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By Turker L

The leaching of Tellness (Norway) ilmenite concentrate in hydrochloric acid and mixed aqueous HCl-alcohol solutions at boiling temperatures was investigated. It was found that the alcohols methanol, ethanol and ethylene glycol all substantially increased the leach rate and in the case of methanol and ethanol this was achieved at lower boiling temperatures compared with aqueous HC.

Jan 1, 1986

By S. C. Sun

Pennsylvania has ample reserves of high-alumina clays which are potential sources of alumina, but many of these clays contain large amounts of iron, which makes them unsuitable for treatment by acid processes(1). The purpose of this investigation was to determine the optimum conditions for the selective hydrochloric acid leaching of iron (2-4) prior to the sulfuric acid extraction of alumina from Pennsylvania ferruginous high-alumina clays. This was accomplished by first testing the iron-bearing minerals and the clay minerals most often encountered in Pennsylvania clays to determine their rate of dissolution in hydrochloric acid solutions. The results of individual minerals were then based for leaching Pennsylvania clays with a 19% hydrochloric acid solution at the boiling point of the acid for approximately 30 minutes to achieve as high as 90% iron removal and only 2-5% alumina losses.

Jan 1, 1968

By Zengjie Wang

Investigation on hydrochloric acid leaching of the ilmenite from Panzhihua, China was carried out to prepare synthetic rutile. The leaching parameters were optimized to obtain high content of TiO2 in the products. The experimental data suggest that an optimum leaching can be realized with 30% acid, a solid/liquid ratio of 1/4 at 95°C for 4h, and ore ground for -400 mesh size. After the acid leaching, an additional alkaline leaching process using hot NaOH solution was performed, and then the products was in grain form followed by heat treated at 900°C for 2h in order to extract Si and increase the particle size of synthetic rutile. The final product has a high content of TiO2 (about 95%), a low content of chlorine consuming elements (total CaO+MgO =0.07%) and a suitable particle size distribution for chlorination process.

Jan 1, 2008

By Caitlyn J. McKinley, Ahmad Ghahreman, Maziar E. Sauber

Ever-growing global needs for critical metals, such as rare earth elements (REE), and base metals, such as copper and nickel, and their environmental impact motivated the pursuit of sustainable flowsheets. Regeneration of hydrochloric acid in chloride-based leaching flowsheets as a critical unit operation is an example of such endeavours. This study presents an efficient hydrochloric acid regeneration method from a magnesium chloride solution waste by addition of sulphuric acid in relatively low temperatures. The effects of temperature, initial magnesium chloride concentration, amount of sulphuric acid added, and airflow are examined. Experimental work are focused on temperatures between 80 and 95°C, initial magnesium chloride concentrations of 2 to 5 M, 100% to 220% stoichiometric sulphuric acid additions, and airflows between 200 to 600 mL/min. The developed technology recovers hydrochloric acid at a high rate and concentration with a relatively small environmental footprint. INTRODUCTION The mining and metals sector is under increasing environmental and economic pressure to make more efficient use of chemical reagents and energy in the production process. This affects several areas of process and flowsheet design such as the selection of the most appropriate unit operations and the overall design of the process steps paying heed to sustainability. Owing to the inherent inefficiencies of physical and chemical processes used in the mining industry, there will be materials and streams generated that are not a desirable part of the envisaged flowsheet. Thus, methods are implemented to recover and recycle such effluents. If the recovery and recycling are not economical, then procedures are followed to neutralize and dispose these effluents. In many cases, these effluents are potential contaminants or hazardous materials, and their disposal should be looked at in a much larger context. The safe management of the contaminants and hazardous effluents is a daunting problem in the mining industry and is fraught with technological, economic, social, and political challenges.

Jan 1, 2019

By E Yll÷, O HyvSrinen

Outokumpu has developed a new chloride leach process, called HydroCopper«, to treat copper concentrates. Chalcopyrite is quite refractory in leaching and in sulfate milieu an autoclave of high temperature and pressure is required. However, in the HydroCopper«-process copper sulfides can effectively be leached in atmospheric pressure using strong, aggressive chloride solution and copper (II) ions as oxidant. Copper is precipitated from the purified pregnant leach solution as copper (I) oxide, which is filtered and reduced by hydrogen gas to metallic copper powder, which is melted and cast into copper product. Sodium chloride formed in precipitation is decomposed in a chlor-alkali electrolyser, the products of which are circulated back to the process: sodium hydroxide to copper (I) oxide precipitation, chlorine gas to leaching and hydrogen gas to the reduction of copper (I) oxide. During 2003 - 2004 the performance of the HydroCopper«-process was confirmed in a demonstration plant processing one tonne of copper per day. It has been found to be applicable for different kinds of concentrates and can also tolerate a wide range of impurities. A significant advantage of the process is that gold can be leached as a chloro-complex and recovered with active carbon. HydroCopper« can economically recover copper from concentrates and process to a cast copper product. The best utilisation of the process is in most cases achieved when the plant is situated at the mine site. Higher recoveries are attained by the optimisation of the whole operation chain from the mine and the concentrator to the HydroCopper« plant.

Jan 1, 2005

By L. Haavanlammi

The Outokumpu HydroCopper® process is a chloride based atmospheric leaching process alternative that can treat a variety of different concentrates. Chalcopyrite and other copper sulfides can effectively be leached under atmospheric pressure in strong, aggressive chloride solution using copper (II) ions as oxidant. Impurities are removed from the solution as carbonates and ion exchange. Copper is precipitated from the purified pregnant leach solution as copper (I) oxide, which is filtered and reduced by hydrogen gas to metallic copper powder, which is melted and cast into copper product. Sodium chloride solution from copper (I) oxide precipitation is decomposed in a chloralkali electrolyser, to products of which are circulated back to the process. The process has been designed for copper concentrates and is a fast and economical way to produce copper wire rod directly from concentrate. The process can efficiently handle impurities like arsenic and mercury, which can be harmful in the pyrometallurgical processes. The process has been tested in the laboratory and 1 ton/day demonstration plant scale and it has been proven to be commercially viable. The process has been designed to meet the strictest directives for emissions. Other environmental factors are carefully considered to obtain the highest possible eco-efficiency.

Jan 1, 2007

By Mikko Ruonala, Pertti Lamberg, Olli Hyvärinen

The smelting of copper sulphide concentrate is the dominant route in copper production (Figure 1). Heap leaching of oxidized copper ores with weak sulphuric acid together with copper solvent extraction and electrowinning has gained popularity during recent decades, and it accounts for close to 20 % of primary copper production. Heap leaching offers advantages such as lower costs and consequently the construction of a production plant at a mine site is made possible. Limited resources of oxidized copper ores, the long leaching time of chalcopyrite and inability to recover gold inhibit this growth. The HydroCopperTM process developed by Outokumpu Technology at the laboratories of Outokumpu Research, Pori, Finland, is a new chloride leaching technology /1,2/, which offers an alternative to smelting and heap leaching (Figure 1). In the HydroCopperTM process sulphidic concentrates with various mineralogy and grade can be treated at the mine site to produce high-quality copper. Instead of copper cathodes the HydroCopperTM end products are copper wire rod, copper bars or copper billets. One of the advantages of HydroCopperTM technology is that gold can also be recovered in the process simultaneously /3/. To confirm the functioning of the new process and to dimension equipment Outokumpu Technology built the HydroCopperTM demonstration plant in Pori, Finland /4/. It has a capacity of 1 metric ton of copper per day. After testing with Pyhäsalmi copper concentrate in 2003, the first commercial demonstration run with Erdenet copper concentrate took place in 2004.

Jan 1, 2005

By Michael Arnold, Bob Faulhaber, Joe Nichols

"Center Hill Dam is a critical part of the infrastructure controlling floods at the Caney Fork River and reducing flood levels at the Cumberland, lower Ohio and Mississippi Rivers. The Center Hill Dam Foundation Remediation Project was necessary to address Karst features in the foundation rocks and observed signs of distress of the dam. From 2011 to 2014 BAUER Foundation Corp. (BFC) performed deep foundation works for this project. The executed features of work include the installation of two walls. The first wall extends throughout the clay embankment into the underlying rock to provide encasement during the construction of the second wall. Its width of 7.4 feet makes it the widest diaphragm wall ever installed. The second wall is the actual seepage barrier and provides a continuous 2- feet wide wall. It extends through the first wall into the underlying rock and is up to 300 feet deep. The paper introduces the project, the requirements specified by United States Army Corps of Engineers (USACE) for encasement and barrier wall and the approaches taken by BFC. It discusses the ground conditions and describes the excavation equipment as well as the excavation methods used. A special focus is put on the steering capabilities of the hydrocutter equipment and the verticality performance.PROJECTBeginning in 2011, BFC was tasked by the USACE with the installation of a seepage barrier/cutoff wall at the Center Hill Dam Foundation Remediation project under a partially performance based specification. The remediation was necessary due to karst features in the foundation rocks and observed signs of distress, which led USACE to rate the dam with the most critical dam safety action classification (DSAC I). The executed features of work include the installation of two walls. The first wall, an encasement wall, extends vertically through the clay embankment and is embedded minimally into the underlying bedrock to provide embankment stability during the construction of the second wall, the barrier wall. The encasement wall is constructed of overlapping panels 7.4 feet (2.25 m) wide, which is the widest diaphragm wall ever installed, and up to 210 feet (64 m) deep. The second wall is the seepage barrier and provides a continuous 2 feet (0.6 m) wide wall consisting of overlapping panels. It extends through the encasement wall into the underlying bedrock and is up to 307 feet (93 m) deep. BAUER BC40 and BC50 hydrocutters mounted on MC96 and MC128 foundation cranes were used to perform the majority of the works (Figure 1). Excavations were performed under bentonite slurry (encasement wall) and water (barrier wall) and concrete was poured with the tremie method. Adding to the challenges, the project had to be executed in an environmentally sensitive area. Based on the high risk, a special focus was put on monitoring, quality control and geometric accuracy. The WallTracker information management system was used to share all relevant data between BFC and USACE (Roff et al. 2014)."

Jan 1, 2017

By K. Professor Heiskanen

The improvement of grinding circuit efficiency is a constant industrial requirement. It has often been connected to the improvement of classification. The paper discusses some operational aspects of hydrocyclone classification. A hydrocyclone should be operated close to roping but should not with high density slurries go to roping. Unfortunately roping is not well understood and roping models for controlling hydrocyclone operation are not adequate. The paper discusses also some ways of improving the classification in terms of bypass and imperfection. The last part of the paper discusses the effect of bypass and imperfection on circuit performance.

Jan 1, 1997

By M. R. Khalesi, S. Bellec, C. Bazin, D. Hodouin

This paper proposes a classification model to predict the split coefficient of gold ore particles as a function of the particle size and gold content. The model is calibrated and validated using data obtained from the sampling of an industrial grinding circuit. Model calibration is based on a complete simulation of the circuit and involves parameters related to the gold grain distribution in the ore as well as a grinding and liberation model. Since cyanide is added into the studied grinding circuit, assumptions related to gold dissolution in the mills are made to allow simulation results which reflect industrial behaviour patterns.

Jan 1, 2011

By Nageswararao K

A series of tests was carried out on one of the rock-pebble milling circuits treating complex nickel ores at Kambalda Nickel Operations of Western Mining Corporation. A mathematical model to describe the behaviour of a 508 mm hydrocyclone was developed from the data.A "flat" reduced efficiency curve was observed for the system. This was attributed to a marked difference in the specific gravity of different size fractions of the feed. A modified approach in describing the shape or the reduced efficiency curve resulted in accurate prediction of the hydrocyclone performance.

Jan 1, 1981

By P. K. Davis, B. Gharib

The results of a previous basic study of the flow and design characteristics of hydrocyclones demonstrated that a recovery as high as 99% with a product rating* of 0.95 can be achieved on a batch+ basis with a single, water-only cyclone if it is configured properly. The next logical step was to demonstrate continuous processing of gob for the efficient recovery of coal by means of a laboratory-size demonstration system. A project to design and construct such a single-¬cyclone system was sponsored by the US Department of Energy, which also sponsored the initial study. A recovery of 93% with a product rating of 0.89 was demonstrated. The system design and the data taken are discussed.

Jan 1, 1990

By S. A. Sayed, M. N. M. Ahmed, M. A. Doheim

The performance of a 12.7 cm hydrocyclone was investigated by considering the effect of design variables (diameters of the vortex finder and apex) and operating variables (pressure drop and solids content of the feed) at a medium feed solids concentration of mixed minerals. Cut-size was found to be the most important parameter in hydrocyclone design and operation. The effect of feed pressure in reducing hydrocyclone cut-size is less pronounced at medium feed solids concentration with a mixed mineral feed. The choice of vortex finder diameter and apex diameter becomes more sensitive at medium feed solids concentrations. The effect of feed solids concentration in increasing the cut-size becomes less marked at higher concentrations. Predictions of an empirical model were found to be in good agreement with experimental data. Comparison of results obtained from the model with those predicted by theoretically derived models showed the latter to be more promising, with the turbulent two-phase model giving closer agreement with the experimental data

Apr 1, 1995

By K. Rajamani

A mathematical model based on the pertinent fluid dynamic equations to predict the performance of the hydro cyclone has been developed which will eventually replace the empirical model. Experimental measurements of fluid velocity profiles made in a 75 mm hydrocyclone by laser Doppler velocimetry (LDV) agree well their predictions by solving the Navier-Stokes equations numerically. Particle slip velocity and particle trajectory were computed which in turn, yields separation curve of the hydrocyclone.

Jan 1, 1988

By Jose A. Delgadillo

The hydrocyclone problem has been a challenging task for the last 30 years. In the 80’s and 90’s Computational Fluid Dynamics solution to this problem began to appear. These were unsuccessful due to over simplification. In the past 3 dimensional solution with ?-e model and Reynolds Stress Model have been published. In this paper RSM and ?-e models are compared with velocity profiles measured in 75 mm and 250 mm diameter hydrocyclones. It is shown that results are not satisfactory with RSM or ?-e and that a model called Large Eddy Simulation is needed to describe velocity profile evolution and size classification.

Jan 1, 2005

By F. Boylu

In this study, Ca-bentonite was subjected to a series of systematic hydrocyclone tests with the aim of developing separation procedures and in turn achieving optimum recoveries. In hydrocyclone tests, vortex and apex diameters and also feed pressures were investigated. In each hydrocyclone set, vortex diameter was kept constant while the other two parameters varied to produce bentonites con-centrates of various smectite contents. The separation efficiencies were evaluated based on the cation exchange capacity (CEC), particle size and swelling index. The detailed hydrocyclone tests showed that, upgrading of Ca-bentonites require procedures different from the bentonites reported in the literature. Sodium and mixed bentonites are easy- to-disperse and easy-to-separate whereas calcium types need to be scrubbed rigorously for disintegration. Scrubbing properties of ca-bentonite were investigated as a function of scrubbing time and percent solids by weight (PS). The scrubbing conditions at 700 rpm for 1.5 hours and percent solids of 30 % were found more effective for achieving a better quality bentonite. In addition to the parameters mentioned above, the effect of percent solids on hydrocyclone separation was also studied. Although Ca-bentonites permit studying at higher percent solids, increasing solids content of the pulp deteriorated the quality of the clean products. Application of an appropriate separation scheme enabled the development of a unique separation procedure involving stage wise scrubbing followed by hydrocycloning which yielded calcium bentonite concentrates with CEC of 90 meq/100 g and high swelling indexes of 12 mL from the original bentonite of 65 meq/100 g and 7.0 mL, respectively. These results indicate that upgraded bentonite products can be conveniently used in various diverse industrial applications including bleaching earth, desiccant, cat litter, paper etc.

Jan 1, 2014

By L. H. E. Weyher

In a previous paper presented at the 1966 Annual Meeting of AIME we reported our work, conducted at the Pennsylvania State University, on the hydrocyclone washing of fine coal.' The initial evaluation based on that work demonstrated the feasibility of hydrocyclones as fine-coal cleaning devices, and in that previous paper we presented selected test data that showed in principle how product yield and assay respond to variations of the major cyclone operating variables. The present paper reports in greater detail on the findings and presents a comprehensive evaluation of our data as follows: ? Hydrocyclone throughput rates were related to feed pressure and other variables by regression equations. These equations are compared with other capacity- versus-pressure drop expressions taken from the literature on classification cyclones.

Jan 1, 1968

By D. T. Jr. Tarr

History of Development The hydrocyclone, probably because of its basic simplicity, has been used for various classification applications since before 1890. A patent was granted in the United States in 1891 to Bretney on a device for separating sand from water, collecting the sand in a closed chamber for intermittent discharge, practically identical to some present-day water desanding cyclones. Between 1900 and 1937 there were 30 or more additional patents issued on liquid cyclone configurations or their use. About 1937 liquid cyclones began to be used commercially in the treatment of cellulose fiber in the pulp and paper industry separating contaminating particles from the fiber in water suspension used for making high grade paper products. Nichols Engineering & Research Corp. of New York was marketing a liquid cyclone for cleaning sand and din particles from fiber suspensions in the pulp and paper industry by 1937. The designs during this period were such that the cyclones discharged a small amount of relatively high density material into a chamber connected to the cyclone apex which in turn discharged the collected dirt material intermittently. By the early 1940s hydrocyclones as we know them today began to appear both in the pulp and paper industry and in coal prorzssing.18 Considerable experimental work was done on small, mostly 3-in.- diam, cyclones operating at relatively high pressure drops, in the range of 50 psi, to remove very small contaminating particles from cellulose fiber in the production of high-grade writing papers in the paper industry.18

Jan 1, 1985

By W. Rubarth

The kaolin losses in hydrocyclone classification are determined by the fines, which are discharged together with the water to the underflow. This paper presents an improved technique of water injection to the conical part of the cyclone applied especially for small cyclones in kaolin preparation. In small hydrocyclones water, injection is a sensitive process. Therefore, the process was stabilized by controlled water injection dependent on the measurement of the underflow shape. Three applications of this innovation are presented. In the first case, the water injection is applied for the separation stage in dilute suspension where the final product is produced in the overflow of a 50mm hydrocyclone. The underflow contains sand and residual kaolin. For a higher kaolin recovery, the underflow is usually treated downstream in washing cyclones. The wash water injection results in a 45 ? 50% - reduction of the kaolin fraction <25µm in the underflow. Thus, water injection to the classifying cyclone leads to a separation comparable with a downstream washing stage. An additional hydrocyclone stage can be deleted. The second application refers to a classification in dense suspension. Here, the underflow of the last hydrocyclone stage was directed to a washing in a 50mm hydrocyclone. The additional injection of 3L/min water in to the conical part of the cyclone reduced the kaolin losses by half.The third application was executed in the washing stage equipped with 75mm hydrocyclones where the underflow is directed to flotation. Using the water injection the kaolin recovery in this stage was increased by approximately 20%. Keywords: hydrocyclone, classification, kaolin beneficiation, water injection, underflow washing

Sep 1, 2012

By Y. H. Kim

A simulation procedure has been developed that realistically portrays aggregate growth and disintegration for particular types of floc structures in water and wastewater treatment processes. The procedure requires local dissipation rates and specification of an interaction distance between colliding particles. A principal difficulty encountered in polymer flocculation, however, arises from changes in conformation of adsorbed macromolecules. Therefore, in systems where polymer flocculation occurs by bridging, dynamic changes in the particle size distribution depend upon the interaction of nonlinear. stochastic hydrodynamics with particles whose growth results from a number of concurrent and sequential random processes.

Jan 1, 1988