Mining (Barnes, Strohmayr, Brindley and Munro, 1998) presented the testwork and initial plant surveys that showed that the mineralogy of the ore controls the metallurgy of the concentrator. This paper presents the data obtained from the subsequent years of operation treating both the supergene and primary ore types. A review of the actual supergene mineral distribution in feed and subsequent recoveries compared to those predicted as part of the flowsheet design is also presented.

Jan 1, 2003

By R. B. August, J. N. Dunlevey

The Quaternary Age aeolian dune sands of the Sibaya Formation on the northern KwaZulu-Natal coast are well known for their heavy mineral content. Although ilmenite, rutile and zircon are the economically important members of the heavy mineral suite, many other nonsilicate minerals such as monazite, xenotime, chromite, magnetite, and spinel that are normally considered to be eitherun common or even rare are also present and these sands provide a unique opportunity to study such complex minerals. Monazite is the general term used for a complex series of rare earth phosphates dominated by lanthanum, cerium and neodymium with monazite-Ce, monazite-La and monazite-Nd recognized as distinct end members of the solid solution series. In addition to the elements indicated by the simplified formulae (LaCeNd) PO4monazite can also accept significant quantities of other elements from the lanthanide and actinide series (Pr, Pm, Sm, Eu, Gd, Tb, Dy,Ho, Er, Tm, Yb, Th, Pa, U, Np). The monazite grains in the Sibaya Formation occur as both composite grains, composed of two or more distinct mineral phases, and homogeneous grains. The net physical properties of the composite grains, and their response to magnetic and electrostatic separation methods are related to size and composition of non-monazite component. However, the homogeneous monazite grains also display significant variation in their physical properties related to their chemical composition.

Jan 1, 2003

By Ann M. Hagni

The mineralogical, chemical, microtextural, and particle size character of electric arc furnace (EAF) dusts are being studied by reflected light microscopy, scanning electron microscope-energy dispersive spectroscopic analysis (SEM-EDS) and electron probe microanalysis (EPMA). The dusts consist predominantly of metallic iron, iron oxide, and calcium-iron-manganese silicate phases, together with smaller amounts of iron-manganese-zinc-calcium, iron-calcium-zinc-manganese, and calcium-iron-manganese silicates. The samples vary in their zinc contents. Chlorine occurs in phases containing iron, lead, zinc, manganese, and calcium. The dust particles range greatly in size from 1 to more than 300 ~m, but most particles are about 1 to 6 ~m. Larger particles. about 20-50 um across. also are present. They are predominantly spherical in shape, but some are cenospheres, and others are more angular particles, some of which are broken spheres and cenospheres. Their internal microtextures exhibit evidence of liquid immiscibility, exsolution, skeletal crystal growth, and oxidation react i on rims. Because EAF dusts have been classified by EPA as hazardous wastes, there is heightened interest in the treatment of these dusts to render them non-hazardous. The mineralogy of products of pyrometallurgical treatment of EAF dusts by flash furnace and pyrohydrolysis are currently under study.

Jan 1, 1991

Crystalline glass defects (usually referred to as stones) come in a wide range of compositions and from a variety of sources. Complete identification requires a determination of the mineral phases present and their textural arrangement. Until the source has been determined, no remedial action can be taken to eliminate the problem.

Jan 1, 1989

By J Stojanovic, V Kasic

Gold-bearing polymetallic sulfide deposits are common in Serbia, and mostly occur in the Karpato-Balkan and, to a lesser extent, the Serbo-Macedonian metallogenic province. These deposits û Coka Marin (Majdanpek), Grabova Reka (Blagojev Kamen), Lece (Medvedja) and Veliki Cip (Boranja) û are dominated by Cu and/or Pb-Zn mineralisation that contains a variety of Pb, Zn, Cu and Fe (¦ Sb, As, Bi) sulfides and sulfosalts, as well as native elements. Gangue minerals are composed of quartz, carbonates and rare silicates and barite. Based on their gold content these deposits can be divided in three groups:1. Polymetallic deposits with a high gold content (&gt;1 g/t).2. Polymetallic deposits with an intermediate gold content (0.1 to 1 g/t), and3. Polymetallic deposits with a low gold content (&lt;0.1 g/t). Gold occurs as native gold or as an alloy with silver. Native gold ranges in size from 5 to 20 ¦m, with a few rare grains over 100 ¦m, as isolated grains or as microveins (in the first group of deposits). Its distribution within the deposit in uneven. Native gold in the second group is smaller in size (1 - 5 ¦m, rarely 20 ¦m), where it is uniformly distributed in a quartz-silicate matrix. The third group is of no economical importance. The subject of research has been the first group of polymetallic deposits.

Jan 1, 2008

By K Knorr, S Birch

The mineralogy of new certified-reference-materials (CRM) for X-ray fluorescence from Western Australia (ASCRM 030 to 035) was analysed by X-ray diffraction using the BRUKER energy dispersive one-dimensional detector LYNXEYE-XE. The samples were studied using standard-less quantitative phase analysis, based on the Rietveld method. This method delivers the relative amount of crystalline phases. All materials were found to be high-grade iron ore predominantly consisting of hematite and goethite and very low amounts of magnetite. In addition, the gangue mineralogy was characterised. It consists of low-per cent amounts of carbonate (siderite/calcite), quartz, kaolinite, chlorite and gibbsite.Furthermore, all samples were analysed with the external standard method. This is an elegant way to probe for amorphous content without adding an internal standard. All six samples were found to contain up to 16 per cent amorphous or nano-crystalline material.CITATION:Knorr, K and Birch, S, 2013. Mineralogy of new Australian x-ray fluorescence standards, in Proceedings Iron Ore 2013 , pp 269-274 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 12, 2013

By R. L. Bleifuss

The object of this study was to evaluate the oxidized taconites of the western Mesabi iron range and to establish a correlation between the various basic taconite types and their concentratability. This study was made at the Mines Experiment Station of the University of Minnesota under the sponsorship of the Great Northern Railway Company. The initial work included a study of the original mineralogical and stratigraphic facies of the fresh taconite and traced the oxidation and leaching patterns developed during the conversion of this material to oxidized taconite. Subsequent studies have extended this work to include the semi- taconites and also the wash and heavy media ore types widely developed in the area. Each basic, original mineralogical facies or taconite type produces during alteration an equivalent secondary oxidized facies which has a unique mineralogical composition and texture. These control the concentratability of the oxidized taconites. Actually the influence of the original mineralogical composition of the iron formation extends even further and determines whether the most likely product of oxidation and leaching will be a wash ore or a heavy media ore and even to the direct shipping ores where the ratio of hematite to goethite is largely determined by the original taconite type.

Jan 1, 1964

By B. Amero, W. Petruk, D. R. Owens, D. R. Morris

Samples taken at different heights in the lead blast furnace of Brunswick Mining and Smelting corporation were studied to determine the phases present in order to interpret the reactions In the furnace. The main phases in the blast furnace feed are Pb3Ca2S13011, Zn ferrite (ZnFe204), and hardystonite (Ca2ZnSi207); rninor ones include lead and a Pb silicate. The temperature in the furnace varies from about 300°C at 4.2 m above the tuyeres to 1150°C at 1.1 m. There is no evidence of reactions in samples from points cooler than 800°C. Some reaction occurs between 950° and llOO°C and the lead sinter is nearly decomposed at about 1150°C. The first evidence of reaction was the decomposition of Pb silicate to lead and S102. At higher temperatures the Pb Ca2Si3011 decomposed to form lead and hardystonite (Ca2ZnS120rf. The Zn required for hardystonite was derived from the Zn ferrite which apparently re-equilibrated to a new Zn ferrite with less Zn. The decomposed sinter consists essentially of lead, hardystonite, wustite and a Zn ferrite with a low Zn content.

Jan 1, 1984

By D. R. Hudson, M. J. Donaldson

"Study of gravity concentrates from the gold-recovery circuit of the Kambalda nickel mill has enabled an assessment to be made of the nature, relative abundance and compositional variability of platinum group element (PGE) minerals and other associated heavy minerals that are present in the Kambalda nickel deposits. The major platinum minerals are sperrylite, PtAs2, and nioncheite, (Pt. Pd, Ni)(Te, Bi)2, and the major palladium minerals are sudburvite, (Pd, Pt, Ni)(Sb, Te, Bi), stibiopalladinite, Pd6Sb2, and palladoarsenide, Pd2 (As, Sb), together with a palladium antimonide and a palladium arsenide that have not been fully characterized. Palladian melonites, which contain up to 10 wt% Pd, and palladian nickeline are also important PGE hosts. Sperrylite and sudburyite are by far the most abundant discrete minerals in the gravity concentrates.Gold occurs as argentian, cuprian and nickeloan—cuprian gold, and as the tellurides calaverite, petzite and auriferous hessite. Silver is present in petzite, hessite and volynskite. Other rare phases contained in the gravity concentrates include native bismuth, altaite, frohbergite, breithauptite, gersdorffite, parkerite, scheelite, tantalite, cassiterite, rutile, bunsenite, gahnite, barite and uvarovite.Descriptions of in-situ occurrences of PGE minerals at Kambalda are rare. Michenerite, PdBiTe, and testibiopalladite, PdSbTe, have been described from a telluride-rich quartz-carbonate vein that intersects massive sulphide ore in Lunnon Shoot. Moncheite has been observed in chalcopyrite-rich stringers, and sudburyite occurs as inclusions in nickeline in a quartz- carbonate veinlet. No discrete PGE minerals have been found within the massive and matrix ore zones in the Kambalda ore- shoots, and the geochemical distribution of PGE suggests that the formation of discrete PGE phases may be related to post- magmatic processes—in particular, metamorphic segregation of sulphides, and the interaction of the ore sulphides, containing PGE in solid solution, with younger hydrothermal fluids. This has led to local redistribution of the PGE, with concentration in footwall stringers and veins, and in reaction zones."

Jan 1, 1984

By Mayumy Amparo Cabrera-Ramírez

Polymetallic nodules are a widespread resource in the Pacific Ocean, particularly in the areas of Clarion-Clipperton (Cronan, 2000). The most abundant mineral phases are formed by iron and manganese oxides, with minor elements such as nickel, copper, cobalt, molybdenum and rare earths elements (Cronan, 1977; Cronan and Moorby, 1981; Iyer and Sharma, 1990; Mangini et al. 1990; Banerjee et al. 1991). In the Clarion-Clipperton Zone (CCZ), several authors mention that there are three main mineral species of manganese oxides, which have been recognized and which are associated with different processes of formation: todorokita (Mn2+, Ca, Mg) Mn34+ O7. H2), vernadite dMnO and birnessite enriched in Fe and (Na, Ca) 0.5 (Mn4+, Mn3+) 2O4. 1.5 H2O. In nodules of hydrothermal origin have been found todorokite, birnessite, vernadite, goethite and pyrolusite. Although there are many oxides and hydroxides of manganese and iron in amorphous and microcrystalline phases that make up the bulk of the nodule (Frondel et al. 1960; Cronan 1977; Dymond 1981; Calvert and Piper, 1984; Aplin and Cronan, 1985; Martin and Lallier, 1993; Achurra et al. 2009), identifying specific mineral phases is difficult due to the intergrowth of different phases and associated detrital material.

Jan 1, 2011

By Mayumy Amparo Cabrera-Ramírez

Polymetallic nodules are a widespread resource in the Pacific Ocean, particularly in the areas of Clarion-Clipperton (Cronan, 2000). The most abundant mineral phases are forme d by iron and manganese oxides, with minor elements such as nickel, copper, cobalt, molybdenum and rare earths elements (Cronan, 1977; Cronan and Moorby, 1981; Iyer and Sharma, 1990; Mangini et al. 1990; Banerjee et al. 1991). In the Clarion-Clipperton Zone (CCZ), several authors mention that there are three main mineral species of manganese oxides, which have been recognized and which are associated with different processes of formation: todorokita (Mn2+, Ca, Mg) Mn3 4+ O7. H2), vernadite dMnO and birnessite enriched in Fe and (Na, Ca) 0.5 (Mn4+, Mn3+) 2O4. 1.5 H2O. In nodules of hydrothermal origin have been found todorokite, birnessite, vernadite, goethite and pyrolusite. Although there are many oxides and hydroxides of manganese and iron in amorphous and microcrystalline phases that make up the bulk of the nodule (Frondel et al. 1960; Cronan 1977; Dymond 1981; Calvert and Piper, 1984; Aplin and Cronan, 1985; Martin and Lallier, 1993; Achurra et al. 2009), identifying specific mineral phases is difficult due to the intergrowth of different phases and associated detrital material.

Sep 14, 2011

By P. A. Botha

Most sinter producers prefer to use a range of iron ores with the aim to optimize their sinter blends. ISCOR is however limited to the use of ore from two deposits, namely Sishen and Thabazimbi. Only sinter produced from Sishen ore is described in this report. The Sishen iron ore deposit provides high-grade hematite ore with a mean iron content of 65 per cent. Three major ore types are developed: massive, laminated and conglomeratic. The main ore mineral is hematite with minor to trace amounts of quartz, mica, phosphates and, in places, carbonates. A sinter product is characterized by its mineralogical composition and metallurgical properties. The production rate also plays an important role in the economic evaluation of sinter quality. Sinter-pot tests were conducted with varying basicities, given as the ratio of CaO to SiO:< and coke content. The results of these tests were characterized by mineralogical and metallurgical methods. Basicity of a sinter mix directly influences the mineralogical composition and metallurgical properties. The content of calcium ferrite and calcium silicate increases with increasing basicity, thereby increasing the reducibility and cold strength of the sinter product. Experiments performed during this study provided a model for the optimization of the sinter mix with respect to its mineralogical and metallurgical parameters.

Jan 1, 1991

By U. Lauwers

The influence of different waste materials in sinter blends on the quality and mineralogical composition of a sinter is described. As a result of partial preservation of the original textures of waste materials in the final product the degree of assimilation of the original material in the sinter product can be ascertained. Recycling of waste materials such as dolo char , arc-furnace slag, scrap fmes, mill scale and BOF-mud via the sintering process a saving on costs of raw materials such as flux and fuels, and a reduction on pollution can be achieved. A comparison of a typical sinter with a sinter produced through the utilization of waste materials showed a distinct correlation between certain types of waste material and some metallurgical properties. Dolochar in a sinter blend acts as part of the fuel and flux that are normally added to a sinter mix. Generally dolochar improves the quality of the sinter and decreases the consumption of coke. Other waste materials adversely influence the quality of the sinter. The glass and calcium ferrite content of a sinter when dolochar is used in the blend is similar to that of a sinter produced with only coke as a fuel in the sinter mix. The glass content is lower and the calcium ferrite content is higher, in a sinter produced from dolo char in the blend compared to a sinter produced with additions of other waste materials. Changes in the mineralogical composition are related directly to the metallurgical properties of the sinter product.

Jan 1, 1991

By Lancucki C. J, Nickson N. M

X-ray diffraction and differential thermal methods were used to determine the mineralogy of some clays used by the heavy clay industry in the Adelaide area. A detailed analysis was made of the mineralogy and particle size distribution of eighteen samples from beds in two pits in the Recent sediments in the Adelaide plains, of six white clays developed from the weathering of the Adelaide series of sediments, and of four Recent alluvial clays from a pit in the Mount Lofty ranges south of Adelaide. Structural clay products in the Adelaide area are manufactured from mixtures of these clays, so the mineralogy and particle size distribution was determined of eighteen clay mixtures used to make red bricks, cream bricks, facing bricks, pipes and tiles.Knowledge of this mineralogy is important in understanding the ceramic behaviour of the clays.INTRODUCTIONIn this investigation an account is given of the clay mineralogy and particle size distribution of some ceramic clays from the Adelaide area. The clays are used in the manufacture of structura,l clay products and the results to &apos;be described are part of an overall &apos;plan of study covering the heavy industrial clays and shales of Australia. Previous work has been published (Cole and Carthew, 1953; Ferguson, 1954; Ferguson and Hosking, 1955; Cole and Nielsen, 1958/59).In this work no attempt has been made to examine clays from all pits engaged in supplying materials for the structural clay industry. However, in 1954 the senior author collected detailed samples from two pits working in Recent alluvial clays in the Allenby&#183;Gardens and Beverley areas near...

Jan 1, 1963