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By Ernest Burchard

FLUORSPAR is found in most of the states from the Rocky Mountains westward, and commercial production of the mineral has been reported from Arizona, Colorado, Nevada, New Mexico, Utah and Washington. The map in Fig. 1 indicates the general distribution of many of these deposits but it is by no means complete. In the summer of 1926 the writer examined certain deposits of fluor-spar in Arizona, California, Colorado, New Mexico and Washington; in November, 1927, revisited the Jamestown, Colo., district, and in earlier years examined deposits in Colorado and New Mexico. Based on notes of his own and. on descriptions and other data by H. A. Aurand, H. W. Davis, R. B. Ladoo, V. C. Heikes, W. D. Johnston, Jr., and by producers of fluorspar, he prepared the following brief descriptions of deposits and estimates of reserves of fluorspar, originally for the use of the subcommittee on fluorspar of the Joint Committee on Foreign and Domestic Mining Policy and on Industrial Preparedness respectively of the Mining and Metallurgical Society of America and the American Institute of Mining and Metallurgical Engineers. Descriptions of many fluorspar deposits in various western states and districts have been published. It is not feasible to summarize this literature here, but the appended bibliography will indicate to the interested reader what papers are available.

Jan 1, 1933

By Richard Chojnacki

The western united States is not usually noted for the production of fluorspar; however, many significant fluorspar districts do occur in the Rocky Mountain region and constitute a resource of sizable dimension and major potential. This is particularly true within the area of the West served by the rail lines of the Union Pacific Railroad (see Figure 1). Fluorspar deposits near the Union Pacific have produced over 1.3 million tons of finished fluorspar products from 2.3 million tons of ore. Approximately 80% of this production was of acid-grade and 20% of metallurgical-grade fluorspar. Production of ceramic-grade was negligible. Through the years substantial production has come from eight mining districts. Five of these have produced metallurgical-grade and three acid-grade. The best-known fluorspar producing area in the West is the Jamestown Mining District. It was one of the first producers of fluorspar in the western United States and is estimated to have produced over 500,000 tons of finished fluorspar from over a million tons of ore. The district encompasses approximately 36 square miles in central Boulder County, Colorado, about 9 miles northwest of the City of Boulder. Although small shipments were made from the district as early as 1873 or 1874, significant sustained production was not achieved until 1940 when the General Chemical Company, now a division of the Allied Chemical company, acquired the Alice, Burlington, Chancellor,

Jan 1, 1971

By JAMES E. TILSLEY

Veins at St. Lawrence near the tip of the Burin Peninsula in southeast New/ oundland have been the major Canadian source of fluorspar. Some 2.8 million tonnes were shipped during the period 1933-1977, mostly from five of the more than forty veir.s known. Most of the veins occur in granite. individual veins may be several km in length, comprising a number of mineable lenses up to 760 m long and 25 111 thick. Fluorite content averages about 50 per cent, but may exceed 90 per cent locally. Quartz, calcite, barite and a few sulphides are the other vein constituents. Jn recent years, gravity concentrates were shipped to a flotation plant at Arvida, Quebec, where the fluorspar concentrate was used as a flux in the making of alum in um. Competition f rom Mexican fluorspar was a major factor in the closure of the mines. Ample reserves are available should economic conditions improve.

Jan 1, 1984

LARGEST known fluorspar deposits in the world are mined in southern Illinois (Hardin County), and northwestern Kentucky (Crittenden County). Colorado, New Mexico, Montana, and Utah are the principal western sources in the U. S. Rosiclare Fluorspar District Hardin County, Illinois The Rosiclare area is located in the southern part of Hardin County on the Ohio River where the Illinois Central Rd. branch line terminates and provides transportation. Fluorspar has been mined commercially in this area since 1870. Aluminum Co. of America and Rosiclare Lead & Fluorspar Co. are the two major producers in this area. Ozark-Mahoning Co. operates a concentrating plant in Rosiclare but the bulk of its ore is mined near the town of Cave-in-Rock.

Jan 1, 1958

By Michel Grenier, Gopal Kunchur, Stephen Hardcastle

This paper presents the findings of a dust study in a typical fluorspar processing plant. The primary purpose of this study was to identify employees and occupational groups exposed to high dust levels and determine compliance with personnel regulations for regular and extended work shifts. The range of airborne concentration of respirable silica and fluoride compounds in specific areas and on personnel was determined. State of the art dust monitoring equipment and tracer gas techniques were used to measure dust concentration, pinpoint dust sources and map major airflow trends in the mill. Results of the survey indicated silica dust concentrations in excess of permissible limits being produced mainly by crushers at the south end of the building. Tracer gas releases and gas chromatographic analysis further showed that prevailing south to north air currents tended to carry and spread dust produced by the crushing operations throughout the process plant. Airborne concentrations of fluoride compounds measured during the study were always well below the prescribed threshold limit value (TLV) for the contaminant. Recommendations, including a mechanical exhaust ventilation system on crushers and transfer points, scheduled preventive maintenance on existing bar sprays and wearing of personal protective equipment were made which significantly improved the work environment. Further testing conducted after Installation of the dust extraction system revealed significant improvements in most areas of the mill.

Jan 1, 1991

By Gill Montgomery

The problems of the domestic merchant fluorspar producers are more or less common with those of many other producers of metallic and non-metallic minerals. For more than ten years the American fluorspar producers have seen an ever lowering price in the market-place for the fluorspar product, while their labor and material costs-continue to mount steadily. This cost-price squeeze has forced out of business all but a few of the merchant producers, and only two captive producers continue to operate, and one of them has announced early curtailment. The prices of domestic fluorspar, of all grades, have declined because of the competition from cheaper foreign imports, principally from Mexico, Spain and Italy. Tariff protection on fluorspar, particularly on the highest or acid grade, has never been sufficient to cover the production cost differential between foreign and domestic fluorspars. Low ocean and barge freight rates have also contributed to the barring of the product of domestic mines from, the major consuming centers along the Gulf and East Coast. Because of the freight disadvantage, all but one or two fluorspar producers in the western states have had to suspend business. More than 80% of the domestic fluorspar is being produced in Illinois and Kentucky fluorspar districts which adjoin on both sides of the Ohio River.

Jan 1, 1964

By Lawrence Pelham

Introduction Fluorspar demand or consumption has been taken for granted in recent years, except for those that produce, market, or consume the commodity. Thinking used to be that as the steel and aluminum industry goes, so goes fluorspar. This is much less true today. The industry is becoming more dependent on chemical industries that feed primarily off hydrofluoric acid (HF) production. The US Bureau of Mines (USBM) published an assessment of world fluorspar reserves and resources. It created a foundation of valuable data that can be used to monitor fluorspar availability. Celebrations were held this year commemorating the 100th anniversary of the isolation of fluorine. The US and other countries continue to struggle with the controversy of ozone depletion and the effect of fluorocarbons on the atmosphere. Goals for the government's strategic stockpile are being reevaluated. The market for fluorine chemicals is changing and diversifying, making it a challenge to assess and forecast fluorspar/fluorine demand. US production and distribution Fluorspar Fluorspar shipments from US mines reached an all-time high near the end of World War II in 1944 at 375 kt (413,800 st). Eighty-two mines produced more than 453 t (500 st) each, and 10 mines produced more than 9 kt (10,000 st.) each. Illinois supplied 43% of total shipments. Consumption in 1944 was 372 kt (410,200 st), of which 56% was used by steel producers and 32% by HF producers. This was the last year that US production exceeded US consumption. The post-World War II record for fluorspar shipments occurred in 1951 at 315 kt (347,000 st) 58 mines produced more than 453 t (500 st) and eight mines produced more than 9 kt (10,000 st).

Jan 11, 1986

By Wm. I. Weisman, C. W. Tandy

Consumption of fluorspar in the United States in the last ten years has doubled to 1.34 million tons. One main, reason for the increase has been the use of the basic oxygen furnace to produce steel which requires considerably more fluorspar than the open hearth. The increasing consumption of aluminum and fluorocarbon chemicals will require more fluorspar, Since 1964 domestic fluorspar prices have advanced over 70%. Maximum prices were attained in 1971 and remain stable. These higher prices have brought about the expansion of production capacity at many of the present mines and mills. Exploration has been intensified, resulting in new discoveries, which are being brought into production. Many deposits, heretofore considered uneconomical, are being reappraised for possible development. Companies who have not previously mined fluorspar are actively seeking and acquiring new properties. The outlook for the continued health of the domestic fluorspar industries is favorable at present prices; however, it is doubtful that production will be greatly increased. New production will have to come from presently inaccessible areas of much greater distance from consuming centers. Prices will have to be higher to support this production. Domestic fluorspar production meets only 20% of domestic consumption. Thus, reliance on imports on fluorspar in the future will become increasingly more critical.

Jan 1, 1975

By Patrick R. Taylor

A kinetic study of the fluosilicic acid leaching of galena was performed under the presence of different oxidants. Fluosilicic acid concentration, agitation speed, concentration of solids and particle size, type and concentration of oxidant, and temperature were the variables studied. Hydrogen peroxide was found to be the most effective oxidant, its effectiveness being proportional to its concentration. As expected, an increase of leaching temperature increased the overall extraction and extraction rate. The same was found by decreasing the galena particle size. It is thought that leaching using hydrogen peroxide is controlled by fluid film mass transfer due to the calculated apparent activation energy. Reaction by-products such as sulfur and sulfur compounds retard the leaching rate. A mathematical model is proposed and compared to experimental results.

Jan 1, 2003

By Francis W. Brown, Philip R. Hunt, Douglas N. Halbe

Refractory arsenopyrite ore from Western Mining Corporation's Lancefield deposit in Western Australia is treated by fluosolids roasting of a flotation concentrate followed by cyanidation of calcine and flotation tailings. The project development is reviewed from original testwork through circuit design, operating experience, and subsequent expansion.

Jan 1, 1990

By R. M. Foley, Hidesaburo Kurushima

About 25 pct of all Japanese pyrite comes from the Yanahara mine on Honchu Island. For the past 40 years lack of an economical recovery process forced the operator, Dowa Mining Co., to sell the pyrite for its contained sulfur only, leaving 7 million tons of high grade iron ore waste. Introduction of the Dorrco FluoSolids roasting system enabled the company to make use of its iron sulfides and also to find a market for the mine's considerable pyrrhotite production. The success of this project is of great importance to Japan's economy since it points the way toward material increase in her natural resources. Prior to use of the present process, no practical method was available for commercial exploitation of known large tonnages of pyrrhotite, while the copper content of the even larger deposits of pyrite made the roasted residue unacceptable for the iron and steel industry. In Europe, large amounts of copper-bearing pyrite cinder are given a chloridizing roast for separation of the copper and iron but this treatment is not economical in Japan where salt is imported from as far away as Egypt.

Jan 10, 1958

By Robert B. Parsons

"Investors in flow-through shares are going to need an expanded road map to find their way through a growing maze of tax rules affecting such shares. At the end of 1985, no fewer than three new sets of important tax amendments were tabled which could have a significant effect on flow-through share issues. This proposed legislation is discussed this month in Tax Notes.IntroductionIn a flurry of legislative activity at the end of 1985, the federal government tabled legislation which includes the introduction of new rules which will have a notable effect on investors in flow-through shares and on companies that issue such shares.First, on November 26, 1985, Bill C-84, the legislation to implement most of the changes announced in the May budget, was introduced in Parliament. This legislation includes the rules for the $500,000 capital gains exemption, a matter of considerable interest to flow through share investors.Next, on December 2, 1985, the government tabled a Notice of Ways and Means Motion which would extend the time horizon for spending flow-through share funds to include the 60-day period following the calendar year. But all news was not good news. On December 4 the government released its proposals for a minimum personal income tax, which would include rules that would catch an investor's CEE expenses and capital gains."

Jan 1, 1986

By Kelly Cristina Ferreira

Na operação do alto-forno é comum observar flutuações em seu comportamento, seguindo o ciclo de vazamento de gusa e escória. O acumulo de liquido no cadinho e sua influência no aumento da força hidrostática são as principais causas dessa flutuação.O cadinho é uma parte crucial na operação do alto-forno por muitas razões. No entanto, por ser o local de acumulo de gusa e escória, este deve ter volume suficiente e facilitar uma drenagem sem distúrbios. Por isto, o estado do redutor/combustível, chamado “homem morto” desempenha uma importante função. Este trabalho apresenta uma breve revisão sobre os principais indicadores do estado interno do homem morto no cadinho do alto-forno.

Aug 16, 2017

By Gerald W. Longenecker

For decades, traditional hydraulic engineering approaches have been used for sizing stream channels when stream relocation efforts have been necessary to allow for the advancement of quarry and other surface mining operations. These approaches have been based on various ydraulic models to design channel cross sections and slopes that could pass the required regulatory design storm such as the 2-, 5, lo-, 25-, 50-, or even loo-year events. Designing the stream channel to handle these more extreme ,storm events would often lead to large channel designs which required extensive bank and channel bottom stabilization techniques including concrete, rip rap, gabions, or other expensive approaches. The constructed channels often required ongoing maintenance to remove accumulated sediment and other debris which would settle out and reduce the hydraulic capacity of the channel.

Jan 1, 1998

By Animesh Jha, Chris Dometakis

"Without the use of a flux, only a poor dispersion of ceramic phase can be achieved. A molten-flux-assisted ceramic phase dispersion technique for producing aluminium alloy metalmatrix composites has been developed. In this paper, we report the physical chemistry for the dispersion of TiB2 in molten aluminium. In particular, aspects of the interfacial energy and the thermodynamics of the dispersion reactions are briefly discussed for enhancing the volume of dispersion phase in the molten metal and for controlling their morphology. This investigation also addresses the role of molten flux in the fabrication of AI-alloy mmc using a casting technique. The morphological aspects of the dispersion are explained on the basis of the classical theory· of nucleation.IntroductionMetal matrix composites (MMCs), have long been recognised as an important class of material due to their greater wear resistance, specific stiffness and temperature capability when compared to conventional monolithic alloys. Particulate reinforced composites produced by melt casting techniques have been amongst the first MMCs to achieve commercial market viability. The advent of melt mixing techniques such as the Duralcan™ process have enabled low cost, easily fabricated composites based on the AI-SiC and AIAlz0 3 systems to be produced. In this process, uncoated ceramic particles with diameters 10ltm and larger, are incorporated into conventional monolithic alloys with reinforcement levels up to 25 volume percent. The AI-7Si-SiC metal-matrix composites have good wear resistance, high strength, low density and high thermal conductivity. The combination of these physical and mechanical properties has become a major attraction for the fabrication of light-alloy composite disc rotor brakes for the automotive sector2. However, in silicon-free alloys, SiC is thermodynamically unstable above the composite melting point and is extensively attacked by the melt to form aluminium carbide3 :"

Jan 1, 1996

By Ernest B. Snyder

The word "line" has been used loosely for many forms of the common steel plant flux. For example, many people use the word "lime" for nigh calcium and dolomitic limestone, for high calcium and dolomitic quicklime (also called caustic lime, calcined lime; burnt lime, pulverized and pebble lime) and ;van for clinkered dolomite. Calcium hydroxide, also called slaked lime and hydrated lime, is called "lime" but is seldom used as a flux except when the quicklime air slakes in open boxes or bins. All of the above forms of "lime" are used in the steel plant. Calcium hydroxide is used for water treatment, acid neutralizing, and as a lubricant for wire drawing. All the other limes are used as fluxes in the sintering plant, blast furnace or steel producing furnaces. In the production of self-flux or super-flux sinter, high calcium and dolomitic limestone fines are used. Where quicklime fines are available, they may be added to the sinter mix also. The blast furnace uses both high calcium and/or dolomitic limestone. A few trials have been made using iron oxide stabilized dolomitic lime in an attempt to reduce coke consumption and to increase the production rate. The trials were very successful but would' not be economical, except in periods of coke shortages, with resulting extremely high coke cost and exceptionally high hot metal demand.

Jan 1, 1979

By P Kumar, J Safarian

Understanding how ore interacts with flux particles at elevated temperatures to create molten slag is crucial since it governs the dynamics of a chemical reaction. This study explores the smelting behaviour of pre-reduced Nchwaning manganese ore when combined with lime, with the objective of examining the evolving interaction between pre-reduced ore particles and lime over time. The research sheds light on the interaction between solid and liquid and the phases that emerge during this process. To achieve this, a sessile drop furnace was employed to rapidly heat the materials positioned adjacent to each other on an alumina substrate and to observe the smelting process as it unfolded over time. This method allowed for the direct observation of the melting temperatures and the flux-ore reaction progression rate, and the potential disruptive events that might occur. By comparing the molten interfaces of the fluxed materials at various time intervals, this study provides insights into the relative rate of slag formation from the two materials. The results indicate that the main slag formation initiated at approximately 1400°C and continued to advance with time, with complete mixing occurring around 1500°C. The possible phases formed were identified using Scanning Electron Microscopy and modelled using Fact Sage thermodynamic software. In addition, the iron particles in the pre-reduced Mn ore were separated and settled from a rich MnO-containing slag. It was found that the separation of molten iron droplets from the slag depends on the rate of solid MnO particles dissolution into the adjacent slag phase.

Jun 19, 2024

By Raymond D. Potts

"Minntac is a taconite mining, concentrating and pelletizing operation located near the town of Mountain Iron, Minnesota, U.S.A. It is totally owned and operated by USX Corporation and represents its largest source of domestic iron units. Minntac began producing fluxed pellets in 1988 and has produced both acid and fluxed pellets since then. This paper compares the acid and fluxed pellets produced at Minntac. It reviews modifications that have been made to the plant flowsheet and discusses areas recognized for improvement since the beginning of fluxed pellet production. It also comments briefly on the performance of Minntac fluxed pellets in USX blast furnaces and the future of fluxed pellets at Minntac.IntroductionMinntac was built in three steps with each step designed to produce 6 million long tons of acid pellets per year. The actual production has varied though. Figure I shows the production by year at Mirmtac. Step I began production in 1967, Step 2 in 1972 and Step 3 in 1978. Mirmtac produced 16.5 million tons in 1979 but only 3.5 million tons in 1982 when the facility was shut down for six months because of the lack of demand for pellets. Since the initial start up, Mirmtac has produced over 200 million long tons of pellets. Until 1987, all the pellets produced were ""acid"" pellets. In 1987, equipment to produce ""fluxed"" pellets was installed and tested. In 1988, full scale production of fluxed pellets began."

Jan 1, 1991

By Frederick V. Lawrence

Broadly speaking, fluxes are substances which promote wetting and spreading or enhance the fluidity and manipulative properties of materials in joining, fusion, and smelting operations. The term most strictly applies to substances used to facilitate soldering and brazing; but in .he discussion which follows, the definition will be broadened to include materials used to promote fusion in arc welding and which aid in he smelting of metals. In each of the mentioned applications, the role of flux and its composition differs considerably; consequently n the discussion which follows, fluxes for soldering, brazing, arc welding, and smelting applications will be considered separately. Soldering and Brazing Fluxes Soldering and brazing are metallurgical joining processes in which a joint is formed using a filler metal of composition dissimilar to that of he joined pieces (base metal). The filler metal, older or braze, is always of lower melting point than the base metal. Consequently with these) recesses there is no melting of the base metal. The successful creation of the joint depends upon the wetting and spreading of the solder or braze around or throughout the joint. The obstacles to successful soldering and brazing are contaminants and tenacious oxide films on the metal surfaces. In soldering and brazing applications, fluxes act to remove and exclude oxides and other impurities from the joint. There is no fundamental difference between soldering and brazing. The distinction between them is made on the basis of temperature. Joining operations carried out at temperatures above 500°C are termed brazing. The higher temperatures used in brazing enable higher melting point filler metals to be used which generally provide stronger joints. The higher temperatures of brazing processes also require fluxes which are substantially different from those used in soldering and which will remain effective at high temperatures. Consequently the distinction between soldering and brazing can also be made on the basis of the fluxes used.

Jan 1, 1975

By Frederick V. Lawrence

Broadly speaking, fluxes are substances which promote wetting and spreading or enhance the fluidity and manipulative properties of materials in joining, fusion, and smelting operations. The term most strictly applies to substances used to facilitate soldering and brazing; but in the discussion which follows, the definition will be broadened to include materials used to promote fusion in arc welding and which aid in the smelting of metals. In each of the mentioned applications, the role of flux and its composition differs considerably; consequently in the discussion which follows, fluxes for soldering, brazing, arc welding, and smelting applications will be considered separately. Soldering and Brazing Fluxes Soldering and brazing are metallurgical joining processes in which a joint is formed using a filler metal of composition dissimilar to that of the joined pieces (base metal). The filler metal, solder or braze, is always of lower melting point than the base metal. Consequently with these processes there is no melting of the base metal. The successful creation of the joint depends upon the wetting and spreading of the solder or braze around or throughout the joint. The obstacles to successful soldering and brazing are contaminants and tenacious oxide films on the metal surfaces. In soldering and brazing applications, fluxes act to remove and exclude oxides and other impurities from the joint. There is no fundamental difference between soldering and brazing. The distinction between them is made on the basis of temperature. Join¬ing operations carried out at temperatures above 500° C are termed brazing. The higher temperatures used in brazing enable higher melting point filler metals to be used which generally provide stronger joints. The higher temperatures of brazing processes also require fluxes which are substantially different from those used in soldering and which will remain effective at high temperatures. Consequently the distinction between soldering and brazing can also be made on the basis of the fluxes used. Soldering Fluxes Even thoroughly cleaned and degreased, metal surfaces still possess tenacious oxide films which inhibit the soldering of the joint. The reactions which form these films increase with increasing temperature. The rate of oxide formation and the tenacity of the film varies with each base metal. Aluminum, magnesium, stainless and high alloy steels, aluminum and silicon bronzes when exposed to air form hard, adherent oxide films. These metals require highly active and corrosive fluxes to remove and prevent the reformation of oxide films during soldering. Metals such as copper and silver, on the contrary, form less tenacious films at a lower rate, so that mild fluxes are sufficient. Soldering fluxes must dissolve or remove oxides and promote rapid wetting and spreading of the solder. The flux removes the oxide film by loosening and floating it off into the main body of the flux. The oxide removal is often aided by the alloying of the solder with the base metal, undermining small areas of the oxide and detaching them (Anon., 1959). The flux coagulates and suspends the oxide particles which have been loosened. The flux forms a protective cover preventing the reformation of the oxides, permitting the spreading of the solder and the formation of a metallic bond between the solder and the base metal. Constituents of Soldering Fluxes: Soldering fluxes are commonly grouped into three categories: highly corrosive, intermediate, and noncorrosive. One normally would choose to use the least corrosive flux which will give satisfactory performance.

Jan 1, 1983