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By K. Johnson, B. Schiffer

Demonstrating aquifer restoration is an essential component of regulatory approval needed to mine uranium, copper, and other minerals by in-situ recovery (ISR). A PHREEQC geochemical model provided a useful means of forecasting the time for restoration and predicting future groundwater quality following low pH mining at Strata Energy’s Ross ISR Project in northeast Wyoming. The model simulated groundwater quality at three phases of the process: at the end of mining; during restoration; and post- restoration. The model utilized the one-dimensional reactive transport and dual porosity features of PHREEQC. Mineral surface ion-exchange, dissolution/precipitation reactions, and adsorption processes were simulated to estimate water quality as the pH was shifted from circumneutral to acidic during mining and back to neutral during restoration. The model results showed that cost-effective management of mine water could meet regulatory requirements. Additionally, the model was used to interpret results from a field trial and inform operational decisions. The predictive approach and geochemical understanding developed have application in assessing aquifer restoration for other ISR projects.

Mar 2, 2022

By Regina N. Tempel, Laurie S. Balistrieri, Lisa L. Stillings, Lisa A. Shevenell, Maggy F. Lengke

Dexter pit lake, within the townsite of Tuscarora, Nevada, has been in existence since 1990 and provides a natural laboratory for the study of cycles of trace elements associated with ore deposits (e.g. As, Cu, Pb, and Se). Our goal in this study is to develop and calibrate methods of geochemical modeling that may be applied to estimating the concentrations and fluxes of trace elements in pit lake systems. Our initial modeling work considers limnology, hydrology, wall rock mineralogy and geochemistry, benthic fluxes, and colloid composition. Results from our work may be useful in evaluating water quality in the arid West.

Jan 1, 2000

By R. D. Schmidt

An in situ leaching geochemical simulator consisting of flow, mass transport, and graphics support programs has been developed. Two dimensional flow in heterogeneous porous media is modeled using a semi-analytic boundary integral technique. This method involves mapping streamlines to straight line segments in the complex potential plane. Leachant concentration and mineral values are modeled in this plane using the (one dimensional) potential coordinates. A fully implicit finite difference scheme is used to solve the resulting coupled system of four concentration equations. Graphical representations of streamline patterns, concentration histories, profiles and recovery curves are generated. An application of the model to uranium leaching in a heterogeneous aquifer and ore zone setting is presented.

Jan 1, 1985

Geochemical data on Australian granites and pegmatites9 and the.,mineral.components of these rocks, is presented and compared with that obtained in similar studies in.the U.S.òS.R and:.elsewhere.The petrochemical character of tin granites and the trace.-chemistry of their component minerals, particularly biotites, have some significance as ore guides in prospectingfor tin.The primary geochemical dispersion of tin can be readily tested both in the laboratory and field by colourimetric methods, after volatilization with ammonium iodide, using modifications of.the method described by Wood (1958).Secondary dispersions of tin in residual soils or.alluvia can likewise be readily tested by rapid colourimetric methods in the field, but simple hydraulic methods,.handling larger-. sample volumes, give reliable outlines of dispersion patterns.

Jan 1, 1963

Geochemical data on Australian granites and pegmatites, and the mineral components of these rocks, are compared with that obtained in similar studies in the U.S.S.R. and elsewhere.The geochemical character of tin granites and the trace chemistry of their component minerals, particularly biotites, have some significance as ore guides in prospecting for tin.The primary geochemical dispersion of tin can be readily tested both in the laboratory and field by colourimetric methods, after volatilization with ammonium iodide, using modifications of the method described by Wood (1958).Secondary dispersions of tin in residual soils or alluvia can likewise be readly tested by rapid colourimetric methods in the field, but simple hydraulic methods, handling larger sample volumes, give reliable outlines of dispersion patterns.INTRODUCTIONThe search for tin ores, whether lode or placer in type, is usually directed on genetic grounds to country within or adjoining acid intrusives.A long established means of prospecting is to test samples for cassiterite by panning or other hydraulic separation.These methods can be used on crushed lode material or the natural materials from placers.With the advent of new techniques for extraction and for colourimetric analysis for tin (Wood, 1958 and Ross and White, 1961) a means is available for rapid analysis of materials not susceptible to quantitative testing by hydraulic methods because of the fine sizings of cassiterite or the occurrence of tin structurally held in minerals. The new methods thus opened up the field of tin prospecting by extending the search for ore guides to genetically associated rocks and minerals, wall ror-ks of veins and a wider range of superficial deposits.

Jan 1, 1963

By S. Litke

Elemental sulfur was stockpiled at the Mount Polley Mine for use as a source of sulfuric acid as part of research into leaching copper from oxide ores, but the project did not proceed beyond an initial pilot- scale evaluation. Since placement, the sulfur has oxidized and some sulfuric acid leached into the underlying rock. The reaction of the acid with these underlying materials has been studied as part of an evaluation of the effects of leachate from the pile. The rock underneath the sulfur pile is composed dominantly of primary and secondary alumino-silicates with less than 1% carbonate (calcite) and iron sulfide (pyrite). In its unaltered condition, the rock is classified as non-acid generating. Conceptually, it was expected the sulfuric acid would be neutralized by the rock to varying degrees resulting in a series of pH-controlled weathering fronts progressing from leached near the contact with the sulfur pile (pH <3), to active neutralization by silicates (pH 4–5), to active neutralization by carbonates (pH >7). The rocks underneath the pile were sampled to determine the extent to which the rocks had reacted and their long-term stability after removal of the acid source. INTRODUCTION When rock is blasted and excavated to facilitate mining ore, it is typically placed and stored on the surface in piles. The resulting drainage may have a neutral to basic pH (i.e., non-acidic drainage) or a low pH (i.e., acid rock drainage, ARD) depending on the mineralogy of the rock being stored in the piles. Acid- base accounting (ABA) can be used to characterise the two types of rock: potentially acidic drainage generating (PAG) and not potentially acidic drainage generating (NAG) (Price, 2009). According to Price (2009), NAG is defined as having an excess of neutralization potential (NP) in the rock in the form of calcium carbonate-like minerals when compared to acid potential (AP), i.e., a Neutralization Potential Ratio (NP/AP = NPR) greater than 2.0, whereas PAG is classified as having an excess of AP (i.e., an NPR less than 1.0). This is a conservative estimate and may be slightly modified depending on the mineralogy at specific mine sites. Rock with an NPR of 1–2 is also capable of generating acid (Price, 2009) and, depending on the mineralogy, may also be classified as PAG. Drainage from PAG material can generate acid immediately, or many years after it has been exposed to surface conditions. Disposal techniques depend on the category (i.e., NAG or PAG) and reactivity of the rock stored in the piles.

Jan 1, 2019

By Joseph R. Hatch

When compared to average shale composition, average coal is enriched in sulfur and selenium, has similar amounts of arsenic, beryllium, lead, antimony and molybdenum, and is depleted in at least 26 other elements. Within a coalfield, or region, some coals are enriched (10X average shale) in silver, arsenic, cadmium, cobalt, germanium, molybdenum, nickel, lead, selenium, uranium, and zinc. Important factors controlling element distributions in coal include geochemical conditions (primarily pH) in the peat swamp, composition and depositional environment of coal roof rocks, thermal maturity (rank), nature and intensity of any epigenetic mineralization, composition of ground waters that come in contact with the coal, and degree of weathering.

Jan 1, 1983

By William W. Shilts

"In carrying out a geotechnical survey of a proposed gas pipeline route from the Arctic Islands south to Longlac, Ontario, the Polar Gas Consortium contracted the drilling of several hundred 2- to 2D-m-deep boreholes in drift and bedrock. Samples from these holes were made available to the Geological Survey of Canada, where they were subjected to stratigraphic and trace-element geochemical analyses. The geochemical characteristics of the clay and sand-sized heavy mineral fractions of till samples from these boreholes have been summarized in a series of geochemical profiles.From the proposed pipeline terminus at Longlac northward to the vicinity of God&apos;s River in Manitoba, tills contain significant amounts of Paleozoic carbonate rocks and Proterozoic sedimentary rocks derived from the Hudson Bay basin and lowlands. Within this section, two sites were enriched in base metals, indicating the possibility of local mineralization of possible economic interest.From God&apos;s River northward to Seal River, Manitoba, no evidence of local mineralization was noted. The heavy mineral fractions of the tills are universally enriched in Mn-rich siderite thought to originate on or in the Paleozoic section of the Hudson Bay lowlands.From Seal River northward to Thelon River, near Baker Lake, tills contain only components originating west of the Hudson Bay sedimentary basin. Near the Keewatin-Manitoba border, all till is enriched in uranium, which probably originates in the ""young"" porphyritic granites underlying much of the region, and produces a distinctive airborne radiometric anomaly.At the Thelon River, multiple till sections are variously enriched in Cr, Ni, U, Cu and Mo in the vicinity of a distinctive aeromagnetic anomaly.From Thelon River northward, several coincident zones of chromium and uranium enrichment are found where the line of boreholes crosses east-west-striking belts of volcanic, ultramafic and sedimentary rocks of the Prince Albert Group.The results of this study indicate that till tends to have characteristic element associations or concentrations over each of several broad regions along the pipeline route. These are related both to large-scale bedrock associations and to largescale effects of glacial dispersal. In addition, the samples, collected more or less at random with respect to local bedrock geology, have intersected several small-scale geochemical anomalies that appear to be related to zones of mineralization of possible economic interest."

Jan 1, 1980

By S. M. Flaherty, R. E. Scheffel, A. Guzman

Geochemical conditions within a leaching operation are heterogeneous. This variability arises mainly from hydrological controls imparted by physical characteristics of the ore and by heterogeneous metallurgical properties at the rock-fragment and industrial heap scale. The resulting chemical conditions are responsible for stratified mineral recovery, non-uniform extraction and prolonged leach cycles. This paper presents field data from a sulfide-leaching operation which clearly demonstrate the impact of chemical heterogeneity on metal recovery and the potential use of modern measuring techniques to facilitate operational monitoring and decision making for optimization of leaching operations.

Jan 1, 2006

By R. W. Boyle

"The concept of using chemical methods in prospecting dates back at least to the middle of the 16th century. Modern methods of geochemical prospecting, however, based on secondary haloes and utilizing trace-element techniques, were first practised in the U.S.S.R. and the Scandinavian countries in the 1930's. After 1945, methods based on soils, stream sediments and vegetation were rapidly developed in the U.S.A., the United Kingdom, Canada, France and other countries.The modern methods of geochemical prospecting owe their rapid development in the 20th century to the following:1.-Recognition of the primary and secondary dispersion haloes and trains that are associated with all mineral deposits. 2.-Development of accurate and rapid analytical methods utilizing the spectrograph and the various specific sensitive colorimetrie reagents, especially dithizone. 3.-Development of polyethylene laboratory ware of all types and the development of resins. This permitted greater freedom of field analyses and reduced the incidence of contamination.4.-Development of gas chromatography. This permitted the rapid and accurate determination of hydrocarbons in petroleum prospecting.Future research in geochemical prospecting should be focused on the following tasks: 1.-Definition of geochemical provinces and their relation to mineral deposits. 2.-Development of methods for discovering large low-grade deposits. 3.-Development of methods for discovering deeply buried deposits. 4.-Further development of methods to outline primary haloes. 5.-Eiucidation and formulation of techniques to relate the size and intensity of anomalies to the grade of the deposits. 6.-Development and refinement of biogeochemical methods, especially those based on indicator plants, chlorotic or toxic effects, and microbiological techniques. 7.-Definition of the types of primary and secondary haloes associated with accumulations of oil and gas."

Jan 1, 1967

By Ernest E. Thurlow

The Geology Division of Northern Pacific Railway Company has adapted to its exploration efforts field procedures for geochemical sampling and semi-quantitative analysis which have been developed through research by the U. S. Geological Survey. The sampling is done in conjunction with reconnaissance geologic mapping on aerial photographs or during field checking of maps which have been prepared largely by photogeologic interpretation.. Stream sediment or soil samples are taken and readily soluble combined heavy metals are extracted with ammonium citrate followed by colorimetric titration with dithizone at the sample site. The effectiveness of this approach has been demonstrated both in positive and negative results, thereby assisting in the elimination of large areas of land from further immediate attention and in providing targets for followup exploration. An occasional sample is submitted for spectrographic analysis as a check on the possible presence of other elements of economic significance. Field laboratory procedures are also being implemented for determining molybdenum, mercury, and other metals which may be valuable in themselves or useful as pathfinder elements in outlining mineralized areas. A lead-zinc occurrence in Oregon and a copper deposit in Montana were readily detected and outlined by stream sediment and soil sampling and a heavy metal anomaly that lacks obvious interpretation has been found in northwestern Montana. Detailed mapping and additional sampling are followed by other exploration techniques if warranted.

Jan 1, 1964

By Robert E. Delavault, Harry V. Warren

IN the worldwide search of buried orebodies and for entirely new areas of mineralization, geo-chemistry is taking on an increasingly important role. Indeed, geochemistry itself is splitting into various specialties-hydrogeochemistry, pedogeo-chemistry, and biogeochemistry. This article primarily relates to developments in these fields in British Columbia, but many of the remarks are applicable to the whole continent.

Jan 10, 1953

By José Luis Lee Moreno

This paper presents a preliminary phase of a study being conducted by the Department of Geochemistry of the Consejo de Recursos Naturales No Renovables in the vicinity of the Pachuca-Real del Monte Mining District. This district is located in central Mexico, about 100 km northeast of Mexico City. It has been in operation for the past 450 years and has produced about 38 million kg of silver and about 190 thousand kg of gold. At the present it is being worked by the state owned mining company of Real del Monte and Pachuca. The rocks of the area consist mainly of Tertiary volcanics, ranging in age from early Oligocene to late Pliocene. Ore bodies are recognized as epithermal, vein type fracture fillings. The main ore minerals are argentite and acanthite normally accompanied by base metal sulphides, Gold is present in small amounts as native gold and in other minerals. Orientation geochemical studies performed on soil and rocks over known veins in the district, showed zinc to be the best indicator. Lead and silver anomalies are restricted to the immediate vicinity of the veins, mercury shows the mineralized structures only when the "C" horizon is sampled, while antimony gave erratic values. The El Chico area is about 10 km north of the Pachuca-Real del Monte district and covers approximately 400 sq km. Geological evidence indicated the possibility of an extension of the Pachuca ore bodies in this area. Results obtained from soil and rock samples from El Chico, showed several anomalous area. Detailed investigations proved these anomalies to be related to faults and fractures which in several cases have been found to be mineralized. Drilling is planned with preliminary results expected by late 1974.

Jan 1, 1974

By Lee Trudick

The secondary dispersion of copper, zinc and fluorine in A horizon soils was examined in Pope and Hardin Counties, IL, by sampling 122 sites along five traverses. Four of the traverses were taken above a deeply buried manto; a fifth intersected a vein complex exposed at the bedrock surface. Plants at each site were examined and analyzed for fluorine and on one traverse for copper and zinc. The A horizon soils were also tested for lead, manganese, barium, nickel and cobalt. The total content of copper, zinc, and other heavy metals in soils was determined by atomic absorption spectrometry (AAS) after acid bomb dissolution. Fluorine in soils was determined by fluoride ion-specific electrode after fusion with NaOH. Several cold- leach methods were also used. The analysis of A horizon soils for copper and zinc by AAS after acid bomb dissolution is a promising geochemical tool in the search for fluorspar. The acid bomb dissolution method is simple and takes little laboratoy time; it Produces a total dissolution of the sample with relatively little loss of the elements, and 20 elements can be analyzed from the same sample. In this study, the highest copper values were 80 times the local background level of 25 ppm and anomalies of this element tended to outline the fluorspar orebody better than either zinc or fluorine. The greatest zinc value was 15 times the local background level of 100 ppm, while the highest fluorine values were approximately four times the local background level of 165ppm.

Jan 1, 1982

By John B. Gustavson, Thornton L. Neathery

A geochemical survey was conducted in the gold district in Alabama. Eight old mines were found to be sufficiently large in tenor and tonnage to be economical today. Four of these appeared to be amenable to exploration for new blind deposits. A gaseous aspiration AA method was used on soil samples. The results indicate that arsenic, antimony, and zinc may be good pathfinders for lode gold and residual placers in the saprolite. Antimony and zinc display a high correlation coefficient at gold-bearing locations in contrast to non-mineralized areas. The low cost of this method could make it a tool for selecting detailed targets to be drilled and trenched in the saprolite. Outcrop sampling was found to be inefficient due to paucity of outcrops and lack of correlation between the trace elements and gold in the rock samples, due to extensive weathering. Schistosity changes and silicification, on the other hand, have been found to be helpful in exploration around granite plutons.

Jan 1, 1977

By John B. Gustavson

Gold was first discovered in Alabama in 1830. Before a decade had passed more than 20,000 people were employed in the various gold districts scattered across east-central Alabama. By 1849 most of the presently defined gold districts were known with such towns as Arbacoochee, Chulafinnee, Goldville, Pinetucky, and Idaho being the principal mining camps. The California gold rush of 1849 signaled the end of intensive prospecting in the Alabama Piedmont for the precious metal. Reactivation of many of the old gold districts has been attempted several times since 1849. Significant activity and development took place between 1874 and 1880, 1888 and 1916, and 1929 and 1936. Locally, some of the development met with moderate succes. The last productive gold mine in Alabama ceased production in 1935. The sharp increase in gold prices since 1973 has caused renewed interest in the potential values of gold of the Alabama gold districts. Most of the gold workings have been abandoned for nearly 75 years and are for the most part inaccessible for convential property evaluation. The early gold miners and prospectors in Alabama were more intent upon finding and mining the valuable metal than in recording their activities for future generations. No matter how interesting or historically significant these records might have been the miners kept no records and left behind them few maps as clues to their activities. Inasmuch as most of the old gold districts have been extensively mined and prospected during the past 150 years, there is very little chance of finding large deposits through conventional outcrop prospecting methods. Similarly, the present geologic knowledge of the various districts is insufficient to launch successful exploration programs looking for large blind lode deposits in new locations within the general gold bearing region.

Jan 1, 1975

By John B. Gustavson

This paper describes a case history of geochemical prospecting. An area of known mineralization was available for an orientation survey which led to the selection of elements and criteria for a reconnaissance survey in the area offsetting the known mineralization. Certain anomalies were found which were then made subject of confirmation sampling and of rock geochemical investigations. Inasmuch as the geochemical prospecting technique specifically led to a detailed area which now serves as a target for drilling and other exploration efforts, the geochemical prospecting part of the program is considered successfully concluded and, therefore, reported on here. Whether the target area will turn out to host the deposit or not is, of course, of utmost importance to the Company, but is of less importance to this paper. We will describe the concepts, the planning, the execution, the analysis and the interpretation of this typical geochemical prospecting case. A number of people on the staff of International Oil & Gas, Inc. have participated in this prospect, as have students from Southeast Missouri State University and their professor, Gary M. Lowell. In addition, the Missouri Geological Survey has been most helpful with records and letters on the century-old prospecting and mining in the general area. Many valuable discussions have also been held with geologists from the industry who, from time to time, have visited the area, examined the property and reviewed the status of the project. The support and interest from all these parties has made it possible to pursue and expand this exploration concept from one of being just "more of the same kind" to the most chal-1enging and exciting with which this author has ever been involved, namely the prospect for tin porphyry deposits in the mid-continent United States.

Jan 1, 1977

Selective leach analytical techniques applied to surface geochemical samples in the search for deeply buried mineral resources gained popularity in the late 1990s. Several commercial assay laboratories introduced their own selective leach methods, adding to the few established commercial methods at that time. Many of these laboratories promoted their methods with orientation data showing favorable responses to both precious and base metal mineralisation, concealed beneath extensive thicknesses of overburden. However, many explorationists remain confused about the utility of these geochemical methods. This confusion is due primarily to the lack of objective orientation surveys over significant mineralisation, comparing all commercially available selective leach methods and to the lack of a creditable theory explaining the formation of these selective leach anomalies. An&nbsp;EXTENDED ABSTRACT&nbsp;is available for download. A full-length paper was not&nbsp;prepared for this presentation. An orientation survey was designed to fill the first void û an objective survey over significant mineralisation. With the help of 17 mining companies and assay laboratories, an orientation survey was conducted over five significant covered gold deposits in Nevada, USA , representing over ten million ounces of gold. Hopefully the results of this survey will help provide fuel for those working on the second void û a theory to adequately explain the formation of these selective leach anomalies.

Jan 1, 2008

The highland region of Papua-New Guinea is relatively rugged terrain where stream gradients are steep. In areas where porphyry copper deposits outcrop the streams commonly expose primary sulphide mineralization in unoxidized rocks. Stream sediment geochemistry combined with float examination and broad geological mapping proved to be an effective tool for detection of outcropping bodies of mineralization. After discovery, detailed stream sediment sampling, soil sampling and rock chip sampling, together with detailed geological mapping proved adequate to delineate drilling targets. Reconnaissance stream sediment sample density was dictated by geology and access and a density of one sample per 25 Km2, or less, was desirable to ensure a high degree of confidence in the programme. Research indicated that the base metals occur in sulphide form in stream sediment and that the -80 mesh size fraction gave the most reliable results. The evaluation of results from any one area relied on the interpretation of the local geology. Basic histogram methods for determining background and threshold values for metals in stream sediments were

Jan 1, 1973

By John E. Riddell

This review is based on a questionnaire sent out in 1959 to 24 Canadian exploration companies, known to be active in the mineral exploration field, concerning their practice in the use of applied geo-chemical techniques in Precambrian terrains. Of the companies questioned, 21 returned completed questionnaires and of these, 15 companies stated that they had some experience in this type of work. Of the companies who stated that they had no experience in geochemical prospecting in glaciated Precambrian areas it is interesting to note that only three have reported that they do not use applied geochemistry at all. The others have reported that they make use of applied geochemistry in New Brunswick and in the Cordillera in areas of light glaciation. Their opinion is that it is a useful aid when accompanied by other techniques in evaluating mineralized areas. GEOCHEMICAL SURVEYS Table I reviews the type of geochemical surveys used by these companies, and the following points of interest should be noted.

Jan 11, 1960