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By C. O. Hawk

A PART of the Bureau of Mines effort to improve the conversion of coal to liquid fuels, batch autoclave tests were made on the hydrogenation of bituminous coal by a dry method, which featured charging the autoclave with dry ingredients only-coal, catalyst, and hydrogen. This innovation, which omitted the liquid vehicle used in earlier work, limited the products to those made from the coal charged. The effects of the common process variables (catalyst, hydrogen pressure, temperature, and residence time) were studied. Tin catalysts showed the highest activity in the widest variety of forms and were the easiest to disperse; dry mixing in the autoclave during the heating-up period usually sufficed. Ammonium molybdate, on the other hand, was inactive when dry mixed, but it compared favorably with the best catalysts known when applied by impregnating the coal with a solution of a molybdenum compound. As a group, metal naphthenates were the most effective; in fact, molybdenum naphthenate was the most active catalyst the Bureau tests disclosed. One-hundredth of a percent of molybdenum in this form (calculated as the metal in weight-percent of maf coal) induced 90-percent conversion of coal. However, because of their high cost, naphthenates have as yet only technical significance in coal hydrogenation. Long residence time and high reaction temperatures tend to increase the amount of thermal decomposition products formed (light hydrocarbon gases and/or char). High hydrogen pressure favors the production of liquids.

Jan 1, 1965

By Rodolfo Zanella

Au/TiO2 catalysts prepared by deposition-precipitation with NaOH (DPN) (~3 wt%) and urea (DPU) (~8 wt%) were tested in crotonaldehyde hydrogenation at atmospheric pressure. There is no differences in activity (mole.gAu -1 s-1) and selectivity between both DPU and DPN samples for a given activation treatment. This is due to the fact that DPU and DPN samples exhibit similar gold particle size distribution, although the gold loading in DPU is much higher that in DPN. The DPU samples were reduced under H2 at different temperatures (120-500 °C) or under air at 300 °C with various flow rates, to vary the average particle size within a large range, 1.7 to 8.7 nm. The selectivity to crotyl alcohol (selective hydrogenation of the carbonyl bond) is high, 60-70 %, and almost constant as a function of the particle size. The selectivity to crotyl alcohol is also constant for conversions between 10 and 50%. These results suggest that the adsorption mode of crotonaldehyde is of ?3 or ?4-type. In contrast, the TOF depends on the gold particle size, it drastically increases when the gold particle size is ~2 nm. Our results are in agreement with former studies that suggest that the gold atoms involved in the hydrogenation process are those of low coordination.

Oct 1, 2003

By Irina A. Pulyaeva

Hydrogenetic Fe-Mn crusts are ubiquitous in the ocean basins and play an important role in marine mineral-deposit research because of their widespread occurrence and high concentrations of valuable and rare metals. Directed research, which started in the last quarter of the 20th century, has provided significant results, with substantial amounts of data produced on Fe-Mn crusts structure, composition, and distribution in the global ocean. Detailed study of several seamounts has given confidence about the scale of Fe-Mn crust development and their characteristics. Now, commercial interests gain more and more attention. However, at the same time some theoretical questions related to Fe-Mn crust history including controls on metal sources and concentrations have not yet been answered. Here, we present the overview of age, composition, distribution, and geological setting of hydrogenetic Fe-Mn crusts from Pacific and Atlantic seamounts and discuss the geological evolution and conditions that led to the formation of potentially economic concentrations of metals. The age, composition, and distribution of Fe-Mn crusts in the Atlantic and Pacific oceans were determined by using a Fe-Mn deposits database compiled from our original data, published papers, published databases, and other international sources. Comparative analysis of Fe-Mn deposits from the Atlantic and Pacific oceans shows that there are similarities in basic characteristics of crust formation in both oceans. Simultaneously, there are significant differences in the scale of Fe-Mn crust distribution and composition that can be explained by differences in geological settings and characteristics of the deposition environment.

Jan 1, 2011

By Irina A. Pulyaeva

Hydrogenetic Fe-Mn crusts are ubiquitous in the ocean basins and play an important role in marine mineral-deposit research because of their widespread occurrence and high concentrations of valuable and rare metals. Directed research, which started in the last quarter of the 20th century, has provided significant results, with substantial amounts of data produced on Fe-Mn crusts structure, composition, and distribution in the global ocean. Detailed study of several seamounts has given confidence about the scale of Fe-Mn crust development and their characteristics. Now, commercial interests gain more and more attention. However, at the same time some theoretical questions related to Fe-Mn crust history including controls on metal sources and concentrations have not yet been answered. Here, we present the overview of age, composition, distribution, and geological setting of hydrogenetic Fe-Mn crusts from Pacific and Atlantic seamounts and discuss the geological evolution and conditions that led to the formation of potentially economic concentrations of metals. The age, composition, and distribution of Fe-Mn crusts in the Atlantic and Pacific oceans were determined by using a Fe-Mn deposits database compiled from our original data, published papers, published databases, and other international sources. Comparative analysis of Fe-Mn deposits from the Atlantic and Pacific oceans shows that there are similarities in basic characteristics of crust formation in both oceans. Simultaneously, there are significant differences in the scale of Fe-Mn crust distribution and composition that can be explained by differences in geological settings and characteristics of the deposition environment.

Jan 1, 2011

By Peter E. Halbach, Andreas Jahn

Co-rich hydrogenetic ferromanganese crusts are typical marine interface products of growth processes taking place on sediment-free substrate rocks on the seafloor. They grow very slowly and preferentially in water depths below the oxygen-minimum zone (OMZ) and have so far been found even in water depths of up to more than 5000 m, i.e. also below the calcite compensation depth (CCD); these deep ferromanganese crusts are particularly rich in Fe. It is assumed that the O2-minimum zone is the most important source layer of dissolved manganese, the decomposition of fecal pellets here also contributes to this Mn-budget. The process of hydrogenetic precipitation is basically an inorganic colloidal-chemical as well as a surface-chemical mechanism. Microbial mediations can be assumed, in particular since steps of redox-reactions are involved. The two main components of the hydrogenetic substance are hydrated d-MnO2 (vernadite) and x-ray amorphous Fe-oxyhydroxide, both of which are intimately intergrown with each other forming the extremely fine-grained hydrous oxidic material. In seawater, elements occur as dissolved hydrated ions or as inorganic as well as organic complexes which, in general, have either a positive or a negative surface charge depending on the pH of the respective marine environment. These complexes form hydrated colloids that interact with each other or with other dissolved hydrous metal ions. The main agent to oxidize the dissolved Mn2+ ions is oxygen, transported upwards from deeper water by turbulent eddy diffusion and turbulent rise processes at seamount slopes.

Jan 1, 2017

By R. Siwik, N. K. Davé

"The national reactive tailings (RATS) program is a co-operative industry-government effort to develop practical techniques for closure of reactive tailings areas. This paper summarizes the RATS program objectives and areas of research, and details the Noranda/CANMET project on the Waite Amulet tailings.Geophysical and biohydrogeochemical investigations were carried out at an inactive copper-zinc mine tailings site, Waite Amulet, in Noranda, Quebec. Geophysical investigations consisted of seismic, electromagnetic conductivity and electrical resistivity surveys to determine the thickness of the layers above bedrock and to map conductivity variations within the tailings and the immediate outlying area. Biohydrogeochemical investigations consisted of installing multilevel piezometer nests to determine groundwater flow patterns and porewater chemistry, obtaining solid core samples and characterizing for physical, chemical and mineralogical parameters, and iron oxidizing and sulphate reducing bacterial counts.The geophysical survey indicated a bedrock ridge extending under the tailings from the northeastern outcrop which may act as a porewater boundary layer. The survey also indicated a 2 to 20 m clay layer underlying the main tailings dam. Preliminary results of the saturated zone porewater chemistry have indicated three major zones of high electrical conductivity varying between 1,000 to 12,000 µs and pH between 3.4 to 8. Lower pH and high metal and sulphate concentrations were obtained in a shallow zone near the water table. With depth, the concentration of metal and sulphate ions decreased and pH increased below the water table. The underlying clay layer is relatively impervious -and most of the seepage from the tailings is probably exiting from the sides of the impoundment dam."

Jan 1, 1987

By A. Y. Smith, R. J. Allan, E. H. W. Hornbrook, R. W. Boyle, W. Dyck

"HYDROGEOCHEMICAL METHODS in the Canadian Shield can be based on analyses of the following :(1) spring waters and their precipitates;(2) stream and river waters;(3) lake and muskeg waters;( 4) ground waters from drill holes, wells, faults, etc.;(5) waters issuing from diamond drill holes, faults, shear zones, etc. into mine workings and open pits; also analyses of precipitates associated With these waters.The first four can be utilized in both reconnaissance and detailed surveys. The last is suitable only for detailed work.For hydrogeochemical methods of prospecting to be effective, the following conditions must be present. 1. Natural waters must come into contact with mineral deposits and remain in contact with them long enough for the solution of detectible amounts of ore, gangue or indicator elements. 2. Dispersion patterns must be present in the hydrologic systems in order to trace the elements back to their source. These patterns may take the form of trains (e.g., increasing amounts of elements upstream toward t he source (s), Figure 1 ) or halos (e.g., increasing amounts of elements in bodies of water toward the source (s), F igures 2 and 3)."

Jan 1, 1971

By M. Lghoul

Acid mine drainage (AMD) remains one of the major environmental problems for the mining industry particularly for many abandoned mine sites. The production of AMD as is commonly known can significantly affect the surrounding groundwater and surface water of the mine site. With the objective to investigate the impact of the AMD produced at the abandoned Kettara mine site (Morocco), groundwater sampling campaign was performed at this site. The sampled waters were analyzed to determine the hydrogeochemical composition, and then results were analyzed using different studied methods such as multivariate statistical analysis and geochemical modeling techniques. Investigation results show that the hydrochemistry of sampled waters is characterized by the relatively significant enrichment of Ca2+, Mg2+ and SO4 2-. The typical mine waters belong to the (Ca2+ +Mg2+)-SO4 2-type. Seasonal variations in major ion concentrations were partly attributed to dissolution/ precipitation processes. The saturation index (SI) calculation of the representative dissolved minerals in waters show that groundwater samples are undersaturated with respect to most potential sulphated secondary minerals.

Aug 1, 2013

By Gautam Chandra Mondal

An attempt has been made to carry out qualitative assessment of mine water discharges from the different mines of West Bokaro Coalfields of Hazaribag district of Jharkhand, India. A total of 33 mine water samples were analyzed for pH, electrical conductivity (EC), major cations (Ca, Mg, Na, K), major anions (HCO3, SO4, Cl, NO3), and heavy metals (Fe, Mn, Cu, Zn, Pb, Cr, Ni, Co, As). The hydrochemical data has been evaluated in terms of major ion chemistry, solute acquisition processes and suitability of mine water for domestic, industrial and irrigation uses. The pH of the analyzed mine waters varies from 5.27?8.43 indicating acidic to alkaline nature of the water. The electrical conductivity (EC) values varied from 276 µScm-1 to 1598 µScm-1 for measured samples and spatial differences between the EC values reflects the wide variation in lithology, surface activities and hydrological regime prevailing in the region. The anion chemistry of the analyzed water samples shows the dominance of SO4 and HCO3 with a minor contribution from Cl, NO3 and F. The observed high values of sulphate in the mine water of the area may be attributed to the oxidative weathering of pyrites. On average chloride is contributing 5% of the total anionic balance (TZ-). Fluoride and nitrate have low concentrations and on average contributing <2% the total anions. The cation chemistry indicates that 79% of the samples are Ca>Mg>Na>K, while the 6% belong to Ca>Na>Mg>K and 1% of Ca>Mg>K>Na. Weathering of rock forming minerals and cation exchange processes normally control the levels of these cations. Concentrations of some heavy metals (Fe, Mn, Ni, Cr) are found to be well above the prescribed permissible levels recommended for the drinking water. The water quality assessment for drinking purposes indicates that most of the mine water having high TDS, total hardness (TH) and sulphate concentrations. This suggests that mine water of the study area is not suitable for direct use in drinking and domestic purposes and needs a proper treatment before its utilization. The assessment of water for irrigation uses show that the water is good to permissible quality and can be used for irrigation uses. However, high values of salinity, %Na, SAR, RSC and Mg-hazard at certain sites restrict its suitability for agriculture uses. Keywords: mine water; ion chemistry; quality assessment; West Bokaro coalfields

Sep 1, 2012

By Regina N. Tempel, Mae S. Gustin, Mark A. Engle

This study characterizes the hydrogeochemistry of groundwaters near opalite-hosted epithermal hot-spring type mercury deposits in the Ivanhoe mining district, Elko County, Nevada. Local groundwaters generally range from Ca-HCO3 to Ca-Mg-Na-SO4 type waters with background mercury concentrations ranging from 0.014 to 0.32 ug/l. Leaching experiments conducted on mineralized rocks, using typical water chemistries to represent local groundwaters, yield total mercury concentrations ranging from 6.3 ug/l to 27.4 ug/l after one year of reaction. Geochemical modeling indicates dissolved mercury is dominated by HgO(,) and that precipitation of quicksilver controls mercury concentrations to an upper limit of 63 ug/l.

Jan 1, 2000

By Russell G. Slayback

An integral part of site investigations for shafts and underground workings should be hydrogeologic evaluations of the need for and method of ground-water control. Such investigations should include: 1. Classification of the problem by aquifer type. 2. Integration of other site investigations with hydrogeologic programs, including assessment of the need for water control. 3. Planning and conduct of aquifer tests tailored to the aquifer situation. 4. Evaluation of pumping requirements to achieve water control objectives. 5. Scheduling of dewatering for optimum results and costs. 6. Evaluation of environmental impacts of pumpage and water discharge. 7. Planning of operational monitoring for program modification and liability limitation. Early hydrogeologic involvement can result in avoiding unnecessary duplication in site investigations.

Jan 1, 1981

By Roger Beckie, Leslie Smith, Craig Nichol

To study the hydrogeological processes that control the movement of water through unsaturated waste rock, an intermediate-scale (8m x 8m x 5m) waste rock pile has been constructed and instrumented. The constructed pile is monitored for moisture content, matric suction, temperature, matrix water chemistry, gas chemistry, gas pressure, rainfall, evaporation, discharge volume and discharge chemistry. The pile is built upon a grid of 16 contiguous lysimeters. The experiment is designed to investigate the mechanisms that create rapid water flow through a pile and its exchange with slower-moving matrix water.

Jan 1, 2000

By Michael Day, Paul Kos, Scott Brinton

Quantitative hydrogeologic characterization of fractured rock is challenging because fracture systems are convoluted and difficult to characterize discretely. For large-scale water resource impact analyses, it may be more appropriate to use a watershed water balance approach and analyze fractured systems in terms of “bulk” hydraulic parameters over a large enough scale (hundreds of meters), so that the fractured media may be evaluated as “equivalent” porous media [1]. This is a common investigative methodology for mountain watersheds in fractured bedrock terrain because it does not rely on discrete flow paths but instead evaluates inputs to (recharge) and outputs from (discharge) the ground-water system [2,3]. This paper describes the use of this methodology to perform a practical and cost-effective hydrogeologic characterization and mining impact analysis for a proposed granite quarry in a mountain watershed. The key conclusions of the study guided the mine planning that was designed to minimize impacts to the fractured granite hydrogeologic system and preserve recharge to downgradient sedimentary aquifers.

By Michael Day, Paul Kos, Scott Brinton

A hydrogeologic characterization and impact analysis was performed for a proposed quarry at the Hitch Rack Ranch located in the Little Turkey Creek watershed southwest of Colorado Springs, Colorado. Continuous multiple channel tubing, nested piezometers, stream flow measurements, and mapping of known seeps were used to define the three-dimensional potentiometric distribution and areas of groundwater recharge and discharge. Water balance considerations, mass balance calculations, and potentiometric response to earth tides and barometric fluctuations confirmed that the granite fracture system in the ridge area of the proposed quarry has an extremely low bulk hydraulic conductivity resulting in minimal groundwater discharge to sustain the baseflow of Little Turkey Creek. The Little Turkey Creek valley forms the major conduit for groundwater flow exiting from the upper part of watershed underlain by granite. This conclusion has significant implications with respect to mine planning to minimize projected impacts to the hydrologic system and preserve this recharge component to downgradient Denver Basin sedimentary deposits.

By Michael Day, Paul Kos, Scott Brinton

A hydrogeologic characterization and impact analysis was performed for a proposed quarry at the Hitch Rack Ranch located in the Little Turkey Creek watershed southwest of Colorado Springs, Colorado. Continuous multiple channel tubing, nested piezometers, stream flow measurements, and mapping of known seeps were used to define the three-dimensional potentiometric distribution and areas of groundwater recharge and discharge. Water balance considerations, mass balance calculations, and potentiometric response to earth tides and barometric fluctuations confirmed that the granite fracture system in the ridge area of the proposed quarry has an extremely low bulk hydraulic conductivity resulting in minimal groundwater discharge to sustain the baseflow of Little Turkey Creek. The Little Turkey Creek valley forms the major conduit for groundwater flow exiting from the upper part of watershed underlain by granite. This conclusion has significant implications with respect to mine planning to minimize projected impacts to the hydrologic system and preserve this recharge component to downgradient Denver Basin sedimentary deposits.

By Nathan Painter, Kevin Andrews, Andrew Karpa

Groundwater flow in bedrock units is an important factor to be considered for most mining situations, both underground and open pit excavations. Characterization of the hydrogeologic system into which a mine will advance is an important factor for slope and entry stability, mine dewatering design, and potential environmental considerations including stream loss and water well damage. In addition, hydrogeologic characterization of bedrock is important for locating water wells and for groundwater contamination mitigation. Hydrogeologic characterization for a site begins with a desktop study and often evolves to include drilling, geologic logging, monitoring well installation, groundwater sampling, pump testing, and packer (Lugeon) testing. In addition to these methods of hydrogeologic data collection, downhole geophysical logging of exploration and monitoring well boreholes provides detailed information associated specifically with in-situ conditions of each hole. The basic suite of geophysical logging tools used for hydrogeologic characterization often includes Optical or Acoustic Televiewer (O/ATV), full wave sonic, gamma-density, fluid temperature, resistivity, specific conductance, and flowmeter. For many hydrogeologic settings, groundwater flow in the bedrock is dominated by discontinuities, or fractures, in the rock. O/ATV logging allows for determination of the frequency (clustering), orientation, and aperture width of in-situ fractures, while sonic logging allows for estimation of intact rock strength. Fluid temperature logging and flowmeter measurements provide insight with regard to potential groundwater inflow zones, and other tools provide information for geologic unit contacts. This paper outlines the process and benefits of using downhole geophysical logging for hydrogeologic characterization and provides generalized examples from industry experience.

By William J. Stone

Large reserves of coal and uranium exist in the San Juan Basin of northwestern New Mexico. The mining and development of these resources necessarily also involves depletion of area water resources and disturbance of the hydrogeologic framework. In an effort to better define the water resources and hydrogeologic framework of this region, the New Mexico Bureau of Mines and Mineral Resources, the U. S. Geological Survey, and the State Engineer&apos;s Office are presently engaged in a cooperative study of the Hydrogeology and Ground-Water Resources of Northwestern New Mexico. The purposes of this paper are to introduce our project, review tine coal and uranium resources of the San Juan Basin, and discuss the various hydrogeologic considerations recognized in their exploitation.

Jan 1, 1976

By Leslie Carver

The effects of longwall mine subsidence on water resources were studied at a West Virginia coal mine (mine Z) by Carver (1994). Data were obtained for 137 domestic supply wells and springs and 12 baseflow streams. Subsidence caused short-term dewatering (of a few days to weeks) of wells located on lower hillslopes and valleys, and long-term dewatering of hillslope and hilltop springs (with no recovery yet). New or increased spring discharge was observed at lower elevations. Unsubsided water supplies experienced no dewatering beyond a nearby panel&apos;s 27°-38° angle of dewatering influence zone. Subsidence from longwall mining beneath streams commonly reduced discharge when panel ages were less than two to three years. However, "normal" discharge was typically observed over panels greater than three years in age; such streams exhibited lower baseflow recession constants, moderated winter baseflow, and increased summer baseflow compared to unsubsided streams.

Jan 1, 1994

By G. Bloomsburg, R. E. Williams, S. D. Vincent

A modeling scheme is developed to simulate the hydrogeologic effects of mine design and development in unsaturated rock. Simulations are conducted using the UNSAT2 finite element computer program and hydrogeologic data from the site of a proposed mined-out waste repository at Yucca Mountain, NV. Results of the simulations are analyzed for: •variations in the direction of ground water flow and in the distribution of pressure head caused by the design of the mined out openings; and •mine design variables that affect the predicted rates of mine water inflow. Evaluating the hydrogeologic impacts of mine design and mine development in unsaturated rock is significant in several respects. Characterization of the preemplacement of wastes along the fastest path ground water flow system at the Yucca Mountain site has been a primary research effort. Ultimately, however, the degree to which waste isolation is achieved will depend largely on the post-mining hydrogeologic environment as altered by the mine design and on the radionuclide inventory and resulting heat effects of the repository. Therefore, an ongoing characterization of the proposed mined-out nuclear waste repository at Yucca Mountain, NV, is recommended. Modeling results indicate that: •mined out openings will affect the movement of ground water, both in rate and direction; •hydraulic effects of mine development depend on the hydrogeologic environment and on mine design geometry; •mine water inflow is possible in the unsaturated zone, even for mines developed in hydrogeologically homogeneous rocks; and •mine water inflow can occur at values of down ward flux that are appreciably less than the saturated hydraulic conductivity of the overlying rocks.

Jan 1, 1991

By Colin J. Booth

Hydrogeological impacts of active longwall mining were studied at two sites in Illinois. At the site with the more transmissive sandstone aquifer, aquifer permeabilities increased an order of magnitude due to subsidence. Piezometric levels declined with subsidence due to increased porosity, and ahead of mining due to a transmitted drawdown. Levels recovered rapidly at first and fully over two years. At the site with the less transmissive aquifer, impacts were similar except that recovery has been limited. Local aquifer enhancement through increased yield can occur, but only where the aquifer is transmissive enough for recovery.

Jan 1, 1986