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By L. G. Bergh

The experience developing a supervisory control and information systems in a SX pilot plant is presented. The plant is located at the Process Control Laboratory, Santa Maria University, in Chile. In this work, the problem of controlling this process is discussed and related literature is briefly reviewed. Then, an innovative control scheme organized in three levels, local, hydrodynamic, and metallurgical supervisory controls is presented in an architecture including field controllers, PLC, and PC networks. Operating decisions in the metallurgical supervisory control are taken with incomplete information from on-stream analyzers. The control proposed is based on metal and acid concentration predictions of intermediate and exiting streams through the use of dynamic and static models and flow rates and input concentration measurements. Preliminary results are presented. The main objectives are to develop and test intelligent techniques in a hybrid system, and to study measurement and supervisory control problems. It is expected to produce reliable results that will contribute to improve the efficiency of this emerging and important process.

Jan 1, 2007

By Chuck Edwards

"Cameco operates the high-grade McArthur River uranium mine in northern Saskatchewan, and is constructing the high-grade Cigar Lake uranium mine. Cameco has studied the concept of underground milling of high-grade uranium ore. Compared to conventional milling on surface, the underground milling scheme appears to offer significant cost savings and a lower environmental impact. This paper describes the underground milling scheme, presents process flowsheets and plant layouts, and provides an assessment of potential benefits from underground milling.INTRODUCTIONCameco CorporationCameco is the world’s largest uranium producer, with three operations in Saskatchewan (Rabbit Lake mine/mill, McArthur River mine, and Key Lake mill), two in the United States (Crow Butte and Smith/Highland ISL operations) and two new mines being developed in Canada (Cigar Lake project) and Kazakhstan (Inkai project). Cameco provides uranium fuel refining and conversion services at its Blind River and Port Hope facilities in Ontario. Cameco is part owner (31.6%) of Bruce Power that leases eight nuclear power plants located in southern Ontario. Cameco is the majority shareholder in Centerra Gold Inc., which operates gold mines in the Kyrgyz Republic and in Mongolia.Global Uranium Production RequirementsCentral to Cameco’s view of future uranium supply requirements is the belief that the world is experiencing a nuclear renaissance. This belief is supported by a number of developments, including:•,?Countries representing half the world’s population are now constructing new nuclear power plants. Many countries without nuclear power have begun to plan for it, seeking reliability, clean air and energy independence.•,?Accelerated growth for this industry is also becoming much more likely. In Asia, primarily in China and India, 92 reactors are under construction, on order or planned to help meet rapidly expanding economic needs. Other Asian countries, such as Vietnam and Indonesia, with large populations and rapidly growing economies, are also expected to follow.•,?In the United States the “Energy Policy Act of 2005”, the first energy legislation introduced in over a decade, was signed. This legislation includes provisions recognizing, for the first time at a national level, the clean air contribution of nuclear energy and its critical role in meeting energy security. Upon signing this landmark legislation President Bush stated, “We will start building nuclear power plants by the end of this decade.”"

Jan 1, 2007

By R. S. Forgan

The synthesis and study of a systematic series of phenolic oximes have shown that substitution in the 3-position can greatly affect extractive efficacy. Solid state, solution and gas phase analytical techniques, including X-ray crystallography, EPR and IR spectroscopy and collision induced dissociation mass spectrometry have been assessed for their applicability in interpreting the origins of differences in extractant strength. The dominant substituent effect on pH0.5 is the change in ligand pKa, with the more acidic ligands being stronger extractants. The influence of the 3-substituent on the stabilising intracomplex H-bonding of their copper(II) complexes also affects extractant strength. The 3-NO2 substituted ligand shows the lowest pH0.5 value, due to a combination of its low pKa and a stabilising bifurcated H-bond assembly around the copper(II) centre. Appending an aminomethyl group to the 3-position gives a ligand capable of binding a metal and its attendant anion. These metal salt reagents show potential to open up new flowsheets for the processing of high tenor copper feeds.

Jan 1, 2007

By M. Olper

Commercial copper plants utilising current best technology are tending towards ever increasing scale, the concentrate requirements of which cannot be serviced by a single mine. In such cases, raw materials are often sourced from different mines, which are often far away from the production plant and usually with very different ore compositions. These plants tend to use the traditional thermal processing steps of smelting, converting to blister, anode refining and casting to produce copper anodes that are then refined in a sulphate electrorefining operation. These thermal steps are in some cases troublesome and require the recycling of considerable quantities of material. A new process was developed taking advantage of the latest developments of the first thermal step of the classic loop, the smelting of copper concentrate to high grade matte or white metal using the well known AUSMELT Top Submerged Lancing Technology. The white metal and/or high grade matte product is converted directly to copper cathode and elemental sulphur using the ECUPREX technology. This approach provides an alternative to the traditional thermal steps of conversion to blister, thermal refining and anode casting, which, especially at small scale, can be expensive and problematic in terms of technical and environmental concerns. At first evaluation, this new process can be operated at low capacities, thereby, changing the traditional approach to copper production. Instead of taking the concentrate to the copper production plant, the copper production plant is taken close to the mine with some significant economic and technical advantages.

Jan 1, 2007

By S. Hosseinpour

Chromate conversion coatings (CCCs) are usually applied to these alloys to enhance their resistance to localized corrosion and to improve paint adhesion. The special properties of these coatings such as their low electrical contact resistance (ECR) make them suitable for satellites. This study is aimed to develop advanced CCCs with the proper appearance, morphologies and surface roughness and to evaluate their role on the ECR and thermo physical properties on hardened aluminium alloy of Alclad-7075-T6. Coating characterization was performed by means of scanning electron microscope (SEM) and atomic force microscope (AFM). ECR of coatings were measured by special laboratory designed instrument and a and c were measured by Emissometer and Reflectometer respectively. In addition, corrosion performance of the CCC-coated alloys was determined by 168 hr exposing to salt-spray testing in accordance with ASTM-B117. The results of accomplished experiments on the developed CCCs in this study have been agreeable concerning available acceptability criteria for satellite surfaces.

Jan 1, 2007

By T. Kagawa

Ever-increasing demands for non-ferrous metals owing to population growth and improvements in the standard of living in the world, under the constraint of limited availability of natural resources, would easily make us imagine that more efficient and sustainable developments in mining and smelting activities are required in the near future with due consideration for environmental concerns. In order to realize the efficient and sustainable development of mining and smelting activities and operations, the following issues are indispensable: (1) to investigate the up-to-date pollution control technologies of mine and smelter, (2) to promote those technologies, (3) to develop technologies which are environmentally friendly. This paper discusses the recent technologies for environmental conservation/prevention and their diffusion in the world, and also the key technologies required for the most desirable sustainable development.

Jan 1, 2007

By G. Karcas

Concurrently designing both the solvent extraction and the electrowinning processes of a copper SX EW project, in an integrated and consecutive approach, with one technology partner, will ensure continuity in the process flow and smooth execution of the engineering function with minimum duplication, time loss and errors, maximizing time efficiency resulting in excellent quality and quick and effective start-up of the plant. Projects will benefit significantly from the common technology partner approach as not only will the SX and EW processes be optimally efficient individually, but the overall process efficiency will be optimized eliminating the common problem of efficiency losses and integration difficulties when combining two consecutive processes which also require to circulate flows between them. Plant operation will also benefit from the fact that impurity control will be on a global basis, rather than concentrated on certain parts of the process, hence, better results and more efficient control. The operation of equipment will be more effective and efficient. Further, proprietary technological equipment that focuses on maximizing plant performance, such as Dispersion Depletor Gate (DDG) Fences and Outokumpu Cathodes, will be applied throughout the plant as the design philosophy will be to utilize technology to maximize production.

Jan 1, 2007

By D. Kim

Kennecott operates one of the largest and most modern copper refineries in the world at Magna, Utah, USA. The inputs to the refinery are anodes produced at Kennecott Smelter, which has extremely high contents of lead and bismuth. In order to minimize undesired effects in the electrolytic refining process, unwanted impurities, especially bismuth, must be controlled. This paper describes the process development of practicing state-of-the-art quality control and presents the pilot test results of using the MRT Technology for Bi production.

Jan 1, 2007

By J. E. Gebhardt

Advances in computational modeling provide unprecedented process simulation tools for the process engineer to examine and explore options for optimizing heap leach operations. A phenomenological model developed within a computational fluid dynamic software framework provides a general heap leach modeling tool that describes reactive dissolution and fluid flow through the stockpile. A one-dimensional form of the model is used to parameterize the kinetic leach reactions for a mixture of copper sulfide and oxide minerals against data from operational leach tests. A two dimensional version of the model provides a means to investigate the effects of irrigation rate, lift height, air injection, bacteria limitations, and other factors on recovery and pregnant leach solution concentrations. The model was calibrated for the Nifty Copper operation and ore type in order to simulate heap performance. Model simulations are reported for the chalcocitetype ore and compared to process data. The application showed that the multidimensional nature of heap leaching causes heterogeneous effects that are not always adequately described by one-dimensional models. Irrigation flow rate and aeration effects were simulated for a multi-lift heap section, and model results indicated that air injection at the base of the second lift would be required to achieve expected copper recovery under these lift height and flow conditions.

Jan 1, 2007

By R. Blosser

Phelps Dodge introduced a process improvement model known as Quest for Zero in 2001. In 2004, the focus of Quest for Zero shifted from corporate-led initiatives to projects led by site personnel. The Hydrometallurgical Division at Morenci focused on two (2) significant process improvements: reducing electrolyte bleed and organic losses. In September 2004, Morenci kicked off a bleed reduction project to reduce electrolyte bleed by 45%. By the end 2005, electrolyte bleed was reduced by 55% through understanding and reduction of variance. Significant process changes made during this time period include changes in acid-addition strategy, reduction of uncontrolled bleed, and optimization of bleed placement. In April 2005, the organic reduction project began with the goal of reducing losses by 15%. Operational improvements during this project included improved organic recovery systems, mixer speed optimization, and picket fence installation. By the end 2005, this project reduced organic losses by 35% and current losses are 48% lower than at the start of the project. These projects and smaller Questfor Zero projects have resulted in sustainable annualized savings of $13 million in Morenci hydrometallurgical operations. Through the use of Six Sigma tools, process variances can be controlled and reduced.

Jan 1, 2007

By A. Warczok

The computer simulator of slag cleaning in an electric furnace is based on a set of mathematical models describing heat liberation, the rate of slag reduction and gravitational coalescence of matte and metallic copper inclusions. The simulator consists of a mass and heat balances as a frame, in which the kinetic equations of the slag reduction and phase separation are incorporated. Friendly user-screen interface allows for dynamic control of process parameters in real time together with simulation of typical operations, such as furnace charging with liquid slag, solid reverts and coke, tapping out of the slag and matte, motion of electrodes and control of the transformer. The batch, semi-continuous or continuous process can be simulated. The process parameters are displayed and continuously recorded for further analysis. The computer simulator is a powerful tool for process optimization, training of furnace operators and the design of new slag cleaning installations.

Jan 1, 2007

By L. Voisin, K. Itagaki

In the reductive smelting of the copper concentrate like a blast furnace operation using coke as fuel and reductant or in processing the copper concentrate which contains coal in the bulk, a sulfur-deficient matte phase often coexists with an iron base alloy in the bottom of the smelting furnace. This alloy is generally called furnace residue or speiss when considerable amount of arsenic or antimony is contained in the alloy and in the extreme case of reducing condition the alloy is saturated with carbon. As a fundamental study to know the behavior of some precious metals such as silver, gold and platinum between the sulfur-deficient matte and the furnace residue or the speiss which are in equilibrium under reducing condition, the phase relations and distribution of precious elements in the Cu-Fe-S-As and Cu-Fe-S-Sb systems saturated with carbon were determined at 1473 K by a quenching method.

Jan 1, 2007

By P. Reyes

The start up and operational optimization of the No. 3 Oxygen Plant at the Caletones Copper Smelter of the Codelco - Chile El Teniente Division is summarized. In addition, the economic impact of such optimization on the production cost of oxygen and others aspects associated to the operational robustness as well is detailed.

Jan 1, 2007

By E. A. Morris

It has been shown that Alberta oil-sands fluid coke can be effectively used to reduce SO2 to elemental sulphur while simultaneously producing sulphur-impregnated activated carbon (SlAC). In the capture of mercury from industrial flue gases, SIAC has proven to be a highly effective adsorbent material. The current research aims at developing an existing SlAC technology to meet the needs of copper smelters for mitigating both mercury and SO2 emissions, while making elemental sulphur as a co-product. The challenge behind this undertaking is that these flue gases generally contain percent levels of 02 and H20 vapour (2-12%). The focus of this study is therefore on the feasibility of reducing SO2 using fluid coke under copper smelter flue gas conditions, as well as the optimisation of SIAC properties for capturing vapour phase mercury. It is hypothesised that mercury capacity is strongly affected by the 02 potential of the activation gas due to changes in surface sulphur types arising from different reduced sulphur species. To verify this, gas chromatography is used to analyse the reaction products while XPS and XANES will be used to describe the nature of sulphur on the SlAC surface. CVAFS analysis of mercury capacity will finalise the hypothesis assessment. Preliminary results indicate that 02 at 5% does not play a significant role in SSA or pore development. As expected, increased residence time contributes to SO2 reduction and elemental S yield.

Jan 1, 2007

By E. Nurminen

Thermal transport properties of copper flash smelting flue dust have been investigated. Such values of the dust are needed to correctly model the process and to optimize its heat recovery performance. Dust accretions on heat recovery boiler walls may have a significant influence on the boilers heat transfer efficiency. Measurements of the thermal transport properties have been made for industrial flue dust and for pure sulphate components. The measurements have been conducted at temperatures up to 400 °C and the effect of porosity on these properties has also been investigated. The results indicate that the flue dust and the sulphate components are effective thermal insulators and the dust build-up on the boiler walls is likely to greatly decrease the heat transfer efficiency of the boiler.

Jan 1, 2007

By P. H. Reynolds, S. Liaghat, A. Zarasvandi

"Darreh-Zerreshk and Ali-Abad are two relatively small porphyry copper-type deposits in Yazd Province in central Iran. They are located within the central Iranian volcano-plutonic belt, formed above the collisional convergent margin of the Iranian lithospheric plate from the late Eocene to the Miocene. This paper discusses the geochemical characteristics of the igneous rocks, and 40Ar/39Ar geochronology of plutons and alteration phases associated with the Darreh-Zerreshk and Ali-Abad deposits. The deposits are spatially associated with igneous complexes that consist of older and barren granites intruded by intermediate-composition granitoids, which are the carriers of Cu mineralization. The granites have relatively high content of Nb, Y, and K, a prominent negative Eu anomaly, and were probably derived from melting of, or contamination of mantle-derived magmas by, continental crust. Porphyritic diorites, quartz monzodiorites, and granodiorites show enrichment in light rare earth and large-ion lithophile elements, depletion in middle rare earth elements, and have no negative Eu anomaly. These intermediate-composition granitoids were derived from melting of the upper mantle or lower crust, and their differentiation was controlled partly by fractionation of hornblende. A pilot K/Ar whole-rock dating study suggests that the pre-ore granites were emplaced in the Oligocene. Dating by the 40Ar/39Ar method of nine samples of secondary biotite and sericitized rocks from drillcore within the mineralized and altered zones in both deposits yielded a well-defined age of ca. 16 Ma. This date is interpreted to be the time of hydrothermal alteration and of porphyry copper type mineralization in this part of Iran."

Jan 1, 2007

By M. Hajian Heidary

In this investigation, effect of pressure depth on the globulizations of AZ91 magnesium alloy was studied. Cylindrical samples of AZ91 alloy with 1 cm and 2cm in height and 2.5cm in diameter (H/D = 0.4 and 0.8) were prepared, then the samples were hot pressed at 10 and 30% strain at a constant temperature of 200°C; subsequently reheated at 555°C in different times. Results obtained from optical microscopy (OM) showed that the thickness of the samples and consequently, depth of strain affected regions have remarkable effect on the degree of globulization. In addition, it was found that at a constant strain and holding time, structure of thinner samples is more globular than thicker ones.

Jan 1, 2007

By J. Satur

In copper mineral processing, pyrite coexisting with copper sulfide minerals like chalcopyrite is separated by flotation as tailings and its oxidation in tailing dams causes the formation of acid mine drainage. This paper proposes carriermicroencapsulation (CME) as a new method for suppressing pyrite flotability, as well as its oxidation. In this method, an organic carrier combined with Ti is used to form a thin Ti02 layer on pyrite, which gives a hydrophilic property and acts as a protective coating against oxidation. To form the coating, a ground pyrite sample was treated with Ti-catechol complex solution under various conditions. Bubble pick-up experiments and flotation experiments showed that the treatment of pyrite with Ticatechol complex changed the hydrophobic nature of pyrite into hydrophilic even in the presence of xanthate as a flotation collector. Oxidation testing of the CME-treated pyrite by 0.02 kmol m-3 HN03 showed that Fe release was suppressed by the CME treatment with respect to the control. This is assumed to be due to the formation of Ti02 coating on the pyrite surface. The effect of CME treatment on chalcopyrite wettability is also discussed.

Jan 1, 2007

By J. Font

New approaches for the fire refining process of blister copper have been carried out at the Codelco Norte Smelter. These have been mainly focused on modification and improvement of the process configuration based in fluid-dynamic and metallurgical studies of the oxidation and impurity treatment stages. This paper presents the results of the laboratory simulations and industrial tests performed in the 250 t anode furnace, evaluating two different process configurations: ? Bottom Bath Agitation System in the vessel during the oxidation stage, ? Dual Flux Injection System during the impurity treatment stage. The results show the possibilities of effective removal of high content of sulfur from the melt during the oxidation stage by using the bottom bath agitation. The use of the dual injection system demonstrated the significant improvement in the removal efficiency of impurities. Cu2007

Jan 1, 2007

By Gus Van Weert, Peter Kondos

"Ore sorting has been quite successful in providing a separation means in the rock size range of 1 to 6 inches; a range where mineral dressers do not have many options. The industrial minerals and recycling worlds have embraced this technology. However, ore sorting has not found wide application in the base or precious metals mining industry. One reason for this is thought to be the reliance of most sensors on rock surface characteristics, not very useful in case of sulphides, non-existing in case of gold. Microwave heating, however, is specific for sulphides and graphite (or carbonaceous matter) embedded in the rocks; washing or even drying does not appear necessary. Separation can be done afterwards by already existing ore sorting technology using infrared sensors. Test results on six Nevada gold ore samples are presented in detail. Some simple test procedures are also presented for those wishing to explore the microwave potential of sulphide sorting in their own operations.INTRODUCTIONMineral processing in the base metals industry most often involves upgrading of the ore, concentrating the valuable mineral fraction by classic methods, such as flotation. Since the liberation of minerals in the ore occurs mostly at or below the 100 micron level, the industry has been living with fault lines, so to speak, between blast hole spacing (10,000 mm), run-of-mine ore size (100 mm) and beneficiation size (0.1 – 0.01 mm). The acceptance of ore sorting will inevitably lead to the revisiting of the following questions: “Exactly how much below ore grade rock ends up in the mill because the geologists or the miners cannot define the resource boundaries more precisely? How can the economics of dilution be improved? How many ore grade rocks are lost with the overburden?”"

Jan 1, 2007