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By Sterling S. Cook

The U.S. Bureau of Mines is conducting core leaching experiments with sulfuric acid on oxide copper ores from the Cyprus Casa Grande and ASARCO Santa Cruz deposits in Arizona to further our understanding of the leaching process in supergene copper ores as it relates to in situ mining. Leach solutions from atacamite mineralization contained 5 to 30 g/l copper and few extraneous ions. Leachant from chrysocolla ores, with grades similar to the atacamite, contained 2 to 9 g/l copper and abundant extraneous ions. Quartz and K-feldspar had no impact on leach solution composition at any acid concentration (up to 40 g/l) while illite and sericite had minimal impact. Biotite, calcium-rich clay and limonite have a significant impact on solution chemistry when there is abundant free acid in solution. High acid concentrations increase acid consumption in ores with abundant biotite and limonite gangue. High acid concentrations can be used in ores with quartz, K-feldspar, and sericite gangues without increasing acid consumption per unit of copper removed.

Jan 1, 1988

By Cao Changlin, Gong Qian, Hu Jiexue

The thiosulfate, effects copper of concentrations of and ammonia ou the extractlon of gold from sulfide gold concentrate have been studied. The experimental results showed that it is possible to reduce thiosulfate concentration. Above 95% of gold extraction was obtained in O. 2M thiosulfate leaching solution in two hours under the suitable conditions. Therefore, the process of washing residue was simplified, the consumption of thiosulfate and the loss of thiosulfate carried were reduced. by washing residued.

Jan 1, 1992

By W lethlean, Laurie Smith

When coarse gold is present in an ore, there are advantages in physically recovering this gold in the grinding section of the ore processing plant. This reduces the risk of the coarse gold being locked up in the grinding section equipment, reduces the quantity of activated carbon to be eluted and reduces the risk of gold passing out of the cyanide leaching circuit only partially dissolved. The free gold may be recovered by various mechanical means utilising the significant difference between the specific gravity of the gold and waste minerals. Frequently, sulphide minerals and ball mill attrition steel in the form of fines and chips are present in the ground ore and behave in a similar manner to the gold in the concentrating process. These materials must be removed to produce a concentrate suitable for direct smelting and several stages of cleaning, sometimes utilising different physical principles, may be required. The removal of these materials invariably results in a loss of gold from the final concentrate. The rejected materials containing significant quantities of gold are returned to the grinding section, consequently the opportunity for a high and early recovery has been lost. The quantity of gold returned to the grinding section will vary according to the number and type of cleaning stages and the physical characteristics of the materials and the gold but surveys of the gravity concentration processes suggest that it may be as high as 50%. To maximise the recovery of gold from the primary gravity concentrate, some operations batch cyanide leach this concentrate with or without additional reagents. The method of agitation and solution recovery vary. The most common method of agitation is by a high-speed propeller mixer and the least expensive but time-consuming method of solution recovery is by decantation after settling and by repeated decant washing. The pregnant gold solution is either introduced into the main ore leaching circuit or the gold is recovered by direct electrowinning. After commissioning in 1994, Union Reefs Gold Mine (URGM) experienced below expected recovery of gold from the gravity concentrate generated from the Knelson Concentrators. It was shown that the recovery into the Knelson Concentrate was high but that the subsequent mechanical concentrating techniques of tabling and magnetic separation resulted in significant gold being returned to the grinding circuit.

Jan 1, 2000

By NA NA

Power point slides

Jan 1, 2000

By A. Pratt, G. Deschênes

This paper quantifies the detrimental effects of pyrite and stibnite on gold leaching kinetics. Means to reduce the effect of these minerals by addition of lead nitrate and oxygen are presented. A significant retarding effect was observed when the pyrite concentration was 20%. A pretreatment with lead nitrate reduced the extent of gold surface coating by Ag, Fe and S. Stibnite, at a concentration as low as 20 ppm, significantly affected the gold leaching kinetics through forming a passivating film of Sb(V) oxide possibly Sb2O5. The most practical way to alleviate the effect of stibnite is to leach the materials at a moderate pH with addition of lead nitrate. A low temperature reduced the efficiency of lead nitrate to counteract the effect of stibnite. The increase of dissolved oxygen is not favourable to alleviate the coating of stibnite on gold.

Jan 1, 2004

By William R. Bond, Jim V. Rouse, Laura L. Damon

As noted by Damon (1990), "The time that a heap (of gold ore) is on the reusable leach pad is of critical economic importance." The Interim Neutralization Study, conducted by Brohm Mining Corporation (Brohm), at the request of the South Dakota Department of Water and Natural Resources and reported by Damon indicated that improvements could be made in leaching and pointed out the need for a better understanding of the gold ore leach procedures. To provide data on an actual heap, personnel from Brohm and GEOCHEM installed a series of pressure/vacuum lysimeters in an active Brohm heap, and conducted subsequent testwork to evaluate the efficiency of leaching. The objectives of the testwork included efforts to:

Jan 1, 1992

By Y. Topkaya, R. E. Johnson, B. R. Palmer, Bruce E. Kurtz, Anatoli Omelian, John I. Choi

This paper relates to hydrometallurgical studies on the recovery of soluble aluminum values from aluminum-bearing ores, i.e., Georgia clays. At least 50% of the soluble alumina values were recovered by leaching the calcined clays from aqueous solutions, comprising simultaneously contacting a stream containing an effective amount of a reducing agent such as sulfur dioxide and a stream containing an effective amount of an oxidizing agent such as chlorine gas for a time sufficient to dissolve alumina. The recovery of alumina from this aqueous slurry of the calcined clay by leaching with sulfur dioxide and chlorine gas showed much better results than that by leaching with concentrated sulfuric acid and/or concentrated hydrochloric acid at 100O C. The leaching reactions between the aqueous slurry of the calcined clay, chlorine gas, and sulfur dioxide were strong exothermic reactions for several hours, requiring no external heating.

Jan 1, 1993

By R. Y. Wan, Corby G. Anderson, L. Ernest Krys, M. C. Fuerstenau

Since 1942, refractory precious metal concentrates at the Sunshine mine have been processed for antimony metal recovery using a novel leach-electrowin method. This is counter to most antimony production facilities where pyrometallurgical techniques are usually relied upon. The key step for removal of the antimony has been an ambient pressure alkaline sulfide leach. In 1990, a comprehensive laboratory study was undertaken to better understand this process. Factors studied included temperature, agitation, concentrate regrind, alkaline species concentrations, sulfur species concentrations and solids concentration. Details of these studies, as well as a brief description of Sunshine metallurgical processes, will be presented.

Jan 1, 1993

By Fathi Habashi

THE MOST important arsenic minerals are shown in Table 6-1. The recovery of arsenic from arsenic sulfides is treated in Chapter Four. Arsenical ores may be either leached directly, or first smelted to volatilize as much arsenic and sulfur as possible, and the resulting product, called speiss, is then leached. A speiss is mainly a complex mixture of metal arsenides, but its [Table 6-1. Arsenic minerals. Arsenides Niccolite NiS Smaltite CoAs2 Skutterudite CoAs3 Sulfarsenides Cobaltite CoAsS Enargite CuaAsS4 Arsenopyrite FeAsS Arsenic sulfides Realgar As4S4 Orpiment As2S3] composition varies widely, depending on the type of ore treated. A speiss usually contains 15-35% arsenic. Methods of leaching are describedd in the following paragraphs.

Jan 1, 1970

By G. M. Wenberg

Bacterial leaching of copper and uranium is practiced in environments containing available sulfur and iron and having a strong acidic reaction. However, many mineral deposits do not have these conditions; the chalcocite and native copper ores in Michigan's Upper Peninsula are examples. Bacterial and fungal populations were observed in samples taken from the White Pine Copper Company tailing pond and mine, and isolates were prepared of the dominant species. The isolates were then screened for solubilization of copper from tailing, ore, and concentrate during incuba¬tion in a carbon and nitrogen supplying medium. Certain Penicillium fungi solubilized significant amounts of copper under neutral to slightly acidic conditions. Leaching apparently was accomplished by release into the medium of metabolites which chelated with the copper.- The process was found to be highly dependent upon the medium and the concentration of copper in the source material. The paper describes sampling and screening techniques, presents the results of experimentation to standardize procedures and maximize the yield of copper, and discusses the nature of the leaching process. This preliminary research reveals a biological process which may find use in mineral extractions but whether it can be applied economically remains to be determined.

Jan 1, 1969

By Alafara A. Baba, Yakubu A. Dallatu, Kehinde I. Omoniyi, Shemang Y. Chindo, Edith B. Agbaji

With the rise in global demand for pure copper, there is an urgent need to consider the processing of low-grade chalcopyrite ores. Ammoniacal leaching solutions have been reported as effective and efficient leachants for the dissolution of chalcopyrite. This work reports on different parameters that influence the leaching kinetics of a Nigerian chalcopyrite-rich siderite ore obtained from the Wase local government area of Plateau state, Nigeria, and assayed as 11.30 weight percent copper.

May 1, 2023

By Alafara A. Baba, Yakubu A. Dallatu, Kehinde I. Omoniyi, Shemang Y. Chindo, Edith B. Agbaji

As a result of the rise in global demand for pure copper, there is urgent need to consider the processing of low-grade chalcopyrite ores. Ammoniacal leaching solutions have been reported as an effective and efficient leachant for the dissolution of chalcopyrite. This work reports different parameters that influence the leaching kinetics of a Nigerian chalcopyrite-rich siderite ore obtained from Wase Local Government Area, Plateau State, Nigeria, and assayed as 11.30 wt% of Cu. At the optimum leaching conditions (0.4 mol/L NH3-( NH4)2SO4 leachant concentration; 75 °C reaction temperature; 45 μm particle size), the extent of chalcopyrite ore dissolution reached 87.4% within 120 min. The dissolution rate was affirmed to conform to the diffusion control mechanism with the activation energy, Ea, of 38.84 kJ/mol and a reaction order of 0.661 for the leachant concentration being established. The leaching mechanism was affirmed by characterizing the raw ore and the leached product by XRD and SEM-EDS analysis. Ascertaining optimal leaching conditions for copper using alkaline leachant is advantageous from the environment and economic points of view.

Jan 6, 2023

By G. Deschênes

In an earlier study (Deschênes et al., 2009), gold and silver were shown to be efficiently extracted from samples taken from the Kupol Mine in Russia using lead nitrate in a cyanide leach system. In the current study, a com-parison of the technical and economic merits of a new technology called CANMET enhanced leaching process (CELP) was made with the cyanidation/acidification-volatilization-recycling (AVR) process using eight metal-lurgical variability samples, as well as a large composite sample, which was to represent the initial two years of Kupol mill feed. The composite sample leach feed assayed 33.4 g/t Au and 289 g/t Ag. The metallurgical results from the large composite sample demonstrated that CELP produced very similar gold and slightly higher silver leach extractions compared to the conventional cyanidation/AVR leach conditions at 1/2 the cyanide concentra-tion (1,000 ppm NaCN in CELP vs. 2,000 ppm for cyanidation/AVR leach conditions). It was estimated that the total cost per ton was approximately the same for the two technologies (total cost of CELP with the use of Merrill-Crowe at $46.48/t, with cyanidation/AVR at $46.13/t). However, the implementation of CELP would eliminate a capital expenditure of approximately $5 million for an AVR system based on a 2005 feasibility level cost estimate. Eight variability samples used to confirm the composite sample results showed that, on average, the gold leach extractions with CELP and the conventional leach conditions were very similar, but the average silver leach extraction was 2.1% higher for CELP. Furthermore, CELP silver leach extraction was 4.6% higher on average compared to conventional cyanidation for the four mid-grade variability samples evaluated. The decision was made to remove AVR cyanide recovery from the flowsheet and implement CELP at Kupol. The ability to use the conventional leach equipment with CELP and simplify the flowsheet was also a factor, given the remote location of the Kupol Mine.

Jan 1, 2010

By G. Deschênes

In Part I of the work, gold and silver were shown to be efficiently extracted from Kupol samples using lead nitrate in a cyanide leach system. In Part II, a comparison of the technical and economic merits of a new technology called CELP (CANMET Enhanced Leaching Process) was made with the cyanidation/AVR(Acidification-Volatilization-Recycling) process using 8 metallurgical variability samples as well as a large composite sample which represented initial two years of Kupol mill feed. The composite sample had 33.4 g/t Au and 289 g/t Ag. The metallurgical demonstrated that the CELP produced very similar gold and silver leach extractions compared to the standard Cyanidation /AVR leach conditions at 1/2 the cyanide concentration (1000 ppm NaCN in CELP vs. 2000 ppm for cyanidation/AVR leach conditions). It was estimated that the total cost per ton, were approximately the same for the two technologies (total cost of the CELP with the use of Merrill-Crowe at $46.48/ton, with cyanidation/AVR at $46.13/ton). However, the implementation of the CELP would eliminate a capital expenditure of approximately $5 million. Eight variability samples used to confirm the previous results showed that on average the gold and silver leach extractions with the CELP and the feasibility leach conditions were very similar for gold extractions, but 4.6% higher for silver extractions compared to the conventional cyanidation. The decision was made to remove AVR cyanide recovery from the Kupol flowsheet and implement the CELP at Kupol. The ability to use conventional leach equipment with the CELP and simplify the flowsheet was also a factor, given the remote location of the Kupol Mine.

Jan 1, 2009

By F. Milton Lewis

Several alternatives are available for treating lover grade gold ores averaging 0.04 to 0.10 ounce per ton. These include heap, vat and agitation leaching and may involve conventional zinc precipitation or carbon adsorption-electrowinning systems. Each of these processes have their inherent economic and operating advantages and disadvantages and the selection of the optimum method for a given gold ore is solely based on economic evaluation of the applicable processes. In this paper an effort is made to provide engineering feasibility estimates for the above processes under varying operational conditions such as ore grade and price of gold.

Jan 1, 1974

By Fathi Habashi

METALS COMMONLY leached may come from one of the following sources: 1) Occurring in nature in the native state, e.g., gold, silver, platinum metals, copper. 2) Produced as by-product of a metallurgical process, e.g., gold, silver, platinum metals, selenium. 3) Produced by reduction of an oxide ore, e.g., copper, nickel. GOLD AND SILVER Cyanidation According to Mellor (1923) the alchemists of the eighteenth century knew that gold was soluble in aqueous solution of potassium cyanide, and the early jewelers probably utilized this fact in gilding. He also mentions that Scheele in 1783 and later Bagration in 1843 noted the solvent action of aqueous solutions of alkali cyanides on gold. Yet it was not until 1887 that the value of this observation was recognized, when MacArthur and Forrest (1887) made use of it in leaching gold from its ores. Since then, the process has spread to every gold and silver mining district in the world.

Jan 1, 1970

By Bernard Scheiner

A number of wells were drilled at two phosphogypsum stacks, one at P-21 owned by IMC and the other at Agrico's South Pierce Stack. Each well was sampled, and composites representing 5-ft increments were leached with synthetic rainwater to determine the extent of metal and nonmetal migration. To simulate what was occurring in the stack, composite samples were placed in a column, so that the column represented the stack in miniature form. Leaching experiments showed that both metals and nonmetals moved down the column when water was added to the top of the column. Data obtained from P-21 showed that with time the concentration of metals and nonmetals reached equilibrium values. The concentration of Ca, SO4, F, Si, and PO4 were -600 ppm,~1,500 ppm, 32 ppm, 14 ppm, and 22 ppm, respectively. Column leaching of South Pierce material, representing 0 to 55 ft of stack, showed that after 355 in. of water, the stack was near equilibrium values down to the 33-ft level. With continued addition of water, the portion of the stack at equilibrium would continue to increase and eventually reach the values observed for P-21. The test showed that the sulfate concentration of the effluent from the stack would never reach the USEPA standard value of 250 ppm. During the leaching test, it was determined that the permeability of the phosphogypsum in the columns was 0.000103 cm/sec. This number was used in the modeling. The data obtained from the leaching experiments cast some doubt on the practice of entombment now being practiced for closure of phosphogypsum stacks. The data clearly shows that with time, the amount of material leaching from the stack is low in concentration, with only the calcium and sulfate at higher levels. When a stack is closed at an existing operating plant, allowing rainwater to fall on the stack and capturing the solution in the existing pond system would eliminate the need for covering the stack, since with time the closed stack would continue to leach and at some point reach the equilibrium values of the P-21 stack. Entombment means that the leachable material in the stack will always be there and will require monitoring forever. Allowing rainwater to decontaminate the stack may be the best environmental solution to the problem.

Jan 1, 1999

By J. M. Scharer, Bruce E. Halbert, Lysane Bouduc, Douglas B. Chambers, Jennifer L. Kirkaldy, Carol M. Pettit

Io contrast to acid mine drainage (AMD), neutral mine drainage (NMD) has not yet received widespread attention. Metal and sulphate concentrations can be elevated and of concern in neutral drainage from waste rock and tailings. In the present paper, metal release in high ionic strength mine drainage at neutral pH is evaluated at several mine sites. Specific factors including oxidation rates, buffering capacity, and hydrology are also addressed and their effect on the production of contaminated NMD from mine wastes is evaluated. Case studies are presented involving current seepage water quality and predictive geochemical modelling to illustrate the possible time frame and magnitude of the contamination.

Jan 1, 2000

By R. J. Roman

The results of column leaching tests on 3 different mixed oxide/sulfide ores from a Chilean deposit are presented. The 3 samples contained different ratios of oxide copper minerals to chalcocite and chalcopyrite. The results of the column leach tests are interpreted in light of the shrinking core model for coarse particle leaching. The copper recovery from the oxide minerals and the sulfide minerals each conforms to the shrinking core model with the total recovery equal to the weighted average of the individual minerals. The use of column test results to predict field heap leaching results using the multi-mineral shrinking core model is discussed.

Jan 1, 1993

By S. P. Fleming

An acid mine drainage sludge containing 0.26% nickel, 0.21 % cobalt and 4.5% manganese was leached in a one-liter reactor with sulfuric acid in the absence and presence of sodium sulfite. The effects of temperature (25°C and 52°C) and sodium sulfite concentration (up to 0.03 molar) on the leaching rate were particularly investigated. The leaching rates of nickel and cobalt with sulfuric acid have been determined to be controlled by diffusion through product layer. It has been found that effective leaching conditions to give more than 90% extraction of nickel, cobalt and manganese while keeping the iron extraction below 10% come with an elevated temperature and a low sodium sulfite concentration at pH 3; for example, 52°C and 0.01 molar sodium sulfite.

Jan 1, 1992