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By J. J. Kellar

The near-infrared (NIR) (12,000-4,000 cm-1) region of the electromagnetic spectrum, between the mid-infrared and visible, has often been viewed by spectroscopists to be of limited utility. This is unfortunate, and recently the use of the NIR has increased greatly, primarily for the quantitative analysis of food and agricultural products. However, many other areas of application of NIR spectroscopy remain unexamined. In this paper a novel use of NIR in the area of flotation chemistry is demonstrated. Specifically, it is shown that NIR/Internal Reflection Spectroscopy (IRS) can be used to quantify collector adsorption reactions in-situ.

Jan 1, 1990

By F. Alsobrook

Industrial minerals are receiving increased attention by metals, coal and other companies seeking to diversify and stabilize earnings. Each industrial mineral has a unique set (and sub-sets) of business dynamics, however, and the diversity can present a bewildering maze to the corporate planner. Shrugging off this complexity and relying on serendipity for entry opportunities often results in unsuitable acquisitions. An effective alternative used in exploration can also be applied to strategic planning. By providing focus and direction, this flexible methodology can prevent wasting corporate resources on random pursuits and result in a quicker, more satisfactory achievement of diversification goals.

Jan 1, 1990

By J. B. Pautler, A. E. Gross, M. G. Strominger

The U.S. Bureau of Mines research on the use of cement as an agglomeration aid allowed precious metals heap leaching to become an economically viable method of precious metal recovery during the 1980's. However, many agglomerated ore bodies still exhibited poor heap/agglomerate strength. Precious metal recovery was often too slow or required prohibitively high levels of cement to be economically sound. Problems with heap ponding, blinding, and solution channeling and "wash-out" indicated that there was a need within the industry to improve on existing agglomeration technology. An in-depth research effort was undertaken to satisfy this need. Three years of research led to a patent on the use of vinyl addition polymers as effective agglomeration aids. A close working relationship between Brewer Gold and Nalco Chemical Company aided in the development of this program. This paper details the pilot test work, the full-scale evaluation at Brewer Gold Company, and conclusions.

Jan 1, 1990

By R. Hogg, A. C. Maffei, D. T. Ray

Based on standard population balance models for agglomeration and size reduction processes, a simplified model has been developed to describe simultaneous growth and breakage in the flocculation of agitated suspensions. The results of semi-batch flocculation tests have been used for estimation of the model parameters and empirical relationships have been obtained to describe the effects of process variables and to establish scale-up criteria. Application of the model to the design, operation and control of continuous flocculation processes is discussed.

Jan 1, 1990

By O. A. Bascur

An expert process operation advisor system can increase plant efficiency, even in a complex, natural environment where not all elements of the production process can be measured directly. This system, develaped and tested in a Frasch process sulphur mine, monitors key process variables with extended qualitative pattern processing and provides on-line advise to the operators of sulphur production wells. An expert system framework captured common sense rules generated from years of experience obtained in the operation of a sulphur well monitoring system. The existent operating procedures were enhanced by process analysis using a qualitative modeling approach which provided extended rules for on-line classification of a well operational status and an expert alarm system. The methodology for development and implementation of the process advisor is presented in this report. Qualitative process modeling, statistical process control and heuristics were incorpomted into the process advisor resulting in a more efficient use of heat, an extended well operational life and the resulting cost savings. The computer process advisor also allowed the operator to concentrate his attention on the weak wells or wells in trouble. A process management system improved plant operation by automatically storing well data into a commercial database for operator validation. The enhanced relational data base system provided valuable and timely information for planning and decision making. The synergistic combination of on-line process analysis tools, expert control systems and database technology is shown to facilitate the flow of materials, energy and infomation in a modern plant.

Jan 1, 1990

By S. S. Cook, S. E. Paulson

The US Bureau of Mines is conducting core leaching experiments with sulfuric acid on oxide copper ores from the Cyprus Casa Grande and Asarco/Freeport Santa Cruz deposit in Arizona to further the understanding of the leaching process in supergene copper ores as it relates to in situ mining. Leach solutions from atacamite mineralization contained 5 to 30 g/L (0.05 to 0.28 oz/gal) copper and few extraneous ions. Leachant from chrysocolla ores, with grades similar to the atacamite, contained 2 to 9 g/L (0.02 to 0.08 oz/ gal) copper and abundant extraneous ions. Quartz and K-feldspar had no impact on leach solution composition at any acid concentration up to 40 g/L - (0.39 oz/gal) while illite and sericite had minimal impact. Biotite, calcium-rich clay, and limonite have a significant impact on solution chemistry when there is abundant free acid in solution. High acid concentra¬tions increase acid consumption in ores with abundant biotite and limonite gangue. High acid concentrations can be used in ores with quartz, K feldspar, and sericite gangues without increasing acid consumption per unit of copper removed.

Jan 1, 1990

By T. V. Vasudevan

Floc properties such as density, size, size distribution, porosity, and shear strength govern the effectiveness of flocculation as a process for solid-liquid separation. The floc characteristics desired for removal of suspended solids by sedimentation or filtration, for example, are known to he different. In this study, an attempt has been made to evaluate the effects of various physical and chemical factors on the density and shear strength of the flocs.

Jan 1, 1990

By A. J. Getz

Major precious metals projects are underway in Australia, Papua New Guinea, Indonesia, the Philippines and New Zealand. This article reviews the status of those projects. Included in this review are project location, reserves, method of resource exploitation, anticipated production, and other unique conditions. The article is limited to major precious metals projects in the Western Pacific region. This is not meant to negate the attractiveness or importance of the many other projects in that area. The geographical setting of these five countries are shown in [Fig. 1]. The gold output of the countries has increased dramatically during the 1980s. [Table 1] compares 1980 and 1988 production figures. The compound growth rate is 120%. That reflects the attractiveness of the region’s resource base as well as the impact of price increases, new exploration models and processing technologies, and changes in government policies. If the 10 projects discussed here are all brought onstream, their combined output - at about 130 t (4.17 million oz) - would amount to an increase of greater than 50% over 1988 production from this region. Table 2 shows indicative production levels for each of the 10 projects. Dollar amounts are in US currency unless otherwise specified. Australian dollars have been converted to US dollars at the rate of 1.28: 1.00.

Jan 1, 1990

By R. R. Klimpel

The grinding of coal-water slurries has received increasing industrial attention during the last decade. In particular, there is long-term interest in the use of pulverized coal-water slurries to replace oil in combustion equipment and the development of coal gasification/liquefaction processes which require coal-water slurries as feed. More specifically, the use of coal-water slurries in gasification requires grinding a high density slurry containing the smallest amount of water consistent with slurry pumping and spraying. As part of a fundamental engineering research support program aimed at the industrial implementation of dense coal-water slurry grinding, this author has published several papers on how specific rates of breakage vary as a function of slurry rheology, Klimpel (1982, 1982/83). These papers demonstrated that there is a consistent pattern of change in specific rates of breakage of coal in dense slurries with controlled variations in slurry rheology. By matching rheological data with laboratory grinding results, it was possible to identify directly slurry conditions that correspond to: (1) slowing down of breakage rates, (2) the occasional acceleration of breakage of some sizes, and (3) conditions where chemical additives will increase rates of breakage.

Jan 1, 1990

By R. L. Grayson

Productivity achievements in underground coal mining over the past ten years highlight the improvement of management practices as well as the adoption of new technology. Research findings and results from operational studies characterize the aspects of good management that translate into high productivity. In concert with these findings, the Mine Management Support System (MMSS) is being developed, under co-sponsorship of the U.S. Bureau of Mines and the West Virginia University Energy and Water Research Center, as a knowledge-based system to enhance more efficient management of underground coal mines. Concentrating on capturing the intricate knowledge needed to manage a mine effectively, MMSS will encompass information and rules on work scheduling, desired work practices, regulations impinging on operations and planning, responses to operating problems, and the labor-management work agreement.

Jan 1, 1990

By Carl E. Nelson

Shallow epithermal stockworks hosted by maar eruption craters contain over ninety percent of the bulk mineable gold identified to date in the Circum-Caribbean region. Pueblo Viejo (Dominican Republic) and Santa Rosa (Panama) contain combined gold reserves of over 600 tonnes. Bulk mineable gold deposits are also being discovered in and around veins that were formerly mined underground. Bellavista, El Recio and San Martin (Costa Rica) contain combined announced gold reserves of over 50 tonnes. Representative rock suites collected at 8 bulk mineable gold deposits include 291 samples of veins and vein stockworks, hydrothermal eruption breccias, sinter, variably altered host, unaltered host, nearby intrusive rocks and basement. Analyses completed to date show that Circum-Caribbean epithermal ores are enriched in arsenic, mercury and antimony as well as gold and silver. Exploration efforts in the region naturally focus on districts with past production. However, an order of magnitude more bulk mineable gold has been discovered in shallow epithermal stockworks outside of the old bonanza vein camps. Exploration guides include basal island arc volcanic sequences, hydrothermal and hydrovolcanic (maar) eruption breccias, thinly-bedded carbonaceous maar sediments, and hot spring-related silicification and argillic alteration.

Jan 1, 1990

By Lynton Gormely

Oxygen transfer in a stirred tank bioreactor has been modelled mathematically to determine the trends in transfer efficiency (kg transferred per kWh) with transfer rate, tank depth, superficial velocity, and mixer power.

Jan 1, 1990

By L. G. Austin

The use of crushed power station slags, both natural and coated, as granules for roof shingles shows some promise. Test shingles weathered for some years showed rust spotting and granule deterioration as serious problems. Chemical analysis on a particle-by-particle basis using a scanning electron microscope-energy dispersive spectroscopy system showed the wide variability of chemical composition of the granules within a given sample. Analysis of particles acting as sources of spotting within the weathered samples showed high iron contents but no rules could he developed for predicting the long-term stability of different compositions.

Jan 1, 1990

By Prisbrey K., N. Choi, A. Burbank

Large tonnages of low grade refractory gold ores are not presently being treated because they resist direct cyanide heap leaching and because they are too low in grade for more expensive oxidizing pre-treatments. If they could be oxidized while remaining in heaps, they could be economically leached with cyanide. The solution is to use bacteria to partially oxidize the encapsulating pyrite mineral which allows cyanide dissolution of the gold in a separate treatment. A variety of refractory ores from different locations was crushed to minus three quarters inch, loaded into columns, and inoculated with T. ferrooxidans. The bacteria attacked the pyrite causing biooxidation, and gold recovery increased 30 to 120 percent after three months curing.

Jan 1, 1990

By D. Butler

Subsurface density changes can be detected by very precise surface gravity measurements. A feasibility study, combined with field experience using modern instruments, will indicate the probability of success. In addition to projected anomaly parameters, surface conditions that effect the survey precision must be evaluated. Examples with excavated zones at 9 m (30 ft) of depth and [+] 22 microgal error are compared to the same model at 30 m (98 ft) of depth. The figures illustrate anomaly detectability. The survey error is a function of surface topography and lateral density variation in the very near surface.

Jan 1, 1990

By Alain Broussaud, Guy Fourniguet, Jacques Franck, Pierre Conil

Steady-state simulation is now in current use to assist mineral processing plant design and optimization. However, the reliability of results generated by simulators has not until now been seriously investigated. A simulator supervision algorithm was designed and programmed to study both the influence of the reliability of experimental data on the accuracy of unit operation model calibration, and the influence of unit operation model accuracy on the results of direct plant simulations. An application to a grinding flotation plant is described and discussed. The approach may open the way to the quantitative analysis of the risks taken in mineral processing projects, which would be similar to the application of geostatistics to mining projects.

Jan 1, 1990

By Robert D. Brown, Charles A. Sorrell

The decade of the 1980's saw "advanced materials" become a key factor among the industrialized nations, with the United States, Japan, and the European Economic Community being the major competitors. All three have identified communications technology, advanced materials, and biotechnology as the keys to future industrial leadership and the closing decade of the 20th Century is expected to be an era of rapid development and restructuring. The progress of EC'92, the effort to develop uniform standards and remove trade barriers in Europe; the determination of Japan to commercialize advanced structural ceramics, alloys, composites, and superconductors; and the emergence of less developed countries as major supplies of commodity materials pose enormous challenges to the position of the United States as an industrial and financial leader. A consensus is developing that the industries that are first to commercialize the large array of new structural materials and electronic, optical, and magnetic materials and devices will be those who determine the structure of national and world economics. Many technical, economic, legal, political, social, and cultural factors are important determinants in the race to commercialize new materials. Millions of words have been written about these factors and their interdependence; yet the sheer complexity of the problems, the rate at which changes are taking place, and the economic risks involved are so great that government policy makers and industrial decision makers find adequate understanding to be very difficult. Of the many factors involved in advanced materials, the Bureau of Mines has the statutory responsibility to provide information on where materials can be found and how they are mined, extracted, purified, combined, and recycled. It is obvious that minerals availability is essential to implementation of any new technology just as there can be no commodity metals industry if the ores are not available. Because "minerals availability" for commercialization of advanced materials and devices is more complex than for commodity materials and a new mix of materials and processes is emerging, the Information and Analysis Directorate of the Bureau of Mines is redirecting resources to provide reliable information for policy and decision making. The Office of Advanced Materials Coordination (OAMC) was established as a staff operation in July 1987 to assist the efforts of the divisions and branches. The key issues and problems were defined and the role of the Bureau was outlined (Sorrell, 1987, 1988). In February 1990, the functions of OAMC were transferred to the new Branch of Advanced Materials, a line organization parallel with the Branches of Ferrous, Nonferrous, and Industrial Minerals, and was given the responsibility for developing new methods to acquire, analyze, and disseminate information about new materials. The purpose of this paper is to provide definitions, a summary of major issues and problems, an overview of minerals and processing availability problems, and a perspective of the ways in which the mining and materials industries can help to ensure domestic availability of raw and processed materials.

Jan 1, 1990

By Y. Numata

2-Mercaptobenzothiazole (MBT) is a heterocyclic-mercaptan and belongs to a group of molecules containing nitrogen and sulfur as electron donor atoms. MBT has been employed as a collector in flotation under names of MBT, Captax, and Flotagen. It is a major constituent of reagents in the 400 series of the American Cyanamid Co. Current applications of the reagent include flotation of copper minerals, tarnished or oxidized lead, copper activated sphalerite, and nickel ores. It has been used successfully in the flotation of pyrite in acid circuits in the range of 4 to 5.

Jan 1, 1990

By G. L. Mowrey

One of the critical parameters of any automated coal mining system is the ability to only cut coal and not the rock / waste surrounding it. To do this the system must be able to detect where the coal-rock/ waste interface is. The U.S. Bureau of Mines is investigating a new approach to vibrational coal interface detection (CID) by utilizing an adaptive signal discrimination (ASD) system to perform feature extraction and classification of complex vibrational signals. Accelerometers, geophones, and piezoelectric films are mounted on mining machines and/or strata and are used to monitor vibrations produced during mining operations. Selected data are digitized and the ASD system is trained on known types of vibrations (e.g., "cutting coal" and "starting to cut roof"). A signal classifier is then generated which can be used to identify unknown waveforms. The ASD system can be retrained if mining conditions change significantly.

Jan 1, 1990

By S. R. Bryan, J. D. Stephens, D. R. Rothbard

The distributions of gold and associated elements in mineral grains from a pyritic gold ore were studied by optical microscopy, and by SEM and SIMS imagery. Products studied were a sulfide flotation concentrate, a calcined sulfide concentrate, a cyanide leached calcine, and a cyanide leached pressure oxidation residue. Individual pyrite grains are compositionally zoned and solid solution gold occurs in some, but not all zones. Most of the gold in calcined products is present as metallic coalesced grains that are smaller than 100 angstroms. Gold lost into cyanide leached residues from the calcines tends to be in “semi-dense” grains that cannot be distinguished from gold-free grains except by SIMS analysis. The gold in cyanide leached pressure oxidation residues occurs as solid solution gold in unoxidized pyrite remnants.

Jan 1, 1990