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By W. A. Selvig

[THE BUREAU OF MINES receives many requests for information regarding the low-temperature carbonization properties of American coals. This report presents in collected form the results of Fischer-Schrader bench-scale, low-temperature carbonization assays at 500° C. made by the Chemistry and Physics Section at the Pittsburgh station of the Bureau of Mines. Most of the assays were made of coals tested in connection with a survey of gas and coke-making properties of American coals,4 which was started in 1928 by the Bureau in cooperation with the American Gas Association. Other coals were assayed in connection with miscellaneous investigations. Since 1930 about 400 samples of coal were assayed from nearly every coal-producing State, Alaska, and British Columbia, Canada. The results of the tests on about two-thirds of the coals are scattered through more than 50 separate publications. This paper summarizes the data in the published reports as well as all unpublished data obtained to January 1, 1956. The report also includes a detailed description of the procedure used in making the assay.]

Jan 1, 1957

Early in 1936 the Interstate Oil Compact Commission and other groups interested in forecasts of demand for petroleum requested the Bureau of Mines to make a physical inventory of crude-oil stocks in the United States. Accordingly, the 74th Congress -appropriated funds for conducting such a survey during the fiscal year ended June 30, 1937. In the discussions end hearings2/ relative to the need for the survey, the opinion was expressed that crude oil held is storage for long periods had lost so much of its gasoline content that the economic significance of total stocks should be discounted materially. Therefore, a primary objective of the survey was to

Jan 1, 1938

By William W. Adams

Accidents to men employed in the quarrying and related industries of the United States were more numerous, absolutely and relatively, in 1937 than in 1936. Fortunately, the entire increase was in the category of nonfatal injuries, as accidents causing death declined in number and in proportion to the number of man-hours worked. Employment increased. More men were employed, more man-days and man-hours were worked, and the average employee had more hours of work than in 1936. Reports covering all commercial operations showed that 84,094 men were employed an increase of 5.1 percent over 1936. The number of man-hours of work performed by the industry was, 158 millions, an increase of 7.6 percent. Seventy-seven men were killed by accidents, a, reduction of 14 from the year before, and 6,348 men were injured and disabled for more than the remainder of the day on which the accident occurred, 11 percent more than in 1936. The fatality rate of 0.49 per million man-hours of exposure in 1937 compared favorably with the rate of 0.62 for the previous year, whereas the non-fatal-injury rate of 40.10 was 3.2 percent higher than the rate of 38.87 for 1936.

Jan 1, 1940

By R. F. Stewart

A key step in changing coals to fluid fuels and chemicals is the conversion of coal to synthesis gas by gasification with steam and oxygen. As oxygen represents one of the largest single expenses in gasification, its cost is a vital factor in the economy of the process. At present, the most economical method for producing tonnage oxygen is by the conventional rectification of liquefied air. Several alternate methods have been proposed for producing oxygen from air: (1) methods based on physical or chemical sorption of oxygen from air by liquids or solids or (2) the oxidation of certain inorganic com-pounds to higher oxides unstable at higher temperature levels. Economic limitations are discussed by which these methods may be evaluated. Chelated metals of the salcomine type are promising chemical sorbents of oxygen from air. This report covers a study of the reversible sorption of oxygen by salcomine and other chelates. The presence of water in the salcomine structure was verified; it is the loss of this water that causes slow deterioration of salcomine during cycling.

Jan 1, 1959

By Launa G. Mallett, Charles Vaught

This report is intended to help mine safety trainers better prepare to teach the influx of new underground coal miners who are entering the industry. This is done by identifying two different approaches to instruction and discussing the ways they may affect how well prepared new hires are to deal with a dynamic and hazardous workplace. One approach is based on the use of a syllabus. Those using a syllabus are more likely to rely on lecturing or direct instruction. This is a good way to get across factual information, but does not provide a context within which miners can fit the discrete facts so that they form an integrated whole set of concepts, principles, and skills. The other approach is based on the use of a curriculum. Those using a curriculum may be more likely to help miners integrate concepts and skills that give them an overall picture of the complex mining environment and how they fit into the workplace. This will better prepare them for the decision-making and problem-solving activities that will help them work safely and productively

Jan 1, 2008

By Dennis R. Dolinar, Christopher Mark, Gregory M. Molinda

Despite more than half a century of experience with roof bolting, no design method has received wide acceptance. To begin to improve this situation, National Institute for Occupational Safety and Health (NIOSH) conducted a statistical study of roof bolt performance at a number of mines throughout the U.S. Case histories were collected from 37 mines with a variety of roof bolt types and patterns in a wide range of geologic environments. Performance was measured in terms of the number of roof falls that occurred per10,000 ft of drivage. The study found that roof falls are rare when the roof is strong and the stress is low, even with light roof bolting patterns. The focus of this paper is on the more difficult conditions, where the roof is weaker and/or the stress is higher. Analysis of the results led to guidelines that can be used to make preliminary estimates of the required bolt length, capacity, and pattern. The guidelines are based on the depth of cover (which correlates with stress) and the roof quality (measured by the Coal Mine Roof Rating (CMRR), and the intersection span. Another contribution is a formula for estimating the horizontal stress level in the eastern U.S. coalfields as a function of the depth of cover. The design guidelines are currently being implemented into a computer program called Analysis of Roof Bolt Systems (ARBS).

By D. J. Stoops

The object of the research described in this paper was to investigate the effect of metallurgical and surface treatments on the corrosion behavior of arc-melted reactor-grade zirconium in cupric or ferric chloride solutions. An apparatus was constructed and specimens of various metallurgical conditions and surface treatments were tested for 6 days at 35° C., with aeration. Some correlations were observed between corrosion rate and the metal's condition and treatment, Specifically, the unattacked or least attacked specimens were those that had been etched as a final treatment before testing. The most severely attacked specimens were those that had been vacuum-annealed as a final treatment before testing. The moderately attacked specimens were those neither vacuum-annealed nor etched, but having a final surface treatment which left a cold-worked surface. Attack by cupric and ferric chloride was by pit- ting with no preference for grain boundaries, The corrosion scale was cow posed predominately of very fine zirconim particles, Particles from the FeC1,-corroded specimens were more pyrophoric than those from CuCl2-corroded specimens, and appeared to have a higher surface area to volume ratio. Comparison of results to those of previous investigators showed that at certain salt concentrations the more pure, reactor-grade zirconium was quite resistant to attack while the less pure, graphite-melted zirconium was severely attacked.

Jan 1, 1962

By Charles Zahn

Gas chromatography is a method of separating mixtures of gases and volatile materials by entraining their vapors in a gas stream, which passes over an appropriate stationary phase. Two techniques are in common use: Gas-Liquid Chromatography, in which the stationary phase is a liquid supported on an inert solid, and Gas-Solid Chromatography, where the stationary phase is a solid adsorbent, such as charcoal or alumina. In both techniques components emerge from the column after a characteristic residence time. Gas chromatography is applicable as a qualitative or quantitative tool in a wide variety of problems in chemical research and processing. It may also be employed for purification and separation. A running bibliography on gas chromatography has been maintained at the Bureau of Mines synthetic liquid fuels laboratories, Bruceton, Pa., for several years for the benefit of research workers, who use chromatography as an analytical tool. Since the number of references grew and interest in the technique became more wide-spread, the Bureau is publishing this list rather than maintain it as a purely internal source.

Jan 1, 1958

By J. Hyvarinen, A. D. Look

"INTRODUCTION AND SUMMARYElectricity is used extensively in open-pit metal mines to provide illumination, heat, and power to operate hauling and loading equipment, drills, pumps, signal systems, and other machinery. Good installation and maintenance of equipment and power, circuits, are essential to minimize the hazards of shock, burns, and fire.In the 13 years from 1931 to 1943, 20 fatal and 82 nonfatal injuries resulted from the use of electricity in open-pit mines in the United States ; 4/ these figures represent about, 10 percent of all fatalities and 1 percent of the nonfatal injuries. The ratio of fatal to nonfatal injuries from electricity in such mines was very high during this period; the figures show one fatality to every five accidents from this cause.Electricity may cause personal injury through abnormalities in equipment, such as short-circuit, accidental ground, overload, and poor contact; however, each year some fatal electrical accidents are due to persons touching uninsulated ""live wires."" These contact injuries are the result of careless body movements of persons in the vicinity of 'wires at places not normally frequented, or of accidental contact with live circuits when handling metal objects. Electrical hazards can be minimized by the enclosure or elevation of current-carrying parts; ample working space around equipment, adequate insulation, locking switches in the open or closed position under certain conditions, identifying and warning devices, protective grounding, insulating flooring, platforms, or rubber gloves, and proper inspection and maintenance."

Apr 1, 1949

Effective in the 1987 Minerals Yearbook, the following changes have been made: "Asphalt" has been deleted; "Greenland" is included in the "Potash" chapter; "Meerschaum" is included in the "Clays" chapter; and "Staurolite" is included in the "Abrasive Materials" chapter. QUARTZ CRYSTAL Cultured quartz crystal production increased significantly in 198?, following 2 years of reduced production. Consumption of domestic lascas as feedstock for cultured quartz crystal increased. Imports of lascas from Brazil also increased. Although no lascas was mined in the United States during the year, the domestic producer supplied material to consumers from company stockpiles. Specimen-quality natural quartz was very much in demand; quartz crystal for this application is discussed in the Gem Stone chapter.

Jan 1, 1989

By Frank E. Cash

Since ventilation adequate in quantity as well as quality is of paramount importance to the health and safety of men working underground in coal mines, mining officials, employees, and State inspection departments should give it the closest possible attention. MINING LAW OF ALABAMA The law governing, and regulating the operation of coal mines in Alabama was enacted in 1911 and amended or revised in 1923, 1925, 1930, and 1935. The original law and subsequent revisions were progressive steps in safeguarding the health and safety of underground employees.

Jan 1, 1939

By Z. Zhiqun, V. A. Marple, B. Y. H. Liu

"IntroductionIt is commonly understood that aerosol particles may be injurious to human health if they are of a size that enables them to enter the respiratory tract. Coal Workers' Pneumoconiosis (CWP) is one disease known to be caused by coal mining related particles.The location in the respiratory tract where the particles are deposited is primarily a function of the equivalent aerodynamic diameter (EAD) of the particle. The equivalent aerodynamic diameter is the diameter of a spherical particle with a density of 1.0 gm/cm3 with the same falling speed as the particle in question. For a spherical particle the calculation is rather simple in that the equivalent aerodynamic diameter is simply the diameter of the particle in question multiplied by the square root of the density of the particle. For irregularly shaped particles, such as coal particles, there is no simple way to make the EAD calculation. For example, Figure 1 is only one of an infinite variety of particle shapes that can be found in practice and the aerodynamic size of this particle and, therefore, its deposition location in the respiratory tract would be nearly impos-sible to estimate accurately.The normal method for determining the aerodynamic diameter of particles has been to experimentally measure the size of the particles in a settling chamber or with an inertial classifier such as an impactor, cyclone or a centrifuge, since inertial classifiers have the property of classifying the particles according to their aerodynamic diameters."") However, these devices can only give limited information on the EAD of a single particle with a specific shape. Impactors and cyclones, for example, collect particles in size ranges and not at a specific size, so the determination of the EAD of a specific particle is not possible. A centrifuge, on the other hand, can measure the EAD of a specific particle but the equipment is costly and procedure laborious, and it may not be possible to disperse a particle of a specific shape into the centrifuge. The centrifuge can be used to determine the EAD of clusters of spheres in various arrays, but introducing particles of a specific irregular shape may not be feasible. Furthermore, the EAD is a function of the orientation of an irregularly shaped particle and the orientation of a particle in an inertial classifier is unknown. The orientation may also vary as the particle passes through the classifier.Because of the difficulty in determining the EAD of an irregularly shaped particle, we have undertaken a program to apply theoretical numerical methods to calculate the EAD of any shape particle. In our laboratory we have, for some time, been using numerical methods to determine the flow field of air within instruments such as impactors, (2) inlets, (3) and virtual impactors (4) Recently, this technique has been expanded into the three-dimensional regime, and the flow fields and particle motion characteristics within cyclones (5) and glove boxes have been studied. We have now begun to use these numerical three-dimensional flow programs to study the flow field around irregularly shaped particles to determine their drag coefficients, falling speed, and thus, their EAD."

Mar 1, 1989

By Fred N. Kissell

Tracer gas decay curves were experimentally obtained in a full-scale model coal mine working face area. The concentration of tracer gas was found to decay in exponential fashion but with a change in slope. This change in slope is attributed to eddy zones in the face area. A simple theory was developed that allows one to calculate the approximate amount of gas in the eddy zones and thus estimate the size of the eddy zones.

Jan 1, 1974

By H. D. Jacobs

The Bureau of Mines undertook a research program to insure an adequate supply of iron raw materials for future iron and steel making needs. A sample was obtained of oxidized taconite from the western Mesabi Range in Minnesota, and the metallurgical response of the taconite to beneficiation by a process that included selective flocculation-desliming-cationic flotation was evaluated. The sample contained 35.3 pct iron and represented approximately 2 billion tons of crude material. Selective flocculation and flotation were evaluated in a pilot plant with a feed rate of 900 Ib/hr. Concentrates averaging 61.7 pet iron and 5.1 pet silica were obtained, with an accompanying iron recovery of 67.2 pet. About 83 pct of the process water requirements were reclaimed from the slime and froth tailing and then recycled.

Jan 1, 1980

By Carroll W. DeKock

Thermodynamic data for selected metal sulfates were critically evaluated and compiled as part of the Bureau of Mines program to provide a scientific base for use in developing new technology and predicting the feasibility of new processes. Values for Cp°, S°, H° - H°298, -(G° - H°298)/T, ?Hf°, ?Gf°, and log Kf as a function of temperature are given in tabular form. Thermodynamic data were compiled for VOSO4, Cr2(SO4)3, MnSO4, FeSO4, Fe2(SO4)3, CoSO4, NiSO4, Cu2SO4, CuSO4, CuO-CuSO4, ZnSO4, and ZnO-2ZnSO4, together with their stable hydrates.

Jan 1, 1982

By Robert A. Clifton

This Bureau of Mines report discusses the mineralogy of zeolites, the properties that make them commercially valuable, the conditions of formation of both natural and synthetic zeolites, and present and potential markets.

Jan 1, 1987

By J. M. Stuve

A novel calorimetric solution technique, recently developed at the Bureau of Mines, was tested using synthetic samples of chalcocite (CU2S) and covellite (CuS). The solution of these refractory sulfides was accomplished by oxidation with bromine in a moderately acidic, aqueous solution. The resulting values for the standard enthalpies of formation (?Hf°, 298.15) for CU2S(c) and CuS(c) were -18.1 ±1.1 kcal/mol and -13.3 ±1.1 kcal/mol, respectively. These values are in good agreement with published formation values derived from other methods of physicochemical measurement.

Jan 1, 1982

By G. L. Oldright

This paper is the third1 of a series of five papers that is to appear on smelting in the lead blast furnace. The objects of this investigation are to determine the conditions obtaining within the blast furnace be direct experimentation, and to correlate the behavior of the furnace at various times with the main factors governing the operation of the blast furnace, and metallurgical losses. ACKNOWLEDGEMENTS The writers wish to express their appreciation to the management of the international Smelting Company at Tooele, Utah, for their kind cooperation which made possible the assembling of these data.

Jan 1, 1929

By F. W. Cox

Exhaust emissions were measured from 25 aircraft turbine engines using Jet A fuel. Analytical apparatus, procedures, and results are described. Carbon monoxide, carbon dioxide, nitric oxide, nitrogen dioxide, and aldehydes were measured at engine operating modes representing power levels used in airline operation. Carbon monoxide, hydrocarbon, and aldehyde emissions were highest at idle and lowest at takeoff; oxides of nitrogen were lowest at idle and highest at takeoff. Of the total oxides of nitrogen emitted, nitrogen dioxide constituted from 10 to 100 pct, depending on the exhaust gas temperature. Engines retrofitted with smoke-reducing burner cans produced less carbon monoxide, hydrocarbon, and aldehyde emissions, and slightly more oxides of nitrogen then engines with standard burner cans.

Jan 1, 1972

By Ronald D. Hill, Elmore C. Grim

1. Potential groundwater pollution resulting from large-scale surface mining in western states should be evaluated. 2. Criteria should be developed for the design, construction, operation, and abandonment of sediment ponds for maximum removal of suspended solids. 3. Methods should be developed for reducing suspended solids discharges from surface mines to less than 30 milligrams per liter. 4. A manual should be developed in the form of guidelines for sediment and erosion control planning and implementation. These guidelines must be designed to cover all phases of the coal surface mining operation (i.e., before, during and after mining). 5. A mine road manual should be developed for use by surface mine operators and State and Federal Agencies. Erosion, water control, and dust control should be covered in detail. 6. The block-cut, head-of-hollow fill, and mountain-top removal methods and techniques of contour mining should be evaluated, designed, and ultimately demonstrated in steep, mountainous terrain. Designs should be prepared for single and multiple seam applications. The demonstrations must show that these mining systems will secure rapid achievement of reclamation require¬ments and provide maximum, safe, economic coal recovery in an environmentally safe manner. 7. A Blasting Manual should be developed for use by industry and enforcement agencies. Stress should be placed on how to keep vibration levels and air blast pressures well below accepted safe criteria. Also, methods that can be used to control noise should be listed. 8. Investigations should be conducted on the effect of continued vibrations from blasting on structures that are near quarries. 9. Additional guidelines need to be developed for sampling and analysis of overburden material and associated coals for trace elements and noxious strata. Samples are extremely sensitive, and the source and manner of their collection, handling, storage, and treatment, as well as the techniques of analysis, need to be developed and described. This information can be used to predict possible future problems.

Jan 1, 1974