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By V. N. Medvedev, A. M. Bryukhanov

Stationary mine air control equipment enables monitoring of CH4 concentration only in sensor locations. CMC-4 individual indicator built into a caplight has been developed in Ukraine, extending CH4 monitoring to manned job sites. Major technical characteristics of the indicator are demonstrated. It features two operation thresholds: 1st threshold 1.0 to 2.0% vol. 2nd threshold 1.5 to 2.5% vol. Basic absolute accuracy ± 0.2% Caplight battery is a common power supply for the lamp and CH4 indicator, providing at least 10 hours of the system non-stop operation. Average pre-failure life is at least 10,000 hrs. It features: an explosion proof design and intrinsically safe test circuit; a small-sized sensor as an integral part of the caplight; a hybrid microcircuit to facilitate functioning of methane monitoring unit. The CMC-4 indicator weight is the weight of the caplight itself and equals 2.4 kg. A two-threshold design makes possible to distinguish between methane sources: slow accumulation due to diffusion or sudden rushes due to a gas-dynamic event. CMC-4 indicators in addition to stationary equipment minimize the risk of CH4 explosion underground determined as a product of accident intensity by calculated time interval.

Jan 1, 2003

By A. Z. Dimitroff

Immediate detection of methane buildup or of sudden liberation of large quantities of methane in the face area is essential to avert disasters in coal mines. Proper timely detection and handling of methane have always presented problems in extremely gassy mines, and these problems have been magnified by present accelerated mining methods. Strict rules and regulations have been established by coal-mining companies, States, and the Federal Government, which provide for periodic inspections for methane in face areas when electrical equipment is working. Other provisions require the operator' to shut down electrical face equipment and change or adjust ventilation when more than 1.0 percent of methane is detected. Nevertheless, human failure to detect such conditions has been responsible for numerous ignitions arid explosions Recognizing this fact, Marling J. Ankeny, former Director of the Bureau of Mines, proposed in 1958 the development of an automatic methane-monitoring device. He envisioned such a device as being entirely dependable, capable of giving a warning when a predetermined concentration of methane in air is reached, and capable of deenergizing the equipment and rendering it inoperative when a dangerous concentration of methane is present in the air. Such a device has been developed by the Bureau of Mines Health and Safety Research and Testing Center in Pittsburgh, Pa.

Jan 1, 1967

By Julian S. Edwards, C. Frederick C. Pearson, Sevket Durucan

Information gained at the site investigation stage of the Carsington aqueduct project led the designers to suspect that methane might be encountered during tunnelling and therefore gas detection techniques, including emergency shutdown systems, were introduced. After construction, on completion of the excavation and lining of the tunnels, a survey showed that methane was entering the aqueduct dissolved in infiltrating groundwater. General body air concentrations were very low but on closure methane concentrations rose rapidly within the aqueduct. A research project has now been initiated to investigate the mechanism of methane generation and entry rate into the system, the results of which are being taken into account in the preparation of future operating procedures.

Jan 1, 1989

By P. J. D. Lloyd

The widely employed IPCC models for the release of methane from underground coalmining operations are reviewed, and put in the context of the South African National Communication on greenhouse gas emissions. Then attempts to calibrate the model via measurements on South African coalmines are described. These attempts failed because it rapidly became clear that the IPCC model, involving methane adsorbed by the coal and released (a) by the depressurization of the strata caused by mining, (b) from the broken coal and (c) from coal remaining in roof, floor, pillars or goaf after mining, was not valid. Instead, measurements showed that the methane release was very variable, sporadically falling to zero. Carbon dioxide concentrations were monitored at the same time as methane, and followed methane concentrations. An alternative model was developed, in which methane was largely displaced from the coal and held in fissures, cleats and pores, which, when intersected by mining, released methane into the ventilation stream. In a key test of this hypothesis, methane concentrations around a continuous miner were monitored both during operation and after shutdown. Even during operation, methane became undetectable. It is hypothesized that heating of the South African coal-seams during the emplacement of the igneous dykes that cut so many of the seams caused displacement of the methane from the coal into the pores. This fissure-held methane, or free methane, is released rapidly once a pathway through the coal into the mine atmosphere is established. In contrast, methane adsorbed in the coal, and measured as the seam gas, desorbs relatively slowly. Measurements suggest that on average about 50%of the adsorbed methane is lost one day after mining. By that time, the coal will have left the mine, so that the remaining seam gas will be released to the atmosphere outside the mine. Attempts to measure methane emissions from surface coal-mining operations showed very little detectable methane. Coal from surface operations, which was milled and exposed to atmosphere, adsorbed gas from the air. It is concluded that methane release from surface operations is probably less than 3Gg/a. It is estimated that the total methane release from the coalmining industry amounts to about 72 Gg/a, as opposed to the National Communication estimates of 323 Gg/a in 1990 and 317 Gg/a in 1994. However, there are large errors associated with these estimates, and it is recommended that the methodology outlined in this report be extended to as many mines as possible to reduce the errors that are inherent in the physical processes underlying the release of methane from South African coalmines.

Jan 1, 2005

By Alan P. Cook

Methane levels have been measured around continuous miners and compared with computer simulations of methane flow. A multi-channel data logger, reading continuously from six methanometers, has shown methane levels to vary at different positions around a continuous miner, with the cutting drum and the immediate face area not necessarily recording the highest concentrations. Methane levels in the driver's cabin are generally low compared with the return side. Computer simulations, using computational fluid dynamics, have been supported by the measured data, and have shown that methane behaviour within the first few metres of the face varies considerably for different bord and pillar development stages. Methane is diluted rapidly to acceptable levels, but the distance required for this is extended when ventilation flow to the face is restricted.

Jan 1, 1995

Continuous remote sensing of methane concentration in underground mines. Approach A methane transducer, developed as a fixed point rib-or face-mounted operating device, measures ambient levels of methane and produces a signal that is proportional to the measured concentration. How It Works The methane transducer, developed under contract for the Bureau of Mines, uses a catalytic-type sensor which will detect methane concentration. The transducer is mounted vertically, as shown. This type of mounting minimizes dust accumulation on the sensing element, which might cause degraded operation. The unit must not be located in an area where water can continuously drip or run on It. The transducer generates an electrical signal proportional to methane concentration at the sensor. A sensor failure output indicates the status of the sensing element A circuit within the methane transducer detects whether the sensing element is shorted or open. A high signal (approximately 8 Vdc) on the failure output Indicates the sensor element is operating In Its normal range. A low output (less than 1 Vdc) indicates an element fault. The methane transducer, enclosed in a stainless steel

Jan 1, 1982

By J. F. Brune

This paper analyzes the explosion hazard resulting from the formation of methane-air mixtures in the mined-out gobs of underground longwall coal mines. Although direct examinations of the gob atmosphere are difficult due to the inaccessibility of these gobs, evidence from methane drainage practices and investigations of numerous mine explosions suggests that explosive methane zones can form within longwall gobs. Explosions and fires resulting from these methane accumulations have led to severe and fatal injuries to the miners. Most recently, this was demonstrated in the explosion of the Upper Big Branch Mine in West Virginia, where 29 miners lost their lives.The paper also reviews current research on numerical modeling of gas flows in longwall gobs and outlines how targeted injection of nitrogen into gobs can effectively reduce the volume of such explosive methane zones. The paper concludes that comprehensive monitoring of gas compositions, along the accessible fringes of the gobs along with inertization, improved ventilation schemes and further research are necessary to control this explosion hazard and make mining operations safe.

Jan 1, 2013

By BruneJurgen F., Richard C. Gilmore, Matthew Schreiner, Ray Johnson

Explosive pockets of methane-air mixtures accumulate in underground coal mines and, when ignited, produce an air-blast wave that can disturb combustible coal dust on the floor, roof, and ribs. To prevent explosions, the coal dust must be continuously diluted through application of inert rock dust, usually powdered limestone. Application of powdered dust process creates a respiratory nuisance downwind, where miners cannot work until the dust settles. Rock dust suppliers have developed wet and foam applied products to reduce the nuisance and limit the interruption to mining during dust application. To test the effectiveness of these alternative dust products, researchers at the Colorado School of Mines (Mines) have constructed a full-scale explosion test drift located at the Mines Edgar Experimental Mine (Edgar) to study the dispersibility of different rock dust applications. This paper examines the use of Pentaerythritol tetranitrate (PETN) detonating cord to produce controlled air-blasts that simulate methane-air explosions. The air blasts are generated with curtains of detonating cord that produce shockwaves with wind speeds between 30 to 70 m/s (100 to 225 fps) depending on the length of 5.3 g/m (25 grain/ft) detonating cord used. These velocities represent the minimum air speeds required to trigger propagating coal dust explosions. Researchers have conducted 40 test blasts with various lengths of detonating cord. Results show the two primary waves and two reflected waves each decaying into airblast waves with overpressures of 14 to 27 kPa (2 to 4 psi). Pressures were recorded with commercial piezoelectric transducers and custom-built, bi-directional probes to record the total and dynamic pressures of the wind generated in the explosion. Researchers were able to generate consistent and repeatable wind speeds and air-blast durations sufficiently similar to a methane-air explosion to study the dispersibility of various rock dust products and application methods

Jan 1, 2019

By Thomas H. Dubaniewicz

Fiber optic systems are being deployed in locations where explosive gas atmospheres are normally present or are present under fault conditions. The National Institute for Occupational Safety and Health, Pittsburgh Research Laboratory (NIOSH, PRL) conducted a study of laser safety in potentially flammable environments. Researchers conducted experiments to estimate the mean and standard deviation of laser powers needed to ignite 6% methane-air atmospheres using single mode optical fiber tips covered by two types of iron oxide (Fe304 and (FeMn)203) mixed with a ceramic adhesive. The iron oxides, heated by a 1064 nm continuous wave laser, ignited the methane-air mixtures ,at similar powers. The minimum igniting power and maximum non-igniting power (10 tests) were 407 and 350 mW, respectively, using a 62.5 pm fiber. Laser beams guided by 125 and 80 pm diameter cladding single mode fibers produced similar methane-air igniting powers. Ignition was not observed using coal particles at powers that produced ignition with the iron oxides. Threshold ignition delays using the single mode fiber were approxinlately proportional to the inverse square of the igniting power. Ignition delays were significantly longer than the reported activation time for a comnlercial fiber optic power limiter. Comparisons are made with the results of other researchers. Published by Elsevier Ltd.

By Ruschitzka C

The productivity and economic success of a German hard coal mine is attributed to the high productivity of a small number of operation points; however high rates of production are associated with increased gas emission at the working sites. Therefore modem high technology is required in order to reach the planned production rate, since high methane concentrations often cause unplanned breakdowns in operation. The optimised simulation of gas emission is a fundamental planning tool for mine design as well as for determining the potential of a coal deposit and has increased in significance over the last years. Methane-INFO enables the three-dimensional, graphical simulation of a working site taking account of different aspects such as the mine design, ventilation, production rate, geology, seam quality, gas exhaustion, etc. The following paper gives a short overview over the benefits of the discussed system.

Jan 1, 1995

By A. L. Baxley

An Untapped Energy Resource As much as 20 billion cubic feet of natural gas per day are flared from remote oil fields for lack of a commercially viable means of capturing, transporting, and marketing such gas. The magnitude of these gas flares can be put into perspective from an early satellite photograph (Fig. 1) which shows lights from the major cities of Russia and Eastern Europe dwarfed by the natural gas being flared in the Persian Gulf. Together, these wasted resources contain the energy equivalent of about one-half of the gasoline consumption in the United States today (Fig. 2). Additional trillions of cubic feet of natural gas are "shut-in" because of no economically viable means of commercial recovery. Methanol and liquified natural gas (LNG) are the only two practical fuel products which can be produced economically from these gas supplies. Many of these gas supplies are less than 500 million cubic feet of gas per day, making an LNG facility uneconomic. In contrast, barge-mounted methanol plants can economically convert billions of cubic feet of gas per day into safe, clean-burning methanol. The methanol approach offers the only economical route to transform vast, known reserves of natural gas into a highly versatile primary liquid fuel. Methanol Barges: An Innovative Solution The barges will be towed to suitable offshore and upriver locations such as Alaska, South America, Africa, Southeast Asia, Australia, New Zealand, and the South Pacific Islands, as well as fields in the Persian Gulf and Mediterranean Sea. At the offshore production site, a barge will be anchored by a single point mooring buoy that will also serve as an entry point for natural gas feedstock and an offloading point for methanol (Fig. 3). At some sites the barge would be beached. Each barge will produce methanol and store it in internal tanks with a capacity of 18 million gallons. The methanol will be offloaded into conventional tankers and safely transported directly to market. Unlike LNG, methanol requires neither specially built carriers nor specially built receiving terminals. Once a particular gas field has been exhausted, the barge will be towed to another location to continue production. Each barge will measure 320 by 500 ft, approximately the size of four football fields, and will have the capacity to produce 1 million gallons or 2800 metric tons of methanol per day, from approximately 100 million cubic feet of natural gas per day (Fig. 4). The barges will use the highly successful "low- pressure" design developed by the Lurgi Company of Germany, a process proven in land-based methanol plants throughout the world during the last ten years. The decision to use Lurgi technology for "sea-trans- portable" methanol plants was based on the higher efficiency and greater operability of the technology compared to other commercially proven processes. The conversion plant will be designed to accept a wide variety of feed gas compositions, and will produce chemical-grade methanol for the broadest market base (Fig. 5). To minimize costs and construction time, the barge-mounted plants will be built in the high technology environment of a domestic or foreign shipyard. Selection of the construction site for each barge will be dictated by the location of the production site and by the relative construction costs. A number of shipyards have the capacity to build several barges per year. The detailed marine engineering to integrate the design of the processing plant with the floating platform can be performed by numerous major engineering companies around the world. Production Economics The barge-mounted plant concept not only assures large volumes of methanol, but it also keeps the overall production cost low by minimizing construction cost and providing access to low cost natural gas feedstock with no alternative or a negative value. Together, these advantages make the barge-mounted methanol plants economical today. The cost structure of a new barge-mounted methanol plant differs from that of existing methanol producers around the world (Fig. 6). For example, if a U.S. Gulf Coast producer is paying $4.70/MMBtu in 1985 for natural gas, the barge plant could afford to pay about $1.6O/MMBtu for gas and be able to deliver methanol to the Gulf Coast at the same price. At some future date such as 1990, a gas cost of $6.70/MMBtu for a domestic producer would have cost parity with about $3.60/MMBtu gas cost for the barge plant. In many foreign markets, feedstocks other than natural gas are used for methanol production (Fig. 7). For example, most of Japan's capacity is based on LNG while Western Europe uses residual oil or naptha. Because these feedstocks are substantially more ex- pensive than natural gas used by U.S. producers, the barge plants will compete even more favorably in these foreign markets. As crude oil prices rise, the value of methanol in each of these markets will increase. However, the hierarchy of methanol values in these markets should remain unchanged. Furthermore, the cost advantage for using methanol in these markets will improve as world energy costs increase since the value of remote gas should not escalate significantly.

Jan 1, 1982

By J. Shen

Direct methanol fuel cells have been the subject of considerable research in the last decade. Performance levels realized in cells, stacks, and systems show that this technology is a promising power source for a wide range of portable applications. A direct methanol fuel cell (DMFC) operates directly on a methanol fuel stream typically supplied as a methanol/water vapour or as an aqueous methanol solution in liquid feed DMFCs. The fuel streams in DMFCs are usually recirculated in order to remove carbon dioxide and to re-use the diluent and any unreacted fuel in the depleted fuel stream exiting the DMFC. The concentration of methanol in the fuel circulation loop is an important operating parameter because it determines the electrical performance and efficiency of the direct methanol fuel cell system. The methanol concentration in the circulating fuel stream is usually measured continuously with a suitable sensor, and fresh methanol is admitted in accordance with the signal from the sensor. There are many factors to consider in developing a methanol sensor suitable for DMFCs. These factors include sensitivity, cost, size, simplicity, reliability, longevity, concentration range, and dynamic response. In particular, reliability and low cost should be addressed. Methanol concentration sensors measure methanol concentration by means of detecting the variations of physical/chemical properties of the solution. In this work, methanol concentration sensors based on electrochemistry, electric-capacitance measurement, infrared sensing, ultrasound sensing, and other techniques are reviewed to discuss their advantages and disadvantages.

Jan 1, 2005

By H. J. Glass

Collection, preparation, and analysis of blasthole chippings is expensive. Frequently, interpolation of grades at unsampled locations is considered using techniques like kriging. A pre-requisite for kriging is that an experimental variogram is established. In order to assess the quality of the experimental variogram, a measure is developed in this paper. The measure is derived from analysis of the time-honoured expression relating the variance, semivariance, and covariance. It reflects the weighted average deviation of the summed semivariance and covariance from the biased variance. The proposed measure allows assessment of the influence of key variables on the quality of the variogram. Using simulated data, it follows that the quality improves with an increasing number of samples, increasing density of the sampled locations, increasing regularity of the sampling pattern, and increasing uniformity of grades in the absence of correlation. Application to real data shows that the minimum number of samples could coincide with a marked decrease in the value of the measure. Establishing a threshold value is subject to further research. Keywords: variogram, variance, covariance, semivariance, minimization, sampling.

Jan 1, 2003

By T. Serradj

A study has been carried out to: develop a method for routine characterisation of rock strength and drillability through the particle-size distribution of crushed or drilled rock products, defined by the Protodyakonov index; establish correlations between the Protodyakonov index, uniformity coefficient and the constant grading equations; and propose an alternative rock characterisation index to classify rock strength and drillability for the northeast region of Algeria

Dec 1, 1996

By J. H. Wright

Longhole sublevel stopes excavate ore with which the production geologist has only remote contact; therefore, predicting grade and tonnage from such a stope can be a problem. However, the longholes themselves yield data that can be used to improve those predictions. Here, a radial distribution method of weighting sample data is discussed, which is useful in forecasting grade and tonnage from certain longhole sublevel stopes.

Jan 1, 1985

By S. C. Brown, R. C. G. Oliveira

Surface wettability, or contact angle, dictates a number of multiphase ensemble interactions that influence particulate dispersability and adhesion behavior (e.g., filler compatibility] in addition to a number of other phenomena including biocompatibility and bulk powder segregation. The wettability of particulate surfaces significantly impacts nearly all process industries; however, the available techniques to access this quantity are either relative, or tedious-and are application or industry specific. In this study, key features of existing techniques have been combined to design an improved method to delineate particle wettability that is simple, versatile and capable of providing reproducible measurements in an industrial environment.

Jan 1, 2003

By Yoshiak Mizuta, Hi Keu Lee

The manuscript of this paper was not available for publication when the Proceedings went to press. Should the authors elect, they may distribute copies at the time of the Symposium

Jan 1, 1986

By O E. Jr Crenwelge

Recently promulgated regulations governing blast induced ground vibrations in the mining industry contain a frequency criterion as one option for verifying compliance. This criterion is based upon an oversimplified method which assigns the entire peak particle velocity amplitude to one frequency. Depending upon the nature of the vibration time history, it is possible that this frequency may not even be one of the predominant frequencies of the signal. In addition, the criterion does not specifically define the data analysis approach to be used by the industry for obtaining either the amplitudes or the frequencies of the vibration components. And because personnel in this industry generally have little understanding of vibration phenomena, a number of different approaches are currently being used for satisfying the criterion. This paper presents a method for obtaining both the Fourier amplitude-frequency spectrum and the integrated predominant amplitude-frequency components for the vibration record. The method is both physically and mathematically correct and is in common use in a number of other industries. Therefore, it should be of help to regulators, blasters, and consultants charged with developing, enforcing, or implementing ground vibration criteria.

Jan 1, 1988

By R. Stanevich

Studies by the National Institute for Occupational Safety and Health (NIOSH) and the Bureau of Mines (BOM) have demonstrated that: (1) 90% of diesel particulate is less than one (1) micrometer in aerodynamic diameter; (2) more than 90% of the respirable mass in electric coal mines was greater than one (1) micrometer in aerodynamic diameter; and (3) in coal mines using diesel equipment, average diesel concentrations can represent up to 53% of the MRE respirable coal dust standard. For mines approaching the 2 mg/m3 standard, compliance may be easier to attain by controls directed at diesel exhaust particulate as opposed to coal dust control. First, however, a Simple instrument is needed to measure diesel exhaust particulate concentrations. This paper describes such a sampler, its construction, and use. While results from this sampler are primarily utilized to identify control areas, NIOSH is also using the sampler for estimating worker exposures in epidemiologic studies.

Jan 1, 1988

By W. J. Schlitt, J. H. Templeton

The chemical reactions that occur within a copper-leach recovery system are discussed, and the impact on the overall acid balance is evaluated. Both oxide and sulfide mineralogy are addressed, and their effects on acid consumption, generation and solution buffering are presented. Two case studies that apply the discussed chemistry show the practicality of using a computer spreadsheet acid-balance model for the early planning and design of copper-leach systems.

Jan 1, 1998