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By F. -U. Schneider, F. Wellenkamp

Based on previous investigations of ultrafine comminution in planetary ball mills, a new centrifugal mill has been developed which permits similar high stress conditions. Because this new type of mill is equipped with an immobile chamber, devices for measuring energy, for cooling the milling vessel, as well as, in continuous operation, for material feed and discharge can be more easily attached than to planetary ball mills. Observations of particle behaviour have shown that, in the case of dry grinding, most of the material is found on the mill walls even after short grinding times. Due to the fact that energy dissipation takes place mainly in the zone near the wall, a grinding system which reduces the amount of ball filling required is at an advantage.

Jan 1, 1995

By J. Drzymala, K. L. Wolters, T. Chmielewski, T. D. Wheelock, D. H. Birlingmair

Microflotation tests were conducted with a modified Hallimond tube equipped with a fritted glass disk and magnetic stirrer to determine whether the results would support an equation that predicts a linear relationship between particle size and the reciprocal of particle density in water for a specified flotation recovery in a given time. Data obtained with the tube for either hydrophilic or hydrophobic solids fit the equation satisfactorily. It was also shown that the natural flotability of molybdenite is somewhat less than that of elemental sulphur and that sodium dithionite is a good depressant for sulphurised pyrite. In addition, it was found that the untreated pyrite and galena used in the study were hydrophilic and did not float by particle-bubble attachment.

Jan 4, 1992

By B Oostendorp, R van der Merwe, P

In order to assess whether polysaccharide depressants are strongly or weakly and reversibly bound to the surface of talc, a series of experiments was conducted on New York talc in which the floatability of the talc in a microflotation cell was determined. The talc was conditioned in solutions of carboxymethyl cellulose (CMC) or guar gum in 10-2 ionic strength Ca(NO3)2 or Mg(NO3)2. The talc was then washed with four successive aliquots of water, or cation solution, to try to remove the polymer and the flotation response of the talc was assessed. CMCs of different charge (DS) were used to assess the effect of charge on the strength of bonding. The results show that CMC and guar gum could be removed to a large extent from the talc surface by washing with water (the floatability was restored), however very little could be removed from the surface by washing with cation solution. The higher charge CMC was easier to remove from the talc planes in the absence of cations than the lower charge CMC. Thus CMC bonding to talc has been shown to be irreversible or very slowly reversible only if cations are present, implying that cations are necessary to keep the polymer bound to the surface of the planes to effect depression. The presence of ions in solution also had the effect of maintaining surface coverage of the talc by guar gum.

Jan 1, 2005

Microfluidic Solvent Extraction for Mineral Processing of Copper Leach Solutions

Sep 13, 2010

By Elisabeth Kolar, Rik Catthoor, Frederik H. Kriel, Rossen Sedev, Gareth Hatch, Army Research Laboratory, Craig Priest, Scott Middlemas

"This paper reports solvent extraction of rare earth elements (REEs) carried out using a microfluidic device and considers the REE loading limit of the organic phase under laminar flow. The microfluidic device contacts aqueous and organic phase streams for a precisely defined contact time (subsecond resolution) and then separates them for offline analysis. Experiments are reported examining the effect of contact time on extraction. We focus on three REEs: one ‘light’ (Nd), one ‘mid’ (Dy), and one ‘heavy’ (Yb) REE, which are extracted using Cyanex® 572. It appears that loading limits may be locally exceeded in the organic phase near to the liquid-liquid interface, where third phase deposits are observed. Third phase formation was also observed close to the liquid-liquid interface in two-dimensional confinement, showing similar third phase adsorption on glass plates. It is also shown that, under microfluidic flow, a typical first ‘split’ between heavy REEs and light REEs can be carried out without exceeding loading limits.INTRODUCTIONMicrofluidic solvent extraction has emerged as a useful tool for studying extraction of metals in a mineral processing context (Ciceri, Mason, Harvie, Perera, & Stevens, 2013; Ciceri, Perera, & Stevens, 2011; Kriel et al., 2015; Mason, Ciceri, Harvie, Perera, & Stevens, 2013; Priest, Zhou, Klink, Sedev, & Ralston, 2012; Priest et al., 2011). The main advantages are the extremely well-defined and tunable flow behaviour, large surface-to-volume ratios, short contact times, and minimisation of sample and reagent amounts. Two main flow configurations have been studied to date: droplet-based and co-flowing streambased extraction. In the former, droplets are formed at a microchannel junction (usually a T-junction or flow-focusing junction) and flow downstream as plugs or ‘free’ droplets. In our case, stream-based extraction, the chip is a plate (often glass) with embedded microchannels (i.e. with cross-sections of tens of micrometres) that carry the aqueous and organic phases in contact without forming droplets. Thus, these chips play the role of a mixer in a conventional mixer-settler and phase separation takes place by branching the streams or collection in a vessel at the chip outlet. Stream-based extraction requires stable streams that are usually supported by a particular channel geometry (e.g. guide structure or small ‘pillars’) or surface chemistry, and flow parallel bounded by the liquid-liquid interface(Aota, Nonaka, Hibara, & Kitamori, 2006; Hibara et al., 2005; Hibara et al., 2002). Phases are disengaged downstream at a Y-junction, which is a qualitative difference between microfluidic and bulk extractions."

Jan 1, 2016

By Shaohua Ju, Feng Jiang, Jian Jian, Hongying Xia, Jinhui Peng, Libo Zhang

Microfluidic solvent extraction of zinc from sulfate solution was studied using di-2-ethyl hexyl phosphoric acid, D2EHPA, in sulfonated kerosene as diluent. The influence of different parameters on the extraction of zinc, such as flow rate, temperature, flow rate ratio, extraction concentration, and saponification ratio of extractant were investigated and the conventional and micro fluidic extraction were compared. Under the optimized conditions, micro fluidic extraction efficiency of zinc is up to 97.1%. It is better than that conventional extraction. Therefore, microfluidic solvent extraction can achieve high efficiency and low consumption of extraction process.

Mar 1, 2018

By Norman Pilling

The micrographic analysis of silicon steels is possible if a dilute solution of nitric acid and methyl alcohol in nitrobenzol is used. The action of this reagent differs from that of sodium picrate in that there is no persistent deep-seated staining and the solution is used cold. THE technical difficulties hampering the metallographic analysis of silicon steels are chiefly the result of the extreme corrodibility of these alloys. The addition of silicon to iron in increasing quantities, up to about 6 per cent., rapidly increases the susceptibility of the alloy to chemical attack, not only in acid solution, but in water. This renders the preparation of metallographic sections very difficult, because of a non-selective attack upon the finely polished surface by the water used as a lubricant in polishing. This water attack masks the true structural details revealed by suitable etching reagents. It is thus necessary to use alcohol as a polishing lubricant in the last stages of preparation and to avoid all etching reagents having an aqueous base. A specific reagent for the identification of iron carbide in ferrous alloys, and the one hitherto used almost exclusively by metallurgists, is an alkaline aqueous solution of sodium picrate, which stains this constituent selectively. Its application to silicon steels has not proved successful, as its distinctive selective action is more or less completely hidden by the general attack of the aqueous solvent on the silico-ferrite, greatly accentuated by the fact that this reagent must be used at its boiling temperature (105° C.). Thus, a powerful metallographic aid to the study of the higher silicon alloys, such as transformer steels, is lost. A new reagent has been developed for the purpose of overcoming this difficulty. It is with some hesitation that the list of etching reagents, already overburdened, is increased, but the properties of this new reagent are advantageous in several ways and a definite field for it may be found in the metallography of ferrous alloys.

Jan 1, 1924

By R. M. Brick, R. G. Treuting

DESPITE the basic importance of slip in the plastic deformation of metals, and the considerable experimental investigation, thought, and speculation that have been devoted to the fundamental nature of these processes, surprisingly few data have been reported regarding the microscopic appear- [ ] ance and distribution of slip lines,[$] the external manifestation of the slip process. Photographs hitherto reproduced in the literature are in general at low or unspecified magnifications with no correlation to the prior shear. A single-crystal cylindrical tensile specimen of alpha brass about ½ in. in diameter, one of many previously prepared by H. L. Burghoff,1 was available for study. A plane about 3/16 in. wide, parallel to the specimen axis and normal to the plane containing the slip direction and the specimen axis, was ground and metallographically polished along the entire 5-in. gauge length. Heavy etching produced a surface free of both scratches and flow. The specimen was strained in tension until slip markings first became visible on the polished surface (Figs. I and 2). Restressing the crystal caused additional markings to appear at an initially lower [ ] stress than previously was required. Stretching the specimen to produce a dense concentration of slip lines caused such variations in level in the polished surface (normal to the slip direction) that microscopic study at higher magnifications became impossible. After annealing 15 hr. at 850°C., the specimen recrystallized to form two grains with a boundary approximately normal to the specimen axis and about midway along its length. Each was X-rayed, and two planes were again polished along the length of the specimen, in this case each parallel to the slip direction in one of the two crystals. A light longitudinal scratch parallel to the specimen axis was drawn down the center of each plane. A Huggenberger extensometer was attached to the crystal A, whose slip plane would have the higher resolved shear stress of the two, and the specimen was again strained in tension.

Jan 1, 1941

By Yonghua Li, Fanling Meng, Weitao Zheng, Xiaodong Wang

The NiTi thin films were deposited onto copper substrates by magnetron sputtering. Tensile tests were carried out on CSS-44100 electron universal test-machine. X-ray diffraction profile Fourier analysis method has been used to study the mechanical properties of deformation NiTi thin films. The surface micrographs of the NiTi thin film were obtained using scanning electron microscopy (SEM). It has been found that the dislocation density and the deformation storage energy density increased with elongation increased. Microhardness was calculated from the dislocation data. The results showed that the microhardness values were not in a good agreement between calculated values and measured values. The oxide layer on the surface of NiTi thin film affects the measured values of microhardness. The Vickers hardness measured values are larger than the calculated values. The experimental results showed that a series of parallel cracks grew in a concerted fashion across the thin film and the cracks were equally spaced.

Jan 1, 2015

By L. L. Swift

AT the present time there are four base metals being used for automotive bearing alloys. Of course there are numerous variations in the amounts of alloying elements added to each base metal and nearly all of these alloys have the conventional, if not classical, duplex structure; that is, they are composed of a hard constituent embedded in a soft matrix. The well-known theory is that the former will wear well, while the latter will be plastic enough to allow the bearing to be broken in and conform to the contours of the shaft. The requirements of the modern bearing have been most aptly described by W. M. Corse: In order to meet the engineering demands of today a good bearing metal must be able to carry the weight of the shaft and stand up under steady or suddenly applied loads, or even blows in some types of service. A certain amount of plasticity is desired to compensate for minute irregularities in the shaft or bearing surface, and to permit yielding, thereby avoiding dangerous stresses in bearing and shaft and preventing overheating and rapid wear of parts. Less plasticity is required in a bearing metal if the surfaces of bearings and journals are machined accurately, aligned, and kept in alignment. It is desirable, of course, that a bearing metal have a low coefficient of friction. Under most operating conditions the friction depends on the unit pressure of the bearing, the speed, the temperature, and the properties of the lubricant. A good bearing metal must have a low rate of wear to reduce the necessity for frequent replacements, and adjustment of the bearings. It must wear more rapidly, however, than the journal or shaft running on it, because replacement of the journal or shaft is more difficult and costly than replacement of the hearing., The hardness of, the bearing alloy is a property closely related to several of the foregoing. With a duplex microstructure, the measurement of hardness with any of the usual commercial devices means little. The Bierbaum method of measuring the hardness of the individual constituents was developed to, fill this need. MICROCHARACTER The Bierbaum microcharacter2.3 measures the scratch-hardness of a solid by pulling a weighted diamond point over the surface. The diamond point is ground. so that it is the corner of a cube, and mounted

Jan 1, 1938

By L. L. Swift

AT the present time there are four base metals being used for automo-tive bearing alloys. Of course there are numerous variations in the amounts of alloying elements added to each base metal and nearly all of these alloys have the conventional, if not classical duplex structure; that is, they are composed of a hard constituent embedded in a soft matrix. The well-known theory is that the former will wear well, while the latter will be plastic enough to allow the bearing to be broken in and conform to the contours of the shaft. The requirements of the modern bearing have been most aptly described by W. M. Corse: In order to meet the engineering demands of today a good bearing metal must be able to carry the weight of the shaft and stand up under steady or suddenly applied loads, or even blows in some types of service. A certain amount of plasticity is desired to compensate for minute irregularities in the shaft or bearing surface, and to permit yielding, thereby avoiding dangerous stresses in bearing and shaft and pre-venting overheating and rapid wear of parts. Less plasticity is required in a bearing metal if the surfaces of bearings and journals are machined accurately, aligned, and kept in alignment. It is desirable, of course, that a bearing metal have a low coeffi-cient of friction. Under most operating conditions the friction depends on the unit pressure of the bearing, the speed, the temperature, and the properties of the lubricant. A good bearing metal must have a low rate of wear to reduce the necessity for frequent replacements, and adjustment of the bearings. It must wear more rapidly, however, than the journal or shaft running on it, because replacement of the journal or shaft is more difficult and costly than replacement of the bearing.1 The hardness of the bearing alloy is a property closely related to several of the foregoing. With a duplex microstructure, the measure-ment of hardness with any of the usual commercial devices means little. The Bierbaum method of measuring the hardness of the individual constituents was developed to fill this need.

Jan 1, 1938

By S Hapugoda, J R. Manuel, M J. Peterson

Microindentation testing using the square–pyramid–shaped Vickers indenter is a well-established technique to determine the microhardness of minerals and materials. However there is a paucity of published microhardness data from Fe ore samples. It is acknowledged that an iron ore’s particle mineralogy and texture is critical to its processing properties, and it is therefore considered that the microhardness of different mineralogical/textural types may also relate to these properties. Mineral microhardness potentially provides inputs to the modelling of breakage characteristics during comminution, as well as the relationship between mineral chemistry and microhardness, and mineral microporosity and microhardness. Microhardness can be determined as single crystal microhardness, for more coarsely microcrystalline samples, or as ‘aggregate microhardness’ for cryptocrystalline or finely microcrystalline samples.Variations in the texture and mineral chemistry of common Fe ore minerals (eg martite and microplaty hematite, ochreous and vitreous goethite etc) are well established and this study provides microhardness data on different textural forms of Fe (oxyhydr)oxides from a variety of different Fe ore deposits. The data indicated that in general, the mineral grain size, microporosity and texture were the main influences on Fe (oxyhydr)oxide microhardness. There were no apparent systematic variations between microhardness and minor element mineral chemistry, with the possible exception of Al content in goethite (for goethites with Al content >0.5 wt per cent), and for goethite total element contents >90 wt per cent (determined by electron probe microanalysis, EPMA). Higher Al concentrations and lower total element concentrations in goethite EPMA analyses correlated with lower goethite microhardness. Microporosity and grain size were more important than texture to hematite microhardness. Different textural forms of dense hematite (eg martite, recrystallised interlocking hematite and specular hematite) with similar grain size exhibited comparable microhardness. Microhardness values for hematite and hydrohematite with little or no evident microporosity were also similar, whereas more porous forms of martite, microplaty hematite or hydrohematite exhibited lower microhardness.CITATION:Peterson, M J, Manuel, J R and Hapugoda, S, 2017. Microhardness testing of hematite-goethite Fe ores – implications for their textural characterisation and geometallurgy, in Proceedings Iron Ore 2017, pp 319–330 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By T. S. Li, D. Ilievski, I. Livk

Micromixing of the fluid and the particulate phases in a continuous gibbsite precipitator was investigated for three different micromixing states, namely maximum mixedness (MM), complete segregation (CS), and maximum mixedness of the fluid but complete segregation of the particulates (MMF-CSP). The influence of the micromixing on continuous precipitation of gibbsite was studied at different precipitation conditions via simulation. Three different cases were considered with respect to the precipitation kinetics: (1) gibbsite secondary nucleation is favoured with slow crystal growth and agglomeration rates; (2) gibbsite crystal agglomeration and growth are dominant mechanisms with secondary nucleation suppressed; and (3) gibbsite crystal growth is the only relevant phenomenon. Simulation results for the cases (1) and (3) showed that the crystalline products for both the MM and MMF-CSP micromixing states were very similar, but the product obtained from the CS micromixing state was considerably different. This indicates that at those precipitation conditions the fluid micomixing has the dominant effect on the product properties, and the particulates micromixing effect is insignificant. However, when operated under the conditions of fast crystal growth and agglomeration kinetics, i.e. case (2), both the fluid and the particulates micromixing were found to affect the precipitation process, resulting in a significantly different product. Computational Analysis in Hydrometallurgy 35th Annual Hydrometallurgy Meeting held in conjunction with the 44th Annual Conference of Metallurgists ofCIM Calgary, Alberta, Canada Edited by

Jan 1, 2005

By S. Seetharaman

The present paper presents. the concept of micro-models and illustrates the application of the same in the simulations metallurgical processes. Development of micromodels requires access to accurate thermodynamic, thermophysicaland kinetic information for the relevant systems with suitable models to extrapolate the data as functions of temperature and composition. Experimental measurements and modelling of the thermodynamic properties, sulphide capacities and viscosities of oxide melts carried out in the department are presented. The incorporation of these models in process models, with special reference to ladle refining of steel is illustrated. Typical example of micro-modelling of solid-gas reactions is also presented.

Jan 1, 1999

By Lj. D. Andric

By the micronization-milling of the material, the size and the structure of its particles are changed and it comes to the increasing of the potential energy of the system as well as to the chem-ical activity of the material what is the result of an increased free surface and of the concentration of the grate defects, that is of the internal energy of the system. All these changes that are reached, show that new characteristics of treated materials are got by micronization process. Controlling the process of the micronization and by purpose directing of the new characteristics of the activated materials, we can have the positive effects and use them in more technologies. Talc is important nonmetallic mineral raw material that is widely used as either the basic raw material, or as filler. This has stimulated its technological investigation, as well as the investigation of its physical-chemical characteristics. In this paper are shown experimentally reached results of the physical-chemical characteristics of the talc during the process of the micronization in high energetic mill. In this paper, the optimum conditions of miconization of talc in high-energy-speed rotary mill and its influence micronization on a degree of Fe2O3recovery by hydrometallurgical methodes, are presented. The X-ray analysis of the obtained products showed that high quality talc with low content of can be obtained by these physical-chemical processes In this paper, the principles and application or fine and ultra-fine grinding high-energy attriton mill with small balls, enabling fast, efficient grinding, low energy consumption, short grinding time and easy handling will be described.

Jan 1, 2014

By Ashok M. Raichur, S. P. Vijayalakshmi

"Recent advances in technology and the growing environmental concern have laid emphasis on the usage of fine clean coal. Coal fines are also generated in large amounts during various coal processing operations and are difficult to be treated, handled and disposed. Since most of the operations use water as the carrying medium, the fines so generated contain lot of moisture. Conventional technique for processing coal fines includes flocculation by a polymeric reagent followed by moisture removal using a rotary drum or a pressure plate filter, which produce a product with more than 30% moisture. Polymeric flocculants though required in small amounts, need high shear mixing for good performance and operate only in a narrow pH range. Moreover they increase the viscosity of the solution by many folds. Hence it becomes imperative to emulate newer methods for efficient fine coal processing. One such method is the novel use of microorganisms in coal processing.The present investigation deals with the utilization of two gram-positive microorganisms, Mycobacterium phlei and Bacillus subtilis, as bio flocculants and dewatering aids in fine coal processing. Preliminary characterization done on J-coal and M.phlei showed that they are negatively charged over most of the pH range. B.subtilis was found to possess positive charge below pH 4.7. The adhesion studies proved the high potential of microorganisms for adsorption to surfaces. Adhesion tests were conducted at various experimental conditions by varying parameters like pH and ionic strength of the suspension. Results obtained showed that adhesion is always higher in the presence of an electrolyte like KNO3 and most of the adhesion takes place in 15 minutes. With change in pH the amount of B.subtilis adhering on to J-coal remained almost constant and for M.phlei it decreased at higher pH values. Increase in ionic strength did not increase the adhesion of bacteria. Flocculation experiments confirmed the ability of the bacteria to act as bio flocculants. It was seen that about 98% of the coal settled in about 2 minutes on the addition of bacteria along with the addition of the electrolyte. The electrolyte was found to be indispensable for efficient flocculation of the coal suspension and for the attainment of a clear supernatant after flocculation. Also the optical micrographs revealed the formation of large, tight flocs when the electrolyte is present along with the bacteria. Further, flocculation tests were done in the pH range of 2-10 and the flocculation efficiency was found to be independent of pH."

Jan 1, 2003

By A. Vilinska

Microorganisms have a tremendous influence on their environment through the transfer of energy, charge, and materials across a complex biotic mineral-solution interface. Recent developments in biotechnology have not only aided hydrometallurgical leaching operations but also shown great promise in mineral beneficiation processes. The adhesion of bacteria on minerals alters the surface properties relevant to flotation and flocculation of minerals. The biomodification of mineral surfaces occurs through the attachment of microbial cells, oxidation reactions and adsorption or chemical reaction with the metabolite products. Several types of heterotrophic and chemolithotrophic bacteria have been successfully applied in flotation and flocculation processes for the last two decades. Al-though the potential of microorganisms in minerals beneficiation has been realised by several re-searchers from their laboratory investigations, the studies were mostly confined to pure mineral systems and there is hardly any sincere effort to apply the methodologies on ores. This paper presents a brief summary of the literature in bioflotation and bioflocculation, and attempts to outline new dimensions of research for a practicable application of this technology in mineral industry.

Jan 1, 2014

By M Miettinen

That microorganisms, both living and dead, and products derived from the organisms, can function as flotation agents and flocculation agents is abundantly clear. They can modify the surfaces of minerals. They can function as flotation collectors and as flotation depressants and activators. In many cases they or their products can function as specific flocculation agents. Problems that must be solved before such microorganisms or products from the organisms can be used in commercial operations include culturing the organisms at a cheap cost and reduction in dosages required for various separations. These tasks are formidable. However, the concept of using such natural materials in place of various chemical reagents that may be toxic is very attractive. An attempt is made to show some of the promise of microorganisms in mineral bioprocessing and to consider the problems that must be overcome before commercial application of the technology is realised.

Jan 1, 2005

By R. W. Smith, A. Raichur, M. Misra, I. A. H. Schneider

The concept of microorganisms as chemical reagents (flocculants, flotation modifiers and flotation collectors) is quite new. Potential uses for microorganisms include their use in place of certain conventional flotation reagents and as flocculating agents in minerals engineering processes. In addition, in some studies micro-organisms have been used to modify mineral surfaces and, thus, the flotation or flocculation of the minerals.

Jan 1, 1995

By N. Kuyucak

Acid rock drainage (ARD) resulting from the natural oxidation of sulfide mineral wastes has become a major concern to the mining industry, both during the operational period and after mine closure. ARD is generally characterized by high acidity and high concentrations of dissolved metals and sulfates. If the generation of acid cannot be prevented or controlled, it must be treated to eliminate acidity and to reduce the concentration of heavy metals and suspended solids before release to the environment. Microorganisms play an important catalytic role in the generation of ARD. Several prevention, control and treatment technologies that are based on microbiological activities have been developed. The role of microorganisms and biotechnology in the generation of ARD and their role in the methods used for prevention, control and treatment are discussed in this paper. Recently developed passive and biological treatment processes that have been implemented at mine sites are emphasized in this paper. Benefits, limitations and design criteria for passive biological processes are also presented.

Jan 1, 2000