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By Immo H. Redeker

Abstract-North Carolina is the leading state in the US in lithium mineral production. Spodumene is mined in open Pits and concentrated by flotation by the two companies, Lithium Corp. of America and Foote Mineral Co. North Carolina State University has a mineral research laboratory in Asheville, N. C., with trained personnel, batch and pilot plant facilities to assist in the state's mineral development. The NCSU Minerals Research Laboratory assisted both lithium-producing companies with spodumene concentration problems and has lately worked closely with Lithium Corp. of America to develop the best flowsheet for spodumene and byproduct recovery. The concentration of North Carolina spodumene and byproducts from pegmatites is presented and illustrated with figures.

Jan 4, 1979

By Immo H. Redeker

North Carolina is the leading state in the US in lithium mineral production. Spodumene is mined in open pits and concentrated by flotation by the two companies, Lithium Corp. of America and Foote Mineral Co. North Carolina State University has a mineral research laboratoy in Asheville, N. C., with trained personnel, batch and pilot plant facilities to assist in the state's mineral development. The NCSU Minerals Research Laboratory assisted both lithium-producing companies with spodumene concentration problems and has lately worked closely with Lithium Corp. of America to develop the best flowsheet for spodumene and byproduct recovery. The concentration of North Carolina spodumene and byproducts from pegmatites is presented and illustrated with figures.

Jan 1, 1980

By Immo H. Redeker

The Kings Mountain area of North Carolina is the lithium pegmatite center of the U.S., if not of the whole world. We have two spodumene and by-product mineral producing companies, Lithium Corp. of America, and Foote Mineral Company. We also have Kings Mountain Mica and Kings Mountain Silica Companies producing mica. feldspar, quartz and clay from weathered pegmatites in that area. Figure 1 gives the location of the spodumene pegmatite area in North Carolina. The two spodumene producers mine typical pegmatite ore in open pits after removing amphibolite or mica schist overburden which is sold to aggregate producers. The ore reserves are discussed elsewhere in this session. They are in the order of plus 50 million tons but not unlimited. 1.2 The major minerals found and concentrated from the North Carolina spodumene pegmatite ores are tabulated on Table 1.

Jan 1, 1977

By D. Raicevic

Interest has recently been revived in the recovery of tantalum from the Bernie Lake pegmatite deposit. A gravity concentration process was developed to give satisfactory recovery and concentrate grade. The application of high-intensity magnetic separation was also stud1ed. A pilot-plant investigation that confirmed the laboratory testing and provided a commercial-grade concentrate 1s described.

Jan 1, 1968

By M. M. Fine

THE results of a research and development lab- oratory and pilot-plant mineral-dressing investigation by the Bureau of Mines of the complex copper-lead-cobalt-nickel ores of southeast Missouri are reported in this paper. This investigation, in cooperation with the National Lead Co., showed that separate concentrates of lead, copper, and cobalt-nickel could be made by fine grinding and flotation. An industrial plant built subsequently by the St. Louis Smelting and Refining Div. near Fredericktown, Madison County, Mo., produced such concentrates during the war years. Present commercial production at the mill is limited to lead and copper concentrates, but research to permit economic utilization of the cobalt and nickel values is continuing.

Jan 7, 1951

By Andrzej Wala

Constantly increasing demand for energy materials and metal ores brought about tremendous progress in mining techniques which are characterised by a high degree of mechanization and concentration of works. One of the recent trends in underground mining mechanization is connected with an application of heavy machines with diesel engines [l],[2]. The introduction of diesel engines in mining all over world caused not only improvement in economic conditions but also the necessity to prevent contamination of air in the mine by toxic agents in diesel exhaust emissions. A generally used way of eliminating exhaust gases is proper ventilation of the cross cut by means of providing permanent exchange of air that would guarantee in every point of the cross cut and in every moment the decay in concentration of exhaust gases beyond threshold limit [3][4][5][6][7][8][9][10]. The present paper is an attempt to define a mathematical model describing the changes of concentration in cross cut face to which fresh air is distributed by ventilators and tubes in a forcing way. Obtained model should offer its practical adaptability to engineering calculation of the amount of fresh air needed for diluting and eliminating exhaust gases beyond threshold limit. Justness of these models has been confirmed by investigation of the growth of nitrogen dioxide concentration in air environment in some cross cut faces of Kiirunavaara iron ore mine in Kiruna (Sweden).

Jan 1, 1980

By E. W. Davis

THE large iron-ore producers on the Mesabi Range are able to maintain the silica in their shipping products at from 8 to 10 per cent by mixing ores of various grades, some assaying 4 per cent silica and some as high as 18 per cent silica. For each ton of 4 per cent silica ore mined, a ton of 14 per cent silica ore can be mined and mixed with it and the average grade maintained at 9 per cent. This mixing operation has made possible the utilization of large cluantities of ore too lean to be used alone. and herein lies the advantage of the producers who operate a number of mines at the same time. As the grade of the ore from one of the properties falls off, a little high-grade ore from another property can be mixed with it and the average maintained, while if one property alone were being operated all of the ore below grade would be left behind.

Jan 1, 1930

This report describes the investigational work on the development of a fire-assay method capable of concentrating, in a button of nickel sulphide, all six of the platinum-group metals present in samples of ores, concentrates, and mattes. In the method adopted, the sample is fused with a mixture of sodium carbonate, sodium tetraborate, nickel carbonate, and sulphur. The nickel sulphide formed during fusion collects the noble metals and carries them to the bottom of the crucible. The nickel sulphide button is dissolved, and the noble metals are isolated and determined. The coefficients of variation range between 1,0 and 4,9 per cent for the various platinum-group metals when they are present in concentrations between 0,3 and 75 p.p.m.

Oct 15, 1971

By J. Liniecki, w. Chruscielewski, T. Domanski

INTRODUCTION Mining is the Polish greatest industry employing about 350 thousand miners in more than a hundred underground mines. The mining regions are located mainly in the south of the country - see Fig. 1. [ ] The coal mining dominates, however, and the zinc-lead and copper-ore mines presently employ about 16000 miners. All these mines are rather deep and wet. Their drawing shafts are between a hundred to more then thousand meters deep. The cross-adit of working area of mines ranges from several kilometers to a few tens of kilometers. The numbers of mines per mine differ also considerably and depend on the territory and type of mines. The largest coal mines employ about ten thousand miners but the largest metal ore mines do not employ more than four thousand miners. In all the mines the electric motors or diesel engines are being used. The intensity of mine ventilation, characterized by the volume of fresh air injected in to the main ventilating shaft per miner and per unit of the power consumed by the engines is about 6 cubic meters per minute per man and per horsepower. The studies of the potential alpha energy of radon daughter products /RnDP/ could be divided into the three developmental stages: I-st - stage /1966-1970/ the stage of so called Pilot Survey. During this stage concentration of potential alpha energy of RnDP in the air was measured in selected typical mines in all mining regions of the country. II-nd - stage /1972-1974/ was the periodical control of concentration of potential alpha energy of RnDP in the air of zinc-lead and copper-ore mines which have been chosen and recognized during the first stage as being the most hazardous ones. Air-sampling system /ASS/ measurements were applied during this stage.

Jan 1, 1981

By W. D. Macleod

This paper describes a mineral dressing process for the upgrading of tin ores. The process described is called 'agglomeration' and. is similar in many respects to flotation. Many variables have been examined experimentally both on batch and continuous operations and are reported upon herein... Using a Mt. Pleasant tin ore, assaying 0.5% Sn, an upgrading to 8% Sn, with a recovery of 95% could be obtained by this process.

Jan 1, 1966

By J. D. Miller

Physical separation of bitumen from low-grade Utah tar sand deposits containing a relatively high viscosity bitumen phase (Sunnyside and Tar Sand Triangle deposits) has been accomplished by traditional size reduction and froth flotation techniques. At appropriate experimental conditions more than 90 percent of the bitumen can be recovered in a concentrate, containing more than 20 weight percent bitumen, which should be a suitable feed material for subsequent hot water or thermal processing. The efficiency of bitumen recovery depends on the extent of size reduction, promoter and dispersant addition. Rejection of greater than 60 percent of the sand at ambient temperature and ease of water removal from the concentrate make such a process strategy both energy and cost effective. The energy required to achieve effective separation by the ambient temperature process is significantly less than the energy required for the recently developed hot water process. The flotation behavior of the tar sand has been analysed with respect to flotation pH, contact angle measurements and the apparent iso- electric point of the bitumen. The best flotation response at pH 7.8 to 9.0 can be correlated with the maximum in contact angle developed between the air bubble and bitumen surface and with the apparent iso-electric point of the bitumen (-pH 8.0).

Jan 1, 1981

By A. P. Watts

FOREWORD THE problem of concentrating the disseminated lead ore of southeast Missouri is extremely simple. The economic mineral is galena and the gangue is dolomite. The ore assays from 4 to .6 per cent. lead, 80 per cent. of which is recovered in a 70 per cent. concentrate.. The ore is crushed through 10 mm. and sized on 2 mm.; the oversize is jigged, while the undersize is tabled, and the slime treated by flotation. The district is the largest lead producer in the world, the output of metallic lead for the year 1915 being 183,906 tons. Over 20,000 tons of ore a day is being treated. The management of the different properties is progressive and always open to suggestion. The fact; however, must not be lost sight of, that the problem in the district is peculiar, as the average ore contains but 80 to 120 lb. of a metal normally selling at about 4c. per lb. The low price of the metal limits the treatment system to one of low cost. An elaborate treatment is neither logical nor advisable. An engineer first visiting the district may consider that the method of treatment could be improved

Jan 10, 1917

Discussion of the paper of A. P. WATT, presented at the St. Louis meeting, October, 1917, and printed in Bulletin No. 130, October, 1917, pp. 1476 to 1563. THE CHAIRMAN (0. M. _BILHARZ, Miami, Okla.).-Mr. Watt's reference to sorting or hand-picking of the ore in the lead district, which is being introduced at Mine La Motte, is especially interesting. I believe, from my former experience in the district, that hand-picking should be practised to some extent by all the companies in the Lead Belt. I know that a great many thousand tons containing only very small amounts of lead are passed through the mills, which, of course, is not to the advantage of milling machinery. That procedure may be Warranted at times of high prices, but I think that hand-picking should ordinarily be adopted to some extent: ERNEST GAYFORD, Salt Lake City, Utah.-On page 1525, speaking of the settling of slime previous to treatment either on slime tables or by flotation, Mr. Watt states: "The settling area allowed per ton of dry slime varies from 11 to 16 sq. ft.-an average for the district would be about 13 sq. ft. of settling area per ton of dry slime. This figure applies when the, discharge contains 20 per cent. solids." Mr. Ramsey, of the Dorr company, is here and I would like to ask him whether a settling area of 13 sq. ft. per ton of dry slime per 24 hr. is not considerably above the average area of Dorr settling tanks, and whether 20 per cent. solids is not above the general dilution for that' capacity? I should also like to know what is the general average on slimes of that character. E. R. RAMSEY, Denver, Colo.-An allowance of 13 sq. ft. per ton does seem rather large. I am not familiar with the settling characteristics of the dolomitic gangue, but as an average over the country, I should say that 6 or 7 sq. ft. would be nearer correct for discharge at that consistency. L. A. DELANO, Bowie Terre, Mo.-We have had an opportunity to try our tanks at the highest capacity, and-find that by thickening the slime to 30 per cent. solids we average 12 sq. ft. per ton of dry slime. ERNEST GAYFORD.-DO you find any definite ratio between the thickness of the discharge and the settling capacity of the tank? Do you consider that the tank has a larger capacity if the discharge is 3 to 1 than if it is 50 per cent. solids? L. A. DELANO.-I think it has greater capacity with the thinner discharge. It depends a good deal on the density of feed to the tanks; in our case the feed contains 2.5 per cent. solids.

Jan 1, 1918

Beaches contain the residue of eroded rocks which have resisted weathering, and it is common to find in all beaches some of the harder, heavy minerals. The natural sorting action of waves and winds tends to concentrate the heavy minerals into banded deposits.The value of such deposits is extremely variable. Even amongst the more concentrated deposits, the principal minerals, in the vast majority of cases, are magnetic, titaniferous magnetite and other forms of iron oxide, which, in the present state of mineral economics and technology, are of little or no value.Valuable minerals of fairly common occurrence in beach sand deposits are rutile, zircon, ilmenite, monazite and chromite, and each of these minerals, as well as others of less common occurrence, is obtained from beach deposits in various parts of the world.Along a stretch of 300 miles of coast from Coff's Harbour in New South Wales to North Stradbroke Island in Queensland, occur unique concentrations of heavy minerals. The principal minerals which occur are rutile, zircon and ilmenite, and for some years these deposits have contributed half to three-quarters of the world's consumption of rutile and zircon 1, ,2. The only other notable beach sand concentrations in Australia are at a number of places in the southwest of Western Australia, where deposits containing highgrade ilmenite are being developed.

Jan 1, 1950

By Geoffrey G. Hunkin

This is a brief state of the art paper describing current (1975) Uranium recovery plant flowsheets, some notes on system selection, design philosophies, and materials of construction. The in-situ, or borehole solution mining, of Uranium is a process which has been developed over recent years to better match Uranium mining and milling technology with the size, shape, grade and territorial distribution of the remaining identified Uranium deposits of western United States. Solution mining recovery plants are pure hydrometallurgical units ideally suited to automation, modular design, and mobility. Similar to conventional Uranium mills, two basic flowsheets, one acid and one carbonate, are in use, but the predominance is reversed so that the majority of plants employ the alkaline carbonate flowsheet, All plants incorporate resin bead ion exchange Uranium recovery for both acid and alkaline circuits.

Jan 1, 1976

The gold concentration profiles which develop inside the activated carbon particles during the adsorption process were measured, so as to obtain additional direct proof of intra-particle mass transfer rate-control and to determine how individual carbon particles in a population vary in their gold uptake behaviour. The observed gold concentration profiles inside the activated carbon particles were typical of situations where an intra-particle mass transfer mechanism is rate-controlling. Gold di-cyanide penetrated the carbon particles with a wave-like front until it was uniformly distributed throughout the particle. This corresponds with the profiles predicted by the film and surface diffusion model. However, the rate with which gold di-cyanide was transported inside the individual carbon particles varied within the population of carbon particles. This variation was characterized by a lognormal distribution in surface diffusivity. Because the estimated variances of these surface diffusivity distributions were small, the dynamic adsorption behaviour of the carbons used in the present study did not deviate significantly from that predicted by a model based on film mass transfer and a single surface diffusivity. Van Deventer (1984, 1985 and 1986a) reported data that could not be adequately described by a model based on film mass transfer and a single surface diffusivity. In this study a model based on film mass transfer and a wide lognormal distribution of surface diffusivity values was applied to his data. It was shown that a population of carbon particles with a wide distribution in surface diffusivity values could offer an alternative explanation to the mechanism proposed by Van Deventer which was based on film mass transfer, with partitioning of the carbon into micro- and macropores with surface diffusion in the macropores and slow mass transfer into the micropores.

Jan 1, 1997

By H. S. Rankin

THIS paper is condensed from several reports by members of the staff of the Minerals Testing Laboratory of the Tennessee Valley Author-ity, on a series of experimental tests in the beneficiation of barite of the Valley area. These experiments were conducted upon a large number of samples taken from several mines in three different districts. The area contains numerous producing deposits, nearly all of which are hampered by the high iron and silica content of the ores. Because of the small difference in specific gravity between the iron oxide and the barite, a gravity separation is generally poor. The removal of the iron thus offers a special problem. Some of the operators have turned to magnetic separation to meet the shipping requirements for less than one per cent iron. The present experiments were conducted to determine the application of decrepitation or flotation in simplifying the concentra-tion of the barite by removing the iron oxide and silica in one operation. Practically all the barite marketed in the area has been as "off-color" crude. The bleaching studies were made to determine the bleach-ability of the ores to alleviate this inferior grading, placing them on the market as bleached barite.

Jan 1, 1938

By V. F. Bannikov, A. P. Kozlov

"The purpose of this study was to develop a theoretical and technology framework for designing new combined technologies for processing tailings containing non-ferrous and noble metals using dry separation. The main goals of the study were: identifying the distribution patterns of valuable components in various fractions in dry separation processes; examining the patterns identified for different types of non-ferrous and noble metal tailings; developing a theoretical and technology foundation for the development of innovative technologies for the efficient processing of tailings with minimal process water consumption. To examine the possibility of efficient recovery of valuable components from refractory tailings using dry separation, an experimental laboratory unit was designed and built, composed of novel or modified lab equipment: plasma unit for increasing the magnetic susceptibility of Fe - containing minerals; magnetic separator supporting isodynamic and polygradient fields; pneumatic separator for the dry separation of finely dispersed mineral mixtures; dielectric separator using the resonant frequency of the electric field. The laboratory unit supports various modifications and combinations of the lab equipment. The experimental studies led to the development of a unified process scheme for lab tests of mature and non-ferrous smelter tailings using dry separation methods.INTRODUCTION The huge amount of waste from mining and processing of mineral resources Russia inherited from the extensive use of mineral resources in the Soviet Union and amount of waste continue to grow. Often the content of valuable non - ferrous, rare and noble metals in waste exceeds the balance contents in natural ores of the developed deposits. The availability of a rich scientific reserve for the creation highly effective innovative technologies for waste processing determines the necessity of the acceleration in the resolution of problems of the complex assessment, capitalization and involvement in the processing of technogenic resources in Russia (Chanturiya and Kozlov, 2014.)."

Jan 1, 2018

By Ayumu Tokumaru, Shuji Owada, Gangfeng Liu

"Several million spent catalytic converters are disposed annually worldwideandeach containing about 0.5-1g ofplatinum and 1-2g of all the platinum group metals (PGMs), then,it is fairly significant to recover PGMs from the spent automobile catalyst. The PGMs’ recovery is a proven technology, including pyro-and hydrometallurgicalmethods, and the highestrecovery can achieve approx. 98 wt.% by acid-leaching method, but theserecyclingtechnology seems to be too highlyenergy-consuming. SincePGMs aredistributed only in coat layer in spent catalyst, it is of great significance to enrich the coat layerwith some physical methods as a pretreatment.In this paper, according to the double-deck structureof the catalyst andthe different properties of the two main compositions, alumina-ceria phase of coat layer and cordieritephase of substrate, the concentration of the coat layer was investigated by combiningthree kinds of physical separation technologies, heating-quenching, crushing and surface grinding. In the first stage, thermal stresscouldgeneratebetween the two phasesby thermal expansion difference,to producefracturesin the thinnest part of coat layerand micro-cracksin coat layerand at the interface of coat layerand cordierite substrate. The second stage of crushing, by jaw and roll crushers, could break dominantly the coat layer and the third stage of surface grinding, carried out by attritor, promoted further separation and concentration of coat layer fromthe substrate.We also improved the attritor grinding by adding a new lift-arm to the cell for achieving better mobility of sample particles in the selective surface grinding."

Jan 1, 2014

By Andrea Koschinsky, Peter E. Halbach, Margret Halbach, Andreas Jahn

"Ferromanganese crusts contain hydrous Mn and Fe oxides as main metal compounds together with some economically interesting minor elements such as Co, Ni, Ti and Cu and trace metals such as Mo, W, Nb, Te, Ga, Pt, and REEs. Some of these metals or semimetals have a great future potential as innovative high-technology constituents. All of them are highly enriched in the crusts compared to seawater composition.The Mn in the crusts mainly originates from the O2 - minimum zone in the oceanic water column. The agent for Mn2+ oxidation is dissolved oxygen, transported upwards from colder deep water layers by turbulent eddy diffusion. The Mn itself descends from surface waters and is carried down to the O2-minimum zone by fecal pellet transport. In contrast, Fe is mainly supplied from carbonate dissolution of planktonic skeletons in the water column. These relationships result in the fact that the oceanic water depth strongly controls the metal composition of ferromanganese crusts: the Mn - group metals are more enriched in shallower water, whereas the concentration of the Fe - group metals increase with water depth. The REEs play a very important role with regard to the trace metal composition of the crusts: their concentrations increase with water depth mainly controlled by a decreasing Mn/Fe ratio.In seawater, REEs occur as carbonate complexes; preferably, the light rare earth elements (LREEs) form REECO3 +(aq) and the heavy Rare Earth Elements (HREEs) REE(CO3)2 (aq) complexes. The REEs are transition metals, their 6s orbital of the outermost shell is filled before the filling of lower 4f electron shells is completed, thus the configuration of the valence electrons is similar in all the REEs, and all REEs exhibit similar chemical behavior and exist, dominantly, as 3+ cations. The ionic radius decreases progressively from La3+ (1.18 Å) to Lu3+ (0.97 Å), this phenomenon is called "lanthanide contraction". Due to the fact that REEs in seawater form cationic and anionic carbonate complexes, the two main hydrogenetic constituents, hydrous !-MnO2 and Fe-oxyhydroxide, fractionate the group of REEs by surface absorption processes. According to the pHZPC-concept the ?- MnO2 phase has an electronegative surface, and Fe-oxyhydroxide a slightly positive surface charge at seawater pH. These relationships are the main reason for the observed REEs fractionation."

Sep 1, 2014