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Geochemical projects in progress or recently completed in the Bureau of Mineral Resources, Geology, and Geophysics (BMR) cover a wide range of topics and include research projects, regional studies, and prospecting programmes. However, in these notes emphasis is given to projects which are directly relevant to mineral exploration.FIELD INVESTIGATIONSStream sediment sampling, rock and soil sampling, and geobotanical surveys have been used by the BMR in a number of areas, partly in attempts to locate specific zones of mineralization, and partly to investigate the effectiveness of the various methods under different conditions of climate and topopraphy and in different geological settings.Stream sediment sampling has been most successful in the Territory of Papua and New Guinea. For example, in the South Sepik area, zones of disseminated su1phide mineralisation were found to give rise to anomalies with peak values of up to 1,000 p.p.m. copper, compared with background values of about 40 p.p.m. (Dow et al., 1968). By contrast, the results of rather limited work in the Northern Territory and in the Kimberley district of Westen Australia were inconclusive.Rock and soil sampling, on the other hand, was successfully used in a number of areas in Northern Australia, particularly at Rum Jungle and Tennant Creek.Rum Jungle area In the Rum Jungle area, where uranium and base metal mineralization is mainly associated with a Lower Proterozoic black slate sequence, samples, of c-horizon soil or weathered 'rock are generally collectedfrom the bottom of drill holes, usually 15 to 20 ft deep, bored with a power-operated auger.Surface sampling indicates that such a technique would probably have shown up all the major geochemical anomalies delineated by deep sampling, but the latter gives slightly more consistent and slightly

Jan 1, 1970

By R Smart

This paper examines the longer-term predictive capacity of the GAMSPATH computer program (developed by the Alberta Research Council) for a waste rock (sample MS) obtained from the Kaltim Prima Coal (KPC) mine, Kalimantan that contained significant framboidal pyrite. The model was refined by comparison with the net acid generation (NAG) and column leach tests to provide a basis for calibration of the model for both short term and longer-term reaction trends. The oxidation of pyrite during the kinetic NAG test using H2O2 provides oxygen directly at the mineral surface, generating a measured oxidation rate for pyrite of 1.16 + 10-6 mol m-2 s-1, whereas the oxygen diffusion limited rate in the leach column air equilibrated reaction was of the order 10-8 mol m-2 s-1 as calculated from the GAMSPATH thermodynamic database. Results indicated that the oxygen derived from hydrogen peroxide had to be included as a reactant (eg a reacting mineral) in the simulation to account for the direct availability of oxygen at the sulfide mineral surfaces. Optical investigations identified the proportion, particle size, and surface area, of framboidal and euhedral pyrite in sample MS. The reactive surface areas of the two morphologies were very different (eg ratio: 5:1). To manage these two different pyrite morphologies the GAMSPATH thermodynamic database was updated to include framboidal pyrite, with similar thermodynamic properties and oxidation rate to euhedral pyrite but with a particle size based on the size of the individual internal framboid microcrysts. This modification, with framboidal pyrite reaction based on the size of its microcrysts produced results that correlated well with the kinetic NAG and column leach test results when the measured (kinetic NAG test rate) and calculated (column test rate) pyrite oxidation rates were employed. This provided some confidence that the model could be extrapolated to indicate longer-term geochemical reaction trends.

Jan 1, 2003

By M. Thompson, B. Coles, M. Hale

The use in regional geochemical reconnaissance of replicate analysis of natural coatings of iron and manganese oxides on the surface of pebbles in stream sediment is described. Pebble coatings were selectively analysed for their relative contents of absorbed trace elements by ablating a small quantity of the coating with a laser beam and sweeping the aerosol obtained into an inductively coupled plasma atomic emission spectrometer. Using this procedure, a geochemical survey in northwest Wales revealed anomalous concentrations of Cu, Mo, As, Zn, Cd, Pb and Co in the pebble coatings of streams draining the mineralised Coed-y-Brenin diorite and the Dolgellau gold belt.

Jan 4, 1992

By Otis M. Clarke

The purpose of geochemical research in the Alabama copper belt is to re-evaluate geochemical prospecting methods as related to igneous and metamorphic rocks in a humid climate. It is also a correlation of laboratory research on copper mineral solubility with geochemical anomalies over known mineral deposits. Geochemical prospecting in warm humid climates involves different problems and conditions than geochemical prospecting in semiarid areas. Stems and others (1972) reported soil surveys in a humid tropical environment in Bahia, Brazil, were not effective in outlining areas of copper mineralization. Clarke (1971) reported false anomalies in lateritic soils in Alabama over mafic rocks. Bjorklund (1971) reported biogeochemical sampling in Finland was ineffective in detailed work outlining potential mineralized areas, although it may serve to indicate regional areas of high mineral potential. During this investigation, water, stream sediments, residual soil, and organic matter, mainly twigs, were collected from three known copper-mineralized areas. Samples were selected so as to cross mineralized outcrops and results were correlated with copper stability charts as reported by Silman (1958) and Schmitt (1962). The geochemical research performed in Alabama should be applicable to other humid areas. Geologic, Climatic, and Pedologic Setting The area of investigation is in the southern end of the Appalachian eugosyncline in eastern Alabama. It includes the Hatchet Creek prospect, Pyriton mining district, and Stone Hill copper mine. The copper mineralization is in calcium-rich metasediments that lie along the western flank of a high rank metamorphic belt. All three deposits are in the uplands of the Ashland Plateau section of the Piedmont physiographic province. The Hatchet Creek copper prospect (Clarke, 1963; 1971) consists of three mineralized areas that contain pyrrhotite, pyrite, and chalcopyrite in small crisscrossing veinlets.

Jan 1, 1972

This paper reviews the geochemistry of weathered nickeliferous sulphidic and lateritic profiles, the supergene behaviour of nickel and ore-associated elements, and their implications for exploration in an attempt to distinguish between barren and mineralised nickeliferous profiles. Nickel is an abundant accessory element in ultramafic rocks with background concentrations in some units up to 0.25 weight per cent. Ore-grades in fresh rock are mostly associated with massive and disseminated sulphide zones within magnesium-rich layered ultramafic sequences. In lateritic weathered terrain, nickel is also concentrated in the regolith profile. This process not only upgrades nickel in the gossanous weathered product of sulphidic deposits, but for sub-economic sulphide zones and some ultramafic rocks, is sufficient to result in a supergene resource. Ore-grade accumulations of nickel in regolith after sulphide-poor ultramafic rocks are referred to as lateritic deposits. Nickel sulphide zones and their ferruginous weathering products are collectively referred to as sulphidic deposits and are the major source of nickel in Western Australia. Mineral exploration in the Yilgam Block is hampered by deep lateritic weathered profiles (eg Butt and Sheppy, 1975; Smith, 1977; 1982). During the nickel boom of 1967 - 1972, most discoveries resulted from the location of outcropping nickeliferous gossan and ironstone. Exposed ultramafic terrain with nickel sulphide potential were explored intensively, mostly by gossan and soil sampling. However, up to 85 per cent of the area of the Yilgarn Block is buried by transported regolith. In these covered areas, barren and mineralised rock responses at the surface are similar and soil sampling produced unreliable results due to many false anomalies. A statistical, multi-element approach to regional geochemical exploration has evolved. Potential trace element indicators investigated, include Co, Cr, Cu, Ir, Mn, Pb, Pd, Pt, Sc, Se, and Zn. In recent years, trace element ratios have also been tested with varying degrees of Success.

Jan 1, 1996

By G. R. Webber, P. J. Whittaker

"A multielement (Au, Cu, Pb, Zn, Ni, c-, Ag, As, Hg, Co, and S) geochemical rock sampling survey was carried out in 1977 in the Munro Township area of Ontario to assess the application of rock geochemistry for gold exploration in the region. Detailed sampling with analysis for gold and arsenic was done in 1986 in the immediate vicinity of the Croesus Mine.Samples of quartz veins and rock formations were taken in regional traverses and in more detail near old showings, prospect pits, and trenches. Quartz, graywacke, carbonate rock, and rhyolite contain the highest concentrations of gold for samples taken away from the old workings. Ultramafic rocks and gabbro have uniformly low gold. Basalt samples have slightly higher geometric means, but individual samples contain high gold concentrations. Multielement highs are mostly in mineralized quartz samples. Gold distribution is independent of other elements in most other rock types. Samples near old showings possess elevated concentrations of gold indicating that prospecting for individual mineral deposits by bedrock sampling is feasible. Concentrations of gold greater than 100 ppb are mostly within 30 m of old workings. Those samples which contain greater than 1000 ppb Au were obtained from quartz veins, basalt, graywacke, and rhyolite.High concentrations of gold were not notably concentrated near the Contact Fault although some anomalous samples came from near and on both sides of the fault. Arsenic concentrations are elevated near the Contact Fault. Detailed sampling near the Croesus Mine suggests that gold was introduced with faulting, alteration and quartz veining. Gold and arsenic have been added to the wallrock in the vicinity of the main veins."

Jan 1, 1989

By G. D. Nicholls

There have been very few attempts to isolate the various factors that contribute to the overall imprecision of geochemical analytical procedures, due in part to the difficulty of distinguishing between them. The technique of spark source mass spectrography permits a ready distinction between the contributions to overall precision from sampling error and instrumental and other errors. With conventional methods of sample preparation for this technique sampling difficulties are responsible for 80-90 per cent of the overall imprecision. Examination of the probable location of the major difficulties in sample preparation indicates that the preliminary stage of grinding, mixing and extraction of a first aliquot (about 1/100 of the original sample) is generally perfectly adequate. The difficulty lies in the subsequent stages of sample preparation. Dry mixing techniques are unlikely to give good precision if the sub-samples actually examined by the analytical technique are less than 10 mg in amount. Solution techniques are less prone to sampling difficulty. Fusion techniques, unless conducted with great care, can produce more difficulty than dry mixing. Sample preparation is critical to the success of many analytical procedures. Selection of appropriate sample preparation techniques requires just as much care as the selection of techniques for the actual analysis.

Dec 1, 1971

By Michael M. Kimberley

Stratiform uranium deposits occur in Canada along the north shore of Lake Huron near the base of the Middle Precambrian Huronian Supergroup. Outcrop of the Buronian Supergroup extends for over 400 km from Sault Ste. Marie in the west eastward through Sudbury and then northeastward to Cobalt. Maximum stratigraphic thickness exceeds 5 km. The predominant Huronian rock type is metamorphosed sandstone (quartzite), with sub- ordinate argillite, conglomerate, mixtite (possibly tillite), volcanic rocks, and minor limestone, Much of the quartzite is highly feldspathic. Substantial uranium ore was first discovered in Huronian rocks in 1953 and has been exploited continuously since the initial mine-mill plant was constructed at the Pronto ore body, 30 km south of the present townsite of Elliot Lake. Only one ore body remains in production, however. It is shared by Rio Algom and Denison Mines 14 km north of the town of Elliot Lake.

Jan 1, 1980

By I Warren, M P. Simpson

Adularia-sericite epithermal ore deposits have well-documented alteration mineral zonation patterns with distinctive geochemical signatures. Proper use of whole-rock geochemistry can provide useful vectors for exploration and can enhance efforts to characterise and quantify the mineralogy and intensity of hydrothermal alteration.   Analyses of Au and Ag provide the most direct vectors to orebodies, and pathfinder elements such as As, Sb, Hg, Zn, Pb and Se are similarly zoned around at least some orebodies. However, the minerals that contain these elements occur almost exclusively in veins, and therefore identifying geochemical vectors related to wallrock alteration that is zoned outward from orebodies is crucial for effective exploration.   Distal alteration zones contain quartz-illite-chlorite-carbonate-pyrite, whereas samples proximal to veins contain quartz-adularia-pyrite, with lesser though variable illite-chlorite-carbonate. Therefore, adularia-sericite epithermal ore deposits show K alteration in their cores. The resulting K-metasomatism can be evaluated in several ways. Areas that have been most intensely altered are commonly characterised by highest K contents, but these results can be complicated by variations in rock type across the prospective area. Potassium mass balance results provide a robust and rigorous assessment of K-metasomatism, however, knowledge about the composition of fresh rocks and correct identification of fresh precursor compositions of altered rocks are required. Three alteration indices provide effective evaluation of K-metasomatism: 1.   the K number, which is the ratio K/(2Ca+K+Na) (molar); 2.   Barrie values [(K2O * 100) / Sr]; and 3.   the Rb/Sr ratio. In most places these provide similar vectors, although K numbers can be complicated by the appearance of hydrothermal calcite and/or albite.   Plots of K/Al vs (2 Ca + K + Na)/Al (molar) allow estimation of the intensity of K-metasomatism and its mineralogical products, thereby complementing traditional XRD and petrographic studies of alteration minerals.

Jan 1, 2005

By D. Zaharaki

In the present experimental study the geochemical stability of inorganic polymers was studied by immersing them in various solutions (distilled water, seawater and 0.5N HCl) for a period of 7 months. Inorganic polymers were synthesised by mixing ferronickel slag with kaolinite, potassium hydroxide and sodium silicate solution. The cement like paste was heated at 80 °C for 48 hours and left for curing at room temperature. Their structural integrity was assessed by compressive strength testing after subjection to freeze-thaw cycles as well as high temperature heating. XRD studies were carried out in order to identify new formed phases and provide useful information regarding the progress of the mechanisms involved.

Jan 1, 2008

The mercury, gold, silver, copper, lead and zinc values of soils over altered and mineralised rock were determined to establish the potential use of mercury as an indicator element in geochemical prospecting. The results are presented to show that mercury can be used successfully in prospecting for precious metal mineralization in the Thames-Waihi area.

Jan 1, 1979

Acid soluble calcium is depleted in drainage sediments from hydrothermal alteration centres in the Coromandel Peninsula. The routine analysis of acid-soluble calcium on drainage samples is an economical and effective technique for outlining hydrothermal alteration centres in volcanic terrains.

Jan 1, 1979

By William M. Shepard

The Tintic mining districts of central Utah com- prise one of the major silver-lead producing areas in the United States. Ore valued at nearly $450 million has been produced from these districts since the initial discoveries, in 1869, of veins cutting the Silver City monzonite stock. Subsequent production from the famous manto-type "ore runs", which characterize the Main Tintic district, was followed during the past 40 years by discovery of the blind orebodies of the East Tintic district, including the famous Tintic Standard mine and the most recent discovery, the Burgin mine, currently being brought to full production by Kennecott Copper. The occurrence of blind orebodies of exceptional size and grade in both the Main and East Tintic districts has made this area a field laboratory of major importance for the study of geochemical dispersion halos and alteration features associated with known ore, and has led to the discovery of additional concealed orebodies. The larger share of the basic data-gathering and interpretation has been done by members of the U.S. Geological Survey who have been studying the Tintic mining areas since before the turn of the century. These studies have been supplemented and expanded by the geological staffs of the local operating mining companies, by exploration geologists and by students.

Jan 4, 1966

By S. B. Ballantyne, D. R. Boyle

"Detailed studies have been conducted on the dispersion of uranium in stream waters and sediments around various types of mineralization and hitherto unexplained anomalous areas in the Okanagan Valley and Highland region of south-central British Columbia. These studies were part of the jointly funded and planned Federal-Provincial Uranium Reconnaissance Program of the Geological Survey of Canada and the British Columbia Ministry of Energy, Mines and Petroleum Resources. Statistical analysis of regional data indicates that U in stream waters and sediments varies considerably for different rock types, thus affecting data interpretation. In addition, the data demonstrate a poor correlation between U in stream waters and their associated sediments which can be largely accounted for by variations in climate and water and sediment composition. Regional trends in the distribution of U can be explained in terms of the above secondary factors as well as primary metallization phenomena.Significant correlations between U and F, and U and Mo can be explained by certain magmatic and mineral-forming processes. U shows little correlation with other base metals.The dispersion characteristics of U in the vicinity of Miocene "" basal type "" mineralization ; uraniferous pegmatite terranes, anomalous lineaments in granitic terranes and high-background volcano-sedimentary areas are discussed. Highly anomalous U concentrations in waters and sediments may not always be indicative of mineralization, and guidelines for interpretation require a sound knowledge of the geological and secondary processes operative in the area."

Jan 1, 1980

By Seong-Taek Yun, Chil-Sup So, Seung-Jun Youm

The greisen-bordered quartz veins are spatially, temporally and genetically associated with a late Cretaceous granite intruding an early Palaeozoic, limestone-rich formation. Paragenetic data indicate three stages of hydrothermal mineralisation, the first typically in or within 500 m of the granite stock and showing vertical zoning between deeper Mo and higher W, the other two more abundant in the upper and outer parts of the mineralised area. Fluid inclusion and stable isotope data indicate that hydrothermal veins formed over a temperature range of 120-395 degrees C from low-salinity fluids. Early wolframite and molybdenite deposition in stage I occurred at temperatures of 300-395 degrees C from magma-derived, low-salinity, CO2-rich fluid, mainly as a result of fluid boiling and associated CO2 effervescence. Progressively larger volumes of local meteoric water entering the system led to the successive deposition of scheelite in stage I vugs, stage II base-metal sulphides and stage III fluorite-carbonates. Remobilisation of W and its later deposition of scheelite in the outer and shallower portions of the system occurred at 215-275 degrees C and stage II and III mineralisation from lower-temperature fluids that became progressively lighter in stable isotopes. It is concluded that the influx of meteoric water increased with distance from the cooling pluton

Jun 18, 1905

By Stephen Day, Maria Falutsu, Gary Coulter

Open-pit mining began at Red Dog in 1989. Mining is expected to continue past 2030 but closure planning is an ongoing process. Geochemical studies of rock and tailings were begun in 1996 as part of development of closure plans to address leaching of metals and ARD. The deposit has many different primary and secondary sulfur minerals in amounts that preclude the use of conventional geochemical characterization methods. This paper will describe development of a specific chemical method to estimate the speciation of sulfur and classify wastes according to reactivity.

Jan 1, 2000

By L. L. Damon

A geochemical study of cyanide neutralization processes was conducted at Brohm Mining Corporation to gain a better understanding of the leach pad behavior and to develop a simplified procedure to quantify the attainment of compliance with permitted cyanide neutralization criteria. Such attainment is a prerequisite for off-loading spent ore from the leach pad at the "load/unload" gold heap leach operation. The geochemical study program consisted of size fraction analyses and weak acid dissociable (wad) cyanide analyses for various sections of the spent ore from the actual leach pad. Further testwork included size fraction analyses and wad cyanide analyses on the ore from four 29 foot laboratory test columns which were leached and neutralized with different neutralization treatments in parallel with an actual active leach pad. Wad cyanide was analyzed daily on the neutralizing columns and various parameters were monitored weekly on the influents and effluents during the leach cycle and neutralization period. A comparison was made of neutralized effluent chemistry and porewater extraction fluids, as well as an analysis of the selective adsorption of cyanide on various particle size fractions.

Jan 1, 1992

By F. C. Canney

Geochemical prospecting seeks hidden mineral deposits by sampling for variations in the chemical composition of naturally occurring materials. Usually the samples are of soils and other products of weathering and erosion-surface materials extremely susceptible to contamination by human activities. Except when a survey is conducted well away from populated areas, contamination is an ever-present hazard. The program's success is particularly endangered when the contaminants are the elements sought; if these occur erratically throughout an area, spurious anomalies completely unrelated to mineralized areas can be formed. Evenly distributed contamination can be dangerous too, if it raises the background to such a level that true anomalies can no longer be easily detected. Suppose, for ex- ample, that in an area where the lead background is 20 parts per million the soil over a lead vein contains 1000 ppm of lead. Here the contrast would be 50 to 1, which is very satisfactory for geochemical surveying. Now if 1000 ppm of lead from some source were added evenly to the soil in this area, the contrast would be reduced to about 2 to 1, and the anomaly would no longer be readily detectable because a threshold of significance twice the value of the background is the minimum generally used for interpreting geochemical data.

Jan 2, 1959

By F R. M Pires, Y Hasui, A Schrank

The iron ores of Alegria mine are composed of itabirites enclosing minor bodies of high-grade ores. The itabirites are classified according to mineralogical composition in five types: martite-rich, goethite-rich, specularite-rich, magnetite-rich and anphibolite-rich ores. The hematites are martite-rich, magnetite-rich, specularite-rich and more rarely, amphibolite-rich. Other classification criteria of the ores are based on the physical properties and the degree of compaction. As such, the itabirites and hematites can be classified as hard, friable and soft types. The mineralogical/textural evolution of the ores is linked to the pressure and temperature conditions that accompanied the tectonic processes in anphibolite facies and the different degrees of subsequent surficial weathering processes. Petrographic and microstructural studies indicate that the magnetite and amphibole bearing itabirites represent the parent rocks that created the other itabirites and that the specularite itabirites and the hard martite types are related to silica dissolution and redeposition in zones of high and low strain. Most of itabirites ores correspond to chert oxide facies banded iron formation, except the goethite and amphibole bearing itabirite that resemble a silicate or oxide-silicate facies with minor carbonate impurities. The great mass and pods of soft martite itabirites are probably shaley oxide facies BIFs with little volcanic contribution. Trace element contents of the AlegriaÆs itabirites show strong dissimilarities with BIFs associated with volcanism (Algoma type), but closely ressemble to the Lake Superior type, with high content in Cr, Co and low V, Ni, Cu and Zn. Although the absolute contents of REE present in the AlegriaÆs itabirites are, in general very low, the pattern when normalised by NASC is similar to the great majority of the Archean and Paleoproterozoic BIFs elsewhere in the world, and characterised by positive Eu anomaly.

Jan 1, 2002

By John B. Riddell

"AN EXCELLENT review of the status of applied geochemistry was given by Warren (1959) at last year's General Meeting of the C.I.M. The purpose of this paper is to present recent developments and trends. Several important books were announced during 1958: Ginzburg, I. I. Principles of geo-chemical prospecting. (In process of translation from the Russian by V. Sokoloff).Vinogradov, A. P. The geochemistry of rare and zvidely scattered chemical elements in soils. Consultants Bureau, N.Y. Korzhinskii, D. S. Physicochemical basis of the analysis of the paragenesis of minerals. Consultants Bureau, N.Y.In addition to these translations Mason's Geochemistry' has been revised, and Hawkes and Webb (personal communication) are publishing a book on geochemical exploration. A Symposium on Geochemistry was head in Paris in July, 1957, in conjunction with the XVIth International Congress of Pure and Al-lied Geochemistry. The abstracts of the papers presented at this Symposium were published in Geochimica et Cosmocl1imica Acta, 1958, Vol. 14, pp. 150-167."

Jan 1, 1960