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By P. R. Khangaonkar, G. Bhaskar Raju

Three types of flotation columns were developed with a column dia of 8.0 cm and a length of 160 cm. The first type consists of an ordinary column fitted with a porous plate at the bottom. The second type consists of two electrodes at the bottom to obtain very fine and uniform bubbles generated electrolytically and the third is a combination of first and second types, i.e. to get both electrolytic bubbles and air from the compressor through porous plate. Three different ores were tested-gold tailings for recovery of scheelite, copper tailings (chalcopyrite) and oxide copper ore. In the case of scheelite and copper oxides, good results were obtained with the first type of column itself, whereas the third type column was found fairly effective in the recovery of chalcopyrite. The variables like the effect of reagent concentration, column height above the feed point, feed flow rate, current density, air flow rate, particle size etc. were examined.

Jan 1, 1988

By G. J. Grott

Direct Production Costs for Solar Sa 1t approximate the trucking cost for 160 Km. Operations near markets appear unusually attractive at first look. However, many desert operations have been plagued by dust storms yielding salt too high in insolubles for most uses. This paper relates the history of a successful operation in a dust storm area. Saturated brine from the solution mining of LPG storage caverns is evaporated in solar ponds yielding 99.95% sodium chloride (dry basis). Purchased energy is one-eighth that of vacuum pan operations. Production scale tests have proved it works at another desert location using a more complex brine. A new approach for refining soluble salts at ambient temperatures is demonstrated by bench scale and pilot work. Again, savings in purchased energy exceed 80%, even when temperatures are raised to reduce refining time.

Jan 1, 1988

By Robert T. McKnight

Introduction The minerals exploration business, like many businesses, is faced with the problem of valuing future, risky cashflows. These cashflows are derived from those mineral deposits which have been successfully commercialized. Many deposits, however, do not have the quantities or grade of ore to be considered economic at the projected metal prices using the traditional tools of the Capital Asset Pricing Model and discounted cashflow analyses. If one calculates the future revenues, costs and cashflows of one these marginal properties, and discounted it at the appropriate risk-adjusted discount rate, it may have a negative present value. Yet such a property may still have real, positive value in the marketplace. Why would a firm pay money for a property with an (apparent) minus present value? Mining properties such as these are bought and sold in arms- length transactions on a regular basis. Why is this so? Part of the reason relates to the nature of ore reserve information. To generate cashflows, the analyst must t assume that the reserve information is known with certainty when, in fact, reserves are not known with certainty. Mineral reserves are a function of commodity price, extraction costs and the level of (usually drilling) information about the reserves. Stated, or currently known, mineral inventories may vastly understate the true state of nature. Some firms may therefore be buying a property based on a completely

Jan 1, 1988

By K. R. McGinnis

A major cost to a mining company is funding of an exploration program. It is a necessary cost to insure the company's future. But if the exploration effort does not discover an economic are body, there is no return on investment and the days of the company are numbered. However, if you are aware of what exploration geologists are saying, it places the exploration process in a different light. Basically they are saying that ore bodies exist that contain 250,000 tons or less of gold and silver bearing ore that is cyanide amenable utilizing heap leach technology.

Jan 1, 1988

By Anthony D. Hammond, Charles A. Kliche

A slope stability study for the Annie Creek and Foley Ridge Mines was undertaken to provide Wharf Resources, Inc. with a technical assessment of the stability of the slope for an overall pit slope angle of 60°. A rock analysis of the most critical and persistent combination of discontinuities was carried out using probabilistic methods. A detailed discontinuity mapping and assessment of the rock mass provided the orientation data used in this study. The orientation data were reduced and analyzed to identify the discontinuity sets. A statistical analysis provided information about the distribution of the data. A deterministic wedge stability analysis identified the critical combination of discontinuities; those with a low factor of safety were further studied using probabilistic kinematic and kinetic stability analyses. The results from this approach were used to obtain the reliability or probability of failure of the slopes.

Jan 1, 1988

By F. Letowski

A column reactor was applied for leaching with simultaneous flotation a complex sulfide ore in ferric sulfate-solution under oxygen pressure. Elemental sulfur and the flotable, nonreacted sulfides were collected in the froth and separated from the insoluble, nonflotable gangue minerals and solid particles formed during pressure leaching. The two-stage laboratory unit, built from Corning-glass elements is described. Results of the continuous leaching/flotation experiments conducted under 20-40 psig of oxygen pressure are presented, as are supplementary batch leaching experiments with iron precipitation under 150 psig oxygen pressure. High zinc extraction to solution and near total accumulation of lead sulfate in the nonflotable fraction are easily attainable. Relatively poor flotation of pyrite is probably caused by the partial oxidation of its sulfidic sulfur to sulfate.

Jan 1, 1988

By Richard C. Harris

Substantial economic benefits exist today for fine coal preparation and improved technologies coupled with more stringent air quality standards should increase those benefits in the future. The costs of cleaning can be determined with reasonable certainty with proper consideration given to mining methods, plant feed characteristics, refuse disposal and marketing impact. The benefits cannot be as accurately determined but include impact on generating capacity, plant maintenance, emission standards, slagging, fouling, transportation, and handling. Site specific cleaning offers particular benefits in some situations to tailor the preparation plant facility to boiler characteristics. Improved communications and methodologies need to develop to allow the coal producer and the coal user to clean coal to the degree that results in the lowest overall cost for electrical generation.

Jan 1, 1988

By Owen E. Owens

INTRODUCTION This paper deals with the main components in exploring for and developing a gold ore deposit. It addresses geology, exploration drilling, ore reserves, and evaluation criteria in an integrated manner to present an overall picture. Gold forms such a small component of a gold ore body, that particular care should be taken in dealing with the data from a developing deposit. The paper lists the main gold ore deposit types and their character. Their differences, as well as differences to other types of ore deposits, are important to understanding exploration approaches, and problems of ore reserve definition. Gold exploration has enjoyed a great boom in recent years. Many new ore deposits have been developed but experience shows that definition of gold is not a simple straight forward process and this outline attempts to point out some of the important aspects of ore reserve definition including some pitfalls. GOLD DEPOSIT TYPES The Witwatersrand deposits in South Africa produce about 50% of the world's gold. The gold occurs as fine grains in thin beds within gently dipping quartz pebble fan conglomerates usually with associated pyrite grains. It is characterized by rather uniform distribution of gold along thin layers within the conglomerate.

Jan 1, 1988

By M. R. Paterson, M. K. Suddaby

Operational and economic factors tend to favor the application of continuous processes in preference to batch processes in the majority of mineral processing applications. In this paper, the requirement for a continuous elution process is established and the development of a large-scale pilot plant is described. It is based on a continuous elution apparatus that has a number of special features. These are the subject of various patent applications. The apparatus is suitable for adaptation to the AARL, Zadra, and other methods of elution. The performance of the atmospheric continuous elution system (ACE) is concluded to have significant advantages over the batch process.

Jan 1, 1988

By E. S. Bianchin

The more complex control needs of today's mineral processing plants combined with ever-changing digital technology have brought numerous improvements to process control systems. This paper discusses recent advancements in distributed control systems (DCS) which facilitate the implementation of process plant automation. Some of the topics of discussion include integrated function controllers, weigh scale and analyzer interfacing, operator interfacing, personal computers, process information management and process plant management.

Jan 1, 1988

By J. D. Miller

Certain bituminous coals of recent geological age are known to contain a significant quantity of natural (fossil or subfossil) resin. Such resinous coals are found in the western U.S., particularly the Wasatch Plateau coal field in Utah. Some of the seams in this field contain approximately 5% resin which has been recovered by gravity and/or flotation processes since 1929. Resin concentrates thus produced are of low quality and are usually refined by solvent extraction and precipitation. The purified resins are of commercial importance, being used in the adhesive, varnish, enamel and ink industries, etc: Recently, an improved flotation technique has been developed which involves ozone conditioning to selectively float resin from such coals. In this flotation process, a concentrate product which contains 95% resin at a recovery of 80% can be obtained in a single stage from coal containing approximately 10% resin, whereas conventional flotation at a similar level of recovery produces a concentrate having a resin content of 30-40%. Economic analysis shows that the ozone flotation process has good potential for use by industry.

Jan 1, 1988

By E. Topuz

Productivity is the most important determinant in the economics of underground coal mining operations. Lower labor productivity increases labor requirements per ton. This, in turn, increases the unit cost of production. Intensive labor requirements may also affect miner injuries and fatalities by increasing man-hours of exposure necessary to produce a given amount of coal.

Jan 1, 1988

By Graeme J. Jameson

A form of column flotation cell is described in which the contact between the feed and the air stream is made in a mixing device at the top of a vertical downcomer. The air-liquid mixture flows downward to discharge into a shallow pool of pulp in the bottom of a short cylindrical column. The bubbles disengage and rise to the top of the column to overflow into a concentrate launder, while the tails are discharged from the bottom of the vessel. The main advantages of the device described are that the overall height of the column is reduced to about one metre (3 ft), and the column can be self-inducing with respect to the air supply. Experimental results are given from tests on a feed stream to a conventional zinc cleaner circuit. Using wash-water to reduce gangue entrainment, the column gave high concentrate grades and high recoveries.

Jan 1, 1988

By P. F. Hara, O&apos

Stratabound Proterozoic precious metal mineralization in central Arizona is associated with felsic and adnesitic to mafic volcanic rocks and sediments derived from these rocks. Hydrothermal fluids associated with felsic volcanism form gold mineralization within hotspring vent complexes or within asymetric basins, which flank the vent complexes and are filled with tuffaceous sediments. Massive to semi-massive sulfide copper-zinc systems associated with felsic volcanism may locally contain small gold occurances either laterally or vertically zoned from the ore. In andesitio to mafic rocks, zinc-lead-gold-silver-copper bearing mineralization and gold mineralization are both associated with feruginous sulfide bearing cherts. The partitioning of gold into these specific geologic environments may be related to variations in temperature and composition of the hydrothermal fluid and the depth of the seawater-sediment interface below sea level during the mineralization event.

Jan 1, 1988

By Adrian Smith, Debra W. Struhsacker

13.1 INTRODUCTION Cyanide is, a generic term indicating the presence of the cyanide ion (CN-). Cyanide is a very common, naturally occurring compound produced by many biochemical reactions. Many plant species synthesize organic compounds which contain cyanide in the form of cyanogenic glycosides (Knowles, 1976). For example, trace amounts of cyanide are present in the seeds and leaves of many members of the Rosaceae (rose) family (Kingsbury, 1964). Many common items such as lettuce, maize, sweet potatoes, kidney beans, (Oke, 1969) almonds, and cigarette smoke contain cyanide. As examples, a recent chemical analysis of chocolate-covered almonds measured a total cyanide content of about two ppm (Steffen Robertson and Kirsten, 1987); and the U.S. Surgeon General (U.S. Department of Health, 1964) has shown that cigarette smoke contains up to 1,600 ppm total cyanide. The chemistry of cyanide solutions is complicated because the cyanide ion forms compounds and complexes with many elements. Some cyanide species are highly toxic whereas others are relatively inert and harmless. Molecular hydrogen cyanide (HCN) is the most toxic form of cyanide. Under most conditions, HCN exists as a gas which readily dissipates or reacts with the environment to form less toxic or nontoxic forms of cyanide. Thus HCN is an ephemeral toxin, and many naturally occurring geochemical processes reduce the HCN concentration of a heap system with time. As discussed below, free cyanide includes the two species, ionic cyanide (CN-) and molecular hydrogen cyanide. Free-cyanide toxicity in man, mammal s, and aquatic species is we1 1 documented (Doudoroff, 1976; Ecological Analysts, 1979; Towill et al., 1978). The lethal doses reported for human adults vary with the type of exposure as follows: • One to three mg/kg body weight if ingested; • One hundred to 300 ppm if inhaled; and • One hundred mg/kg of body weight if absorbed. Acute toxicity of free cyanide to freshwater invertebrates ranges from 0.028 to 2.295 mg/l, depending on species and test conditions. Generally, free-cyanide concentrations greater than 0.1 mg/l are expected to kill sensitive species in freshwater or marine environments (Doudoroff, 1976;

Jan 1, 1988

By Adrian Smith

14.1 INTRODUCTION From the time the last recoverable gold is extracted from ore on a heap leach, the ore - now spent ore - changes from being the resource, indeed the raison d'etre of the operator, to a potential liability. The spent ore contains process chemicals and constituents leached from the ore both in the interstitial pore water in the heap and on the surfaces of spent ore. If these chemical species were released to the environment, it could have a potential impact on the quality of both surface water and groundwater resources. Accordingly, the spent ore must be left in a condition where it does not present a potential environmental liability. This can be accomplished either on a decommissioned pad or, if the heap leach is operated as a load/unload scheme, in a waste facility. In general, the residual cyanide level in the spent ore is the perceived controlling factor when determining whether the leached material is suitable for abandonment. Regulatory authorities set permit conditions for heap leach abandonment in terms of residual cyanide levels, for example, Smith and Struhsacker (1987). This chapter discusses cyanide degradation and methods for detoxifying a heap leach in order to meet regulatory limits/permit conditions for abandonment. Cyanide degradation and detoxification by "natural" processes are described initially, based on the chemistry and geochemistry discussed in Chapter 13. This leads to a review of chemical treatment processes for detoxification of spent ore. The advantages and apparent disadvantages are then appraised. 14.2 NATURAL DEGRADATION AND DETOXIFICATION For the purposes of discussion, "natural" detoxification processes can be divided into two alternatives: • Passive abandonment (the so-called "do nothing" option); and • Water In the first alternative, the spent ore is merely left on the leach pad to age; the second alternative involves the flushing of the spent ore with water.

Jan 1, 1988

By M. R. Rosen

CARBINDER Polymer 498 is a liquid organic taconite binder which significantly improves fired compression in both fluxed and acid pellets. It has been used commercially in both shaft and straight grate furnaces. This new binder produces an unusual wicking phenomenon during balling wherein the rate of movement of interstitial water is accelerated to the surface of the balls. The phenomenon is proposed to be responsible for the significant improvement seen in fired compression. This paper presents information as to the effect of CARBINDER Polymer 498 on green ball and fired pellet properties. It also describes the wicking phenomenon and discusses a reversal in the normal balling operation procedures required for successful agglomeration.

Jan 1, 1988

By D. L. McClure

Gold mineralization at the Colosseum Mine is submicroscopic and associated with pyrite. Pyrite occurs in breccia clasts, replacing dolomite, in crackle breccia veinlets with traces of quartz, and as disseminations in two small, interconnected intrusive pipe complexes of rhyolitic felsite and breccias of felsite and wall/country rock. Breccia types grade from felsite plus wall rock of Pre-cambrian gneiss to cross-cutting breccias "of felsite, gneiss, and Paleozoic sedimentary rocks that are in contact with the Precambrian gneiss terrane one-quarter mile (40Om) southwest of the Colosseum pipes. Mineable reserves are estimated to be 8 million short tons (7.3 million metric tons) at 0.074 troy ounces of gold per short ton (2.3 g/metric ton) at a cutoff of 0.03 troy ounces of gold per short ton (1.0 g/metric ton).

Jan 1, 1988

By A. M. Johnson

Although known primarily for native copper, the Keweenaw Peninsula of northern Michigan also has deposits of copper sulfide (chalcocite) ore. A number of small, but rich, deposits are present at relatively shallow depths near the base of a thick, steeply dipping sequence of volcanic and sedimentary rocks. Because much of the ore is fracture-controlled, the deposits appear to be ideal candidates for in-situ leaching. Fracture mapping from drill core and borehole logs coupled with borehole packer permeability tests are being applied to evaluate the suitability of the ore for in-situ leaching. A leaching scheme utilizing a bacterial-assisted ferric iron lixiviant is being tested at bench scale. A pilot scale test is being designed to evaluate the system in the field.

Jan 1, 1988

By K. O. Johnson

Contaminant transport of mine and mill tailings is controlled by the hydrologic flow regime and the geochemical mobility of the contaminants. Contaminant' mobility is primarily determined by chemical reactions occurring within an interface zone between the tailings and soil The large geochemical differences between tailings and groundwater create a disequilibrium in the groundwater with respect to the soils when seepage from tailings enters the groundwater. Precipitation and dissolution reactions involving the major chemistry occur to return the perturbed system to chemical equilibrium between groundwater and minerals. Retardation of trace elements depends upon the chemical character of the groundwater and the adsorption substrates. In the case of uranium mill tailings, the mobility of contaminants is controlled primarily by precipitation/dissolution reactions which neutralize the pH, modify the Eh (redox potential), and produce highly adsorptive substrate for retardation of trace elements.

Jan 1, 1988