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By Fernanda de Melo Fernandes

A deposição de filmes finos por plasma melhora várias propriedades físicas, químicas e biológicas de superfícies que contribuem para o enobrecimento dos materiais. O objetivo desse trabalho é estudar a cinética de deposição de filmes finos de cobre, utilizando a técnica da gaiola catódica, alterando a espessura da tampa da gaiola, e sua relação com a variação da potência do tratamento. Filmes de cobre caracteriza-se como bom condutor elétrico e térmico, o que justifica seu uso em microeletrônica, segundo a U.S. Environmental Agency (EPA) existem 282 tipos de ligas de cobre bactericidas, habilitando sua utilização em ambientes estéril. Assim, realizou-se deposições de filmes finos de cobre sobre substrato de vidro, variando a corrente do processo e a espessura da tampa da gaiola. Avaliou-se a variação de peso da amostra depositada, definindo o peso resultante das deposições. Realizou-se também a caracterização por difração de raio-X, microscopia eletrônica de varredura e análise tribológica (calotest). Os resultados mostraram que, o tratamento com espessura de tampa de 12 mm promoveu o filme mais espesso e mais contínuo dentre todos os tratamentos, com uma grande quantidade de cobre depositado, o que induz que a razão ideal diâmetro de furo/espessura da tampa é 0,67.

Oct 30, 2017

By Marlos Henrique Alves Gomes

Aços resistentes ao desgaste são amplamente aplicados em partes estruturais que exigem propriedades como resistência mecânica, tenacidade e resistência ao desgaste abrasivo. O presente trabalho foi realizado devido à necessidade de desenvolvimento de materiais necessários para minimizar os efeitos causados pelo desgaste abrasivo. Os objetivos são: obter microestrutura multiconstituída (ferrita, bainita, martensita e austenita retida) por meio de tratamentos térmicos; e compará-la a microestrutura martensítica revenida. O aço estudado possui a seguinte composição química 0,26%C-1,13%Mn-0,92%Si-0,72%Cr- 0,29%Mo-0,18%Ni-0,17%Cu. Conduziu-se os tratamentos térmicos na sequência apresentada: recozimento subcrítico a 700°C, têmpera em óleo (temperatura de austenitização 940°C) e tratamento isotérmico de transformação bainítica (temperatura de austenitização de 820, 860, 900 e 940°C) ou recozimento subcrítico a 700°C seguido de têmpera/revenimento (940°C e resfriamento em água/250°C por 2 horas). Microscopia Eletrônica de Varredura (MEV) foi empregada para se avaliar a microestrutura do aço. Dureza Rockwell C foi utilizada com intuito de comparar a dureza das diversas microestruturas obtidas. Constatou-se que com a diminuição da temperatura de austenitização houve decréscimo do valor de dureza; e as amostras temperadas e revenidas demonstraram dureza média maior que as amostras que passaram por tratamento isotérmico de bainitização. A microestrutura multiconstituída foi obtida.

Aug 17, 2017

By Jônatas Targino Araujo

As fibras de bambu são ricas em celulose, hemicelulose e lignina. Devido ás suas ótimas propriedades mecânicas conforme solicitação percebeu a abundância de celulose e sua respectiva orientação nas regiões dos entrenós, indicando elevado teor de celulose. Nosso trabalho tem o objetivo de extrair nanocelulose dessa região do bambu, desenvolvendo uma metodologia eficiente na sua produção. As nanopartículas foram obtidas por hidrólise ácida a 64% após lavagem com NaOH e branqueamento com H2O2 e NaOH. As caracterizações das amostras foram feitas com TG, DTG, IFTR e tamanho de partícula por Potencial Zeta. Foram observados dois eventos na análise DTG: um em 54°C correspondente a perca de água e em 330 °C correspondente a degradação da celulose. Os tamanhos das partículas em Potencial Zeta obtiveram picos em 257,1 nm (79,6%) e 67,9 nm (15,6%).

Oct 30, 2017

By Kleiton dos Santos Melo

As fibras de bambu são ricas em celulose, hemicelulose e lignina. Elas apresentam altos módulos de elasticidade e alta resistência mecânica, o que as tornam bastante eficazes como reforço em compósitos. Com o intuito de aprimorar as propriedades mecânicas de materiais poliméricos em escalas diminutas, tem-se buscado a aplicação desses reforços em sua forma nano. A extração de nanocelulose tem sido bastante estudada e, em nosso trabalho, foram feitas adaptações de métodos que mostraram-se mais eficazes. Os nanowhiskers a base de bambu foram obtidos por hidrólise ácida a 64%, após tratamento químico prévio de limpeza e branqueamento. Os materiais obtidos foram então caracterizados por FTIR, TG, DTG e tamanho de partícula por Potencial Zeta, onde seus resultados indicaram que o método de produção utilizado foi eficaz.

Aug 17, 2017

By Cynara Christ Klippel

Devido às exigências de teores de fosforo cada vez menores no aço, o processo de desfosforação tem ganhado destaque nas indústrias. Para aproveitamento das melhores condições termodinâmicas a etapa mais eficiente para o processo de desfosforação ocorre no ferro-gusa. Esse trabalho utilizou quatro misturas iniciais de composição definida com base na literatura, juntamente com o ferro-gusa para ser simulado o processo de desfosforação. A simulação foi feita através do software de cálculos termodinâmicos FactSage e através dos resultados obtidos do programa foram feitos cálculos para avalição da eficiência do processo. Além disso, também foram feitos cálculos baseados na literatura para comparação de resultados e estudo mais aprofundado dos resultados. Os resultados obtidos comprovaram a teoria inicial de que menores temperaturas favorecem o processo.

Aug 17, 2017

By Altair Vieira de Souza

O tântalo é um dos metais mais versáteis na engenharia, podendo ser utilizado desde tecnologias espaciais até a biomedicina. Isso incentiva o estudo de novas tecnologias de obtenção do metal a partir do óxido de tântalo (Ta2O5). Neste trabalho é apresentada uma nova rota de obtenção de tântalo metálico a partir da reação magnesiotérmica do óxido de tântalo, usando como ignição o plasma de hidrogênio. Propõe-se um método alternativo ao processo Hunter, que apesar de ser o mais utilizado, é lento, pouco eficaz na produção de grandes quantidades e gera rejeitos degradantes ao meio ambiente. Foram misturados pós de magnésio (Mg) e Ta2O5 em recipiente projetado para permitir o efeito de catodo oco, e então aquecidos a plasma até a temperatura de ignição. Os experimentos foram realizados variando a pressão de trabalho buscando a redução completa do Ta2O5. Os produtos resultantes desses processos foram analisados por equipamentos de difração de raios X. Os resultados mostram que é possível a obtenção de tântalo metálico (Ta) a partir da redução metalotérmica do óxido de tântalo (Ta2O5) usando como agente redutor o magnésio e o plasma de hidrogênio como agente de ignição. A redução completa do Ta2O5 é obtida com o uso de pressões de 4,5 e 5,0 Torr.

Oct 30, 2017

By Vitor Falcão Artacho

As ligas de alta entropia são sistemas de ligas multicomponentes onde os elementos constituintes estão em proporções atômicas equivalentes ou quase equivalentes. As ligas de alta entropia são materiais avançados com propriedades únicas e promissores como materiais estruturais. Contrário as fases intermetálicas ordenadas esperadas pela metalurgia clássica, fase simples em solução sólida com estruturas CCC e CFC têm sido encontradas nos sistemas de ligas de alta entropia. O objetivo do presente trabalho foi preparar e caracterizar as ligas selecionadas FeCrNiCoAlCu e FeCrNiCo(AlCu)0,5. A preparação da liga foi realizada em forno a arco voltaico em atmosfera protegida. A caracterização microestrutural foi realizada através de microscopia ótica e microscopia eletrônica de varredura e por difração de raios-X. A caracterização mecânica foi realizada por medidas de dureza Vickers e por ensaio de compressão a frio. Os resultados mostram que ambas as ligas são constituídas por soluções solidas de estrutura dendrítica. A microdureza e o limite de escoamento compressivo da liga FeCrNiCo(AlCu)0,5 foi superior à liga FeCrNiCoAlCu.

Aug 8, 2018

By Jorge Costa Silva Filho

Neste trabalho é apresentado o estudo sobre a obtenção de nanofibras de poli(acrilonitrila-co-acetato de vinila) (PANVA). Com o desenvolvimento da nanociência e da nanotecnologia; novos métodos de processamento de PANVA podem ser utilizados para a obtenção de nanofibras e microfibras de PANVA. Neste trabalho, as nanofibras de PANVA foram obtidas por meio do uso da técnica de eletrofiação. Os resultados de microscopia eletrônica de varredura mostraram a obtenção de nanofibras de PANVA com diâmetro médio de ~100 nm. Estas amostras foram submetidas a um tratamento termooxidativo a diferentes temperaturas, 220, 240 e 260°C, sob atmosfera de oxigênio. Os resultados mostraram alterações nas características da manta obtida, indicando a possível ocorrência do processo de formação de estruturas cíclicas a partir da unidade de acrilonitrila presente na estrutura da PANVA.

Aug 16, 2017

By Robert F. Goss

OCAW appreciates the opportunity given to us by the sponsors of this Conference to present our position and policies on the issue of radiation hazards in mining. Our principal concern is the health impact that the mining of uranium has on our members. OCAW represents 1,500 underground uranium miners and more than 10,000 underground miners with 3,000 in the Rocky Mountain region. The U.S. Public Health Service has determined through mortality studies that the number one cause of death among uranium miners is lung cancer. It was also determined that exposure to radon daughters and mine dust correlates with the lung cancer experience of uranium miners. Data from the U.S. Mine Safety and Health Administration has also shown that not only uranium underground miners, but all underground miners, are exposed to radon daughters -- especially underground miners in the Rocky Mountain region. It is our position that any OCAW underground miner is at potential lung cancer risk. The dosages of radon daughters that our miners are exposed to are very many times the background levels of radon exposures in the communities where they live. We are also aware that cigarette smoking accelerates the onset of lung cancer; however, it has to be clear that the available scientific evidence shows that alpha radiation does initiate lung cancer and that cigarette smoke, as a recognized co-carcinogen, promotes cancer already initiated by radiation. It is true that cigarette smoke increases the risk of cancer significantly for miners exposed to radon, but nonsmoking miners have experienced lung cancer rates twice as high as the comparable members of the U.S. population. OCAW's position is that the occupational regulatory agencies should concentrate on the exposures that can be controlled; that is, occupational exposures rather than life-style exposures. Our Union has maintained a consistent posture in relation to carcinogens in the workplace -- that is, exposure to cancer-causing agents should be limited to the [lowest feasible level]. OCAW has interpreted lowest feasible level as the lower limit of detection of the collection and analytical method used to detect the carcinogen. Our posture is based on the available scientific information on carcinogenesis. We have asked the scientific community, many times, to provide us with safe levels of exposure to carcinogenic substances, including radon daughters. The answer has been: "We cannot determine levels of exposure low enough to assure that no cancer will occur." In short, there is not a "safe threshold" for any carcinogen. This statement does not come from one of the few so-called "pro-labor scientists," it comes from the National Cancer Institute and the National Institute for Occupational Safety and Health. I don't need to be a scientific sage, then, to conclude that the lowest level of exposure corresponds to the lowest risk of developing cancer. That is, then, our policy on exposure to carcinogens. It seems there has been an attempt to ignore the fact that lung cancer in uranium miners is the principal cause of death. Uranium miners are no exception from workers exposed to carcinogens. Our policy applies to them. Uranium miners should be exposed to the lowest feasible level of radon daughters and any decrease in the permissible exposure level is a decrease in their lung cancer risk. Accordingly, OCAW has petitioned the Department of Labor for a new permissible exposure limit to radon daughters in uranium mining, which lowers the current exposure standard from 4 Working Level Months (WLM) per year to 0.7 Working Level Months per year. We made our demand to the Department of Labor on April 20, 1980. We are still awaiting action from the Federal Government on our petition. OCAW is also very concerned with other important health impacts of uranium mining. We are concerned with a rate of disabling accidents and fatalities which is twice as high as the same rate in other underground mines, excluding coal. We are also concerned with the rate of respiratory disease fatalities among uranium miners which is almost four times the rate among a comparable U.S. population. We have expressed those concerns when the U.S. Senate proposed a Federal Compensation Act for uranium miners. That proposal, by Senator Dominici of New Mexico, found a quiet death in two Congressional sessions. In conclusion, our position on lung cancer induced by radon daughters is the same position we have taken with all other industrial carcinogens: The lower the exposure, the lower the risk. OCAW is demanding a drastic decrease of the permissible exposure limits. OCAW will never accept that a segment of our membership which mines uranium should take the lion's share of the risk while the uranium mining companies take all the benefits.

Jan 1, 1981

By Ta M. Li

Recent economic and environmental setbacks have not slowed Occidental Oil Shale, Inc.'s program aimed at the commercialization of oil shale. In fact, the firm expects to have a 795 MI (500C) bbl) per day production unit working by the end of 1976. The key to Occidental's ambitious program is an in situ method that extracts the valuable oil by retorting the shale in place. The process will require practically no water and will leave the spent shale in place underground. Additionally, all plant operations are to be located within the mine. These factors thus serve to make the operation attractive from an environmental viewpoint, in contrast to proposed conventional schemes which call for extensive underground mining, crushing and grinding at the surface, and construction of a massive surface retorting facility.

Jan 12, 1976

By Thomas E. Ricketts

Occidental Oil Shale Inc. has spent the last eight years at its Logan Wash. mine near DeBeque, Colorado, developing its modified in-situ oil shale process for obtaining oil from oil shale. Modified in-situ technology involves large underground chambers, or retorts, which are formed by mining out a minimal volume of rock to allow explosive expansion of the surrounding rock into tile mined void volumes. The resulting rubblized retort volume must contain a fairly uniform particle size distribution and void distribution to permit maximum oil recovery during subsequent in-situ processing operations. The more uniform the rubblized volume of particles, the more oil recovery obtained during processing. The processing involves first igniting the top of the retort and then. injecting air into the top of the retort to drive the combustion front downward through the entire rubblized volume. The oil is continuously collected at the bottom of the retort during the processing.

Jan 1, 1981

By Thomas E. Ricketts

Occidental Oil Shale, Inc. constructed two commercial-sized modified in situ (MIS) retorts, Retorts 7 and 8, at its Logan Wash Oil Shale Mine in February and April 1981, respectively. One of the primary objectives of this two-retort program was to examine large-scale blasting reproducibility for commercial-sized retorts. The blast design used 545 blastholes and 550,000 pounds of explosive in ANFO equivalent per retort. Each retort was blasted using millisecond delay blasting caps tied into a single round. The blasts resulted in rubble beds very close to one another and to predicted results obtained using newly developed limited void blasting technology. The heights of the remaining void rooms over the beds after blasting were within 0.3 feet of one another. This excellent reproducibility is brought into true perspective when compared to the scale of the rubble beds which were 230 feet high with volumes of over six million cubic feet each.

Jan 1, 1984

By George Moore

IN spite of many investigations of the occlusion of hydrogen in iron, the nature of the process and the reasons for the accompanying effects upon the metal are still open questions. This is in large part due to three causes: (1) the difficulty of obtaining iron of adequate purity as starting material; (2) the occurrence of allotropic transformations, which compli-cate the effects; and (3) the fact that the body-centered cubic modifica-tion does not lend itself readily to crystallographic investigation. The present paper attempts a critical review and correlation of the somewhat scattered and disconnected existing observations, and an experimental determination of the extent to which the conclusions that appear to follow from these are applicable to iron of really high purity, studied under well-defined conditions.

Jan 1, 1939

By Y Cao, J C. Tien

Occupational health and safety is essential in modern mining workplaces and in China it is often not given enough emphasis due to a lack of knowledge and/or appreciation. Although many health and safety regulations have been passed over the years, serious and relevant laws and regulations on mine health and safety are of recent history (since 2002), the level of stringent enforcement is still inconsistent and accurate field data are scant and not readily available. As of year-end 2006 there were 676 562 recorded cases of occupational diseases in China, of which 616 442 or 91 per cent were miners’ pneumoconiosis. Of these, 146 195 (23 per cent) have died, and an average of 10 000 new cases were added every year between 1991 and 2006. Another report shows that 93.18 per cent of miners have never had a contract with their companies, which means their cases were not even part of China’s official statistics. This study attempts to examine the prevalence of occupational diseases in the Chinese mining industry during 2000–2013, compiled from government annual reports and academic studies. The research will review the correlational analysis among occupational diseases, ventilation practices, protection devices and legislation.CITATION:Cao, Y and Tien, J C, 2015. Occupational diseases in China, with the emphasis on its occurrence in Chinese mine workers, in Proceedings The Australian Mine Ventilation Conference, pp 155–160 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 31, 2015

By Gerald T. Homce, James C. Cawley

Problem: CFOI and SOII data show that 2,287 U.S. workers died and 32,807 workers sustained days away from work due to electrical shock or electrical burn injuries between 1992 and 1998. Method: The narrative, work activity, job title, source of injury, location, and industry for each fatal electrical accident were examined. A primary causal factor was identified for each fatality. Results: Electrical fatalities were categorized into five major groups. Overall, 44% of electrical fatalities occurred in the construction industry. Contact with overhead power lines caused 41 % of all electrical fatalities. Discussion: Electrical shock caused 99% of fatal and 62% of nonfatal electrical accidents. Comprising about 7% of the U.S. workforce, construction workers sustain 44% of electrical fatalities. Power line contact by mobile equipment occurs in many industries and should be the subject of focused research. Other problem areas are identified and opportunities for research are proposed. Impact on Industry: Improvements in electrical safety in one industry often have application in other industries.

By E. A. Metz

Ergonomics is the art and science that tries to understand the complex interrelationships among employees, their work environment, equipment, work methods and job demands. Coal and metal/nonmetal miners are exposed to a higher number of ergonomic risk factors than in non-mining occupations. In addition, studies have shown that these miners experience more degenerative disc disease and osteoarthritis than comparable industrial populations. A general discussion of the risk factors that cause overexertion injuries and disorders will be presented. In addition, the basic principles of ergonomics will be discussed with specific cases to show how successful programs have been developed. A successful ergonomics program should simultaneously improve health and enhance productivity.

Jan 1, 2002

By M. L. Goble

"Inco Metals Ltd. (Manitoba Division) operates a mining, milling, smelting and refining complex, 500 miles north of Winnipeg in central Manitoba. The Thompson Mill is presently operating at 12,000 S.T.P.D. on ore from both underground and open pit mines. The ore is treated in two separate milling and flotation circuits utilizing a common crushing system which is located inside the main mill building. The milling facility employs approximately 43 operating employees, 30 maintenance employees and 20 staff in supervisory or process development roles.In recent years an increasing awareness of the potential hazards of contaminants in the work place has made it mandatory that all employers maintain careful and accurate records of the work environment to which each employee has been exposed during his working career.The importance of this record keeping and general observation of the work place cannot be over emphasized. Proper monitoring of the work place provides an accurate and complete record of the contaminants and physical agents to which an employee is exposed during his work career. This can aid in studies which might be conducted in the future and can also be used as a basis for instituting improvements to the workplace."

Jan 1, 1980

This chapter presents data on occupational exposures from several sources. Data from compliance samples obtained by MSHA inspectors are presented in table 6-1 for coal mine dust and silica dust, and in tables 6-2 through 6-6 for metal fumes. Since these samples were taken for compliance monitoring rather than as part of a survey of the industry, it is difficult to predict how well they indicate actual exposures for all mining operations. In the coal industry, 7.8% of all respirable dust samples during 1986-1995 were above the permissible exposure limit (PEL). Of silica dust samples obtained during the 10-year period, 23.7% were above the PEL in coal, 16% in metal, 10.8% in nonmetal, 9.1% in stone, and 7.6% in sand and gravel. Of metal fume samples, silver samples showed the largest percentage above the PEL-approximately 48% of samples in both metal and nonmetal. Tables 6-7 and 6-8 present data on noise exposures from the MSHA "dual threshold" survey, which was published in the Federal Register [61 Fed. Reg. 66347 (1996)] as part of a proposed rule change for occupational noise exposure in mining. This study examined a group of samples obtained during 1991-1995 and compared the percent of samples that were above two separate specified limits. The first limit was the current noise standard, a time-weighted average of 90 dBA, calculated to include only exposures at 90 dBA and above. The second limit was a time-weighted average of 85 dBA, calculated to include exposures at 80 dBA and above. Tables 6-8 and 6-9 refer to musculoskeletal overload conditions examined in the National Occupational Health Survey of Mining (NOHSM) [NIOSH 1996]. Table 6-8 shows the operational definitions for each condition; table 6-9 shows the percentage of the workforce potentially exposed, by commodity. Across all commodities, a large proportion of workers were exposed to musculoskeletal overloads due to positioning of the neck and back; positioning and motion of the forearms, arms, and shoulders; heavy lifting; and positioning and movement of the lower limbs. The recorded overloads were defined in the survey and did not exceed any NIOSH, MSHA, or OSHA guidelines for musculoskeletal overloads. Further information on this survey appears in appendix A.

Jan 5, 2000

By G. Baldermann, Hüttenrauch

Occupational health and safety are an important tool to increase a company’s economic efficiency. The integration of safety-related tasks into the overall structure of entrepreneurial tasks is an inalienable requirement for the sustainable achievement of positive effects. Investments into technical and personnel occupational safety that are tied in a streamlined organizational structure guarantee the improvement of defined indicators. The labor force is of central importance. Its added value ought to be ensured. It is necessary to move away from the employees‘ hazard awareness towards a safety awareness including many other aspects in order to save costs in the long run.

Jan 1, 2005

By D. Sohn

Work accidents have an essential impact on the economy of a country and in final consequence on each company. The main purpose of industrial OHS is to maintain and promote the health of all employees. Healthy working conditions increase efficiency and motivation and safeguard the success of the business against the background of the extremely dynamic processes of change. Maintaining and promoting the health of all employees, weather in operation, administration or on the mining site, has become therefore not only an ethical requirement but also an economic must. Creating a suitable working environment for people today entails much more than just preventing accidents and work-related illnesses. It is important to be proactive in establishing an even better culture of prevention and to convince everyone, workers and managers alike, of its importance. Especially in the age of rapid changes and above all in view of global competition we are more dependent than ever on healthy, enthusiastic, competent and creative employees. OHS provides you with the necessary competitive edge.

Jan 1, 2007