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By Jan Tegtmeier, Horst Gerhardt

INTRODUCTION Under certain circumstances the closure of former mines which are located above a certain flood level can result in problems such as the emanation of detrimental substances after having completed filling and reclamation operations. This especially applies to uranium mines in which the radiation dose could far exceed the dose of natural background radiation. By means of an example of the uranium mining in Germany in the following it will be demonstrated how to cope with this problem. On the basis of comparative investigations in various vein deposits and using ventilation scheme calculations proposals for the optimization of the necessary forced ventilation can be submitted. REPORT ON SITUATION In the period 1946 - 1989 the former Soviet-German joint- stock company "Wismut" developed into the biggest European uranium producer with a total output of about 220.000 t of uranium. A major mineraldeposit district was the deposit of Schlemaf Alberoda in the Saxon Ore Mountains, in which 80.000 t of uranium were produced. Thus it is among the biggest uranium de- posits of the world, from which various other metals were at- tracted for many centuries. The exploitation of the Schlemal Alberoda deposit involved steep veins in regions near the surface as well as depths of 1.800 m. Until 1991 a total excavation space of 40 million m3, which is flooded at present, was produced. With the average increase in the water level of 80 cm per week the final flood level is expected to be reached in the year 2003. The shaft 373 at present still being used for ventilation will be no longer available since the second quarter of 1998 after flooding the -540 m level because it is not connected with the excavation system near the surface. As a study shows, a radiation dose far above the natural back- ground radiation has to be expected for the town of Schlema due to the extensive mining activities near the surface and due to the subsequent displacement with missing depression fo the main mine ventilating fan. An uncontrolled air flow containing radon leaves the open mine excavation due to the effect of the natural ventilating pressure and emanation caused by the barometric pressure drop with atmospheric pressure fluctuations. This mine air with its high-level radioactive equilibrium results in a high radiation dose in buildings (see Figure l). After having switched off the main ventilating fan in order to investigate the effect of the missing depression the increase in radon concentrations amounted up to 700% in various buildings of Schlema. This was partially due to the inversion state of the weather at that time. The high radon concentration has detrimental effects on the health of the population and of the miners working on the further reclamation in regions above the flood level. ANALYSIS OF THE RADON EMANATION RATE EXPECTED Considering the composition of the radon inflow from the mine workings it becomes evident that 80 % of the radon inflow originates from abandoned excavations and only 20 %from open ventilated mine excavations. This fact has to be taken into account for the ventilation after having reached the final state of flooding. After completing ventilation the radiation dose on the surface is mainly due to the radon emanation from excavations close to the surface. Investigations of the Wismut GmbH showed the in- crease in the specific radon emanation rate by a factor of 100 for abandoned excavations as compared to new drivings. One reason is the larger specific surface of abandoned galleries caused by displacements due to mining activities as well as by fall of hanging. Furthermore the radon can enter the gallery through joints, which have subsequently opened by convergences. All these effects result in a larger free surface available for radon diffusion. The large number of drivings in the deposit sections near the surface and the fact that the highest uranium contents are found near the surface as well as the high fracturing are further reasons for higher emanation rates. Considering these facts it can be expected that the radon inflow of 10.000 kBq/s, which refers to an open mine excavation of about 1.4 million m3, represents a minimum. Only by increasing the specific surface, for which a numerical value has still to be determined, this value will increase with certainty. An extensive radon emanation from the residual excavation, which cannot be flooded, can only be prevented by maintaining the ventilation system. The low pressure produced by the fan in the mine openings prevents the emanation of air containing radon due to the effect of the natural ventilating pressure. Without the controlled withdrawal of the radon the population as well as the miners working on the further reclamation in areas above the flood level would be endangered. Therefore the follow-

Jan 1, 1996

By S. A. Pirzada

A thermal plasma assisted laminar flow reactor has been used to evaluate the kinetics of converting alumina to sodium aluminate in flight. Free energy minimization calculations were used to determine experimental conditions. The experimental variables include: alumina particle size, alumina/sodium nitrate molar ratio, temperature and residence time. A mathematical model for the conversion was developed and validated. Experimental and mathematical results are presented.

Jan 1, 1996

By A. M. Marabini, V. Alesse, Belardi. G.

An alternative flowsheet was designed for the flotation treatment of a complex sulfide ore from the Sotiel Mine in Spain. The ore contains 0.71% Cu, 2.24% Pb and 5.63% Zn. Two specially developed synthetic collectors, methyl-mercapto-benzoxazole (MMBO) and 6n-propoxy-mercapto-benzo-thiazole (PMBT), were examined. MMBO exerts a specific action on copper and zinc minerals after treatment with copper sulfate, and PMBT exerts a specific action on Pb minerals. Flotation operating variables (pH, frother type, frother quantity and feed particle size) were examined by means of rougher flotation tests to determine the optimum conditions for the new collectors. Once the optimum conditions were determined, a series of open flotation circuits were run on feeds of various particle sizes (obtained by different types of grinding). The objective was to obtain high-grade Cu and Zn concentrates. The results of the open-circuit tests demonstrated that a Cu concentrate grading from 18% to 23% Cu and a Zn concentrate grading from 40% to 48% Zn can be produced.

Jan 1, 1996

By G. Van Weert

Oxygen transfer from dispersed air in agitated slurries represents an important unit operation in the minerals processing industry. Gold leaching, iron precipitation and especially bio-oxidation come readily to mind. However, little engineering information is available on the variations between impeller types on such O2 transfer. Engineering literature on the subject, i.e. information which relates slurry density and energy input to O2 transfer, is reviewed and compared to current experimental work. The latter was carried out with minus 50 micron sand/water slurries in a 64 I laboratory tank of standard proportions, equipped with a variable speed drive with torque meter. A standard Rushton turbine and a specifically sized A315 were compared. Results confirm an increasing impairment of O2 transfer with increasing slurry density for both impellers. The volumetric mass transfer coefficient, k,a, in a 10 vol. % slurry shows a decrease of 30% compared to the k,a in water. At 20 vol. % sand this decrease is near 50 %, depending somewhat on superficial gas velocities. Power efficiency, i.e. the kg O2/kWh, decreases about 25 % more rapidly for the Rushton turbine than for the A315 with the addition of sand. However, for equivalent O2 transfer the Rushton turbine was more efficient in this work. Experimental results are presented and their significance for slurry bio-oxidation discussed.

Jan 1, 1996

By Graham G. W. Mustoe, Andrew I. Hustrulid

An advanced numerical model based upon the Discrete Element Method (DEM) has been developed to provide the engineer with unique detailed information to assist in the design of transfer points in large industrial conveyor systems in mining operations. This modeling technique provides a quantitative description of the bulk solids movement through the transfer point. This information consists of the velocity distribution of the bulk solids and the stresses within the bulk solids. The DEM model also gives detailed information concerning the impact forces acting on the transfer structure and the conveyor belts from the bulk solids flow.

Jan 1, 1996

By Greg Barfoot, K. Payne

Condition monitoring of conveyor belting has become an established tool for maintenance programming, replacement strategies and quality assurance for belt conveyor systems. What is less well known is that the condition of the conveyor belting is usually a symptom of problems in other areas rather than the problem source. This paper presents an overview of the state of the art in belt monitoring and the move towards on-line NDT systems. The use of belt monitoring data as an indicator for overall system design, maintenance and operation is also discussed.

Jan 1, 1996

By Marina K. Peshkova, Izabell V. Pomorova

Computer modelling system for definition optimal way of in- vestment under condition of diverse directions of activities mining enterprises has been created. The main purpose of paper is to introduce the new scientific approach of finding effective variants of investment for mining industry under free market condition in Russia, it can be also interesting for domestic and foreign investors.

Jan 1, 1996

By K. Irmscher

During the last years, using modular computer models on the software and distributed computer capacities on the hardware side has become quite common in the mining industry. When tackling real mining problems under the condition of heterogeneous systems, however, some problems become obvious: the incompatibility of the heterogeneous platforms in connection with the heterogeneously structured information and the necessity of interpreting the data. Knowledge based approaches are employed for solving different planning problems in the field of mining industry. The main problems here consist in the knowledge representation and data acquisition. Starting point of the investigation form classifications of mining planning problems and the corresponding models which can be transformed into information models for evaluation. With help of an expert system a practical solution is represented. Distributed systems with mobile computing and communication facilities for immediate access can be used as an additional support for planning and processing. On the base of public or private computer networks (including mobile networks) the foundation is given for a computer supported treatment of planning tasks. Additionally the use of teleworking scenarios in regions of mine planning and data collection in geological applications is prepared. Foundation forms a workflow system on an object-oriented distributed platform.

Jan 1, 1996

By J. A. Chermak

Piles of sulfide-bearing overburden, ore, and tailings have the potential to generate acid drainage (AD) when exposed to an oxidizing environment. Laboratory column experiments were conducted using acid-generating overburden material with an added surface amendment of limestone and/or lime. Artificial rainwater was introduced and allowed to drain through the columns. Results showed that the limestone and/or lime reacted with the acidic rock, resulting in the precipitation of a hardpan layer of gypsum and amorphous iron oxy-hydroxide at the surface. The hardpan layer significantly reduced the effective permeability of the column. Based on this study, hardpan layers can be created as chemical caps to significantly reduce the infiltration of rainwater and snowmelt into acidic overburden or tailings material. Unlike traditional capping methods (for example, clay and high density polyethylene (HDPE) covers), chemical caps are self-healing.

Jan 1, 1996

By Felicia F. Peng

Using granular media for removal of soluble manganese from mine water and industry waste stream has the advantage of forming a compact surface layer of manganese oxide coating on the media. This process can avoid the step involving the separation of voluminous sludge of manganese hydroxide by the high-pH method for soluble manganese removal. The removal of soluble manganese is accomplished by adsorption and oxidation. The adsorption of Mn(II) on the manganese oxide-coated media was rapid through the specific adsorption and may be due to the ion exchange of hydroxyl ions on the manganese oxide by Mn(II). In the subsequent step, the adsorbed Mn(II) form the intermediate manganese complex on the manganese oxide product is oxidized with dissolved oxygen or other available oxidant source in the aqueous solution. This paper presents the efficiency of removal of soluble manganese from mine water by using a laboratory fluidized bed and the recovery of manganese oxide coating on the anthracite coal particles. In order to accelerate the formation of the manganese oxide layer on the surface of anthracite media, dilute potassium permanganate solution is used as an active oxidant. The effects of operation parameters on the manganese removal including pH, flow rate, concentration of feed and oxidant dosage are evaluated.

Jan 1, 1996

By S. Lin

Fan stall is a notorious phenomenon with axial-flow fans. When multiple fans of this type serve a ventilation system, their mutual impacts are very complicated and not well understood. Results from laboratory experiments indicated that the immediate consequence of a fan working across its stall zone (i.e., the pronounced trough on the fan characteristic curve) is that some branches in the system may suffer abrupt and even drastic changes in air quantity and pressure. The quantity range of the fan that causes the abrupt change is called an unstable operating range. The corresponding quantity range of a branch is called a non-achievable quantity range of the branch because any quantity within this range cannot be achieved without changing some parameters of the ventilation system (e.g., branch resistances). These concepts are introduced based on the test results from tubing networks to bring attention to these important characteristics of ventilation systems.

Jan 1, 1996

By Thomas Fliess, Klaus-Christof Ritter, John R. Sturgul

The optimum flow of materials through a smelter is an extremely important phase of the mining cycle. A typical copper smelter will have up to $US 1,000,000 per day of copper being processed. The motion of the overhead cranes in moving the ladles filled with copper matte and slag from furnace to furnace is prescribed but there can be numerous variables to consider. Some of these variables to the system can be: the speed of the overhead cranes, the number of cranes, the size of the ladles, the size of the furnaces, the number of furnaces and the sequence in loading the furnaces. A simulation model was constructed of a working smelter in the SW of the United States. The model has been used to study the effect of varying parameters of the system. The program runs as follows: an input menu appears on the PC screen and the user can navigate through it and change any of the data; the simulation takes place and the results of the simulation sent to a data file. Animation of the system then is shown on the screen in "cartoon" fashion. The software chosen for the simulation was GPSSI H (') and PROOF Professional (') for the animation. The model presented here is believed to be the first reported simulation and animation model for a complete, working smelter.

Jan 1, 1996

By A. M. Raichur

Flocculation of fine coal is usually accomplished with the addition of commercially available organic flocculants. Recently it has been shown that biopolymers derived from microorganisms can be used to flocculate coal. The biopolymers flocculate coal efficiently and render the coal surface hydrophobic. The increase in hydrophobicity can be utilized either to separate the coal flocs from mineral matter. It can also be used for reducing the moisture content of fine coal. In this regard, flocculation and settling tests of fine coal with biopolymers and synthetic flocculants was undertaken and the results are discussed here. Also, a transport model was developed for the time-dependent settling tests for fine coal.

Jan 1, 1996

By A. Davis

Pit lake chemistry depends on the lithology and hydrologic characteristics of the ultimate pit surface, the availability of buffering capacity in the wall rock versus oxidizable sulfide content, and the alkalinity of recharging ground water. In this paper, we assess the geochemistry of 11 existing pit lakes, ranging from the acidic Red Hill and Berkeley pit lakes (pH 2.6 to 2.8) to the alkaline Yerington Pit lake (pH 8.45). Predicted pit lake chemistry is similar to that in existing pits with the long-term pit lake chemistry lying on a geochemical continuum between end members consisting of influent calcium bicarbonate ground water, and naturally occurring sulfate-rich evaporite playa lakes.

Jan 1, 1996

By Takeshi Tanaka, Shinya Ono, Tsuyoshi Kato, Masaji Kato, Yuusaku Tominaga

The knowledge of the macroscopic characteristics of a ventilation network is of fundamental importance for taking counter- measures to increase air quantity in-specified branches, such as those corresponding to working faces at advancing entries or longwall panels. Because the ventilation characteristics are inherent properties of each mine, it takes a long time for an engineer to accumulate experience on how a specific regulator may affect the air quantity in a specific branch of a mine with a complicated ventilation system. A computer-simulation training system, based on the macroscopic ventilation characteristics, is presented in this paper. When a trainee selects a specific condition from five regulator option (closed, almost closed, slightly open, half open, open), the change in air quantity for a network branch is indicated by the color allocated to the ratio of the new air quantity to the old or planned air volume. After the ventilation simulation, the colors in the specified branches are defined by using the fuzzy set theory. The trainee continues practicing the selection of closed/open conditions for different regulators until each of the specified branches is displayed in good state of airflow. The ventilation net- work of the Horonai coal mine is used as an example of the training system to control air quantities in six working faces with 33 regulators.

Jan 1, 1996

By C. G. Anderson

The treatment of materials for the recovery of the precious metals imposes many processing and environmental challenges. Sunshine Mining and Refining Company has developed hydrometallurgical technology for recovery of values from refractory precious metal materials. At Sunshine, the industrial focus of these processes has been for the direct recovery of silver without cyanidation. However, recent work has indicated that these technologies can provide a means for treating complex, refractory gold concentrates. This will be the focus of this paper. The practice of pretreating ores and concentrates to make them more amenable to cyanidation is becoming more common. Several pretreatment options for sulfide concentrates containing gold include roasting, bio-leaching, direct pressure oxidation and nitrogen species catalyzed pressure oxidation. The industrial use of nitrogen species catalyzed pressure oxidation has been limited to the Sunshine refinery where its focus has been for the treatment of silver concentrates. Much of the reluctance, outside of Sunshine, to use this type of technology may be based on the perception that high costs are associated with using nitrogen species (e.g. nitric acid, sodium nitrite) to leach. Also, the use of nitrogen species catalyzed pressure oxidation on an industrial scale is unfamiliar to most metallurgical professionals. A summary of pressure leaching processes which utilize nitrogen species as a catalyst is presented in Tables 1 and 2.

Jan 1, 1996

By R. L. Grayson

Following lip on a USBM-sponsored research project, the authors have utilized the knowledge-base structure and system concepts from the Sun Sparcstation-based worker scheduling system of the Mine Management Support System to develop a PC-based application. The new software adopts the nested-window concept to facilitate data collection and modification on personnel, their availability on a shift, and work priorities for a shift as well as to allocate manpower optimally on a work shift and delineate supervisory training responsibilities. The various components of the software are described in detail, along with enhancements made to the original system.

Jan 1, 1996

By T. W. Eddy

Research was conducted in which elemental mercury and its sulfide mineral (cinnabar) are removed from a copper sulfide concentrate by low temperature thermal applications. The goal of this research was to reduce, volatilize, and collect mercury vapor from concentrated smelter feed in a simulated drying environment while maintaining the chemical integrity of the residual. The study used synthesized concentrates composed of copper sulfide and mercury bearing minerals (such as cinnabar (HgS) or elemental mercury) to determine optimal residence times and temperature ranges.

Jan 1, 1996

By Y. C. Guan

In an attempt to replace the traditional cyanide process of extracting gold, a new technology using ammoniacal solutions has been developed. In this study, the electrochemical behavior of gold in ammoniacal solutions at temperatures above 100°C has been investigated. An electrochemical cell in an autoclave has been introduced to carry out this study. The system consists of a gold working electrode, a platinum counter electrode, and an external saturated calomel electrode (SCE) which is connected to the autoclave system through a Birch wood plug. Techniques used in this study included potentiodynamic polarization, galvanostatic polarization, cyclic voltammetry, and Tafel polarization. The electrochemical reaction mechanisms governing the dissolution process are presented.

Jan 1, 1996

By Felicia F. Peng, Victor Z. Sun, Syd S. Peng

A probability-based analysis method in conjunction with the finite element structure modeling technique to evaluate an entry system stability is developed. Variability of the rock properties and loading surrounding the entry system is taken into consideration to predict a roof stability by using the probability of failure instead of the common safety factor concept. A dynamic programming is applied to establish a recurrence relationship between the degree of potential roof fall and accumulated roof fall index in an area of interested. A probable distribution of roof fall is assessed by using a developed computer program, RFSTAB. The assessment of the roof falling boundary in the longwall entry system is used as the example to illustrate the procedure and effectiveness of this analysis method

Jan 1, 1996