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By L. M. Oshinowo

The incorporation of advanced analysis tools, such as CFD, into the process plant design process has become possible through advances in commercially available computational fluid dynamics software and faster computers. Multiphase modeling is now typically employed in the design phase of process plant design at Hatch. The multiphase models include Lagrange-Euler and Euler-Euler treatment of the multiple phases. Additionally, mixture models with interface-sharpening algorithms are applied to the prediction of free-surface flows in complex geometry. CFD is applied to applications where traditional design rules are not applicable. The additional rigor of CFD modeling in 2D and 3D allows process engineers to come closer to realizing true virtual plant design. The objective of this paper is to outline the benefits and pitfalls in the application of multiphase modeling for rigorous design. Several application examples in the hydrometallurgical field will be presented.

Jan 1, 2005

By F. Moraw

The use of redox fuel cells in which oxygen is replaced by other oxidants such as ferric ions can have significant advantages [1-3]. For example, the cathodic reaction rate (e.g., exchange current density) can be increased by several orders of magnitude compared to the oxygen reduction reaction, and platinum group metal (PGM) catalysts are not required. As a result of the higher aqueous solubility of the oxidant in a redox fuel cell compared to that of oxygen the rate of mass transfer (e.g., limiting current density) is greater by several orders of magnitude. The redox fuel cell can achieve high efficiencies and has other fuel cell advantages. The main issue with the redox fuel cell cathode is the regeneration of the oxidant where low conversion efficiencies are achieved even with platinum group metal (PGM) catalysts. In the work discussed here the Fe3+/Fe2+ redox fuel cell cathode is characterized over a range of electrolyte concentrations and operating conditions, and electrode materials. Cyclic voltammetry and electrochemical impedance spectroscopy are mainly used for electrochemical characterization and mechanistic determination of the cathode redox couple. Further characterization with selected compositions and materials is done in a redox fuel cell (hydrogen - Fe3+/Fe2+). The mechanism and the advantages and disadvantages of the fuel cell redox cathode are discussed with respect to other approaches and other redox couples.

Jan 1, 2005

By T. Melfi, M. James

Attaining required mechanical properties in welds made using the double submerged arc welding (DSAW) process is difficult, and it is becoming more difficult as the strength level of the base materials continues to increase. Producing weld metal with adequate mechanical properties involves factors that are often overlooked and not taken into consideration. Not least amongst these problems is simply finding information to use in selecting the appropriate flux/wire combination. Most of the available data on flux/wire combinations provided by consumables manufacturers is generated using the multiple pass welding procedures required for classification per specifications such as AWS A5.17 and A5.23. This data really gives no insight into the properties that can be expected in a DSAW application. Also, base plate composition plays a very significant role because of the fact that base plate dilution can be as high as 70% in DSAW welds. This means that if any elements are present in the base metal that are deleterious to mechanical properties, they will also be present in significant quantities in the weld deposit. Some of these elements can decrease toughness and increase hardness (increased hardness is a concern if the pipe is intended for sour service). Some of these problems can be mitigated by proper selection of welding consumables. Selection of proper welding consumables means selecting an electrode that provides the appropriate alloying elements to obtain the desired level of impact toughness while also keeping the hardness within any specified limits. In order to attain the necessary impact toughness, selection of a flux with an appropriate composition (in terms of its basicity and its ability to control the nitrogen content of the weld deposit) is required. As with all welding processes, the mechanical properties of DSAW welds are also highly dependent on the welding procedures. This work clarifies how to select appropriate consumables to meet a given set of requirements, and also how to achieve the optimum mechanical properties from those consumables.

Jan 1, 2005

By J. G. Pharoah

Over the last two decades a variety of models for solid oxide fuel cells (SOFCs) have emerged ranging from one dimensional (1-D) to 3-D models, from steady-state to transient models; single- and half-cell and entire stack models. A majority of these models have focused either on the transport processes or on the chemical/electrochemical processes. The approach taken by our research group is to develop a comprehensive SOFC model framework based on the considerations of detailed electrochemical reaction mechanism and by accounting for complex transport processes occurring in the porous media at the micro-scale level. In this paper, we review the state-of-the-art in SOFC modeling and identify the existing gaps that need to be filled in.

Jan 1, 2005

By L. Bichler

Utilizing thermal analysis techniques, pioneering research into the solidification mechanism of a popular magnesium alloy AZ91E cast by the Lost Foam Casting (LFC) process was carried out, Foam characteristics, section thickness and application of vacuum were seen to have profound effect on the cooling rate, thermal gradients and casting temperature profiles.

Jan 1, 2005

By N. Djilali

Many of the transport phenomena encountered in proton exchange membrane fuel cells occur intrinsically at the microscale level. Physically representative models that fully account for the salient physico-chemical and transport processes in PEM fuel cells are necessary to achieve truly predictive models that can be used with confidence to: (i) gain a better understanding of in-situ processes and couplings, (ii) explore new concepts, and (iii) support design and optimization. The development of more general, rationally based macroscale models requires use of knowledge on the microscale level to provide guidance, and to determine the required parameters and coefficients (model "constants"). In this paper we present a new membrane transport model, the binary friction membrane model (BFM2), recently developed to account for coupled protonic and water transport in polymer membranes. This general model is based on rational and physical consideration, removes several of the limitations of the empirical models used to date, and is formulated for all purfluoro-sulfonic acid membranes. The use of the BFM2 in a fuel cell model is illustrated highlighting significant performance predictions compared to existing empirical model. The second part of the paper addresses the fundamentals of two-phase transport in hydrophobic gad diffusion media. Computational and experimental visualizations resolving the microscale dynamics of water transport between the fibres of a GDL are presented, revealing transport mechanisms that are, contrary to assumptions used to date, dominated by fingering and channeling.

Jan 1, 2005

By M. Greyling, C. Panaou, M. Bellino

Commonly the most frequent method of calculating the overall mass balance of a multi mineral platinum-group metal (PGM) concentrator circuit in Southern Africa has been through the use of spreadsheets, typically Microsoft EXCEL®. While there are some advantages in using spreadsheet based mass balances during the conceptual design phase of the project, their use becomes limited in the detailed design phase of the project. This paper discusses the successful application of METSIM® for mass balancing of a PGM concentrator and highlights the benefits gained during the conceptual and design phase of the project.

Jan 1, 2005

By H. Lachmund, R. Bruckhaus

At Dillinger Hüttenwerke/Germany steel production of grades for linepipe applications especially for sour service has a long tradition. The BOF process after replacement of the vessels is optimized by a newly developed lime addition model and variations in lance tip geometry. Equipped with three state-of-the-art VOD tank degassers metallurgical requirements of lowest contents of e. g. sulphur, nitrogen and hydrogen can be achieved. Three continuous casting machines of vertical bending type with solid core even improve already high levels of cleanliness. The vertical part corresponds to the metallurgical length of 12 to 15 m and therefore assures a maximum of cleanliness after solidification before bending. Slab thickness up to 400 mm can be produced with model controlled dynamic soft reduction. The accurate alignments of the casters assure minimized segregation and microporosity. Surface and internal cracks can be avoided by special cooling, bending and straightening strategies.

Jan 1, 2005

By L. Kilburn

"A survey of 281 mineral exploration agreements examines the ratios among three ways that may be used to purchase an interest in a mineral property, viz: pay cash, pay shares and make future expenditures on the property.The dollar value of the future expenditures exceeds that of cash or shares by about nine times in most of the 110 agreements that contain cash-expenditure or share-expenditure components. Results suggest that cash and shares are treated about the same in terms of value.Buyers and sellers have opposing priorities for the way that they prefer to purchase a mineral property. These opposing priorities should give rise to a perceived 50:50 balance between cash/share payment and future expenditures to satisfy the idealized situation described by most definitions of fair market value (FMV). This balance between cash/share payments and future expenditures appears to be rationalized in negotiations to a FMV when expenditures are nine times greater than cash and/or payments.On this basis, it is proposed that the FMV of a property may be determined by aggregating the dollar amount of the cash/share payments plus one-ninth the dollar value of future expenditures, as set forth in the respective purchase agreement, and proportionately applying such aggregate to full property value."

Jan 1, 2005

By J. I. Gazzarri

A model of solid oxide fuel cell AC impedance behaviour has been developed and is used to simulate the frequency response of a single cell with and without mechanical damage. The results indicate that the presence of mechanically induced damage within the components of a solid oxide fuel cell can be detected by comparing the frequency response of the undamaged cell with that of a cell in which in-plane cracking or delamination has occurred. The presence of such defects manifests itself as a new semicircle in the Nyquist impedance diagram of the full cell. A parametric study reveals the resolution capabilities of the method in terms of the geometrical characteristics of the defects.

Jan 1, 2005

By N. Musee, N. Kornelius

This study presents a neural network approach to modelling the liberation of gold bearing ores. A complete mineralogical analysis of unmilled and milled ores, including gold deportment and gangue content are used as inputs to a self-organising neural net which generates order preserving topological maps. The arrangement and shapes of these clusters are coupled to unmilled free gold data to predict gold liberation in milled ores (absolute error: 4.2%). Moreover, the self-organising maps were diagnostic of the quality of data used, indicating that the relationship between particle size and gangue material content requires further investigation.

Jan 1, 2005

By M. Kozlowski, I. Candy, S. Kashani-Nejad

The production of ferronickel and matte from nickel laterite ores is dominated by the Rotary Kiln, Electric Furnace (RKEF) process. Over time, major improvements have been made to kiln operation. In particular, kilns are now required to perform substantial amounts of reduction of the metallic oxides, thereby reducing the load on the electric furnace and substituting less expensive fossil fuel for electrical energy. To the basic refractory lined cylinder have been added: internal features such as dams and lifters, aimed at changing residence times in different sections of the kiln and enhancing gas/solids interaction, on-board fans to introduce tertiary air and on-board scoop mechanisms to allow reductant coal additions to be made at advantageous locations along the kiln. Many of these advances in design have been made on a trial and error basis and by 'borrowing' technology from related kiln processes, supplemented by proprietary modeling to various levels of sophistication. This paper presents a conceptual review of modeling components for the development of a computational model for granular material flow, combustion and heat and mass transfer in a nickel laterite kiln. These components include: granular material flow and segregation models for the simulation of bed motion, heat transfer models that simulate heat transfer by turbulent diffusion and radiation and the distribution of this thermal energy within the bed, and fluid flow models for the prediction of combustion aerodynamics.

Jan 1, 2005

By M. J. Nicol

The leaching of gold with thiosulfate solutions in the absence of ammonia and copper ions was investigated using electrochemical and kinetic methods. In sodium thiosulfate solutions, the electrochemical oxidation of gold was hindered and the leaching rate using pure oxygen as the oxidant was very slow. It was found that the addition of a small amount of thiourea or formamidine disulfide to the thiosulfate solution greatly enhanced the oxidation of gold. However, the enhancement to the overall dissolution of gold using dissolved oxygen as the oxidant was limited. This was attributed to the fact that the oxygen reduction process was unaffected by the additives and remained slow, which limited further improvement to the overall kinetics. An alternative oxidant, the ferric EDTA complex having a reduction potential of approximately 0.12 V, was found to be promising. The cathodic reduction of ferric EDTA was fast and reversible at neutral pH. While the ferric EDTA complex was effective in oxidizing gold, it did not appear to significantly oxidize thiosulfate. A thiosulfate solution containing thiourea and ferric EDTA has been shown to quickly dissolve gold in the form of a powder as well as from gold ores. In the leaching with the ores high gold recoveries of above 90% was achieved with the best performance obtained in neutral solutions (pH 6-7).

Jan 1, 2005

By V. G. Papangelakis, M. Cheung, M. Dry

The high pressure acid leaching of laterite was modelled and simulated using a combination of two commercially available software packages, namely Aspen Plus 11.1 and the OLI Stream Analyzer. New kinetic parameters for the acid-controlled metal dissolution and precipitation reactions at temperature were first determined from previous experimental data on the leaching of limonite. A grain model with cylindrical pellets was used to model the solid-liquid dissolution reactions. Precipitation reactions were modeled via aqueous equilibrium chemistry. A dedicated thermodynamic database previously developed at the University of Toronto was used in conjunction with the OLI software to model the solution chemistry and calculate the concentration of hydrogen ions in solution at the leaching temperature. Mass balances were handled by Aspen Plus. The simulation gave good predictions of nickel dissolution under industrial and laboratory conditions, for the dissolution of limonite and limonite/saprolite blends. Computational

Jan 1, 2005

By R. Browner, J. Collard, D. Ibana

The extraction of cobalt from synthetic pressure acid leach solutions of nickel laterite ores by the direct solvent extraction route using ESPLIM is reported. It first explored the use of gaseous ammonia as pH modifier and then the variables that affect the dispersion of the aqueous phase in the organic phase such as ionic strength, viscosity of the phases, initial droplet size, etc. were explored so that phase hold-up and thus extraction can be effectively controlled. The results show that the technique allows better control of phase dispersion circumventing one of the main weaknesses of conventional solvent extraction.

Jan 1, 2005

By B. Kenney

For SOFCs, composite cathodes comprising an electronically conducting electro¬catalyst (e.g. LSM) and an conically conducting electrolyte material (e.g. YSZ) are considered to improve the electrochemical performance by extending the active reaction zone to regions beyond the electrolyte-electrode interface, as in the case of conventional cathodes. Interpretation of experimental data for composite cathodes, however, is complicated by the mixed conducting behaviour which results in local overpotential distributions throughout the composite cathode. These local overpotentials depend on many factors, such as the composition, particle size, porosity and thickness of the cathode. Reliable experimental data obtained from composite cathodes requires carefully crafted microstructural parameters in order to minimize the overpotential variations. A mathematical model of a composite cathode was developed using coupled differential equations describing transport and consumption of chemical species, oxygen ion and electrons. Simulations under various oxygen concentrations were used to obtain the reaction order of the oxygen reduction reaction. An apparent po2 dependency was then extracted from the predicted Rp vs P02 data. It was found that this p02 dependency can be significantly influenced by the micro-structural parameters of a composite cathode, primarily due to local overpotential distributions.

Jan 1, 2005

By P. Oyanader

"In 2001, the Catholic University of Chile undertook a maintenance benchmarking study of six open pit copper mines having mill capacities varying between 18,000 t/d and 156,000 t/d, and collectively responsible for 58% of Chilean copper production. This paper describes the methodology used to conduct the study, as well as the overall results. Key performance indices were selected to measure the effectiveness, efficiency, and development of the maintenance process. Using a balanced scorecard philosophy, these indicators were divided into client satisfaction, financial, internal process, and learning and growth indices.Maintenance was found, on average, to be responsible for 44% of mine production costs. Percentage planned maintenance of equipment fleets was found to be low by world standards, averaging 35%, 56%, and 44%, respectively, for blasthole drill, shovel, and haul truck fleets. Fleet availabilities were found to be significantly influenced by the percentage of planned maintenance achieved, while maintenance cost per equipment was found to decrease non-linearly with increases in percentage planned maintenance. Investment in technical training (including planned maintenance practice) was found to be low by global standards. The paper concludes that fleet availability and maintenance costs in Chilean open pit operations could be considerably improved by improving and/or developing maintenance planning standards, and investing in training personnel in planned maintenance techniques"

Jan 1, 2005

By C. A. Anderson, C. A. Young, H-H. Huang, L. G. Twidwell

An equilibrium calculational computer program (STABCAL) can be used for titration simulation. The program can handle various forms of titrants: solid, aqueous, gaseous or another solution, and various type of reactions: reductive, oxidative and adsorption. Background chemistry, mathematical considerations, and program development will be illustrated. Also, simple titration applications such as how to determine the acidity of aqueous solutions and alkaline sulfide leaching of gold are presented. Processing of an acid mine water from the Berkeley Pit in Butte, Montana has been used for illustration purposes. The treatment studies included: cementation, sulfidization, and neutralization. The calculational results for the neutralization treatment using various alkaline reagents are compared to actual experimental data and potentially appropriate processes are discussed. Computational

Jan 1, 2005

By C. A. Pickles

Nickeliferous limonitic laterite ores contain considerable free moisture. In this research, the application of microwave radiation for the drying of this ore was investigated. The effects of sample mass, initial moisture content and porosity on the microwave drying rate were studied and the results were compared to those obtained with conventional drying. Microwave drying rates of two to three times the conventional values were achieved. Further enhancement of the microwave drying rate was realized by increasing the flow rate of air over the sample or by operating at reduced pressure. The high microwave drying rates were attributed to the inverted temperature gradient which resulted in internal heating and boiling and this in turn promoted movement of the water, both as liquid and vapour, to the surface.

Jan 1, 2005

The quality of refractory bricks and castables could be determined by direct measurements of their material properties such as elastic properties, porosity, density, etc. using conventional static or non-destructive testing (NDT) dynamic techniques. Quality monitoring of refractory linings is much more challenging and complicated. The static methods require undesirable drilling and sample extractions from the furnace structure. A more desirable alternative is the use of NDT techniques for material quality estimation. The Acousto Ultrasonic-Echo (AU-E) technique is a new stress wave propagation approach for monitoring the quality of refractory linings in operating furnaces. In this paper, the conceptual methodology for the AU-E technique is described, the capabilities and limitations are expanded, and the results from two case studies are discussed.

Jan 1, 2005