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By K. S. Venkataraman

The physical properties of clay-water systems depend on the complicated system of forces between the clay particles themselves, and between the clay particles and the ions in the liquid phase. The kind and distribution of ions in, on, and between the clay particles and the size and the shape of the particles are the basic factors determining the macroscopic behavior of clay-water systems. Understanding the system requires a knowledge of the nature of the clay particles, their size, structure, composition, and surface properties, and of the manner in which they interact with ions [and molecules] in the surrounding liquid [or other medium]. The validity of Professor Brindley's words (Brindley, 1958), written three decades ago in the context of making pottery, whitewares, and electrical porcelains, transcends time, and the basic message is perhaps all the more important in the considerably expanded use of ceramics for structural, thermal, tribological, electronic, and other applications. Silicon carbide, silicon nitride, and sialons have been studied in the last two decades for high- temperature structural and tribological applications, particularly for using in internal combustion engines. Titanates, zirconates and niobates of barium, strontium and lead, have high dielectric constants, and are extensively used in the formulations for making capacitors. Hexagonal ferrites (molecular formula MO.6Fe2O3) are in use for making permanent magnets for fabricating miniature motors, and for assembling loud speakers, particle accelerators etc. Cubic ferrites such as magnesium-zinc ferrite and nickel-zinc ferrite are used as transformer cores, and for other high-frequency applications. In this context, Richerson's recent book (Richerson, 1984) on the general scope of traditional and technical ceramics is a good starting point for an overview of contemporary ceramics technology. Glasses are a whole class of amorphous materials used widely as sintering aids, and for making glass-bonded ceramics and glass-ceramic composites. Composites are yet another burgeoning field where two or more particulate components are used for improving the performance of ceramics. For all these applications, the inorganic starting materials are almost always submicron and near-micron powders. Understanding the powders' physicochemical properties, and their surface chemical interactions with the surrounding liquid/gaseous medium is-necessary for making reliable ceramic parts at competitive prices. Even though ceramics science and engineering has attained its separate identity in universities and the industry, ceramists themselves would concede that ceramics science is a cross-disciplinary field, having incorporated and assimilated within itself many principles from several apparently disjointed disciplines. Principles of material science, graduate-level physics and chemistry, polymer science, surface and colloid chemistry, transport phenomena, particle technology, unit operations commonly used in chemical engineering and mineral processing, and statistics and applied mathematics are integral part of any ceramics curriculum in universities. Added to this is the fact that all bench-scale successes in making ceramic parts are to be scaled-up for larger throughput operations. Understanding and applying process engineering principles of comminution, classification, drying, calcination, etc. then becomes essential. CERAMIC FORMING: Despite the diversity of the materials and processes, conceptually, the steps involved in making ceramic parts have remained the same over several decades: The different components for making the pan (usually one or more powders plus other forming and sintering additives) are proportioned and mixed thoroughly, and the well-mixed formulations are consolidated into desirable shapes known as "green bodies." Usually binders such as wax, clay, organic polymers and surfactants, whether dispersed or dissolved in a suitable liquid are used during mixing the batch for giving strength for the green bodies. In the dried green state, the inorganic powders typically occupy only 55 to 60% of the bulk volume of the body, depending on the particle size distributions of the powders and the forming history, with mostly inter- particle voids accounting for the rest of the void volume. SINTERING: The formed bodies are then fired in high- temperatures kilns/furnaces during which the parts are exposed to a predetermined temperature profile, and "soaked" for a certain duration at the final high temperatures, typically between 1200 K and 1900 K, and then cooled to room temperature. The gaseous atmosphere in the furnace is controlled (oxidizing, reducing, or inert) when necessary. During the initial stages of firing, volatile liquids evaporate, and during the intermediate temperatures between 400 and 600 K, the the organic polymeric additives pyrolize and oxidize into water vapor, CO, C02, and other gases. At still high temperature, the glasses, when present, soften, and simultaneously, the ceramic particles rearrange into a network of grains with definite grain boundaries so as to reduce the total interfacial free

Jan 1, 1990

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Jan 1, 1985

By A. L. Hinde

The recovery of heavy minerals by gravity concentration during grinding is practised widely in the minerals industry. Studies have shown that the grade and recovery of the concentrate depends not only on the performance of the concentrator but also on the degree of liberation achieved in the mills and the scavenging action of the hydrocyclones closing the grinding circuit. In the current study, consideration is given to the development of mathematical models to quantify and unify the operations of comminution, liberation, classification and concentration. The models are based on test work done at production scale with gold ore.

Jan 1, 1985

By J. G. Groppo

Froth flotation has been shown to be an effective method for reducing Loss-on-Ignition (LOI) of ponded or landfilled fly ash. Reduction of LOI is required for many fly ashes, particularly those produced from low-No, burners, in order to meet ASTM requirements for use as a mineral admixture in Portland cement concrete. An additional ASTM requirement, fineness, is critical in determining end use applicability, and in many cases, classification of fly ash is necessary to produce an acceptable product. Hydraulic classification has been shown to be a simple, cost-effective method for classification of a variety of minerals including silica, phosphate, mica, coal, etc. and has shown to be similarly effective on fly ash. The combination of froth flotation and hydraulic classification facilitate the production of a high quality pozzolan that meets or exceeds ASTM specifications. This combination has been rigorously evaluated and results of pilot-scale testing are presented. Pilot scale testing was conducted on fly ash from two active utility storage ponds and demonstrated that high quality, consistent pozzolan could be produced using APT's Fast Float? Technology. Along with the pozzolan, additional production of aggregate for masonry mortar and a low sulfur, medium Btu fuel were also demonstrated. The Fast Float? process incorporates several simple unit processes to ensure pozzolan consistency; classification controls particle size distribution which is critical to achieving early strength, flotation controls the grade with respect to L.O.I. (Loss on Ignition) while dewatering controls the moisture content.

Jan 1, 1998

By J. G. Groppo, T. L. Robl, C. J. McCormick, W. M. Lewis

The combination of froth flotation and hydraulic classification can facilitate the production of a high-quality pozzolan that meets or exceeds ASTM specifications. This combination has been rigorously evaluated and results of pilot-scale testing are presented. Pilot-scale testing was conducted on fly ash from two active electric utility storage ponds. The tests demonstrated that a high-quality and consistent pozzolan could be produced using Advanced Pozzolan Technologies' Fast Float™ Process. Along with the pozzolan, the additional production of aggregate for masonry mortar and the production of a low sulfur, medium-Btu fuel were also demonstrated. The Fast Float™ Process incorporates several simple unit processes to ensure pozzolan consistency. Classification controls the particle size distribution, which is critical for achieving early strength;flotation controls the grade with respect to L.O.I.; and dewatering controls the moisture content.

Jan 1, 2000

The concept of classification in wet, closed circuit ball milling is expanded beyond the performance of the classifying equipment to include all aspects of the fines removal system of the grinding circuit. Design and operating parameters that effect fines removal are identified and discussed, and a quantitative index for circuit classification effectiveness is presented.

Jan 1, 1987

The concept of "classification is expanded beyond the performance of the classifying equipment to include all aspects of the fines removal system of the grinding circuit. Design and operating parameters which affect fines removal are identified and discussed, and a quantitative index for circuit fines removal effectiveness is defined. This approach lends new interpretation to certain observed phenomena, and suggests useful guidelines for circuit design and operation.

Jan 1, 1985

By K. Holmberg, D. Herriot

This paper by Mr. McIvor is yet another contribution to the eternal controversy surrounding the benefits, or otherwise, of high circulating loads in closed circuit grinding. Throughout the paper it is difficult to establish whether the author is referring to effects relating to the mill, classifier, or to the overall circuit. Table 1 is put forward as indicating the advantage of operating at high circulating loads. From the two (it would be interesting to see more) product sizing points provided in each case, the conclusions to be drawn are that cases one and two have very similar size analyses. The third case, however, indicates a much flatter curve, that is to say, higher fines production and a very wide spread of size ranges. If the objective of this circuit is to provide a closely sized product with minimum overground slimes to the downstream process, then it would appear to be the less "efficient" by far. No data is given for product pulp densities either. The term "efficiency" should never be used without a careful and clear definition. In this case, "efficiency" is used to express an apparent percentage reduction in operating work index (Bond) from the measured "standard" at 250% circulating load operation. The Bond calculation is itself based upon

Jan 1, 1990

By Donald A. Dahlstrom, Wai-Ping Kam

The mineral industry and individual processing plants are large consumers of energy. While energy conservation has received some attention in the present Federal Administration National Energy Strategy proposal it is obvious that the mineral industry should also continue to emphasize energy consumption reduction for important economic savings alone. As indicated by other studies, comminution is the largest single consumer of energy in the mineral processing plant (1.3% of total electrical energy consumption in the U.S.A.).1 Fine grinding is the largest portion of this amazing statistic. While substantial energy savings have been demonstrated by new machine developments and improved control methods, undoubtedly there are additional areas in comminution where substantial progress can be made. Some time ago, the U.S. Department of Energy published a report on "Comminution and Energy Consumption" by a committee composed of experts in the field of comminution from industry and academia. They identified the following potential for energy savings by specific areas? Classification device design 9-13% Comminution device design 3-16% Control 9% Grinding additive 3-6% Materials 3% It is apparent that the classification device had the first or second highest savings potential. Obviously, serious research consideration must be given to this technology area. A series of three papers have previously been written on the subject of two stage classification research work for ball mill operation by the authors. Accordingly, a brief review will be made. Previous Research Results on Two Stage Classification The hydrocyclone was selected as the type of classification equipment for this study as it represents by far the majority of the devices used in ball milling. While four different hydrocyclone circuits have been proposed by others,3 only two were considered in this work as illustrated in Figure 1. Flowsheet A is truly counter-current in nature in that the product from the ball milling circuit is taken from the first stage overflow

Jan 1, 1992

By Ping Zhang, Shahram Mozaffari, Andreas Ylmefors

The risk associated with mining induced seismicity and the related rock bursts has become one of the major threats to the safety and sustainability of mining at the Kiirunavaara mine. The causes of mining induced seismicity at the Kiirunavaara mine are very complex and have affected our understanding on the source mechanisms of seismicity and further the mitigation of the seismic risk. Detailed analysis of historical mining induced seismicity at the Kiirunavaara mine was conducted. The focus of this analysis was placed on the classification of large seismic events and the evaluation of the influential factors on the classified seismic events. 145 events with local magnitude larger than 1.5 that occurred between January 1, 2011 and March 31, 2021 were analyzed. For this analysis, seismic events located in the hanging wall were not included, as these have not been observed to cause large damages to the mine itself. It was found that the magnitude of the events had good correlation with the stress change in relation to the production location. The seismic events were classified as mining-front associated, ore-pass associated, mining-front and ore-pass associated and others, according to their hypocenter location. Most of the mining-front associated events, concentrated around the production levels and slightly above and below them, generally correlated with shear cracks, and most of them occurred when the ore flow between two production levels started. The numerical modelling showed that slip of the geological discontinuity, due to unclamping between hanging wall and footwall, could be the major causative mechanisms, which further supports this finding. The ore-pass associated events are located close to the ore passes. Large seismic events located between ore passes have the source mechanism of both fault-slip and non-shear, but events located at the outer side of ore passes were all fault-slip type. By checking with the ore pass scanning data, it was concluded that the most of the events located between ore passes could be pillar bursts. An elastic core concept has been then used to define a critical pillar width. The paper is not intended to be prescriptive but rather to initiate discussion of the possible classification of seismic events at the Kiirunavaara mine and to present new perspectives of the causes of the seismicity for improving the present seismic risk management.

Apr 26, 2022

By L. A. Readdy

Defining classes of ore using geostatistical methods that match historical classifications has presented problems in the past. A simplistic and practical approach to this problem is presented. An example of the approach is presented using a porphyry type system as a case study. The technique described uses area of drill hole influence and known conditions from similar deposits, or the production history of the deposit being studied. It provides a practical bridging mechanism for defining the class of ore on a block-by-block basis using .the error of estimation value developed during kreiging. The approach provides a filtering method that refocuses attention on the adequacy of drill hole spacing.

Jan 1, 1985

By Nick Barton

The ability to estimate that support is unnecessary for various dimensions of opening in certain rock mass environments is of particular relevance in the mining industry, where most excavations are not expected to remain open indefinitely. As Hoek1 observes: "the basic aim of any underground excavation design should be to utilize the rock itself as the principal structural material, creating as little disturbance as possible during the excavation process and adding as little as possible in the way of concrete or steel support". Approximately two hundred case records have been analysed for the purpose of determining the amount of permanent support normally used when a given span is excavated in known rock mass conditions Some thirty cases concerned unsupported openings. Excavations that can stand unsupported appear to have certain common characteristics as regards rock mass quality. However, the mechanical properties of the rock mass are not the only factors controlling the choice of design. The dimension of the opening (span or height) and the type of excavation are two important variables.

Jan 1, 1975

By W. C. Patrick

Introduction The availability of a thorough, simple-to-use roof fall classification system is desirable for several reasons. First, such a system would expedite the reporting of falls for the purposes of estimating material removal costs, analyzing damage levels, and complying with federal regulations to report falls in certain areas of the mine. Second, the classification system would allow the mining engineer to record falls routinely with little time and effort expended. This would encourage him to make observations concerning what type of roof support would work best in a given situation. Third, and probably most important, an adequate roof fall classification system is the first step toward developing a means of predicting the occurrence and extent of future falls. It was with these three reasons in mind that the following classification system was developed. The type of classification chosen reflects the background of the developer and the intended purposes of the system. Hylbert has proposed a geologic-based classification which groups falls as to structural and compositional origin. The need for similar systems is noted by Cox and by Ferm and Melton. Each of these researchers is confronted with a situation requiring a relationship between local geology and roof fall occurrence. Such a relationship would allow the prediction of the relative frequency of falls from a knowledge of local geologic features. The current research is aimed at fulfilling somewhat different requirements, as noted above. Fall geometry has been chosen as the basis of the classification system so fall type can be reported independent of local geological, environmental, and tectonic conditions. This approach parallels that used in the common slope failure classification with groups failures relatively independent of

Jan 1, 1977

By A. J. Rergis

During the past ten years a number of papers have appeared describing zeolite occurrences in the western United States in Mesozoic sedimentary rocks, altered bedded Tertiary pyroclastics, playa lakes, hot springs, and amygdaloidal basalts. With the emergence of natural zeolites as economic industrial minerals it appears, useful to develop a system of classification to delineate those zeolite deposits of economic interest which were not discovered until the middle 1950's. The first attempt at a classification of naturally occurring zeolites was made in 1914 by Lindgren l when he classified the zeolites into eleven groups based on their mode of occurrence. The zoned zeolites in the Mesozoic rocks of New Zealand and elsewhere were classified according to the mineral assemblages by Fyfe, et al.2 in 1958 as a zeolite facies corresponding to low grade regional metamorphism. In 1966, Hay suggested as an alternative to the preceding classification one which would "classify as diagenetic all mineral assemblages produced in sedimentary rocks under conditions in which zeolites are formed." In this paper a classification is proposed with the objective of providing an overall perspective of the zeolite occurrences in the western United States.

Jan 1, 1967

By B. Fitch, E. J. Roberts

Definitions and Terminology Classification is defined within this section as the separation of solid particles into size or weight fractions or classes by differential settling through a fluid. It is usually thought of as a size separation, but is actually made on the basis of particle settling rate, and so is affected by any variations in particle density and shape. The fluid may be liquid (wet classification) or gas (dry or air classification). This section will treat only wet classification. There are two basic types of classification; pool and hydraulic. In pool classification a suspension of feed particles is fed into and out of a pool of some kind at such a rate that only part of them¬ the coarser and faster-settling part-has time to settle out. The remain¬der overflows as fines. In hydraulic classification the feed suspension is introduced into or above one or more columns or pockets through which water is rising at a controlled velocity. Coarse particles subside through the pockets and are removed through spigots. Those which settle slower than the rising velocity in any column or pocket are (at least ideally) prevented from subsiding and so must overflow. Hydraulic classifiers or sizers are capable of making far sharper sepa¬rations than pool classifiers. The force causing settling may be gravity, or alternatively may be from centrifugal acceleration as developed in a centrifuge or hydra cyclone. Two things are needed to characterize the separation produced by classification: first, the size, D„ or equivalently the screen mesh at which it is made; second the sharpness of separation. Separation size may be defined in various ways. In closed-circuit grinding it is commonly specified by some point in the overflow screen analysis: For example, 5% on 65 mesh. In other applications, notably

Jan 1, 1985

By A. Vaillant

Classifiers that are used to separate granular materials into a coarse and a fine stream, are considered. Fundamental Equations are presented which apply to all, such Classifiers and all feed size distributions. The practical, real Classifier is compared quantitatively with the perfect. Classifier. A Formula is introduced for the Real Classifier Selectivity, that defines what portion of each particle size is sent to the coarse outlet duct. This selectivity function is characterized by three Parameters, one of which (b) is a numerical measure of the sharpness of classification. A new dimensionless variable (J) appears in Equations and Graphs for recirculating load, product size distribution and specific surface in the classified product. This variable combines the effects of sharpness of separation, Classifier setting and fineness of a Rosin-Rammler Type feed to the Classifier. Classifier efficiency is defined, based on Specific Surface.

Jan 1, 1967

By P. T. Luckie

Analysis of classifier performance independently of a closed grinding circuit configuration may result in a poor match-up between the grinding device and the classifying device. This paper examines the relationship between classifier and grinding device in dry grinding circuits by employing a semi-empirical methodology.

Jan 1, 1980

A clay binding agent has been investigated to enhance flotation recovery of bitumen from Canadian high fines oil sand in the Clark Hot Water Extraction (CHWE) process. Selective adsorption on fine particles and subsequent agglomeration are critical for the success of clay binder enhanced oil sand flotation. A number of flotation tests have been performed at different reagent dosages under different operating conditions such as pulp pH to evaluate the reagent performance. Dissipative Quartz Crystal Microbalance (QCM-D) analyses of clay binder adsorption on quartz were carried out to better understand process mechanisms. It has been found that use of clay binder in flotation resulted in an absolute bitumen recovery increase of 18%, 25%, and 11% for the high-, medium-, and low-grade oil sand samples, respectively. The QCM-D analyses have revealed that the clay binder was strongly adsorbed on the SiO2 surface.

Jan 1, 2012

By D. Tao

The presence of insoluble slimes in potash ore poses a serious processing problem to the potash industry. These insolubles must be removed prior to potash flotation because of their high adsorptive capacity for amines which are generally used as collectors in the subsequent sylvite flotation. This is usually accomplished by scrubbing of the ore in brine followed by hydrocyclone classification to separate slimes from the salt particles. Insoluble slimes that remain in the ore after the desliming procedure are depressed by reagents such as guar gum or starch during sylvite flotation. In this research, the feasibility of using GP clay binders to replace guar gum for potash flotation was investigated. Batch mechanical flotation tests were conducted with the potash samples provided by a leading potash company. It has been found that GP clay binders increased potash concentrate yield and recovery at the same product grade. Effects on potash flotation efficiency of flotation process parameters such as impeller rotation speed, slurry temperature, binder type, dosage and conditioning time have been investigated to establish the optimum conditions for flotation. Binder GP374G33 has been identified as the optimum substitute for guar gum as slime depressant in potash flotation.

Jan 1, 2008

By H. H. Murray

Industrial usage of clays for current and new applications will continue to grow into the next century. The rate of growth will be highest in the less developed areas of the world. Transportation costs are a significant part of the delivered price, so the location of reserves and processing facilities for kaolin, bentonite, and palygorskite (attapulgite) are reviewed relative to serving these emerging markets. New value added applications will increase in the more developed areas which will require high quality raw materials, more sophisticated processing, and rigorous quality control.

Jan 1, 1998