Search Documents

By Mona M. Fawzy, Ahmed A. Eliwa, Ahmed H. Orabi, Amal E. Mubark, Ebrahim A. Gawad

During the last decades, the growing demand for rare earth elements (REEs) has led to numerous recent studies to recover these elements from various bearing ores and wastes. Therefore, the recovery of REEs from Ras Baroud polymetallic concentrate has been investigated in the current study. Physical beneficiation for the Ras Baroud pegmatite sample was carried out, yielding a concentrate for euxenite (Y), fergusonite (Y), xenotime (Y), monazite (Ce), allanite, thorite, uranothorite, and Hf-zircon, which resulted in raising the concentrations of rare earth elements, Th, Zr, U, and Ti in the sample. Fusion digestion processes with sodium hydroxide were studied using the Conceived Predictive Diagonal (CPD) technique. The three experimental digestion groups proved the dissolution of 99.9, 95.6, 99.9, 52.5, and 0.47% for REEs, Th, U, Ti, and Zr, respectively, under fusion conditions of 723 K, 120 min, 1/1.5 ore/alkali ratio, and − 100-μm particle sizes. Fusion kinetics, isotherms, and thermodynamics were investigated using several suggested models, namely, pseudo reversible first order, uptake general model, and shrinking core model which matched well with the experimental digestion results. Selective recovery of actinide content from REE content of the digested concentrate chloride solutions was accomplished using solvent extraction with di-2-ethyl hexyl phosphoric acid. About 99.9, 99.9, and 4.2% extraction efficiencies for Th, U, and REEs were performed, respectively, using 0.3 mol/L solvent concentration in kerosene as a diluent, 1/2 organic to aqueous ratio, an aqueous pH of 0.2, and 15-min contact time. Thorium and uranium ions were stripped with sulfuric acid solution 2.5 mol/L with 94 and 98% stripping efficiency, respectively. A highly purified REE precipitate was obtained from the raffinate solutions. Zircon mineralization tailings were obtained as a by-product through the alkaline digestion process.

May 4, 2024

By Tahereh Rostami, Behnam Khoshandam

In the present paper, the recovery of mixed spent cathodes is evaluated and performed through a hydrogen reduction process. Firstly, the lithium is isolated by the hydrogen reduction process as LiOH at 600 ◦C for 15 min with 10% H2 with a flow rate of 350 ml/min. In the second step, 98.37% Li is recovered through water-leaching of hydrogen reduction products at 100 ◦C for 90 min with 50 ml/g. The filtration residual is reduced by using a carbothermic reduction process and a hydrogen reduction method. The first one is performed under an Ar atmosphere at 900 ◦C for 210 min and the second one is conducted at 800 ◦C for 150 min. The purer products are achieved using the hydrogen reduction method at lower temperatures and shorter holding times compared to a carbothermic reduction process with recovery percentages of 100%, 99.06%, and 70% for Ni, Co, and Mn, respectively. Given the importance of reducing the emission of toxic gases, the hydrogen reduction process is also a promising method for metal recycling. The obtained results also demonstrated that Li, Co, Ni, and Mn can be effectively separated from the mixed cathode material through the hydrogen reduction process as a sustainable and environmentally friendly recycling process. This study provides an impressive understanding of the hydrogen reduction process and valuable guidance for a larger-scale hydrogen reduction process.

May 3, 2024

By Ebrahim F. Salmi, Tan Phan, Ewan J. Sellers, Thomas R. Stacey

Extension of ore pass length has become increasingly critical for optimising energy-efficient underground mining operations. Long and ultra-long ore passes, spanning from 300 to 700 m, can significantly improve the functionality and viability of underground mass mining operations though suboptimal performance has an extremely adverse impact on production. The public domain lacks substantial information regarding the primary engineering, geological, and geotechnical risks and challenges associated with the design, implementation, operation, and maintenance of such long ore passes. Therefore, the aggregation of past experiences and the insights of experts assume paramount significance. An innovative methodology is introduced to address this evident data deficiency and to establish comprehensive guidelines for the resilient design of such lengthy ore passes — combining gap analysis with expert elicitation techniques. This equips design engineers with the necessary tools to formulate and adapt strategies for assessing the numerous challenges and uncertainties that invariably accompany their projects. Expert elicitation techniques are summarised, and a gap analysis is conducted with subject matter experts, from various countries, collating their extensive ore pass design experience, to create a comprehensive list of effective parameters and key risks that must be considered. Quantitative analysis of the survey results enabled the identification and ranking of the numerous factors affecting the design, operation, and maintenance of long and ultra-long ore passes and highlights the complex technical challenges (substantial damage from rock particle impact, increased dynamic mining stresses leading to failure, air-blasts and back blasts, dust, preferential flow, turbulent and dynamic material flow) that are uncommon in shorter ore passes. Additionally, increasing length heightens the probability of intersecting weak rock or discontinuities, leading to a higher risk of structural failure and instabilities. Faulting, folding, and large-scale structures are also critical geological factors to be considered in the design of such structures. The key geotechnical factor is also the rock type surrounding the pass. Experts highlighted the lack of clear guidelines for decision-making, resilient design, and construction so this work suggests future investigations to determine the complex interaction between the effective parameters, using approaches like the rock engineering system, discovery of cascading hazards, and optimal controls.

May 3, 2024

By Phillip Mackey, Elmira Moosavi-Khoonsari

L'industrie du cuivre traverse une période passionnante, marquée par une forte demande, de bons prix et l'ouverture de nouvelles grandes installations. L'année 2022 a battu des records de production de cuivre, ce qui laisse entrevoir un potentiel de croissance supplémentaire. De grands projets sont en cours, comme la technologie Double Flash à Manyar, en Indonésie, qui peut produire plus de 500 000 tonnes de cuivre par an. À Munda, en Inde, on a construit la plus grande usine de cuivre du monde, qui produit plus de 1 000 000 tonnes de cuivre par an en combinant deux phases. De plus, l’installation de cellules de flottation de dernière génération au Mexique, au Chili et dans d'autres pays témoignent de la volonté de l'entreprise d'utiliser les technologies les plus récentes [1]. L'importance du cuivre dans la transition énergétique est évidente, l'accent étant mis à la fois sur la croissance et sur la protection de l'environnement. Cela se traduit par le développement d'usines de premier ordre dédiées aux pratiques durables.

May 2, 2024

By Patrick Laflamme, Jean-François Boulanger

Les minerais de cuivre sulfurés, qui représentent 80% de la production mondiale de cuivre, imposent une étape de concentration des minéraux, premièrement pour atteindre une teneur en cuivre minimale qui permette le traitement pyrométallurgique, mais aussi pour limiter la présence d’élément pénalisants (délétères). Cette introduction offre un survol des principes, limites et pistes d’améliorations touchant la concentration des minéraux de cuivre.

May 2, 2024

By Étienne Yvenou, Martin Désilets

Le procédé d’électroaffinage du Cu est nécessaire pour atteindre les niveaux de pureté requis pour les applications les plus courantes telles que son utilisation comme conducteur électrique ou thermique.

May 2, 2024

By Serge Perreault

Le cuivre est un métal fascinant qui joue un rôle essentiel dans le développement des différentes civilisations depuis 7000 ans. Le cuivre est aussi un métal polyvalent et essentiel qui est très présent dans notre vie quotidienne. L’un des premiers métaux utilisés par les humains, il est un élément chimique qui se trouve à l’état natif, ce qui est rare pour les métaux. Il apparaît principalement dans des minéraux, notamment sous forme de sulfures, en raison de son caractère chalcophile (c’est-à-dire son attraction pour l’élément soufre). Le cuivre se trouve dans la croûte terrestre sous forme de minéraux de cuivre, tels que dans les sulfures dont la chalcopyrite, la bornite, la covellite et la chalcocite. Il est également présent sous sa forme native ou dans des minéraux oxydés comme la cuprite et dans des carbonates hydratés, comme la malachite et l’azurite. La formation de gisements de minerai de cuivre implique des processus géologiques complexes, notamment l’activité hydrothermale, les intrusions magmatiques et l’altération des roches. Les gisements de minerai de cuivre se trouvent dans divers types d’environnements géologiques, dont les gisements porphyriques, les gisements de cuivre encaissés dans des roches sédimentaires, les gisements de type skarn, les gisements de sulfures massifs volcanogènes, les gisements magmatiques de type nickel-cuivre, les gisements de cuivre oxydé, et d’autres [1].

May 2, 2024

By Joël Kapusta

La pyrométallurgie du cuivre est essentiellement une chaîne de trois étapes successives d’oxydation préférentielle du fer et du soufre et des impuretés moins nobles que le cuivre qui sont contenues dans le concentré de cuivre issu de l’usine de concentration du minerai, aussi appelée concentrateur. La Figure 1 illustre la chaîne complète d’élaboration du cuivre depuis la mine jusqu’au cuivre pur. La voie hydrométallurgique traite le concentré par lixiviation, c.à.d. par dissolution en phase aqueuse à température typiquement inférieure à 100 ou 150⁰C, alors que la voie pyrométallurgique traite le concentré par fusion à température de l’ordre de 1200 à 1300⁰C.

May 2, 2024

By Isabelle Demers, Audrey Jalce

L’industrie minière génère chaque année une quantité considérable de rejets miniers, principalement sous forme de stériles ou de résidus de l’usine de traitement. Les stériles sont des roches sans valeur économique, excavées pour atteindre la roche minéralisée. Ils sont usuellement empilés en surface formant des haldes à stériles. Les résidus miniers sont des roches finement broyées, mélangées avec de l’eau, résultant du traitement du minerai. Ils sont généralement pompés et entreposés en surface dans des parcs à résidus. Cependant, leur stockage peut être sujet à des instabilités géotechniques, mais également géochimiques, pouvant entrainer des problèmes environnementaux majeurs, tels que le drainage minier acide (DMA). Le DMA se produit lorsque des minéraux sulfureux, contenus dans ces deux types de rejets, s’oxydent au contact de l’eau et de l’oxygène [1]. Le DMA se caractérise par une solution acide (pH inférieur à 6) riche en métaux, contaminant les eaux souterraines et de surface et représentant alors un danger pour la faune, la flore et la santé humaine [2]. La remise en état et la fermeture des sites miniers doivent donc être pensées dès la phase d’étude du projet d’exploitation, afin de proposer une méthode de gestion des rejets qui permettra de limiter les impacts environnementaux pendant et après l'exploitation.

May 2, 2024

By Yuqi Zhao, Zhiyong Lin, Leiting Shen, Hongyang Wang

Gibbsite-type bauxite is the main material for alumina extraction by Bayer process globally, while the iron in red mud is difficult to use for the high alumina content. Therefore, the efficient separation of iron and alumina is the premise for the resource utilization of red mud. In this work, the separation of iron and alumina in red mud containing 47.45% Fe and 11.58% Al2O3 was studied through reduction roasting followed by magnetic separation. The analysis methods of XRD, VSM, SEM, and EDS were used to investigate the phase transformation of red mud during reduction roasting. Results show that hematite can be firstly reduced into magnetite, and alumogoethite into magnetite and alumina. Then, the magnetite reduction undergoes the process of Fe3O4→FeO→Fe, while alumina can react with FeO to form hercynite. The hercynite is ultimately reduced into metallic iron and alumina at elevated temperature. The specific saturation magnetization of reduced product is closely related to its main minerals, that is, the specific saturation magnetization of magnetite and metallic iron is higher than that of wustite and hercynite. The mass ratio of Fe to Al2O3 in magnetic concentrate increases with roasting temperature, from 4.55 at 600 °C to 10.27 at 1200 °C. Therefore, efficient separation of iron and alumina in red mud could be achieved through deep reduction-magnetic separation.

May 2, 2024

By NILAMADHABA SAHU, Gajanan U. Kapure, Pankaj Kumar, Sunil Kumar Tripathy

Chromite ore processing tailings and low-grade manganese ores are typically considered waste due to their limited or negligible utility, leading to environmental and storage concerns. Researchers globally have explored various methods to utilize or upgrade these wastes, particularly because dumping chromite ore has been linked to severe health issues through Cr(VI) leaching. Individually, these ores lack economic value, and there has not been research on simultaneously reducing both low-grade ores. In this study, the focus lies on smelting these ores together, aiming to create a precursor alloy for 200 series stainless steel scrap. Initial research indicates the potential for scrap formation, validated through laboratory experiments with varying coke rate, basicity and holding time. The investigation discovered that smelting this combination could yield a metal product consisting of 59 percent Fe, 24.93 percent Cr, 7.56 percent Mn, 0.62 percent Ni and 0.93 percent Si. The optimum basicity was found to be 0.6 with 80 percent recovery. Notably, this process eliminates intermediate steps in 200 series stainless steel production, potentially reducing overall carbon dioxide emissions. This proposed method represents a cleaner, sustainable approach to repurpose these two waste ores, projecting a net profit of US$330/t.

May 1, 2024

By Brianna Eiter, Max Barham, Tim Bauerle

While not well established, there is evidence that the mining industry is encumbered by several work-related fatigue risk factors. Compared to other industries, mine workers are more likely to report inadequate sleep and work longer hours per day. Given these observations, there is a critical need to identify effective ways to intervene, manage, and mitigate mine worker fatigue and sleepiness when present. One barrier to this is confusion around the similarities and differences between fatigue and sleepiness, which can result in these terms being treated as interchangeable regardless of context and make it difficult to assess and mitigate safety risk.

May 1, 2024

By Brendan Donnelly, Jung-Hoon Sul, Lasitha Piyathilaka, Sanghyun Jeong, Benjamin Probyn

The chains of armored face conveyor (AFCs) are constantly in contact with water and wet coal, which results in a significant proportion of unplanned downtime experienced on longwall equipment due to corrosion. While reverse osmosis (RO) is one of the most prevalent water treatment methods for reducing salinity and dissolved solids in coal mining, its impact on the corrosion of the AFC chains has not been well studied. This work studies the direct effects of RO water on the corrosion of AFC chains. Immersion tests followed by surface micromorphology analysis and corrosion indices indicate that the RO water increased the corrosion rate of the AFC chains due to the reduced tendency of preventive films on the chains.

May 1, 2024

By ERIK CHARRIER, ADITYA JUGANDA, Jürgen Brune, Gregory Bogin, Patrick Maier

Confined explosions are a major risk in underground coal mine operations. Depending on confinement, ignition location and obstacles in the flame path, methane explosions can transition to detonations. This research focuses on explosion experiments in a reactor with diameter of 71 cm and length of 30.5 m, along with developing the corresponding computational fluid dynamics (CFD) model that captures the observed flame behavior. The results show that the 2D and 3D CFD models are able predict the experimental flame front propagation velocity, but the 3D model shows more explicit conformity than the 2D model.

May 1, 2024

By Arif Emre Dursun

The aim of this study is to present hazard classifications of location, type and causes of accidents in the Turkish coal-extracting industry using the analytic hierarchy process (AHP). In this study, fatal mine accidents were analyzed by pairwise comparison and weighting, and the most important hazards were identified by determining the effective main and sub-criteria among location, type and causes of accidents. For this purpose, first-, second- and third-level hazards consisting of location, type and causes of accident were determined by using the data of fatal mine accidents in underground and openpit coal mining in Turkey between 2010 and 2020.

May 1, 2024

By Mustafa Kumral, Mehmet Balci

Strategic mine planning centers on solving cut-off grade selection, capacity planning, and block sequencing. Even though significant knowledge has been accumulated on mine planning over the last decades, there is still potential to add value to mineral sourcing by addressing various aspects. To this end, this paper addresses two issues. The effects of (1) grade/metal distribution within a mineral deposit and (2) the economies of scale (EoS) are explored in cut-off grade selection and capacity planning. In doing so, the interdependency between cut-off grade selection and capacity planning is also considered. A case study is implemented on a metallic deposit whose grade distribution exhibits lognormal distribution to detect if grade/ metal distribution influences cut-off grade selection. Also, based on the same ore tonnage and metal quantity, six different datasets are generated with different shape and scale factors. The research outcomes indicate that deposits with lower shape and scale factors of lognormal distribution are more sensitive to metal price and discount rate changes because slight cut-off grade variations significantly change net present value (NPV). While the NPV of the deposit with the largest shape factor is $3,208,112,841 with a cut-off grade of 0.058 oz/tonne, the NPV of the deposit with the smallest shape factor is $93,617,240 with a cut-off grade of 0.027 oz/tonne. Furthermore, the case study is directed to investigate the effect of EoS on a project’s value, with a specific emphasis on the ratio of variable cost to total cost (capacity factor). Two different regression analyses are conducted based on the proposed model for optimal capacity planning and cut-off grade selection, respectively. In the first one, the absolute standardized beta values for EoS of mining and mineral processing costs are 0.736 and 0.425, meaning that capacity planning is highly sensitive to the EoS of mining and mineral processing operating costs. Meanwhile, the absolute standardized beta value for grade variability is 0.054 which means that the effects of grade variability and metal distribution are almost negligible for capacity planning. However, EoS is the most critical variable for capacity optimization. In the second regression analysis, the standardized beta values for grade variability and EoS of mineral processing operating cost are 0.573 and 0.522, so their effects on cut-off grade selection become vital.

Apr 29, 2024

By Shanxi Wu, Jialong Li, Haoyu Hu, Jiqing He, Zhaohui Wang, Bochao An, Shenyi Zhang

There are a large number of thick alluvium and thin bedrock deposits at depth in the Henan coal base. The degree of surface mining is high, and the surface environment is seriously damaged. Using indoor experiments, numerical simulation, and field measurement, it is studied the influence of the mechanical properties of thick alluvium on the surface subsidence characteristics of thick alluvium thin bedrock deposits at depth, taking Zhaogu No. 2 coal mine as the research background. The results show that the compressive strength and elastic modulus of the alluvial layer are linearly negatively correlated with the alluvial layer particle size, linearly positively correlated with the confining pressure, and nonlinearly positively correlated with the loading rate. The thickness of the alluvial layer has the greatest influence on the displacement of surface subsidence and the range of surface subsidence. The advancing mining rate of the working face has the greatest influence on the surface horizontal displacement. The mechanical properties of the alluvial layer affect the evolution characteristics of the caving arch and towering roof beam. The influence range of the 11012 working face is about 550 m, β is about 55.5°, and the maximum subsidence rate of the surface is 12 mm/day. The mining process and separation grouting can be adjusted to control the overburden displacement to reduce surface disturbance and protect the surface ecological environment. The research results of this paper can provide a research basis for the study of surface subsidence under similar geological conditions.

Apr 28, 2024

By Sidi Deng, Sharon Pedraza, Aaron Noble, Subodh Das, Bin Ji, Wencai Zhang, Michael Van Brunt

In this study, a MSWI bottom ash sample was assessed to evaluate the feasibility of various physical beneficiation processes in concentrating valuable elements prior to chemical leaching. The raw sample was initially assayed to determine the content and economic value of various metals present in the material. The potential recoverable value (PRV) of the sample was calculated, and the result showed that the total PRV of the sample was 483 $/ton, with Ti, Sc, Fe, Cu, and Zn being the most valuable metals. Next, various physical separation processes, including size fractionation, froth flotation, magnetic separation, and gravity separation, were conducted to determine the extent to which the valuable elements can be concentrated. The results were compiled into an element-by-beneficiation enrichment ratio (er) matrix that was used to develop suitable beneficiation flowsheets for further consideration. The result clearly show delineation of four products, including a Fe-rich product that can be isolated by magnetic separation (er = 5.0), a Cu/Zn-rich product that can be isolated by flotation (er = 5.3 to 9.4), a Sc-rich product that can be isolated by gravity separation (er = 0.6), and a Ti–rich product that is produced in the residue. Lastly, the leachability of valuable elements from the bottom ash sample was determined by acid leaching tests. The results indicated that it is viable to employ hydrometallurgical methods to recover and purify the valuable metals. This work provides a reference for the recovery of valuable metals from MSWI bottom ash from both the technical and economic aspects.

Apr 27, 2024

By Chun Yu, Jiarui Min, Xuemin Ding, Rongdong Deng, Bao Guo, Yu Miao

Pb2+ plays a modifying role in the flotation behavior of various sulfide and oxide minerals. However, there is currently no consensus on the use of lead salts as modifiers in mineral flotation. Based on previous research, this article provides a comprehensive review of the activation effect of Pb2+ on common oxide and sulfide minerals flotation from the perspective of interfacial reactions. A theoretical model for Pb2+ activation has been proposed in this article. When the pH is less than 7, Pb2+ replaces the metal atoms in the lattice of sulfide minerals or adsorbs on the mineral surface to form PbS. When pH is in the range of 7 ~ 10, chemical adsorption of Pb(OH)+ occurs on the mineral surface, leading to the formation of Me-O-Pb+. When pH = 10 ~ 11, Pb(OH)2 precipitates on the mineral surface. Under this condition, it activates the flotation of quartz but inhibits the flotation of sulfide minerals.

Apr 25, 2024

By Binbin He, Baiwei Lei, Rehamutula·Rouzi, Zheng Wang, Chao Li

Methane explosions are highly destructive and constitute a primary hazard affecting mine safety. Seals are commonly employed to obstruct the propagation of methane explosions within tunnels, with the aim of reducing the damage caused by methane explosions. In order to study the influence of the seals’ position on the parameters of methane explosion damage, this study takes the Lake Lynn Experimental Mine No. 501 in the United States as a background case. It investigates the methane/air explosion damage parameters at different positions of seals in a fully sized roadway using the GASFLOWMPI code. The coupling mechanism between methane explosion gas expansion and reflected waves is analyzed. Finally, the variation patterns of explosion damage parameters are analyzed based on explosion damage criteria. The results show that as the distance increases between the seal and the explosion source, the maximum overpressure and impulse at the seal decrease exponentially, and the decrease is more significant when the seal is closer to the explosion source. The maximum velocity and maximum dynamic pressure increase first and then decrease, reaching their maximum values at approximately 115 m. They are approximately 163.355 m/s and 30.485 kPa, respectively. According to the analysis of explosion damage criteria, it is found that overpressure damage is the main form of methane explosion damage. But the damage of impulse and dynamic pressure is not be ignored. The relative position between the seal and the gas expansion area significantly impacts the parameters of methane explosion damage due to the coupling effect of gas expansion and the overpressure reflected wave from the seal. When the seal is set in the gas expansion zone, the further the seal is from the explosion source, the greater the dynamic pressure damage and the more minor the overpressure and impulse damage. The closer to the explosion source, the more significant overpressure and impulse damage changes. When the seal is set outside the gas expansion zone, the further the seal is from the explosion source, the more minor the overpressure and impulse damage to the seal, and the dynamic pressure damage increases first and then decreases.

Apr 24, 2024