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By J. P. Hager

The formation of the vapor complex AgFeC14 (g) baa been identified and its thermodynamic properties determined. The vapor pressure of silver chloride can be enhanced by a factor of 15-20 due to the formation of the vapor complex. The vapor pressure of both AgCl (g) and AgFeC14(g) were measured using a double-zone transpiration .technique. Gibbs free energies have been determined for the vapor transport reactions. Laboratory kiln tests were conducted to confirm the enhanced recovery of silver through the formation of the AgFeC14(g) vapor complex and to indicate the opportunities for process development using this new vaporization chemistry.

Jan 1, 1985

By Colin Fink

TANTALUM and columbium occur together in tantalite and columbite ores, which may be considered as ferrotantalate (FeTa206), with part of the iron and tantalum replaced by manganese and columbium respectively, the general formula, therefore, becoming (Fe, Mn)O.(Ta, Cb)205. The ratio of tantalum to columbium is not fixed; the amount of tantalum may vary from one-third to three times that of columbium. Minerals having a high content of tantalum are called tantalite, while those possessing larger amounts of columbium are classified as columbite ores. These minerals are found in pegmatites and often occur in veins associated with cassiterite and wolframite, and may contain small amounts of tin, tungsten, titanium and silica.1

Jan 1, 1931

By J. Z. Cheng

The extraction of thorium from industrial radioactive wastewaters discharged from Rare Earth (RE) plants was studied by the liquid membrane emulsion technique using P507- Span80-sulphonating kerosene-HCl. The emulsion conditions, the technological factors such as ratios of oil to the internal aqueous phase and water to emulsion, and the extraction time etc. were investigated.

Jan 1, 2008

By Minji Jun

Leaching of the surface-coated metals from waste acrylonitrile butadiene styrene plastics (WABSP) has been investigated in the ammoniacal solution. The ammoniacal leaching of WABSP (typically containing 4.1 wt% Cu, 1.3 wt% Ni, 0.03 wt% Cr) efficiently dissolved copper and nickel, leaving unleached chromium as fine particles. The results indicate that the anions of different buffer media for metals leaching follow the order: CO3 2− > Cl− > SO4 2−. A declined leaching with high NH4OH–(NH4)2CO3 ratio (8:1) and a steep rise in extraction with high pulp in solution revealed the influence of anion (CO3 2−) and cation (Cu2+) present in the system. The leaching performed in carbonate solution by maintaining 5.0 M total NH3 concentration as NH4OH–(NH4)2CO3 ratio, 4:1; pulp density, 200 g/L; agitation speed, 400 rpm; temperature, 20 °C and time, 120 min yielded the maximum extraction (>99%) of copper and nickel. The study reveals a plausible recovery of the surface-coated metals from the WABSP without altering the properties of polymer material that can be recycled separatel

The main features and recent developments in the processes of benefication and extractive treatments of tin ores are reviewed. The need for development of processes to recover fine tin, tin from low-grade complex ores and from hard rock resources is indicated. The progress in understanding of slag-metal interactions and developments of fuming processes on industrial scale is delineated. the processes and prospects of hydrometallurgical and chlorination methods are briefly indicated.

Jan 1, 1992

By M. A. Halim, V. I. Lakshmanan, T. Sheikhzeinoddin, R. Roy

"Chloride metallurgy is emerging as an alternative process for the production of base metals. Process Research ORTECH Inc. (PRO) has been at the forefront of technological development of chloride metallurgy. PRO has developed an innovative technology for the production of high purity titanium dioxide, iron oxide and vanadium pentoxide from ilmenite ores and concentrates. PRO is also developing its proprietary mixed chloride technology for the extraction of vanadium from other sources such as oil shales. In this paper, results from the test work conducted at PRO for the extraction of Ti and V using a mixed chloride lixiviant are presented.IntroductionTitanium and vanadium alloys and compounds have numerous industrial applications. Titanium dioxide is used in paints, plastics, rubber, paper, inks, textiles and a number of other miscellaneous applications. Currently nanosize T1O2 is being investigated for application in the cosmetics industry. Inorganic sunscreens mainly use T1O2 or ZnO particles, which reflect and scatter ultra-violet light. T1O2 nanomaterial is also finding application in smart construction materials and coatings, as a photo-catalytic converter. Nano TiO2 can catalyze the dissociation of NOX gases and other automotive emissions, thereby reducing the smog in urban centers. After the construction material is exposed to sunlight or ultra-violet light, the T1O2 is photo-activated and degrades the pollutants.Titanium metal and titanium dioxide are produced from ilmenite (FeTiOs) or rutile (naturally occurring T1O2) ore. Only about 6% of the titanium resources are used to produce titanium metal and the rest is used to produce T1O2. Many of the titanium ore deposits currently have unacceptable levels of transition metals which limits their processing by conventional routes."

Jan 1, 2012

By A. E. Raddatz

The U.S. Department of the Interior, Bureau of Mines, is investigating methods for recovering tungsten from domestic resources. A calcine-quench-leach (CQL) technique was developed for the extraction of tungsten from the Golconda, Nevada, hot springs ores. The deposit contains disseminated tungsten, which cannot be beneficiated by conventional techniques and must be treated by hydrometallurgical methods. The CQL procedure consists of calcining the ore at 900° C for 3 hr, quenching in a solution containing 1.5 parts of NazCO3 and 1.5 parts of NaOH per part of WO3 in the ore and at a solution- to-ore ratio of 3 to 1, leaching at 200° C and at 250 psig for 3 hr, and filtering and washing the residue. A series of closed-circuit batch tests showed that 92 pct of the tungsten was extracted from a sample containing 2.32 pct WO3. The pregnant solution contained 11 q of W03/1.

Jan 1, 1982

By C. A. Eligwe, F. W. DeVries, A. E. Torma

This study is an investigation on using hydrogen peroxide for tank-leaching of uranium with sulfuric acid. The optimum sulfuric acid concentration was found to be 0.03 mole 11 -'for a 25% pulp density suspension. The order of reaction with respect to sulfuric acid concentration was found to be ns0.75. The best results vith hydrogen peroxide were obtained at a 4.64 molar ratio of 6202 to U in the ore. The order of reaction was found to be zero with respect to hydrogen peroxide concentration. The theoretical maximum rate effect of Hz02 on uranium extraction was derived as Vm = 8.15 x mole &-'min-'. The highest rate experimentally attained was 8.09 x mole kL'min-'. It was found that the uranium extrac- tion was not affected by the pulp density up to the 50% used in this study. However, the final yieldswere significantly higher (over 90%) for leaches carried out in the presence of Hz02 than (less than 90%) for leaches carried out in the absence of H202. The reaction was found to follow a first order course with respect to substrate concentration (pulp density) regardless of the presence of H202. The effect of temperature was more explicit at moderate tempetatures (30 to 55 C) than at lower (10 C) or at higher (70 C) temperatures. At this latter temperature an almost complete extraction was realized even without H202. The apparent activation energies were found to be AEa = 2.68 kJ mole-' in the absence of H202, 0.5 kJ mole-'with Hz02 at 40 C to 70 C. and 4.72 kJ mole-' with Hz02 at 10 C to 40 C. All these activation energy values suggested that the uranium extraction process is diffusion controlled regardless of the presence of H202. Further, the change in activation energy in the presence of Hz02 indicates the possibility of change in the reaction mechanisms at lower and higher temperatures.

Jan 1, 1980

By M. J. Baker

Energy and Minerals Australia Ltd are undertaking a study of the recovery of uranium from the Mulga Rock Deposits in Western Australia. Approximately 80-90% of uranium identified to date is present as tabular layer up to 5 m thick within a lignite seam 30 m to 50 m below surface. Other metals are also present. Metallurgical studies at ANSTO Minerals laboratories in Sydney have focused on identifying a suitable uranium leaching process and assessing the possible downstream impacts of the organic material in the ore. The extraction of other metals has also been examined. This paper provides the results of testwork performed at ANSTO to date.

Aug 1, 2010

By Andrea Koschinsky

Recent technological breakthroughs in the fields of ceramics, medicine, aerospace engineering and electronics (semi- and superconductors) are constantly creating new uses and an ongoing increasing demand for a variety of rare valuable trace metals. These so-called high-tech elements such as hafnium (Hf), titanium (Ti,) niobium (Nb), tantalum (Ta), zirconium (Zr), molybdenum (Mo), vanadium (V) and the rare earth elements (REE), many of them of strategic importance, occur inter alia at elevated and potentially economic concentrations in marine ferromanganese nodules and ferromanganese crusts, making those deep sea deposits potential future resources of these metals. As these metals are mostly present in the lattice of the manganese and iron phases, which are strongly intergrown, rather than in separate mineral phases within the nodules and crusts (Koschinsky and Hein, 2003), reductive dissolution of the host phases is a prerequisite to release and dissolve the valuable metals. To evaluate the association of these rare valuable metals with their mineral carrier phases, sequential leaching experiments were carried out on selected samples in a first step in our project.

Jan 1, 2011

By Urs Peuker, Thomas Mütze, Thomas Leißner, Inga Osbahr

"Mining in the Ore Mountains (Germany) has taken place for hundreds of years and in several stages. Each stage produced its typical tailing. According to the former state of the art of the processing much valuables could not be extracted. This was caused by complex interlocking of the minerals, low grades, or by upgrading processes not sensitive enough for small particle sizes. Thus the processing of these fractions was uneconomically. Modern technical possibilities and rising metal prices bring these tailings disposals into focus for the processing of strategic metals. Mining disposals can be classified in heaps with coarse, low grade rock, which did not undergo a processing, slags and fly ash from smelting, and tailing disposals from mineral processing. The latter is under investigation to integrate them into a geographic information system. The mineral processing of the material will be part of the database besides information about geographic location, structure, amount of valuables, and details of ownership of the heap. The tailings disposals are composed of coarse, low grade, interlocked particles from density separation processes, medium size particles, which are tailings from flotation, and fines with liberated valuables, which did not undergo flotation. Therefore mineral processing of these disposals comprises the separation of liberated gangue by classification, beneficiation of locked valuables with density separation, liberation of valuables by grinding, and beneficiation of liberated valuables with flotation. The presented work shows the results concerning the composition of one exemplary heap and results of the classification as well as of the preconcentration tests achieved with material from this heap."

Jan 1, 2014

By Kelly E. G

NZ Steel's flushing slag typically contains 1.2 per cent V203. Extraction of vanadium from powdered slag using a salt (NaCI or Na2CO3) roast/leach process was investigated. With NaCl, optimum extraction conditions were a charge containing 10 per cent NaCI, roasting in air at 875°C for 4 hours, followed by leaching in dilute H2SO4. Extractions were typically 30-50 per cent. NaCI roasting did not chemically attack the slag; the phase transformations that occurred were due to high temperature oxidation. Slag particle size had a significant effect on extraction.Optimum conditions for extracting vanadium by Na2C03 roasting were 20 per cent Na2CO3 in the charge and roasting in air for 3-4 hours at 850-875°C followed by water leaching.Na2CO3 roasting involved chemical attack that resulted in the formation of perovskite (CaTiO3) and carnegieite (NaAISiO4).The extent of vanadium extraction depended on the amount of Na2CO3 added and the original slag SiO2 content.Compared to the separate roasting treatments, simultaneous treatment with NaCI and Na2CO3 gave lower vanadium extraction, while requiring considerably higher roasting times and temperatures.

Jan 1, 1982

By Georgios Kolliopoulos

Water is a critical commodity of our generation and a key compound for the chemical and mining industries. Sustainable industrial development is directly associated with the ability to recover clean water from contaminated sources. Forward Osmosis (FO) is a low-energy footprint membrane process allowing the recovery of clean water from high salinity effluent streams. In FO, water is recovered spontaneously into a concentrated draw solution (CDS). Energy is required to separate the recovered water from the resulting dilute draw solution (DDS). In the current work, the fundamentals of the FO process and the most important aspects affecting its performance are discussed. An energy comparison of FO and conventional water recovery technologies is presented. Finally, the opportunities FO presents in the field of hydrometallurgy are analyzed.

By T. Ogasawara, J. P. Barbosa, A. J. Monhemius, F. T. Da Silvia

A thermodynamic analysis of the sulphation of rare-earth phosphates and the water-leaching of rare-earth sulphates was used to guide experimental work on the sulphation and leaching of concentrates from Pitinga. It was concluded that the sulphuric acid digestion of xenotime is technically feasible and could be used industrially to produce yttrium and other rare-earth oxides. Yttrium extractions of more than 90% were obtained by digestion at 503 K for 4 h at an acid:concentrate ratio of 2:1 with particle size -0.053 mm. The apparent activation energy at temperatures less than 473 K, as determined from the Arrhenius plot, was 11.0 kJ/mol, indicating that the reaction is controlled by the diffusion of the reactants or products through the sulphate layer

Jun 19, 1905

By Hassan Saalman, Mahmoud Mahmoud, Omneya El Hussaini

The Ferruginous sandstone ore was obtained from Ramlet Hemeyir area, Southwestern Sinai, Egypt, was found to contain 10% rare earth elements (REE). A representative sample has been subjected to sulfuric acid agitation leaching. About 93% of the REE content was released by mixing the ground sample to -100 mesh with concentrated H2SO4 at solid/liquid (S/L) ratio of 1/2 for 5h at a temperature ranged from 250 to 300o C. The REE was precipitated from the prepared sulfate leach liquor of pH 1.0 by adding 35% oxalic acid at 25o C. The precipitation yielded 98% REE. For selective separation of yttrium, the rare earth cake was leached with 31.5% nitric acid. Next, the aqueous solution was contacted with di-(2-ethylhexyl) phosphoric acid (D2EHPA) where 98% yttrium extraction was achieved. Stripping was done with hot H2O (80o C). Finally, a precipitation with oxalic acid was done followed by ignition at 950o C. A yield of 95% yttrium oxide was produced.

Jan 1, 2014

By Hsing Kuang Lin

Extraction of zinc from chloride solution with dibutyl butylphosphonate (DBBP) in Escaid 110 has been investigated. The distribution coefficient of zinc was found to be independent of equilibrium pH. This independence indicates that the mechanism of the extraction may be solvation. Slope analysis for the system of dilute zinc chloride solution reveals that two moles of DBBP react with one mole of zinc. A series of tests were conducted to bring DBBP to its full loading capacity and the analysis of the results confirms this stoichiometric factor of 2. Extraction isotherms were established by varying either the AIO ratio or the concentration of zinc in the aqueous feed. Both curves were found to be identical.

Jan 1, 1990

By J. Bai, C. Zang, W. Yuan, L. Zhuang

"This study evaluates the efficiency of using mechanochemical reduction to assist the extraction of zinc from zinc ferrites by alkaline leaching. The transition of zinc ferrite into a metastable state after mechanochemical reduction with metallic iron contributes to the ready dissolution of zinc from the activated zinc ferrites in alkaline solution. Zinc ferrites were mechanochemically reduced under conditions of Fe:ZnFe2O4 mole ratio of 2:1, using 5 mm diameter stainless steel balls as the activation medium at a mass ratio of balls to raw materials of 25:1. Subsequent leaching in 6 mol/L NaOH solution at 90°C resulted in more than 70% Zn extraction. These results may be used to further develop a hydrometallurgical process for recovering zinc from zinc ferrites in alkaline solution.IntroductionZinc is an important nonferrous metal required for various applications in batteries, solder, dielectric materials, and piezoelectric materials. High-grade, easily concentrated ores are becoming scarcer: to meet world demands for zinc, it is necessary to develop economical and environmentally safe metallurgical technologies that use secondary materials such as leach residues of roasted zinc concentrates and electric arc furnace dusts. The zinc in the majority of these wastes occurs in the form of zinc ferrite (franklinite, ZnFe2O4), which is very stable and insoluble in most acidic and alkaline solutions (Langova and Matysek, 2009; Youcai and Stanforth, 2000).Several pyrometallurgical and hydrometallurgical processes (Jankovi et al., 2014; Langova and Matysek, 2010; Morcali et al., 2012; Shawabkeh, 2010) have been proposed for the treatment of zinc ferrites. Pyrometallurgical methods are costly owing to high energy consumption and their emissions of toxic gases are considered an environmental problem; hydrometallurgical methods are preferred for process economy and environmental reasons (Copur et al., 2004)."

Jan 1, 2016

By S. Z. El-Tawil, K. A. El-Barawy, M. B. Morsi, M. M. Nasr, Z. I. Zaki

"Tue sulphatization of zinc concentrate produced from heated zinc concentrate of Um Ghieg area, eastern desert by ammonium sulphate as sulphatizing agent is carried out at different conditions to achieve the appreciable formation of soluble sulphates. The maximum zinc recovery as soluble sulphate equfils to 95% upon using 1.5 stoichiometry ammonium sulphate at 600 °C for one hour. Tue obtained leached zinc sulphate solution is subjected· to purification process to prepare high pure zinc metal and zmc compounds such as pure zinc sulphate, zinc caibonate and zinc oxide. The products obtained are analyzed chemically and identified by X-ray analysisTue mechanism and kinetics of the sulphatization process of zinc concentrate are considered where the activation energy is calculated and equals to 33.3 K.J.mol""1 A process flowsheet for the overall sulphatization process of zinc concentrate by ammonium sulphate is proposed.IntroductionConsiderable reserves of zinc ores are present in Um Ghieg area eastern desert, Egypt. The possibility of extraction zinc from these ores and preparing its valuable compounds by choosing a more feasible technology become of vital importance. An attention is focused on the sulphatizing roasting processes (1-9) to achieve the appreciable formation of soluble sulphates. Previous publications are reported in our division by El. Tawil and others (10-16) using ammonium sulphate as sulphatizing agent for the successful treatment of nonferrous bearing materials.Therefore, the present work aims to study the different factors affecting the sulphatizing roasting process of local zinc coocentrate by anunonium sulphate to extract completely zinc and preparing its main compounds. Tue mechanism and kinetics of the different chemical reactloos that 1ake place in the process are considered."

Jan 1, 2000

By K. Saberyan

In this study the extraction of zirconium and hafnium has been investigated by solvent extraction using Cyanex 302 in various media such as nitric, sulfuric and hydrochloric acid has been investigated. Effect of various parameters such as type and acid concentration, extractant concentration, type of diluent, equilibrium time, various foreign ions and finally type and concentration of strip-ping agent have been studied. The results showed that nitric acid was optimum media for extraction of zirconium and hafnium. The extraction of zirconium and hafnium occurred quantitatively in the concentration of higher than 4 M nitric acid but in hydrochloric acid media, quantitative extraction obtains over 8 M HCl. In sulfuric acid media, extraction of zirconium and hafnium is negligible. Stripping studies showed that the optimum reagent for stripping was 0.5M sulfuric acid.

Jan 1, 2014

By R. Schuhmann, A. M. Gaudin, J. Dasher

Occurrrences of South African uranium have been known qualitatively for over twenty years, but no account was taken of them because of their low grade. In 1945, known uranium deposits were few, but their grades were 20 to 100 times higher than South African ores. Viewed in this light, the exploitation of South Africa's uranium is revolutionary indeed. Development of various analytical procedures capable of dealing with the needs of the project accounted for one-half of the cost and included: a) simple and automatic radiometric analytical procedures, b) sampling procedures appropriate to prevent sample contamination, c) procedures for sample and record-storing to accommodate many thousands of analyses per month, d) chemical methods giving high accuracy analyses for high grade samples not at radioactive equilibrium, and e) development of rapid procedures having moderate accuracy for low grade samples i.e., mill tailings and barren liquors. This task is continuing today with major improvements coming from time to time.

Aug 1, 1956