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By L. B. Pankratz

The Bureau of Mines conducted heat-content measurements above 298.15° K for dehydrated analcite (NaAISi2O6) to 1,000°K, kaliophilite (KA1Si04) to 1,800° K, and leucite (KAlSi206) to 1,800° K. Heat content and entropy increments were tabulated, and the heat content data, were given in equation form. A first order transition was noted for kaliophilite near 810° K with a heat absorption of 160 cal/mole. Leucite had a second order transition which became complete near 955° K. In this transition a crystal change occurred from tetragonal (low-temperature form) to cubic (high-temperature form).

Jan 1, 1968

By Árpád B. Palotás, Adel F. Sarofim, John B. Vander Sande, Lenore Rainey Christian, J. Feldermann

"Interest in the fine structure of soots and carbon blacks is motivated by a variety of possible applications. The structure provides information on the origins of the particles and on their adsorptive and reactive properties. This paper describes a method for quantification of the structure of soots and carbon blacks based on direct electron microscopic observation followed by image analysis of these materials. High-resolution transmission electron microscopy (HRTEM) provides a very detailed observation of particle structure. The differences in soot structure, because of its complexity, may not be easily quantifiable with the human eye; therefore, high-level computer software has been used to manipulate HRTEM images. This technique involves the application of fast Fourier transforms (FFT) to single particles and the measurement of characteristic parameters such as interplanar spacings and crystallite sizes from these particles. The methodology and application of this characterization technique are presented here. Results are shown for dif¬ferent samples obtained from soot and carbon black particles selected to illustrate the capabilities of the methodology. Quantitative information can be obtained on structural characteristics, e.g., interplanar spacing, circularity, orientation, elongation, and length distribution of lattice fringes, as well as on the fractional coverage of the extracted pattern. c 1996 Wiley-Liss, Inc.This paper presents a combination of techniques for recognizing and classifying different carbonaceous materials, using their structural morphology. A new method to assess and quantify the parameters which define such structures is proposed and discussed. The technique is based on the use of HRTEM (high-resolution transmission electron microscopy) and computational image analysis.It is well-known that carbonaceous materials like graphite, soots, coals, cokes, chars, etc. possess characteristic structural appearances which can vary from mostly random or amorphous to a perfectly ordered graphitic crystalline structure (Buseck and Bo-Jun, 1985; Buseck et al., 1987). The carbon structure has been variously described as turbostratic (Oberlin, 1989) or as crumpled sheets (Rouzaud et al., 1991) to indicate that parallel layering, reminiscent of graphite, is observed over dimensions of nanometers, but that these planes or crystallites show disorder over larger scales. The degree of order of such structures is strongly dependent on the thermal treatment of the material as well as on the composition of the source of the carbonaceous material. The value of the electron microscope in studying the morphology of such materials has been well-established, and abundant information is available (Ishiguro et al., 1991; Lahaye and Prado, 1978; Buseck, 1992).The use of HRTEM has brought further insight into this matter. Qualitative assessment of the structural order of such materials has been attempted over a long period of time in order to differentiate between various sources or treatments. There is, to date, no successful method available for quantifying the structural characteristics of various carbonaceous materials. This paper presents a technique which is able to recognize dif-ferent materials and to quantify the structural parameters of those materials using HRTEM and computational image analysis, including pattern recognition techniques.In the case of perfectly ordered graphitic crystals, electron diffraction is widely used for obtaining details on structure. Analysis of diffraction patterns can reveal parameters such as interplanar spacing, d002, crystallite size along the c-axis, Lc, crystal size in the plane of the layers, L., mean number of crystallites, Nc, etc.Complicated electron microscopy methods such as defocusing, tilted illumination, axial illumination, etc., often have to be used in order to characterize complex materials such as randomly oriented crystals in soots and carbons. Obtaining the right fo"

Jan 1, 1998

By E. J. Harris

Data obtained from mine ventilation pressure and quantity surveys are required to accurately diagnose ventilation problems, project future air quantity needs, and to locate conditions adversely affecting the efficiency of a mine ventilation system. A method for making mine ventilation pressure surveys with aneroid altimeters was presented in Bureau of Mines Information Circular 7809, and a description of field calculation technique is presented. This report supplements Information Circular 7809 by developing the information obtained during a mine ventilation pressure survey into a single equation suitable, with appropriate modification, for use with desk-top calculators and digital computers. The equation can be used to calculate the ventilation pres sure from the base station to any underground station, or between any two underground stations, and can be programed for semiautomatic sequential calculation using a desk-top calculator. An example of application to a programed desk-top calculator is provided in the appendix.

Jan 1, 1973

By H. H. Heady

This Bureau of Mines report provides specific information regarding the analysis of ores, concentrates, and bullion. It describes analytical services provided by some Federal agencies, and discusses analytical techniques applicable to the precious metals. The appendixes list Bureau of Mines State Liaison Offices and commercial assay laboratories.

Jan 1, 1976

"Minimizing Particle Contamination During Generation of Fresh Dust for Inhalation Studies J. Abraham, MS, Mechanical and Aerospace Engineering, West Virginia University, 1995Correlating Lung Crackle Using Holographic Interferometry Ali Afshari, MS, West Virginia University, 1989Effect of Bit Wear on Dust Generation Mudassar Ahmad, MS, West Virginia University, 1992 The Effect of Surfactants on Suppression of Non-Wettable Particles Ali Alaboyun, MS, Mineral Engineering, The Pennsylvania State University, 1989 Geochemical Characterization of Kerogens, Shales, and Coal Refuse Associated with Allegheny Formation of Cases of Northern West Virginia Dick Andre, MS, West Virginia University, 1987Size and Mass Characterization of Airborne Particulate Matter in Underground Coal Mines Using Diesel-Powered Equipment Indranil R. Bardhan, MEM Report, The Pennsylvania State University, 1992Size and Mass Characterization of Airborne Particulate Matter in Underground Coal Mines Using Diesel-Powered Equipment I. Bardhan, R. V. Ramani, and J.M. Mutmansky, Mining Engineering, The Pennsylvania State University, University Park, PA, Final Report to the U.S. Bureau of Mines, April, 1994Particle Concentrations in a Hazelton Inhalation Chamber Shahram Bavani, MS, West Virginia University, 1985Use and Potential of Lazer Holographic Interferometry and Subsidence Model- Study of an Underground Room and Pillar Mine Richard Begley, MS, West Virginia University, 1984Development of a Mechanistic Model for Prediction of Subsidence in a Longwall Mine Richard Begley, PhD, West Virginia University, 1990Redesign of Micro-Orifice Uniform Deposit Impactor Steve Behm, MS, University of Minnesota, 1991Evaluation of a Two-Phase Spray System for Dust Suppression B. Belle, MS, The Pennsylvania State University, 1996Evaluation of a Two-Phase Spray System for Dust Suppression B. Belle and R.-V. Ramani, The Pennsylvania State University, University Park, PA, Final Report, September 9, 1996A Fracture Mechanics Study of Crack Propagation Mechanism in Coal: The Mechanics of Fine Fragment Formation Z.T. Bieniawski and R. Karl Zipf, Jr., Mining Engineering Department, The Pennsylvania State University, University Park, PA. Final Report, October l, 1988A Mathematical Model for the Prediction of Ambient Dust Concentrations in Mine Atmospheres R. Bhaskar, MS, Mining Engineering and Operations Research, The Pennsylvania State University, 1984Spatial and Temporal Behavior of Dust in Mines-Theoretical and Experimental Studies –R. Bhaskar, PhD, Mining Engineering, The Pennsylvania State University, 1987"

Jan 1, 1998

By David Schlain

"IntroductionThe purpose of this investigation was to study the characteristics of the high-acid electrolytic manganese cell with the idea of fitting it into one of the flow sheets being worked out by the Metallurgical Division of the Bureau of Mines for the recovery of manganese from low-grade domestic ores.In construction, the high-acid cell 3/ differs from the low-acid type in that the cathode and anode compartments are separated by a diaphragm of relatively low porosity, such as alundum. This is necessary because in the high-acid cell the two electrolytes are circulated separately. The anolyte is 15 to 30 percent H2SO4. The catholyte consists of a solution of ammonium sulfate and manganese sulfate with a OH of 4 to 3. The only mixing of electrolytes is that resulting from flow through the diaphragms. In the low-acid cell the two electrolytes are not circulated separately and do not differ so widely in hydrogen-ion concentration. Hence, the canvas diaphragm is sufficient.During operation of the cell, manganese is deposited on the cathode, and sulfuric acid is produced in the anode compartments. Various other reactions take place in the cell. There is considerable decomposition of water; hydrogen is evolved at the cathode, and oxygen is liberated at the anode. When lead anodes are used, some hydrated oxides of manganese are formed at the anodes. The quantity of oxides formed is not as great as it is in the low-acid cell, because fewer Mn++ reach the vicinity of the anodes."

Jul 1, 1942

By J. P. Hansen

Wustite beds were reduced with carbon monoxide and mixtures of hydrogen and nitrogen in the temperature range 900° to 1,300° C to determine the effect of temperature, gas flow, and surface area on the rate of reduction to iron. The composition of the gas stream as it passed through the wustite bed was continuously measured with infrared absorption cells and heated-wire methods. The change in composition was used to calculate the reaction rates. Arrhenius plots of the data give heats of activation of 34 kcal for particles using CO, 27 kcal for particles using H2, 24 kcal for pellets using C8, and 6 kcal for pellets using H2. The velocity of reduction is dependent on the area of reacting interface and the driving potential of the gas (reducing gas concentration minus equilibrium concentration) as well as the exponential temperature effect. The reaction rate was independent of the gas velocity over the range of conditions studied.

Jan 1, 1965

By D. A. Reynolds

The Bureau of Mines-American Gas Association survey of the carbonizing properties of American coals was begun in 1929, and has been continued almost without interruption since that time. Upwards of 100 coals have been carbonized at low, medium, and high temperatures in this survey, and about 200 additional coals have been carbonized at high temperatures only. All survey coals were blended with coal of different rank for carbonization at one high temperature (900° C,). During the past few years, 12-high-volatile A coals were blended with Pocahontas No 3 coal from Kimball, McDowell County, W. Va., and in this report the physical properties of the cokes from these high-volatile coals and their blends are compared.

Jan 1, 1949

By R. P. Vinson

Assessment of workplace exposures is an important tool for helping to minimize dust-related occupational illness and diseases. Real-time particulate monitoring can effectively locate areas where dust controls are needed and determine how well they are working. An affordable, person-wearable, real-time dust monitor is needed. The SKC Inc. Dust Detective (SKCDD) fulfills those requirements (Disclaimer: Mention of any company or product does not imply endorsement by NIOSH). The SKCDD consists of a disposable sampling tube (DST) connected to a small hand-held sampling pump. The SKCDD was developed through a Cooperative Research and Development Agreement (CRADA) between the National Institute of Occupational Safety and Health (NIOSH) and SKC Inc. The relationship of dust concentrations measured by personal gravimetric samplers to those measured by the SKCDD was determined in a laboratory aerosol chamber. A comparison of the means and the relative standard deviation of triplicate measurements of each type of sampling device demonstrated the SKCDD to be a viable alternative means for measuring dust. While it provides accurate measurements for specific coal types, it requires correction factors (those correction factors still need to be calculated) for other coal types.

By G. W. Jones

As a part of it investigations pertaining to the promotion of safety, the Bureau of Mines is investigating various means, useful for the elimination or mitigation of the explosion hazards of combustible gases encountered in mining and industry. Information has been obtained and a procedure developed whereby the explocibility of many complex, gaseous, combustible atmospheres may be calculated in a simple manner without the necessity of performing laborious laboratory experiments. In a previous publication4/ data were given and a method described whereby the limits of inflammability of gaseous mixtures, including methane, hydrogen, carbon monoxide, nitrogen, carbon dioxide, and oxygen, could be determined by calculation. The information published in that report enables one to calculate the limits of inflammability of such gases as are liberated by mine fires, gases from explosives, automobile exhaust ran, uses present after mine explosions, blast-furnace gas, and other gases containing part of or all of the above-listed constituents.

Jan 1, 1938

By William D. Riley

In order to evaluate the corrosion resistance of zirconium in mineral extraction processes, such as a clay-hydrochloric acid leaching process for extracting alumina, the Bureau of Mines conducted corrosion studies in HCl-AlC13-FeC13 environments. A series of weight loss and electrochemical tests were conducted at 25° and 65° C in aluminum chloride (AlC13) plus hydrochloric acid (HCl) solutions containing 0 to 1,000 ppm ferric ion. It was determined that zirconium, which normally exists in a passive state in chloride-containing solutions, undergoes pitting attack in solutions containing more than 100 ppm of ferric ion. It is also shown that an oxide film prepared in air at high temperature offers protection in acid solutions containing levels of ferric ion from 300 to 1,000 ppm.

Jan 1, 1981

By Michael Rieber

The increase in f.o.b. mine prices of coal from $5/ton to over $18/ton in five years [1] has increased the significance of transportation costs. Coals produced in the vicinity of the consumer bear a much lower transport cost than those produced in the west. This differential may be used for flue gas desulfurization, other cleaning, or further processing of local coals. To the extent that western coals are cheaper to produce and have a lower sulfur content, they offset the locational disadvantage. To the extent that they have a lower heating value, the disadvantage is exercabated. Given the other conditions, an accurate analysis of transport costs will help suggest the location of coal mining and the moue of transport both transport costs and tariffs have risen. Together they have increased delivered coal prices, altered the balance between the use of coal and other fuels, helped to alter the location of mining activity, and put pressure on consumers to examine the cost effectiveness of alternative transport modes. Transportation options for long distance coal movements include rail, barge, pipeline, and EHV transmission lines. A summary of system parameters is shown in Table 2.1. Barge transport, pneumatic and slurry pipelines are discussed elsewhere in this report. Together with EHV, they have been the subject of previous studies [2,3,4]. Slurry pipelines have been shown to be especially useful where rails are not available [2] but the technical problems of dewatering, handling, and utilization of lines [5] remain unresolved. They are discussed in Section 3. Barge transportation depends on the location of the mine and consumer with respect to the waterway system. One drawback of barge shipment is interruptions due to winter, and low or high water conditions. Mine mouth power generation followed by EHV transmission of over 500 miles has been shown to be the most expensive means of delivering an equivalent amount of energy to consumers [2].

Jan 1, 1977

By A. L. Engel

This report is a compilation of the results of preliminary tests on ores containing scheelite (calcium tungstate). In most of the ores, scheelite was the only value; but several samples contained other values, such as gold, base metals, or, in one instance beryl. These investigations were made to assist the development of domestic tungsten resources by establishing satisfactory treatment methods suitable for small-scale operations. The samples were obtained through the Mining Division of the Bureau of Mines and represent, for the most part, newly discovered deposits. A previous report2/ discussed laboratory test procedures. A less detailed description of test procedures is included in the present report. As is usual in an investigation of this type, only a limited amount of work was done on most of the samples to indicate the results that could be expected from simple treatment of the particular ore. The occurrence of scheelite and the texture of the minerals present differ greatly in individual ores and must be determined and considered in establishing such details of treatment as grinding to obtain optimum liberation of the minerals, the preferred type of gravity concentration, or possible further treatment by flotation.

Jan 1, 1954

By Robert H. Merrill

Several investigators have obtained solutions for the concentration of stress around circular, ovaloidal, elliptical, and rectangular holes in an elastic, isotropic, semiinfinite plate subjected to uniaxial and biaxial stress. These solutions are used to evaluate the changes in stress around openings immediately under the undercut normally used in conventional block caving operations. The evaluations are based on the assumption that a horizontal undercut removes most of the vertical component of a biaxial stress field. The location and magnitude of the significant changes in stress concentration around the opening are computed. Conditions under which the assumptions used in the evaluations may or may not be consistent with conditions around block caving mines are discussed, and examples of preferred opening shapes for a biaxial (hydrostatic) stress field are shown. This report is a summary of one phase of an investigation to establish design methods for the size and shape of mine openings used in block caving mining methods .

Jan 1, 1962

By L. C. IlsLey, M. W. Von Bernewitz

"Introduction.Several hundred thousand open lights are daily carried in coal mines of the United States, each lamp being a menace to life and property through fire or explosion. They have been responsible for many disasters in the past, and will be again. Flame safety lamps have been available for over a hundred years, but during the last ten years safe and practical electric lamps have been perfected. These have eliminated many of the flame safety lamps, and in a few mines have replaced open flame lamps. But there are still more than twice as many open lamps as electric lamps in our mines, and the open lamps should be discarded in favor of an approved type of electric lamp. There are several electric miners' lamps which have been approved by the Bureau of Mines for safety and efficiency, give good light, and are easily maintained and carried, some flame safety lamps will always be used, hut mostly for detecting gas; although they might be supplanted if some simple, reliable, and cheap gas detector were developed.Explosion Hazards from Open Lights.An open light and gas*** constitute a vicious hazard; while if there be coal dust present in the vicinity the consequences are multiplied many times. An open light and black blasting powder also constitute an explosion hazard, vividly attested by several serious disasters."

Jan 1, 1924

Provide a machine for economically drilling probe holes in coal mines (required where there's a possibility of unmapped, abandoned workings) to check for possible water flood or gas hazards ahead of the face. Approach A lightweight air-powered drill, that mounts on a light-weight frame anchored to the face with an expandable packer, is used to drill one or more probe holes. The anchor installs quickly and will lock the drill in any desired position. How It Works The drill is portable and can be broken down to small components for ease of transportation. One man can carry these sections through restricted access routes to the working place. Components that are separable are the anchor assembly, drill frame assembly, and drill motor assembly. The drilling sequence is as follows: A 2-inch-diameter anchor hole is drilled 2 feet deep. The fixed anchor tube is rubber packer is expanded. A second anchor hole is drilled through a bushing in the anchor frame. The removable anchor tube is inserted and its rubber packer expanded. (This anchoring system withstood pulls of up to 14,000 pounds.) Next, the frame is attached to the anchor with two screw knobs, and the motor is attached to inserted in the hole and the rubber packer is expanded. A second anchor hole is drilled through a bushing in the anchor frame. The removable anchor tube is inserted and its rubber packer expanded. (This anchoring system withstood pulls of up to 14,000 pounds.) Next, the frame is attached to the anchor with two screw knobs, and the motor is attached to the frame with a single locking pin. Installing the anchor and drill takes less than 12 minutes.

Jan 1, 1981

By A. W. Fahrenwald

The art of flotation has developed rapidly. Numerous technical staffs and individual investigators have, by their combined efforts, developed practicable methods of concentrating ores which ten or even five years ago were considered complex and impossible of commercial treatment. Also the work of those who have been engaged in pure research on the fundamentals of flotation has helped greatly to expedite the general development of the process. However, in spite of the highly successful practical operation of the flotation process, results are obtained and things happen that we are unable to explain completely, although much is known about the theory of the process. The rapid stride in flotation concentration, it is noteworthy to point out, is due to the freer exchange of facts and data by the staffs of the larger mining companies and the patent controlling corporations, and by investigators in general. Generally speaking, one may visit any mining plant and by presentation of proper credentials, be shown all that is going on or that is being done.

Jan 1, 1925

By R. D. Haynes

Coal, gas, and oil in many geological formations of the Eastern United States are intimately associated but have traditionally been recovered independently of each other. Oil and gas wells, however, are often spaced sufficiently close to cause the subsequent loss of up to 50 percent of the recoverable coal in the form of pillars or barriers left for mine safety purposes. A long-range planning technique was devised for exploiting oil and gas wells simultaneously with the mining of coal to recover the maximum fuel potential of the formations. Planned plugging of oil and gas wells, determined partly from production predictions via decline curve analysis, is coordinated with a mine development plan to achieve maximum coal recovery and reduce overall production losses of gas and oil due to plugging of the wells.

Jan 1, 1973

By Robert P. Vinson, Kissell. Fred N., Edward D. Thimons

"The Bureau of Mines investigated the presence and extent of methane accumulations in mine roof cavities using a full-scale mine model. Methane was released at a constant rate into the roof of a cavity built onto a 700-ft wind tunnel. Two box-shaped roof cavities were used in the study: one had a volume of 114.7 cu ft; and the other had a volume of 57.3 cu ft. Methane concentration was measured at 28 sampling points in the cavities using 21 different combinations of gas emission rates and air velocities. Brattice hung in the cavity helped reduce methane concentrations without auxiliary ventilation. It was also found that the effective ventilation rate increased by a factor of 40 in the large cavity and by a factor of 20 in the small cavity when air velocity was increased from 100 to 600 fpm.INTRODUCTIONAny location in a coal mine where 5 pct or more of methane is present constitutes a potential site for an explosion and roof cavities are likely locations. Unfortunately, little is known about the buildup of methane in roof cavities. Some research has been done using scale models where no air flows past the cavity so that methane disperses only by diffusion (5) 4 a rare situation in mines.No known cavity-model investigations have been made that simulate air and methane flow conditions normally encountered underground. These Bureau of Mines studies were undertaken to determine the extent and manner of methane buildups in coal mine roof cavities with air velocities in the range normally found in coal mines and with various methane emission rates."

Jan 1, 1978

By Dean H. Ambrose

A computer model was created that generates contact data by means of simulation while altering several variables associated with the machine and its operator. These variables include work environment, the operator's anthropometry, work posture, choice of risky work behavior, and the machine's appendage velocity. In the model, a contact means two or more objects intersecting or touching each other, e.g., the appendage colliding with the operator's hand, arm, head, or leg. This report documents the code development of special features of the computer model, random virtual human motions and behaviors, which made it possible for researchers to study hazardous interactions, such as contacts between the operator and machine. The original idea for random virtual human motions began with the need for a model that, when simulated, would experimentally mimic machine and human actions that could cause actual injuries or fatalities in the workplace. Injury incident investigation reports do not usually contain enough information to aid in studying this problem, and lab experiments with human subjects are also not feasible because of safety issues and ethical issues. Early investigation that evaluated the feasibility of random motions resulted in a primary programming structure and building blocks for code expansion. Basic motions and standard derivation data provided random parameters for the operator's movement in the random motion code. Experimenting with basic motions in preliminary models helped researchers devise a random motion technique that worked with xyz motion parameter values from basic motion parameters. Both values were the building blocks used in motion commands that comprised the core of the random motion code. When the code is executed in a three-dimensional computer model, it generates realistic starting positions for the operator's (virtual human) body and body parts and realistic motions mimicking a work sequence with a valid range of variation in movements. Researchers developed several rules for the random motion technique that, when applied, will maintain directional integrity of a virtual human's basic motions. From previous research, researchers formulated the algorithm that determines the behavior during machine operation. The decision algorithm was needed by the random motion code to randomly select what behavior to use for a simulation execution for a realistic representation of the operator's motions and risky behaviors during work tasks. The operator's chance of avoiding the moving appendage was also a concern to ensure that data reflecting a near-miss would not be considered a contact. Therefore, to filter a database obtained from simulations for actual contacts, it was necessary to track the operator's field of view and determine from this information when the appendage is in and out of the operator's view. NIOSH researchers successfully applied random motions and risky behaviors to examine the speed range of a roof bolter machine appendage for different workplace scenarios and compare statistically which is most likely to cause contacts (and possible injuries) to miners. Researchers in this study believe that the use of such simulations, treated with advanced statistical procedures, are extremely useful tools to evaluate the hazards of tasks where it is not possible to perform experiments with human subjects.

Jan 3, 2004