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By Irwin R. Higgins, Joseph C. Milbourne

The selection of a suitable nitrate removal process depends on a variety of site-specific chemical and environmental issues. The dominant technologies for nitrate removal include biological denitrification and continuous countercurrent ion exchange. The decision to apply either of these technologies, or both together, depends on the nature of the waste water to be treated. Factors that affect the selection of the biological system include the feed composition and feed temperature. Ion exchange nitrate removal systems ere less sensitive to the feed composition but require disposal or destruction of the concentrated pregnant eluate. The paper discusses Tetra's continuous countercurrent ion exchange technology (CCIX™) and fixed film biological reactor, Denite®. The treatment of the ion exchange pregnant eluant is also discussed.

Jan 1, 1995

By T. J. Close

The Silver Peak Range North Wilderness Study Area was deleted from the list of US Bureau of Land Management lands in Nevada to be considered for wilderness designation. This decision was based in part on the US Bureau of Mines mineral investigation of the wilderness study area which found indications of precious- and base-metal-resources. The study area lies between the Silver Peak and Dyer mining districts of west-central Nevada. The Bureau examined 13 mineralized sites, most of which were previously unknown and unclaimed. These sites are along two zones that cross the study area from the Silver Peak mining district to the Dyer mining district. The two zones transect a volcanic center of fractured and altered rocks that contain epithermal veins of quartz and calcite with gold, silver, and base-metals. At the surface, these veins are poorly defined. Exposures of the more than forty veins examined were as thick as 17 ft and as long as 1000 ft. Samples from these veins contained significant amounts of precious- and base-metals-as much as 0.02 oz per ton gold, 2.1 oz per ton silver, 1.0% copper, 2.6% lead and 0.4 % zinc. No vein large enough or of high enough grade to be classified a mineral resource was disclosed by the sample data. However, most do have indications of precious- and base-metal-resources at depth. Subsurface exploration of some of the veins is recommended.

Jan 1, 1995

By Steve Kral

Philip M. Hocker is president of the Mineral Policy Center (MPC), a Washington, DC-based, non-profit organization formed to "address the environmental problems that are caused by mineral development in both the hard-rock mining and onshore oil arenas." Hocker has been involved with resource development and environmental policy issues since the 1970s. He has been a plaintiff in several lawsuits regarding environmental management of federal onshore oil and gas leasing. He was also active in the 1987 campaign to pass the Federal Onshore Oil and Gas Leasing Reform Act. Hocker served on the board of directors of the Sierra Club from 1980 through 1986. He is also a member of SME and spoke at the welcoming luncheon and keynote session of the SME Annual Meeting and Exhibit, Feb. 14, 1994, in Albuquerque, NM. In his role as president of MPC, Hocker has become a major player in the ongoing battle concerning mining law reform. And, while the mining law issue is the most visible and controversial issue confronting the mining industry and MPC, Hocker's organization is also active in clean water reform and other public policy issues that concern natural resource development and the environment. Hocker and MPC invoke a wide spectrum of reactions from the mining industry, most of it negative. Even so, the editors of ME decided that SME members should hear from Hocker his views on domestic mining, including mining law reform, clean water legislation and other environmental issues facing the industry.

Jan 1, 1995

By William D. Cassity, Batric Pesic

Introduction Gold mining on an industrial scale is becoming increasingly dependent on low-grade refractory sulfide ores that contain large amounts of pyrite (FeS2) and arsenopyrite (FeAsS). Gold is usually present as sub-microscopic particles dispersed evenly throughout the sulfide matrix. Without some form of preoxidation, efficient recovery of this finely disseminated gold through cyanide leaching is hampered because the surface of the sulfide particle becomes passivated and impervious to penetration of the cyanide. Traditional methods for recovery of refractory gold from arsenopyrite ores include roasting and autoclave leaching. A modem alternative method is to preoxidize the mineral using the bacterium Thiobacillus ferrooxidans prior to attempting to re- cover the gold through cyanidation. The bioleaching of arsenopyrite ores presents a problem in the mobilization of large quantities of arsenic, present both in the +5 and +3 ionic states. Dissolved arsenic species pose a dual problem: they are -1 to the bioleaching process itself through inhibition of bacterial activity, and they also pose an environmental threat. The arsenate anion (AsO2) has been shown to be more toxic to living organisms, including Thiobacillus ferrooxidans, than the arsenate anion (AsO43) (Collinet and Morin, 1989). There is some disagreement as to the fate of arsenite in bioleaching solution. Mandl, Matulova, and Docekalova (1992) reported that dissolved arsenite concentration was constant during a long-term bioleaching study of chalcopyrite using Thiobacillus ferrooxidans. Torma and Oolman (1992) report that Thiobacillus ferrooxidans has been found capable of oxidizing As3+ to As5+. The solid products of arsenopyrite/pyrite bioleaching include jarosite (MFe3(SO4)2(OH)6 where M can be K+, Na+, NH4+ or H3O+), scorodite (FeAsO4.2H2O), ferric hydroxides, and ferric hydroxysufites (Carlson et. al., 1992; Van Breemen, 1982; Lazaroff et. al., 1982). The particular species formed is a function mainly of pH. Little study has been performed on the effect of solid products on bioleaching. Pesic and Kim (1993) showed that Thiobacillus ferrooridans cells served as a nucleation sites for jarosite particles, which grew rapidly and eventually killed the cell. Most bioleaching studies are performed at low pH&apos;s (<2.0) under uncontrolled conditions. By studying bioleaching of arsenopyrite under controlled pH conditions and at higher pH&apos;s (2.0 to 3.0), the distribution of iron and arsenic between the solid and liquid phases can be controlled, and their effects studied. The objective is to develop a bioleaching process that operates at high efficiency while keeping amounts of dissolved heavy metals low. Pesic, Stohok, and Torma (1993) demonstrated the usefulness of this approach in the leaching of cobaltite (CoAsS) concentrates. Materials and Methods The focus of this study was the bioleaching of arsenopyrite ore by Thiobacillus ferrooxidans. The parameters studied included the effects of pH, and the effects of arsenate (AsO43 and arsenite (AsO2). pH studies included pH set initially but not controlled, and pH controlled continuously with NaOH or LiOH. Bioleaching results from two strains of Thiobacillus ferrooxidans with different adaptation histories were compared. Bioleaching experiments were conducted in 150 ml stirred glass reactors using a strain of Thiobacillus ferrooxidans adapted to arsenopyrite ore, supplied by the U.S. Bureau of Mines. These bioreactors were innoculated with stock cells grown on arsenopyrite ore for 14-16 days. Typical elemental breakdown for this ore was: As, 9.90%; Fe, 18.60%, Stot, 9.26%; Suifide, 7.50%; SiO2, 25.90%. Mineralogically, the ore contained both arsenopyrite and pyrite. Bioleaching efficiency was measured by withdrawing bioleach solution samples at selected intervals, filtering, and measuring the amount of dissolved cobalt, iron, and arsenic by atomic absorption spectroscopy. Because the precipitation of iron and arsenic at higher pH&apos;s would lead to unreliable results, a 100 mg tracer of cobaltite concentrate from the Blackbird mine in southern Idaho was added to solution. Dissolution of the cobaltite tracer was used to indicate bioleaching of the bulk arsenopyrite ore. Cobalt has been shown to be stable in solution even when iron and arsenic were precipitated (Pesic, Storhok, and Tonna, 1993). The pa-

Jan 1, 1995

By S. Mathur

Future Florida phosphate reserves contain higher MgO than presently mined deposits. The high MgO content is contributed by dolomite and Mg-rich clay, palygorskite. Selective flocculation was attempted to reduce the MgO content of apatite in synthetic mixtures of apatite with dolomite and palygorskie. Mixed mineral selectivity was predicted in the apatite-dolomite and apatite- palygorskite systems with Poly(ethy1ene oxide) (PEO) flocculant. Loss of selectivity in the mixed mineral systems was primarily attributed to heteroflocculation, which was minimized by addition of a Site Blocking Agent (SBA), a lower molecular weight fraction of PEO, prior to addition of the flocculant. A 80:20 mixture of apatite-dolomite (or palygorskite) was upgraded as 95% apatite at more than 80% recovery level in the product fraction.

Jan 1, 1995

By K. Hanumantha Rao, K. S. E. Forssberg

The limestone deposit of Gâsgruvan, Sweden contains around 89.2 per cent of calcite. Conventional and column flotation studies have been carried out using sodium oleate and modified fatty acid collectors in the presence of sodium silicate modifier. The effects of collector and silicate concentrations, and particle size on the flotation response of calcite have been investigated. The results have been discussed in comparision to the performance of conventional and column flotation cells. The feed size is found to be a significant factor to achieve a high grade calcite concentrate either by conventional or by column flotation. The loss of selectivity at fine particle sizes is examined using a modified DLVO theory.

Jan 1, 1995

By Denis M. Riley, Neville C. Lockhart, Bruce A. Firth

The potential use of the Kelsey Centrifugal Jig to clean fine coal has been studied. It was found capable of cleaning coal at very fine sizes, at least to 0.038 mm at relative densities as low as 1.6. This effect was however very dependent upon the solids feed rate and the absence of significant amounts of clay slimes. Comparisons with a spiral and a laboratory scale Jameson Flotation Cell were made. The concept of recleaning spiral product was investigated. Use of a spiral to reclean the coarse fraction, and a centrifugal jig or flotation to treat the fine fraction, gave significant improvements in final ash values over spiral recleaning of the full size. Future R&D needs include improving feed rate capacity, and application to problems like pyrite removal that are difficult to solve via flotation.

Jan 1, 1995

By Sandra L. Maxfield, Alan Mair

Strategic design of groundwater monitoring programs can increase public confidence in mine management, decrease financial assurance requirements, and minimize environmental budgets. Monitoring of inorganics is challenging because many occur naturally with baseline concentrations fluctuating spatially or temporally. Evaluating monitoring data to distinguish between a hazardous release or a natural fluctuation in baseline concentration can be controversial. In order to develop an effective program, monitoring parameters should be selected which are mobile and stable. Statistical procedures should be customized to address the uniqueness of groundwater systems. Calculated baseline concentrations should minimize the false negative & false positive rate.

Jan 1, 1995

By Silvano Perla

Peabody Western Coal Co. operates two mines in northern Arizona. The Black Mesa and Kayenta coal mines are unique for several reasons. They both have only two customers: Southern California Edison’s Mohave generating station near Laughlin, NV and the Navajo generating station near Page, AZ. Both mines are close together. Between the two, they ship nearly 11 Mt/a (12 million stpy) of coal. Material is shipped to the power stations in two ways. This first is a 440- km-long (273-mile-long) underground slurry pipeline, the longest in the world. The second is an 11 -km-long (17-mile- long) long conveyor to four storage silos. Product is then shipped by train from the storage silos to the plant sites. Another factor makes these mines unusual. They are both situated in the middle of the 68,795km2 (17 million- acre) Navajo Reservation, home to the Navajo Nation and Hopi Tribe members. Nearly 90% of the Black Mesa and Kayentamines’ 850 employees are tribe members. Peabody Western Coal is the United States’ largest private employer of Native Americans.

Jan 1, 1995

By Ian M. Loomis, Malcolm J. McPherson

A fuel-rich fire exists when the quantity of fuel exceeds the oxygen available to support complete combustion. The transition of a mine fire from Oxygen- rich to Fuel-rich combustion, at this time, represents a point-of-no-return in the fire fighting efforts. Once the transition has been made to fuel-rich the fire can spread at a rate 6 to 10 times as fast as in the oxygen-rich state. Utilizing available technology the fire fighters are left to seal the fuel-rich fie as the only technique to extinguish it. In order to minimize the devastating effects of a fuel- rich fire it is important to understand the means by which the fire becomes fuel-rich and by what means the fire may be returned to an oxygen-rich state. This paper covers: the development mechanism of a fuel- rich fire in a coal mine entry and the physical and chemical effects of applying water to a fire. Experiments concerning these matters have been conducted in a 30 cm square wind tunnel constructed at the Virginia Polytechnic Institute and State University as a model coal mine entry. This paper also addresses the results obtained in testing application of a water mist to fuel-rich fires in this model. These tests have centered on the development profile of a fuel-rich fire in a duct and demonstrate a means of regaining control of a fuel-rich fire by returning it to an oxygen-rich state.

Jan 1, 1995

By E. J. Jacques

A typical problem in ventilation networks with multiple fan systems is the possibility of them interacting. Multiple fan systems are no exceptions in complex tunnels, and may also be met in mines where underground fans are installed. When aiming at controlling a multiple fan system in a ventilation network, e.g. with a view to maintaining an acceptable air quality level, yet at minimum power consumption, transient flow conditions frequently occur. Although in most applications these transients are short compared to the time needed to achieve the planned actions on the ventilation, one should, however, keep in mind that it is important to avoid any bouncing effect between different (adjacent or distant) fan systems. Therefore a simulation of the unsteady-state flows could allow us to learn more about the propagation of transients within the network, and their possible secondary effects Among others, one question that often is raised, is to find out in which sequence and at what time schedule each of the fans in a network should e.g. be started up? Another typical problem, into which an unsteady-state simulation could provide some insight is the following: how should the facilities of variable pitch angle and/or changeable RPM of several fans operating in parallel be handled and combined in order to obtain a flow rate that changes gradually from zero to its maximum value i.e. the sum of the individual throughput flows of all the fans. The literature is not very abundant on the topic of simulating transient flows in networks. There is no doubt that numerical models have been developed (Pollak, Christensen, 1987), most of the time for particular applications (Wala, Kim, 1985), (Tanaskovic et al., 1984), (Schultz, Sockel, 1991), etc. The aim of this paper is to present a model that also simulates one-dimensional compressible flows in unsteady-state conditions with, however, the specific intent to handle networks with more than one fan. PROBLEM STATEMENT The mathematical model chosen to describe the unsteady flows in a ventilation network is based on the dynamic and continuity equations applied to each of its airways. The following basic assumptions are made : - the flow in the airway is considered to be one- dimensional, - - the flow is assumed to be fully turbulent, and hence the ATKINSON equation for calculating the friction losses will be applied. Whether this equation remains valid for transient state flows remains an open question. However, this may reasonably be assumed since the interesting flow frequencies are low. A discussion may be found in (Kämpf, 1987) ; - the airways are assumed to have a constant cross- sectional area along their length. If obviously this would not be the case, it is always possible to subdivide the concerned airway into sections for which the previous assumption holds. Applying the basic equations of mass and energy conservation, the flow in each branch may be described by the Euler equation for Newtonian flows.

Jan 1, 1995

By Lennart Mukka

LKAB has been mining iron ore in northern Sweden for about 100 years and now enters the next century with a major new investment in Kiruna. The under- ground projects involve construction of a new main haulage level, a new mining system and a new ventilation system. This paper describes the Ventilation Procject from the investigation stage through to construction.

Jan 1, 1995

By Jr. Watts

The American Mining Congress and the U.S. Bureau of Mines have formed a collaborative research team to develop, implement, and evaluate a comprehensive control strategy to reduce diesel particulate matter concentrations without degrading other air quality parameters at an underground noncoal mine. Other participating organizations include Caterpillar, Inc., the Mine Safety and Health Administration, and the University of Minnesota. After extensive baseline information and air quality data are collected, available control strategies to reduce diesel particulate matter exposures will be implemented, individually or in combination, and evaluated. This paper discusses the objectives and protocol of the collaborative effort to evaluate diesel particulate control technology.

Jan 1, 1995

By B. Beatty

Discussion by B. Beatty This is a response to M.J. Hrebar&apos;s paper, which tracks in detail the highly productive stripping capabilities of modern large bulldozers at two separate installations. It proves the old adage "economies of scale" and quantifies the advantage of being able to move large loads of dirt over comparatively short haul distances by sliding rather than carrying the load. This discussion examines whether a bulldozer is the most efficient way of using this geotechnical principle. Case 1 - Study eastern US: Contour coal stripping application The energy consumption for the Case 1 mining method (eastern US contour stripping operation) shows the D11 averaged 117 L (31 gal) of diesel fuel per scheduled hour, and produced 333.3 bank m3 (436 bank cu yd) per scheduled hour (0.351 L/m3). Assuming 1 L (0.26 gal) of diesel fuel contains 10.4 kW-hr of energy, the unit expenditure of fuel energy for Case 1 Study was 3.66 kWh/m3. Another way of shifting this material is by using an overburden slusher (OS), as shown in Fig. 1. The OS as shown in Fig. I. The OS is electrically powered and consists of a manned low wall winch (LW ), a remote controlled (radio telemetry) highwall winch (HW) and a hoe. The winches operate to pull the hoe back and forth across the pit. The hoe carries load in the forward direction ahead of a rear mounted blade and returns empty. A spreadsheet (Lotus 123) simulation package, BOSSIM, models the OS operation on a load by load basis over a wide range of pit configurations. The geometry shown in Fig. 2 of the paper was modeled using BOSSI M and the results are summarized in Table1. Table 1 shows a LW with 150 kW (200 hp) and a HW of 120 kW (160 hp) installed power, towing a 15-m3 (19-cu yd) hoe, would accomplish the Case 1 stripping task at about the same scheduled stripping rate (D11=333 m3/hr or 433 cu yd/ hour, OS=342 m3/hr or 447 cu yd/ hour). It was assumed the winches in this equipment have an electromechanical efficiency of 90%. This gives an average electrical energy expenditure rate of 151 kW-hr, and a unit energy expenditure level of 0.44 kWhr/m-3(0.57 cu yd/kWh)-an improvement of 8291%- over the D11 alternative. The energy comparison illustrates the importance of using more efficient electric power if possible, ahead of the internal combustion engine, and delivering power from a fixed ground position rather than through a moving track system. Another important energy observation is the comparative action of the dozer blade and the OS hoe. The former implement continuously digs and spills as it works the load forward. The OS hoe digs the load until full, the blade then lifts due to the contained load pressure and a shear plane forms under the mass, enabling it to slide forward in a force reduced - transporting mode. Economic comparison Table 2 operating cost per scheduled hour and unit cost comparison follows a format used in Tables 2 and 3 of Hrebar&apos;s paper and compares Case 1 Study with the OS alternative. Drill and blast costs are kept constant in both cases, although when larger OS units are considered, it is expected these costs will reduce because bigger hoe sizes will permit larger rocks to be transported efficiently.

Jan 1, 1995

The US economy grew at a rate of 4% in 1994 and the gross domestic product rose to $6.74 trillion. With 261 million people - 605,000 in mining, including petroleum -the United States has l 10 million dwelling units and 200 million licensed motor vehicles. New private housing units authorized in 1994 rose 14% to 1.4 million units. New car production rose 11 % to 6.6 million units, while truck and bus production rose 30% to 5.2 million units. The inflation rate was less than 3% and the prime rate of interest averaged 7.15%. The producer price index (1982 = 100) for fuels and related products and power was down 4% to 78, while metals and metal products rose 5% to 125. Chemicals and allied products rose 3% to 132, and non-metallic mineral products rose 3% to 124. The merchandise trade deficit rose 25% to $166 billion. Disorder in the former Soviet Union led to substantial dumping of mineral materials. With vast mineral resources, the former Soviet Union land area totaled 22.4 million km2 (8.6 million sq miles). In comparison, the North Ameri¬can Free Trade Agreement (NAFTA) area (United States, Canada and Mexico) totals 21.4 million km2 (8.3 million sq miles).

Jan 1, 1995

The choice between EPB - and Slurry Shields is influenced by the following factors: grain size distribution, cohesiveness, occurence of boulders, occurence of gas, feasibility of soil separation and muck disposal, and settlement properties of the soil. The simple equation cohesive soils = EPB Shields and non cohesive soils = Slurry Shield is very often superimposed by other facts. For example, the occurence of a large amount of boulders in weak cohesive soils, where the application of roller discs is not recommendable, may lead to the use of a Slurry Shield with a rock crusher, thus accepting the disadvantage of a sophisticated separation plant; whereas the occurence of contaminated groundwater or gas may exclude the use of a Slurry Shield. In the following examples the choice of a Slurry Shield or EPBS will be explained and justified with regard of the above factors.

Jan 1, 1995

By K. N. Han, J. J. Kellar, Y. Guan

The adsorption of zinc species onto silica in ammoniacal solutions was studied. The adsorption isotherms indicated that the adsorption of zinc increased with increasing pH. The adsorption density increased as the zinc equilibrium concentration increased up to =3.5x10-4 M. Above this concentration, the adsorption density was independent of the equilibrium concentration, and a maxima adsorption density was reached. Temperature had no significant effect on the adsorption density.

Jan 1, 1995

By D. Yeager

Researchers at the U.S. Bureau of Mines have successfully used a genetic algorithm to tune computer models of three column flotation units simulating a separation circuit. The computer models rely on empirical constants that are selected so that the models accurately predict the performance characteristics of individual column flotation units. Unfortunately, these empirical constants have traditionally been selected using a time consuming trial and error process. A new and more efficient approach to selecting empirical constants for computer models has been developed. A genetic algorithm has been used to select the empirical constants for column flotation models used to simulate a three column circuit. Genetic algorithms are search algorithms based on the mechanics of natural genetics. They rapidly locate near optimum solutions in difficult search spaces. Bureau researchers have used these innovative search algorithms to dramatically reduce the time needed to select empirical constants for column flotation models. The approach is applicable to the selection of empirical constants for numerous other computer models.

Jan 1, 1995

By S. S. Peng

To prevent mine floor heave, the mechanisms of floor heave must be fully understood. Based on the field study, the mechanisms of two types of floor heaves are analyzed in this paper. The mechanical models for the two types of floor heaves are developed. The floor heave can be predicted by the developed mechanical models and the control measures are recommended.

Jan 1, 1995

By M. Mohammed, S. J. Jung

The prime criteria in the design of underground openings with complicated geological structures is ground control. Stability of underground openings for deep mines is critical because incorrect orientation or geometry of the shaft, stopes and accessways often results in the failure of openings due to high stress conditions. Current design procedures for complicated orientation and geometry of mines are rapidly becoming inadequate. In this study, the finite element method (ANSYS) has been used with optimization criteria to design safer, more stable underground openings.

Jan 1, 1995