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By Somia Gurunathan, Harry Castrantas

Hydrogen peroxide and calcium peroxide are used to improve the extraction of gold/silver and reduce cyanide consumption in heap leaching and mill leaching operations. FMC's standard grade H2O2 and FMC's Permeox™ solid peroxygen, a formulated product containing cao2, was used for the experimental work. It was found that the rates of release and the longevity of these peroxygens in ore-cyanide mixtures are significantly different. When choosing a peroxygen, one of the key factors is extrac­tion time, with the longer extraction times of heap leaching primarily favoring calcium peroxide and the shorter extraction times of mill leaching primarily favoring hydrogen peroxide. A series of laboratory leach tests showed the choice between H2O2 and CaO2 to be ore and process specific. H2O2 and/or Permeox™ improved the gold extraction in four out of five ores tested. (2 sulfide and 2 oxide). Mixtures of H2o2 and Permeox™ were also found to significantly increase the gold extraction rate. A fifth ore (sulfide) did not respond to peroxygen treatment. In addition, savings in NaCN consumption was obtained with Permeox™. Both peroxygens offer economic incentives to gold processing.

Jan 1, 1992

By Dan Walker

The success of the heap leaching process for extracting precious metals from low grade ores in many cases depends on successful agglomeration of clay fines. This paper relates the development of a new agglomera­tion agent, named Leachit, that has demon­strated an ability in some ores to decrease leaching time. Data from a commercial test­ing laboratory is presented to illustrate a comparison of leaching efficiencies with other agglomerative agents, such as lime and portland cement. Conclusions will point out certain advantages of Leachit to the heap leaching gold recovery industry.

Jan 1, 1992

By Sepp A. Kutschera

are gaining increased interest for over­burden removal and ore production at large open cast mines. The application of bucket wheel excavators is still tied to soft un­consolidated rocks and soils, while belt conveyors can cope with all kind of matri­als restricted only by the top grain _ size. Therefore, mode of transport and the re­quirement of down stream ore processing de­fine the materials size distribution. These requirements are usually met by primary crushing or scalping. The paper discusses general applica­ tion criteria of bucket wheel excavator with systems primary for in-pit overburden crusher removal. and It _indeapits scalper units and discusses their technical and operational features. It further com­pares the capital and operating cost struc­ture relative to the syste

Jan 1, 1992

By Donald R. East

In the planning and design of mill tailing disposal facilities, the chemical and physical nature of the fine­grained material to be disposed of has to be fully understood in order to create an efficient and safe long­term storage facility. Disposal of tailing has become the single most important source of environmental impact for mining projects and the development of many promising ore bodies has been delayed or even stopped due to problems of facility siting and design under pressure of increasingly stringent regulatory require­ments.

Jan 1, 1992

By Sean E. Armstrong, Deepak Malhotra

The current trend in gold ore processing is the development of lower grade or highly refractory deposits. The perplexity of treating low grade oxidized ores has been adequately addressed by heap leach technology. However, refractory gold ores are very difficult to positively characterize the gold association within the mineral matrix. Gold accompanied with refractory sulfitlc or carbonaceous mineralization can often be sub­micron In size and occur interstitially. Mineralogical examination of these ores Is difficult, expensive, and occasionally Inconclusive. Hence, the metallurgist Is given little information for the selection of processing alternatives. The purpose of this paper Is to demonstrate the use of diagnostic leach procedures to assist the metallurgist' s decision-making process to solve some of these problems. By sequentially liberating and/or leaching gold associated with specific minerals, the amount of recoverable gold in each stage can be determined. Through careful interpretation of the results obtained by diagnostic leaching, the metallurgist can devise a flowsheet for treating the ore or solve a problem at an existing plant

Jan 1, 1992

By Jack F. McOuat

This paper describes how Canada's mineral exploration and development industries are on the decline as is its mineral reserve base. Not surprisingly, these are being offset by extensive and growing participation by Canadian companies and personnel in many other countries. The paper illustrates the extent and origins of this foreign activity as well as the present and future impact on Canadian mining and mining professionals.

Jan 1, 1992

By Kambhampati C. Rao, Cecil Lue-Hing, Nabih P. Kelada, William B. Willborn

improvements in the analytical techniques for cyanide speciation can furnish useful information about the behavior of the different cyanide species in the receiving environment. This could be of help to the environmentally concerned public and the regulatory agencies in the assessment of cyanide limits for effluents, stream quality, and land disposal of cyanide bearing wastes. In addition the ability to distinguish the free cyanide and the weakly bound cyanide from the strong ULTRAVIOLET IRRADIATION UNIT (LAMP, COIU3' HOUSING) FIGURE 1 complexes, as well as transformation to thiocyanate is also needed by different industries, such as mining and metal finishing, etc., to evaluate the efficiency of several processes. Cyanide has been used for the recovery of gold since the late 19th century. Although cyanide leach solutions are mostly recovered and used again, a large quantity of cyanide bearing wastewater becomes unfit for use and has to be treated before it can be released into natural waterways.

Jan 1, 1992

By Terry M. Hertel

Zortman Mining has spent approximately three years evaluating the metallurgy of the sulfide ores from the mining area of the possible expansion project. As the test program proceeded, an interesting series of events took place which changed the scope of the work. During the agglomeration work, one of the control columns was inadvertently set up without the addition of lime to the material prior to loading and subsequent leaching. The gold recovery from this column was comparable to those columns that had a lime addition of 10 pounds per ton of ore. In fact, the gold recovery curve had a much steeper slope than those of the other columns. Furthermore, the pH of the pregnant liquor from the "no lime" column recovered to typical levels as fast as the solutions from the "lime" columns. These observations led to the concept that rinsing the ore with water prior to cyanide leaching could be advantageous to the heap-leach process.

Jan 1, 1992

By Matthew A. Omofoma, Andrew P. Hampton

The application of the Cyprus Cyanisorb process was investigated using a pilot scale facility at the NERCO DeLamar Silver Mine (DSM) in Owyhee County, Idaho. The purpose of this process is to remove cyanide from the DeLamar mill tailings slurry prior to its introduction to the tailings impoundment. This will maintain the tailings impoundment solution in a detoxified condition and thus prevent migratory bird mortalities. The cyanide removed is to be collected and recycled to the mill. The process successfully recovered approximately 90 percent of the weak acid dissociable cyanide (WAD), reducing the effluent tailings cyanide concentration from about 300 ppm to less than 20 ppm. This was accomplished by stripping the slurry with air in a packed tower and recovering the volatilized HCN in a packed absorption tower. Data were obtained for the design of the full scale facility including the stripping and absorption towers, currently under construction at the DeLamar Mine site. Finally, test results indicated that the final pH of reneutralization can be optimized to provide for minimal gold and silver losses, while selectively precipitating unwanted metal impurities (Zinc, Selenium, Iron, and Copper) from solution

Jan 1, 1992

By Qiu Rongqing, Huang Kongxuan

This paper summarizes the results of treating arsenic­bearing refractory gold concentrates from six gold Mines of Chi­na by using bioleaching method and discusses the conditions of bioleaching processes. Results indicate that Thiobacillus fer­rooxidans T-3 Strain can intensely oxidize arsenopyrite, how­ever oxidation rate and degree differe considerably for different. During initial inoculation of 5 X 106 cell/ml. FeH contration generaly 4 -8 g/1. Sample size > 80 % - 3 20 mesh and pulp density 10 % ( w /v) and leaching time ,1 -- G clays, arsenic re­moval rate reached more than 80 % , Fe extraction ,10 - GO% desulfurization rate 30-45% after bacterial oxidation of 4-G days.

Jan 1, 1992

By LeRoy D. Poindexter

TWO-INCH TO MINUS #100 MESH IN ONE GO The need to reduce mineral ore to a very fine mesh economically has been a timeless problem in the mining industry. With this as the specific and we.l.l focused objective, the Cyclone Crusher has been designed and is being manufactured. Utilizing space age technology from such military projects as piercing steel plate with plastic particles, the Cyclone uses the physical principles of centrifugal force. Through a combination of very high G-forces and asymmetrical loadings between a cone and anvil, particles are pulverized to very fine mesh gradation. Just how fine the final product will be, of course, is dependant on a number of factors. The machine setting, the feed rate, the gradation of the in feed material, the molecular structure of the material, and the original fracture planes of the material all affect the end result.

Jan 1, 1992

By Dan Slyter

This paper prov ides comparisons be­tween Merrill-Crowe and Carbon Adsorption pl Rnts 11sed for Pree ious Metal Heap Leach Operations. During the first stage of mine devel­opement, the question arises as to type of gold recovery circuit to be employed, Car­bon or Zinc. Several important factors to consider in answering this question are: Au/Ag ratio Solution grades Daily plant production Plant throughput required Plant gold inventories

Jan 1, 1992

By Mike Irish, Deb Mukhapodhyay

It has been demonstrated by Arrowhead Industrial Water that a proprietary reverse osmosis technology can be used efficiently, effectively, and economically to reduce the levels of cyanide species, heavy metals, and other ions as shown in Figure 1 to allow safe discharge of a permeate solution to the environment. A simultaneous benefit of this process was the cost savings of reduction in quantities of cyanide requiring destruction by hydrogen peroxide and recovery of a concentrated gold and silver value in the concentrate solution.

Jan 1, 1992

By J. L. Waldron

This paper presents a theoretical tool used to analyze gold recovery problems at Dee Gold Mining Co. The first step in addressing the problem was realizing that lower gold extraction was linked to high silver grades, and could not be correlated to either the carbonaceous or sulfidic content of the ore. Analyses of metallurgical testwork, blasthole, and mill recovery data demonstrated that decreases in gold extraction correlatP� well to increases in silver extraction. Figure 1 illustrates this for 1991 mill operations. This was the starting point for the work described in this paper.

Jan 1, 1992

By Len H. Steele

To date VMD have designed, built and supplied nine autoclaves to various mining companies in Canada, the US, and Papua New Guinea. Initially, completely fabricated and lead lined units were shipped. The logistics of Placer Dome's Porgera PNG Project necessitated fabricating and lead lining each autoclave in five sections for transportation to site, each piece weighing approximately 30.5 tonnes. Support equipment such as turning rolls, automatic and manual welding machines had to be set up on site to facilitate assembly of these units which was a challenge in planning. This on site erection programme was completed in three months.

Jan 1, 1992

By Deepak Malhotra, Sean Armstrong, Linda Baltich

The economic profitability of any mineral company is dependent upon maximizing mineral recoveries while minimizing costs. The effectiveness of any strategy to meet this objective is dependent upon firstly obtaining quantitative information concerning the steady-state metallurgical balance of the plant, and secondly, how efficiently this information is used to improve/optimize plant performance. This two-step approach can be designated as a "plant audit." Plant audits on a routine basis can be very expensive and time-consuming. Most plants have reduced staffs to cut costs. The remaining staff has to spend time to solve production/operation problems, thereby leaving limited resources (i.e., people, time, and money), for plant auditing. This paper briefly reviews plant auditing categories, and a systematic approach to auditing which has been successfully used at several operations. An example illustrating the use of this approach in gold operations is discussed in this paper.

Jan 1, 1992

By J. A. Meech, C. A. Harris

Expert Systems are being used in the Mineral Industry with ever­increasing frequency. A major advantage of these systems over conventional computer programs is that the knowledge and intelligence of human experts can be captured directly onto a computer for transfer to novices or other lesser experts. These programs allow rapid construction of process models that are not well-understood in fundamental terms, but for which good operational reasoning exists. In addition, user-friendly access to "high-tech" knowledge can be provided to unsophisticated personnel who otherwise might be turned off by unintelligible jargon. As such, these systems can be important training tools for new operators. This paper describes the features of Expert Systems that relate to gold processing plants. Applications include grinding circuit control, supervisory control of reagent addition and pulp density, monitoring and control of CIP/CIL carbon inventories and the operation of carbon stripping and regeneration facilities. A consultative Expert System is described that provides advice on laboratory cyanidation testwork

Jan 1, 1992

By Steve R. La Brooy

Techniques for dealing with copper-gold ores are reviewed. Cyanide has little selectivity of gold over copper, and depending on the reactivity of the copper minerals cut-off grades for gold recovery by direct cyanidation are generally below 0.5% copper for oxide ores and 1 % for sulfide ores. Non-cyanide gold leachants also tend to be reactive to copper. The cheapest option for sulfidic ores is to produce a flotation concentrate for smelting, while transition ores generally need a sulfidisation pre-treatment. The requirement for the concentrate to have a high enough copper grade to be acceptable to a smelter may compromise copper and gold recovery. This can lead to significant gold grades in the flotation tailing, and copper levels in the tailing that are too high for direct cyanidation to be able to recover the gold. Oxidised ores, flotation tailing or other material not amenable to flotation represent the greatest grey area for gold recovery. Copper removal by acid, alkaline or ferric pre-treatment is possible though not generally used. Cyanide pre-leaching to remove copper, followed by copper and cyanide recovery represents a potential option that has been installed at one Australian gold plant, where copper is recovered onto carbon, ahead of the slower leaching gold. Actual cyanide recovery depends on ore mineralogy, allowing for losses as cyanate, thiocyanate, carbonate and ferrocyanide. Alternative options for gold recovery following cyanide leaching include precipitation, ion exchange and solvent extraction of the gold. Ammonia-cyanide leaching may offer another option for more selective gold dissolution from flotation tailing and oxidised materials. A plant is currently under construction in Mauritania.

Jan 1, 1992

Minter's excellent recent paper (1990) on the great paleoplacer gold deposits of the Witwatersrand and its subsequent discussion (Cheney, 1991) and reply (Minter, 1991) provide an informative, interesting and up-to-date review of the geology of these unique ores and some long enigmatic questions regarding their origin. Clearly summarized by Minter (1990) are the compelling sedimentologic and stratigraphic relationships indicating that the Central Rand Group conglomerates are ancient placers and documenting the fluvio-deltaic conditions of their transport and deposition. As Minter (1991) indicates, Cheney's discussion broadens Minter's 1990 coverage of the subject by considering higher and lower stratigraphic units and by adding detailed comments concerning recently published information about metamorphic and age relationships. Cheney's discussion and Minter's reply also readdress the old controversy of epigenetic hydrothermal vs. syndepositional placer origin for these deposits. This controversy has been resurrected by: • recent recognition of hydrothermally-altered granites (HAGS) in the older Archean basement rocks that lie unconformably beneath the Dominion Group rocks north and west of the Witwatersrand depository; • recognition of greenschist metamorphic assemblages in the Witwatersrand strata; and • the presence of interpreted epigenetic mineral assemblages and textures in some of the deposits. These relationships are briefly discussed by Cheney who suggests they may result from later, superimposed metamorphism and deformation and do not prove that the gold was introduced by epigenetic/metamorphogenic processes. In his paper, Minter (1990) cited the 1986 abstract of a subsequently published paper by Hutchinson and Viljoen (1988) who also considered many of these aspects and attempted to integrate them all in a broad genetic hypothesis. In addition, they emphasized the additional important problem of determining the source for the Witwatersrand gold. Although this issue was partially addressed by Reimer (1984), Mossman and Dyer (1985) and Reimer and Mossman (1990), the question has been generally under emphasized in earlier work and was, therefore, not stressed by Minter and Cheney. Reimer (1985) also emphasized the importance of weathering of the basin's Archean hinterland and its affects on Witwatersrand sedimentation.

Jan 1, 1992

By G. E. Mellor, R. E. Lippoth, T. B. Faddies

The Little Rocky Mountains host epithermal- gold-silver bearing vein and stockwork deposits in a syenite intrusive complex. Pegasus Gold Ltd. is currently mining these oxidized deposits by open-pit methods and recovering gold and silver by heap-leach processes. A geologic program has been designed to effectively determine the basic ore characteristics; 1) mineralization; 2) oxidation; 3) structural setting; 4) lithology; 5) alteration; and ultimately, 6) the leachability of the ore. Geologic mapping, sampling, drilling, assaying, and testing are routinely used in exploration, development, production control, mine planning, and ore reserve estimations. Timely and accurate assay results are essential for the program's success.

Jan 1, 1992