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This paper discusses three case studies conducted at Highland Valley Copper mine (HVC) that illustrate operational improvements and insights which resulted from using the McGill University gas dispersion sensors. In the first study, the superficial gas velocity (Jg) sensor was used to implement a gas profiling control strategy for the rougher, scavenger and first cleaner cells in the Cu/Mo separation circuit. The data showed a 40% reduction of down-the-bank Cu recovery at constant Mo recovery which resulted from operating the cells at the target profiles. In the second study, the bubble size analyzer was used to better understand two mechanisms of bubble formation in the two flotation columns that make up the final Mo cleaning stage: the conventional rubber-sleeve sparger and the Microcel(TM) system. The data showed a considerable reduction of bubble size in the Microcel column which resulted in a significant increase in concentrate quality (1-2% Mo absolute) and a dramatic (4-5 fold) increase in concentrate production rate compared to the typical operation. The estimated economic benefit resulting from the improved column flotation operation was an overall 4% increase in Mo circuit recovery. In the third study, real-time measurements obtained from the gas holdup and bulk density sensors were used to infer the pulp density (% solids) in a rougher cell of the bulk flotation circuit. Validation tests demonstrated that this approach provides reliable pulp density measurements. Although promising, more work is required before implementing this approach at HVC.

Jan 1, 2009

By J. A. Finch

The metallurgical performance of a flotation cell is strongly influenced by the features of the bubble population, characterized by the gas dispersion properties, a collective term including bubble size, superficial gas velocity and gas holdup. It is required that gas be well distributed throughout the cell. Gas distribution is estimated here by simultaneous measurement of gas velocity (Jg) at different distances from the center (radial Jg mapping). This communication describes a technique to perform radial Jg mapping together with fundamentals for the interpretation of the data.

Jan 1, 2009

By Y. F. Bulgakov, Y. V. Melnikova, V. S. Zakharov

A new technology of atmosphere in inertization of fire section with the help of gazeous nitrogen is presented in the report. This technology is based on membrane air subdivision into two streams, concentrated with nitrogen (up to 99%) and with oxygen correspondently with subsequent giving them into the place of fire. This technology belongs to environmentally friendly ones and it has a great number of technical, mobile and economic advantages comparing with the rest of well-known methods of fire extinguishing. This technology application in Ukrainian coal mines allowed to reduce the member of isolated places of fire at the expense of their extinguishing efficiency.

Jan 1, 2003

By Michael L. Ogilvie

The proportion of underground coal production as a percentage of overall Australian production has fallen in the last 10 years, with underground production remaining more or less static at about 53 Mt (58 million st). However, underground coal mining remains a viable industry in Australia, due to use of modern longwall mining systems. In 1993-1994, 26 longwalls were in operation, with total production exceeding 39 Mt/a (43 million stpy). Some of these longwalls achieve productivity levels approaching efficient opencut operations, and in some cases, they exceed them. These high-production longwall mines are not without problems when depth and distances from outcrop increase and the gas content of the seams approaches or exceeds critical limits. When gas content of a coal seam exceeds 6 m3/t (233 cu ft/st), gas flows into the mine may be sufficient to interrupt production from time to time.

Jan 1, 1995

By R. T. Jr. Faria, H. Vargas, R. Toledo, S. Cosin, V. P. Souza

"With the purpose of decrease environmental impact, caused by industrial residues (just discarded in the environment) and clay extraction in the ceramic industry, sanitary ware wastes were incorporated into clay. In contrast, it is important to evaluate not only the technological essays but also gases emissions in the ceramic firing process. The pollutant gases emitted in ceramic with residues can be in much larger concentrations than that in a pure clay ceramic firing or, on the other hand, can decrease the pollutant gas concentrations. With the aid of thermal analyses and photo acoustical techniques it was observed that sanitary ware waste can reduce the C02 emission. The gas emissions were shown as in function of firing temperature from 300 DC to 1100 DC. In order to analyze phase transformations during the firing process, clay samples and wastes were both analyzed by x-rays fluorescent chemical analysis and x-rays diffraction.IntroductionResearch works on the structural and physical changes that wastes, mainly industrially produced, cause to the final ceramic product has been rapidly expanding in these last two decades. See, for instance references in [1]. In spite of these examples of a continuous effort to incorporate wastes into clay ceramic motivated by technical and economical advantages, environmental issues are still a matter of concern. However, the gas emission due to the clay firing process and its related atmospheric pollution may be enhanced as a consequence of an incorporated waste [2]. It is known that the firing of clay ceramics in conventional furnaces using fuels such as wood, charcoal, heavy oil and natural gas generates appreciable amounts of gaseous components, mainly carbon dioxide (CO2), carbon monoxide (CO) and methane (CH4). Additionally to the atmospheric pollution, these gas sets could be harmful to the human health and can corrode equipments [3,4]."

Jan 1, 2012

By J Sargeant, T Levi, J Theiler, B Beamish

Two coal samples (810 Panel and Area 900) collected from Clarence Colliery have been tested under a controlled heating procedure to evaluate the gas evolution trends corresponding to increasing temperature. Gas evolution data are normally used to identify key gas indicators and validate the trigger action response plan settings for the mine as part of the Principal Hazard Management Plan for Spontaneous Combustion. The samples were located some 6 km apart and there is a significant coal-type difference between them. At low temperatures (<100°C), the Graham’s ratio (GR) values for the two samples are almost identical. However, at elevated temperatures, there is a significant difference, with the 810 Panel coal having higher GR values than the Area 900 coal. This is most likely due to a difference in the coal reactivity. The 810 Panel coal does not evolve ethylene until temperatures in excess of 140°C are reached, whereas Area 900 coal evolves ethylene once temperatures in excess of 120°C are reached. The 810 Panel coal also produces significant ethane evolution (200 ppm) at low temperatures (50°C) due to the presence of retained ethane seam gas, which decreases as the temperature increases due to desorption from the coal. Once the coal temperature exceeds 130°C, the ethane evolution increases again due to coal oxidation reactions, reaching levels of 50 ppm. In contrast, the Area 900 coal has no significant low-temperature ethane evolution, and ethane evolution only increases once the coal temperature exceeds 120°C. There are also noticeable differences in the trends of other gases evolved from the coal. These findings have implications for the interpretation of gas monitoring results from the two different areas of the mine. They also illustrate the need for obtaining results from each new area of a mine as it develops so that changing gas evolution trends can be identified in advance of mining.CITATION:Beamish, B, Sargeant, J, Levi, T and Theiler, J, 2015. Gas evolution trends for coal from two different areas at Clarence Colliery, in Proceedings The Australian Mine Ventilation Conference, pp 273–278 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By Jerome F. Thomas

The primary purpose of this paper is to review the fire and explosion hazards associated with hydrocarbons heavier than methane. Methane is the classical hydrocarbon encountered in mines whose presence is generally due to bacterial decomposition of organic debris. The higher hydrocarbons are more likely to be found during tunneling when petroleum products either natural or man made are encountered. Fires may be defined as rapid gas phase oxidations accompanied by the rapid evolution of light and heat. Explosions may be defined as uncontrolled fires. The rapidly expanding gases resulting from combustion exceed the speed of sound and generate percussive forces. The essential elements for a fire or explosion are shown on Figure 12: (1) a gas phase explosive mixture and (2) an ignition source. The paper will attempt to review various aspects relative to the explosive mixture; The concentration and composition; Techniques for detection; Techniques for ventilation to reduce concentration below explosive limits. The ignition sources are also listed on Figure 12. An arc originates from an electrical source such as electrical switches, relays and motor brushes. Static electricity can also be an arc source and may be generated by air flowing through rubber bases or a rapidly moving endless belt. A spark is generally associated with abrasion of iron metal. A flame source may be a match, candle. cutting or welding torch, or engine exhaust. If

Jan 1, 1974

By James Corcoran, Richard McLane, Matt Neuner, Joseph DeMello, Hugh Davies

The Los Angeles County Metropolitan Transportation Authority (LA Metro) Purple Line Extension Section 1 (PLE1) is a $3.12 billion USD design-build, underground heavy rail project, connecting an existing station at Wilshire Blvd. and Western Ave. and extending 3.92 miles under Wilshire Blvd, terminating approximately 550 feet west of Wilshire and La Cienega Blvds. The project alignment runs immediately adjacent to the La Brea Tar Pits, world renowned for Pleistocene fossils and continuous seepage of asphaltum (locally known as tar) and gas in an urban setting. This paper presents a successful case history of the planning, design, and construction efforts to safely construct the bored tunnels through Reach 3 of the alignment (between Wilshire/Fairfax Station, and Wilshire/La Cienega Station), in a designated Methane Zone in the City of Los Angeles. Historical context on decades of challenges and studies is summarized. Further, this paper outlines the pro-active partnership between the Owner: LA Metro, the Design Builder: Skanska-Traylor-Shea Joint Venture, and geotechnical design services provided by Golder Associates to safely manage pressurized face tunneling through a confined gas zone near the La Brea Tar Pits. Specifically, a program of in-situ oxidation and soil gas extraction was designed to test and analyze risks associated with pressurized face TBM tunneling through the complex subsurface geological conditions, then implemented during construction. In advance of tunneling, a network of wells was used to draw air into the gas zone to oxidize the 6,500 ppm hydrogen sulfide gas, as well as determine methane recharge rate. During TBM tunneling, the wells were converted to a gas extraction system to evacuate, filter (H2S) and burn (CH4) the gas as the Tunnel Boring Machine passed, providing a preferential pathway for the gas to migrate toward extraction wells, and preventing the migration to adjacent buildings. The team extracted and treated 3,857,000 cubic feet of mostly methane gas over 40 days as the TBMs passed through the zone. Gas behavior, pressures, and concentrations were monitored not only from the extraction system, but also in basements and utility vaults along this section of the alignment.

Jun 13, 2023

DOME MINES, Limited, is a gold producer situated in the Porcupine area of Ontario, 500 miles north of Toronto. During the year 1960, '71 4,600 tons of ore were milled, yielding gold bullion valued at $6,025,370. Prior to conversion to natural gas, an average of 3,200 tons of coal was consumed annually, one third of which was obtained from Canadian sources with the remainder coming from the United States. Due to the distances involved, the freight charges increased the pithead cost by as much as ISO per cent. Steam is generated at a central boiler plant and used for timber treatment, plant heating and process steam. Until August, 1960, steam was supplied during the winter months by two water tube coal-fired boilers, each rated at 200 boiler horsepower at 100 per cent output. Steam requirement was as high as 150 per cent of boiler rating in the colder periods. The summer load was

Jan 1, 1962

By Edward L. Burwell

The Bureau of Mines investigated the use of dilute polymer in brine solutions to increase the efficiency of air in gas flooding model oil reservoirs. Slugs (0.23 pore volume) of 500 ppm polyacrylamide were injected into a model, consisting of a high- and a low-permeability core, that had been previously gas flooded to residual oil. Gas flooding was then resumed. Of the total gas volume injected, the percentage entering the high-permeability zone was greatly reduced after polymer injection but remained unchanged when slugs of water without polymer were used.

Jan 1, 1970

Gas flow and heat transfer phenomena in two industrial-scale waste-heat boilers of the Outokumpu copper flash smelting process were analyzed with a commercial computational fluid-dynamics (CFD) package Phoenics. Various operating conditions were simulated for the first boiler and particularly for the second boiler. The gas flow pattern was compared qualitatively with the physical laboratory models, and the general flow pattern was consistent with the laboratory visualization. The heat transfer simulation was validated with, temperature measurements for both boilers, and good agreement was reached between the computed temperature profiles and the measured data. The computational results indicate that gas flow in both boilers is of three-dimensional and recirculating nature. The numerical tracer experiments indicate that some dead volume is present in both boilers, and the boiler modification reduced the dead volume from 38% to 15% under basic operating conditions. Radiative heat transfer accounts for 65-90% of the total 'heat transported in the radiation sections of both boilers under different operating conditions. The modified boiler is very efficient for cooling the off-gases at almost doubled volume flow rate. The CFD modeling proved to be a useful tool for numerical experiments and analysis of boiler performance for process: optimization.

Jan 1, 1998

IN the preceding chapter on thermochemistry and the reactions in and between metal and slag phases and in the following chapter on fuel combustion the main emphasis is placed on the equilibrium or "static" conditions. This equilibrium viewpoint is not concerned with the rate of change in the process or with the mechanisms or paths followed between initial and final states. The questions of just "how it works" and "how fast" belong to the kinetic aspect of any process; their answers are helpful in speeding up or slowing down and thus controlling its operation, and also in understanding its limitations. Any treatment of kinetic factors in the open hearth such as is attempted here and in Chapter 22 must at present be largely qualitative and incomplete. We are only beginning to get quantitative data on rates of reaction and diffusion at high temperatures, as indicated in Chapter 15. Empirical data in the literature on furnace operating rates do not help much to illuminate the details of gas-flow patterns and the complexities of heat flow in the many parts of the furnace system. This chapter is intended to give the reader an introduction to the problems of the flow of gases through the furnace system and the flow of heat in this system. An adequate discussion would require several times the space available here; it is possible here only to outline a few fundamentals and to indicate some of the conditions of heat and gas flow peculiar to the open hearth. Several good general treatments of these subjects may be found in the literature (see references at the end of the chapter). For the designer of open-hearth furnaces, the principles of gas flow are of paramount importance. They are also important to the operation of the process, at least to the extent of a general qualitative picture of the movement of gases in the system. MOTION OF GASES IN FURNACE DUCTS Fluid flow in general can vary between the extremes of laminar or streamline flow with a minimum energy loss, to irregular

Jan 1, 1951

IN the preceding chapter on thermochemistry and the reactions in and between metal and slag phases and in the following chapter on fuel combustion the main emphasis is placed on the equilibrium or "static" conditions. This equilibrium viewpoint is not concerned with the rate of change in the process or with the mechanisms or paths followed between initial and final states. The questions of just "how it works" and "how fast" belong to the kinetic aspect of any process; their answers are helpful in speeding up or slowing down and thus controlling its operation, and also in understanding its limitations. Any treatment of kinetic factors in the open hearth such as is attempted here and in Chapter 22 must at present be largely qualitative and incomplete. We are only beginning to get quantitative data on rates of reaction and diffusion at high temperatures, as indicated in Chapter 15. Empirical data in the literature on furnace operating rates do not help much to illuminate the details of gas-flow patterns and the complexities of heat flow in the many parts of the furnace system. This chapter is intended to give the reader an introduction to the problems of the flow of gases through the furnace system and the flow of heat in this system. An adequate discussion would require several times the space available here; it is possible here only to outline a few fundamentals and to indicate some of the conditions of heat and gas flow peculiar to the open hearth. Several good general treatments of these subjects may be found in the literature (see references at the end of the chapter). For the designer of open-hearth furnaces, the principles of gas flow are of paramount importance. They are also important to the operation of the process, at least to the extent of a general qualitative picture of the movement of gases in the system. MOTION OF GASES IN FURNACE DUCTS Fluid [flow] in general can vary between the extremes of laminar or streamline flow with a minimum energy loss, to irregular

Jan 1, 1964

By Burgess JM

Research on gas distribution in the iron- making blast furnace has been conducted in three separate areas. Firstly, experimental work has been conducted to determine the important parameters which dictate the pressure losses in homogeneous and heterogen- eous packed beds. Secondly, a theoretical analysis of gas flow through the furnace softening-melting zone has been undertaken to determine the effect of the shape of the zone on the distribution of gas flow towards the furnace walls. Thirdly, a theoretical programme has been undertaken to develop methods for the prediction of furnace soften- ing-melting zone shape from furnace tempera- ture and gas composition measurements.

Jan 1, 1980

By Stewart K. Griffiths

A general method-of-lines numerical approach for modeling gas driven fractures has been developed and tested. The numerical solutions agree very well with known similarity solutions for laminar and turbulent flow. Acceptable accuracy is obtained with a very few numerical grid points and with modest execution times. The model has also been checked against the results of several field tests, in which air was used to drive axisymmetric fractures into permeable tunnel-bed tuff.

Jan 1, 1984

By Leonel Contreras

The gas treatment system, MALIGAS (in Spanish MAnejo y Llmpieza de GASes which means handling and cleaning of gas), is part of the Codelco-Chile Potrerillos Smelter decontamination plan; which includes the newly designed system for the cooling and cleaning of the gas generated from a Teniente Converter and four Peirce Smith Converters. The gas generated in the process is captured by water cooled hoods and mixed with air. Then the gas enters a cooling pre-chamber which utilizes a water cooled screen to capture and remove the coarse and semi-fused particles. At this stage; the gas loses a portion of its heat with temperature falling below 608°C which is a necessary condition to avoid damage to the pipes, ducts and other metallic structure of the gas handling system. The gas is further cooled at the Radiation Cooler to a temperature ranging between 315 and 380°C. The gas is conditioned to avoid damage to the electrostatic precipitators that are designed to clean the gas by removing significant amount of dusts from the: gas stream. This gas stream is currently discharged to the stack, however, it will be treated in a sulfuric acid plant that is currently under construction and is scheduled for commissioning during the second half of 1999. The gas handing and cleaning system has been operated without any significant interruptions. Minimal emissions of SO2 and dusts in the work place are noted. The system requires minimum maintenance. The key to the high availability of the system is due to the good, performance of he Radiation Cooler, which efficiently cools the gas before entering the electrostatic precipitators (ESPs). This enables the ESPs to remove the dusts efficiently.

Jan 1, 1999

By L. Magne, A. Pinto, M. Maldonado, J. A. Finch

Estimation of gas holdup from electrical conductivity measurements has been used in lab and industrial installations. The approach is based on the application of Maxwell's model, which relates the concentration of a dispersed phase in a continuous medium to measurements of the electrical conductivity of the dispersed phase, continuous medium and the resulting mixture (dispersion). When applied to inferring the collection zone gas holdup in a three phase system and to facilitate real-time on-line measurement, the slurry is assumed to behave as the continuous medium and gas bubbles as a nonconducting dispersed phase. This article derives an equation for estimating gas holdup in a three phase system, eliminating the assumption that the slurry behaves as a continuous medium but rather as a dispersion of non-conducting solid particles in water. In this formulation only water behaves as the continuous medium in the sense of Maxwell, and gas holdup in a three phase system is then calculated from the application of the Maxwell model twice: (1) to determine solid content in a two-phase system, and (2) to determine solid plus gas holdup in a three phase system. To validate the new equation and quantify the errors incurred by assuming slurry is the continuous phase a laboratory flotation cell was instrumented to continuously measure the conductivity of two and three phase dispersions with known solids contents. As the amount of gas in a lab flotation machine is difficult to measure directly or by another indirect technique such as using pressure signals, 2.5 mm dielectric plastic spheres having a density of ca. 1.3 g/cm3 were used instead of air bubbles for validation. Experimental results demonstrated that the continuous medium assumption underestimates gas holdup and that the resulting bias error increases linearly with the solid content and decreases with the magnitude of gas holdup.

Jan 1, 2016

By James R. Hein

Methane and hydrogen sulfide vent from a cold seep above a shallowly buried methane hydrate in a mud volcano located 24 km offshore of Los Angeles, California in 800 m water. Bivalves, authigenic calcite, and methane hydrate were recovered in a 2.1 m piston core. Aragonite shells of two bivalve species are unusually depleted in 13C (to -19? d13C), the most 13C-depleted shells of marine macrofauna yet discovered. Carbon isotopes for both living and dead specimens indicate that they used in part carbon derived from anaerobically oxidized methane (AOM) to construct their shells. Although the?d13C values are highly variable among specimens, most fall within the range -12 to -19?. This variability may be diagnostic for identifying cold-seep/hydrate systems in the geologic record. Authigenic calcite is abundant in the cores down to about 1.5 m subbottom, the methane hydrate horizon. The calcite is strongly depleted in 13C d13C = -46 to -58?) indicating that AOM was the main carbon source. Three sources of methane are likely: a geologic hydrocarbon reservoir, and biogenic and thermogenic degradation of organic matter in basin sediments. Oxygen isotopes indicate that most calcite formed out of isotopic equilibrium with ambient bottom-water, under the influence of gas hydrate dissociation and strong methane flux. High concentrations of Ag, Hg, Cd, Tl, and other elements in mud volcano sediment reflect leaching of basement rocks by fluids circulating along an underlying fault. Fossil (geologic) methane was likely transported with these fluids.

Jan 1, 2005

By Christian Müller, Hermann-Rudolf Kudrass, Christian Reichert

Recent studies estimate the depletion mid-point (dmp) for conventional natural gas to be reached around year 2022, and for conventional oil to be reached around year 2017. These numbers are based on simplified assumptions of unchanged demand and do not include increasing reserves from discovery of new fields and also do not include a shifting of resources to reserves e.g. due to an increasing oil price (Gerling et al., 2005). Anyhow, these prospects require conventional hydrocarbons to be substituted in the near future.

Aug 24, 2006

By S. Rajendran

Gas Hydrates (Methane Hydrates) are solid, ice-like substances composed of water and natural gas. They occur naturally in areas of the world where methane and water combine at appropriate conditions of temperature and pressure and are found in ocean bottom sediments and in some permafrost areas. Besides temperature and pressure, factors like bathymetry, sediment thickness, sedimentation rates, and total organic carbon content (TOC) also control gas hydrate formation in the ocean basins. The stability of gas hydrates depends on the critical combination of high pressure and low temperature (0 - 17 bars, 0 - 25°C), which in turn is dependent on the mix of gases from which the mineral is formed. As the critical parameters can be altered by deposition, erosion, slumping, formation or melting of ice cover, rise and fall of sea level, and sudden temperature changes induced by tectonic activities, current flow, or volcanisms, the gas hydrates tend to be very unstable. The Indian offshore is promising for the occurrence of gas hydrates in a total of about 80,000 km2 area in the bathymetry range of 700 to 3000 m as reported in earlier surveys. A gas hydrate stability zone thickness map was prepared using bathymetry and sea bottom temperatures along the continental margins of India. This map is expected to provide the depth window while searching for Bottom Simulating Reflectors (BSR). The study indicates that a minimum water depth of 750 m is required for the formation of gas hydrates, above which the chances for gas hydrate occurrence appear minimal despite other favorable conditions like organic-rich sediments, etc. Single-channel seismic analog records (Gupta et al., 1998) indicate that the Western Continental Margin of India (WCMI) offers a greater promise for gas hydrate occurrences, particularly with regard to the number of BSRs traced on the analog records as compared to earlier surveys.

Jan 1, 2005