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By J. Bleeck, G. Mahrt

INTRODUCTION Many excellent papers have been written and presented regarding agricultural lime and the subject has been covered extensively in books concerning soil science, fertilizing, limestone, etc. We felt challenged to construct a paper that wouldn’t merely be a repetition of past presentations. Therefore, we chose to begin with factors having the most impact on plant growth realizing that the audience is likely to be relatively unfamiliar with this subject. So, we decided to dig deep into the roots of soil and plant growth science in order to better understand the significant role of limestone in this important area. The soil with the higher plants growing upon it forms an open and dynamic ecosystem in which there is flux of energy and material (heat, light, water, nutrients, mineral and organic matter, organisms). Plants root in the soil and then take up oxygen for root respiration, yielding energy for nutrient uptake, water for turgescence and transpiration and use in photosynthesis and the mineral nutrients needed for the synthesis of organic matter. Above the ground the plant takes in light energy and heat using them in photosynthesis to assimilate atmospheric CO2. Photosynthesis is the basic life process of creation. However, we will look at the root room where soil, water, air, and heat economy and the supply of nutrients determine soil fertility and the important role lime plays here. Location is the primary point to be considered when discussing agriculture (climate and soil); secondly, the dynamic and mobility of the minerals (plant nutrients) in the soil; and thirdly the conversion of organic substances into humus. And then there is a great deal of water involved in the growing process. In order to produce 1 kg of dry plant substance, 300 to 800 kg of water must be pumped through the plant and is then lost by transpiration. Cereals, vegetables, and sugar beets consume between 400 to 500 kg of water during the growing process and long-growing crops, such as alfalfa and clover, can consume 600 to 800 kg of water per kg of finished product. Without water, a plant cannot grow. (Reference 1)

Jan 1, 2006

By R. C. Freas

Limestone is a basic raw material in the production of cement, lime, a wide variety of industrial products, and a significant percentage of the crushed stone produced in the United States annually. It is used in fluxes, glass making, mineral fillers, environmental applications such as flue gas desulphurization and water treatment, soil conditioners, animal feeds, and as a construction aggregate. This presentation provides an overview of limestone distribution in the United States, it’s production, the variety of products produced, and a brief review of the primary uses for limestone.

Jan 1, 2006

By F. A. Renninger

Limestone and dolomite are the most common rock types mined and quarried as industrial minerals in the United States. In 1993 over 720 million tons of limestone and dolomite valued at over 3.1 billion dollars were extracted and consumed throughout the nation. While the greatest volume of this vast production is used as aggregate for construction purposes, few people realize how critical limestone and dolomite are to our food chain and our national goals of clean air and water. Limestone, including dolomite, can truly be called nature's gift to the environment. Without a reliable, economical source of limestone the quality of our environment would be severely comprised and the standard of living of our citizens dramatically reduced.

Jan 1, 1995

By O. D. Maurice

"This paper will essentially update the information that is already known and published on the limestones of the Province of Quebec. The excellent report by M. F. Goudge (1935)m is difficult to improve upon and the areas of limestone quarrying are generally the same as they were at the time of Goudge's report. Our knowledge of the limestones of Quebec has been improved considerably in recent years by the publications of T. H. Clark, 2 who, since 1938, has been mapping and reporting on these lime-stones and has discussed their stratigraphy, their structural features, their history and their economic value. One economic aspect is the presence of natural gas in these formations and the possible occurrence of oil. A total of 150 test holes had been drilled to a depth of more than 500 feet by the end of 1967 and, in addition, at least 256 more shallow holes had been put down in the St. Lawrence Lowlands. The information from these test holes has greatly improved our knowledge of the thickness and extent. of the various formations of Paleozoic limestone and shale in Quebec.This paper will then review briefly the limestone occurrences in Quebec, using the old as well as the more recent reports as principal references"

Jan 1, 1970

By F. E. Kottlowski

Widespread high-calcium limestones in New Mexico region are low -in magnesium, but some units include shale interbeds deleterious for sulfur removal usage. Thick limestones in Mississippian Escabrosa, Lake Valley, and Leadville, Pennsylvanian Madera and Hermosa, Pennsylvanian-Permian Horquilla, Permian Hueco and Capitan, Cretaceous U-Bar, and some Cenozoic travertines are high-calcium units. Significant outcrops are in mountains of southwestern, south-central, central, southeastern and north-central New Mexico, southeastern Arizona, southwestern Colorado, and northwestern Chihuahua. Coal-fired powerplants are mainly in northwestern New Mexico and eastern Arizona, thus transport is mainly by railroad.

Jan 1, 1994

By Frank E. Kottlowski

Widespread high-calcium (HC) limestones in New Mexico and adjoining areas, are low in magnesium, but some units include shale interbeds that would be deleterious for usage in sulfur removal. In southwest New Mexico, southeast Arizona, and adjoining parts of Mexico, limestones in the thick Mississippian Escabrosa, Pennsylvanian-Permian Horquilla, and Cretaceous U-Bar units are HC as are strata in the Mississippian Lake Valley, Pennsylvanian formations, Permian Hueco, and parts of the Permian Capitan Limestone of south-central and southeast New Mexico and west Texas. In north-central and central New Mexico, many limestones in the Pennsylvanian Madera Formation are HC as are some of the Cenozoic travertines. In northwest New Mexico, where the present-day mine-mouth coal- fired power plants occur, there are no HC limestones, but to the north in southwest Colorado some beds of the Mississippian Leadville Limestone and Pennsylvanian Hermosa Formations are HC. HC limestones considered contain at least 95 percent calcium carbonate and less than 3 to 5 percent magnesium carbonate. Limits for other impurities are alumina, 1 percent; silica, 2 percent; sulfur 0.05 percent; phosphorous, 0.02 percent; and iron oxide, about 1 percent. Chemical and physical requirements differ slightly depending upon the ultimate use.

Jan 1, 1995

By Stephen G. Wright

Jan 1, 1985

By Lucio Fabio Cassiano Nascimento, Luis Henrique Leme Louro, Sérgio Neves Monteiro, Jheison Lopes dos Santos, Fernanda Santos da Luz, Fábio Oliveira Braga, Rubens Lincoln Santana Blazutti Marçal, Hugo Concolato de Oliveira Freitas, Édio Pereira Lima Júnior

Epoxy matrix composites reinforced with up to 10, 20 and 30 vol% of continuous and aligned natural mallow fibers and 30 vol% of mallow and jute hybrid fabric were for the first time ballistic tested as personal armor against class III 7.62 mm FMJ ammunition. The ballistic efficiency of these composites was assessed by measuring the dissipated energy and residual velocity after the bullet perforation. The results were compared with that in similar tests of aramid fabric (Kevlar™) commonly used in vests for personal protections. Visual inspection and scanning electron microscopy analysis of impact-fractured samples revealed failure mechanisms associated with fiber pullout, rupture and layers delamination. When compared to Kevlar™, the mallow fiber and hybrid fabric composite displayed practically the same ballistic efficiency. However, there is a reduction in both weight and cost, which makes both, mallow fiber and hybrid fabric composites, a promising material for personal ballistic protection.

Mar 1, 2018

By Jean-François Domgin

This paper aims at presenting numerical results showing the impact of different parameters on the limitation of entrained slag from ladle to tundish during the ladle drainage. These parameters are process parameters, slag properties or external actuator acting directly on ladle slag behaviour. Numerical simulations based on the use of the CFD Fluent software illustrate the vortexing and non-vortexing phenomena appearing during the ladle drainage. This numerical tool validated by experimental data acquired on water model has been applied to industrial configurations. It shows that the slag properties (viscosity, surface tension?) or some modifications of parameters (slide gate opening, geometry of the ladle bottom?) have a positive effect on the slag entrainment and also on the decrease of the ladle heel. Finally, the modelling of the behaviour of an external actuator injecting some gas in the region of the nozzle reveals interesting possibility for reducing slag entrainment from ladle to tundish during the final steps of the drainage.

Jan 1, 2006

By Mitchell G, Clarke C

The high oas emissions which are associated with high production lonowall mining have provided a need to investigate the limitations and reouirements of the various gas control methods. The major relationships between oassiness and various other parameters are presented with computer analysis being adopted to assess the respective correlations. Some of the relationships are studied in detail with emphasis being placed on methods for overcomino the changes in conditions resulting from high production levels. The importance of the various drainage systems which can be adopted to combat high gassiness levels are analysed. Logical and necessary steps are also proposed for gassiness prediction and data monitoring as well as various combinations of gas drainage systems. The gassiness prediction methods which are discussed outline the need for a sound knowledge of the established worldwide methods together with a comprehensive study of the local mining and geological environment in order to develop a system which is adaptable to the changing conditions. This is particularly important in mines where high coal production levels are anticipated and the need for accurate gassiness relationships is essential.

Jan 1, 1988

By R. M. Luna-Sánchez

Electrochemical studies, particularly Evans? diagrams, have been employed in hydrometallurgy to simulate and explain the redox phenomena that take place at mineral and metal surfaces during operations such as leaching and cementation. However, despite their utility, in some cases, the combination of the cathodic and anodic branches, determined separately, does not reproduce the chemical environment present when both processes occur simultaneously on a specific surface. In the present paper, limitations of Evans? diagrams are analyzed through two examples: silver sulfide cyanidation and gold cementation on zinc. In both cases, the surface kinetics are sensitive to the local pH and cyanide levels. When the electrochemical oxidation of silver sulfide or the reduction of gold are performed in the absence of its corresponding redox reaction, the local pH obtained does not simulate the real situation and the combined reaction kinetics may be very different from those determined from the Evans? diagrams.

Jan 1, 2003

A localized nonlinear recoverable resource estimate technique has been applied using typical feasibility or new mining drilling data configurations drawn from a massive database from a mined-out area on a hydrothermal gold deposit. The results were then compared with the corresponding 8 m x 5 m grid grade-control data in order to determine the efficiency of the approach and the validity of the recoverable resource estimates for mine planning and financial forecasts.

Jan 1, 2014

By Williams SR

Column Flotation cannot be used indiscriminately. Based on extensive pilot plant experience at Lakefield Research, a number of limiting parameters have been identified for the application of column cell flotation. Parameters of importance are the use of wash water, flotable mineral content, pulp viscosity, type of mineral selectivity being sodght and degree of mineral liberation. The paper discusses when wash water should be used and the positioning of a column within the circuit as this is important to maintain a sound water balance for the circuit and prevent excessive circulating loads. Other areas of debate are pulp chemistry, very low and high weight recovery, for which the conventional column is a poor selection of equipment, and treatment of complex ores, where the separation of valuable minerals is more difficult than non-sulphide, sulphide mineral separation. Based on these observations, the application of column flotation must be carefully considered or can be optimised.

Jan 1, 1993

By J. M. Scharer, Bruce E. Halbert, Pettit. Carol M., Lysane Bolduc

The ratio of neutralization potential (NP) to acid production (AP) ratio is often employed for predicting acidic discharges from waste rock dumps. The available NP was evaluated in laboratory studies of limestone dissolution in simulated acidic mine water. The available neutralization potential strongly depended on the particle size. Using limestone particles of 114" (6.4 mm) or greater, less than 20% of the total neutralization potential was exhausted at the onset of acid conditions. Apparently, the dissolution of limestone became mass transfer limited. Under mass transfer limitations, the rate of pyrite oxidation may exceed the rate of neutralization by buffering minerals. The implications concerning the controls on limestone dissolution were examined using a geochemical predictive model for sulphide mineral oxidation in waste rock. The results have shown that in case of heterogeneous waste rock piles the NP/AP ratio is a reliable indicator for short-tam predictions only. Kinetic data on the depletion rate of the neutralizing minerals and geochemical modelling suggest that waste rock environments with NP/AP ratios as high as 5.0 may turn acidic in the long term.

Jan 1, 2000

By Harshad Bhagwat

The objective of this work is to investigate the inadequacies of current CFD based methodologies of model development for predicting combustion behavior of pulverized coal in furnaces. In the present paper, a steady state CFD model was used for in-depth analysis of pulverized coal combustion. The model accounts for turbulence, coal combustion, convective and radiative heat transfer and motion of coal particles. It also uses coal combustion models to account for important processes such as devolatilization, combustion of char and the evolution of fuel nitrogen during coal combustion. The model predicts fluid flow, heat transfer, progress of combustion and pollutant formation (NOx, etc.). The model uses several parameters, which need to be tuned with experimental data, which is not only limited in quantity but also insufficient in detail. Various existing methodologies like part calibration method for tuning of the parameters are discussed. In the present work, the parameters associated with coal combustion models were tuned and validated with published data obtained from an experimental furnace using one such part calibration methodology. The results clearly show that the model predictions differed with the experimental data not only quantitatively but also qualitatively. These discrepancies were attributed to part calibration methodology. A detailed parametric study was carried out to demonstrate the importance of parameters from various classes, namely, combustion kinetics, heat transfer, process and geometry parameters, and CFD model parameters. This investigation clearly indicates that parameters from different classes have significant effect on combustion behavior. The discrepancies in current methodology are discussed and a need for comprehensive methodology is highlighted. Keywords: pulverized coal combustion, computational fluid dynamics (CFD), pollutant formation (NOx), mathematical modeling

Sep 1, 2012

By Chin Wei Yang

Linear programming (LP) has proven to be a most effective mechanism for modeling a vast array of practical problems, while the development of LP applications in engineering have been extensive enough to show its advantages and limitations. In this paper: we focus on the properties of the widely-wed linear programming transportation (LPT) model formulated and developed by Koopmans (1) . There have been many models of this type applied especially in the field of energy economics (2-7). Since most of these applications can be linked to the seminal work of Henderson (8), we stall present our discussions based on his work.

Jan 1, 1980

By Richard J. Finno

Detailed measurements made at a test section adjacent to a deep braced cut and other published data are combined to illustrate the limitations of the common methods of predicting movements associated with excavations in soft to medium clay. While past performance data can be used to estimate expected responses before construction in many cases, actual wall and soil deformations throughout construction can only be estimated using finite element procedures. Success of such analyses depends equally upon considering all aspects of construction that induce strains in adjacent soil, such as wall installation, excavation and bracing sequence, and time, and adequately modeling soil stress-strain behavior. Even when these two criteria are met, soil deformations can not be predicted adequately when strain levels exceed those that produce peak shear stress.

Jan 1, 1991

By Gorzalczynski. Stan

The recent trend in underground mine developments is ?big is better?. This is most certainly evident in the mine shaft and the conveyances that operate within its compartments. Today, there are several new installations requiring mine cages that can transport up to 170 passengers. The technology in mine hoisting is advancing to address a combination of higher capacity requirements, deeper hoisting depths and faster winding rates, however, some areas of the hoist plant have not changed for the past fifty years. The most notable of these areas is the shaft compartment guide string and the conveyance mounted safety arrest mechanism. The technology in use today for the protection of passengers in a shaft conveyance from a hoist rope severance incident, remains conceptually unchanged from Elisha Otis? design of 1850. The actual retardation components, the safety dogs, have taken on several forms since Elisha?s invention with the last major design change occurring in the late 1940?s. The arrest of a free falling shaft conveyance requires that the shaft guides withstand the energy imparted on them by the safety dogs. There are some very real limitations presented by the use of wood for this application. The new hoisting era will most certainly continue to demand larger capacity equipment but also, an increased awareness toward safety.

May 1, 2002

By S. Gorzalczynski

The recent trend in underground mine developments is “bigger is better.” This is most certainly evident in the mine shaft and conveyances that operate within its compartments. Today, there are several new installations requiring mine cages that can transport up to 170 passengers. The technology in mine hoisting is advancing to address a combination of higher capacity requirements, deeper hoisting depths and faster winding rates, however, some areas of the hoist plant have not changed in the past 50 years. The most notable of these areas is the shaft compartment guide string and the conveyance mounted safety arrest mechanism. The technology in use today for the protection of passengers in a shaft conveyance from a hoist rope severance incident remains conceptually unchanged from Elisha Otis’ design of 1850. The actual retardation components, the safety dogs, have taken on several forms since Elisha’s invention with the last major design change occurring in the late 1940s. The arrest of a free falling shaft conveyance requires that the shaft guides withstand the energy imparted on them by the safety dogs. There are some very real limitations presented by the use of wood for this application. The new hoisting era will most certainly continue to demand larger capacity equipment, but also an increased awareness toward safety

Jan 1, 2002

By R. Hogg, T. F. Dumm, L. G. Austin

The applicability of SEM/EDS techniques to particle-by-particle analysis of respirable coal dust is evaluated. It is demonstrated that the correction procedures needed to account for the failure of most EDS systems to detect light elements (especially carbon) become unreliable for particles in the respirable size range (< 10 µm). Other serious limitations arise from x-ray counting errors for coal particles with low but significant mineral content and particle counting errors for liberated mineral matter.

Jan 1, 1991